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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,333 records · Page 74

Low-Loss Microstrip Transmission Line Fabricated with Improved Liftoff Process

The µ-Spec integrated spectrometer operating at ~500 GHz, employs thin film superconducting Nb microstrip transmission lines deposited directly on a thin (450 nm) single-crystal silicon dielectric. This single-crystal silicon layer is chosen as the dielectric layer due to its low intrinsic loss, with the goal of achieving both high- efficiency and precise phase control in a compact spectrometer architecture. To avoid roughening or etching through the thin single-crystal silicon dielectric a liftoff technique was developed for patterning these microstrip transmission lines and ground plane structures. This two- layer liftoff process was designed for use with sputter deposition and resulted in a US patent. Although this original technique provided precise control of linewidth, results of initial prototype spectrometer devices and separate diagnostic co-planer waveguide resonator devices showed that unexpected loss was being introduced due to the lift-off process. This extra loss was believed to be due to the “tails” (thin tapered regions) at the edge of the metal traces resulting from the sputtering process, as well as an amorphous oxide layer at the Nb-Si interface. We have since demonstrated an improved lift-off technique, which provides a clean metal-Si interface and removes the loss-inducing tails by a two-step selective etching method. This results in a decrease in microwave loss by more than an order of magnitude when measured in co-planar waveguide microwave resonator structures. We present these microwave test results and also SEM and TEM images of the microstrip interfaces and edge profiles before and after application of the improved process.

Hess, Larry A.↗

Mapping the Predicted Solar Wind Hydrogen Flux in Lunar South Pole Craters

The solar wind hydrogen flux is mapped onto the topography of four lunar south pole craters; Shackleton, Haworth, Shoemaker and Faustini. Using altimetry data from the Lunar Reconnaissance Orbiter, we apply an analytic plasma model to map the hydrogen flux onto the surface, time-averaged over a lunar rotation cycle. We present a series of maps including the average flux, geomagnetic modulation, and ion flow energy. These results are intended to inform further studies of dynamic lunar surface processes, such as volatile implantation, sputtering,and weathering. As an example, we also present a map of a surface ice sheet lifetime based on ion sputtering.

William M Farrell↗

Optical Scattering and Microstructure of Ion Beam Deposited Metal Coatings

Thin films of gold and platinum have been deposited onto super-polished fused silica substrates using thermal evaporation, ion assisted deposition (IAD), sputtering and ion assisted sputtering. The influence of ion beam flux, coating material and deposition rate on the films microroughness have been investigated. Coatings of gold and platinum have been bombarded with low energy (10-20 eV) Ar ions from an electron cyclotron resonance (ECR) ion source during deposition. Short range surface microroughness of coated surfaces has been examined using scanning tunneling microscopy (STM) and atomic force microscopy (AFM), while long range surface microroughness has been characterized using an angle resolved optical scatterometer. Results indicate that bombardment with low energy ions causes significant reduction in microroughness of metal coatings.

metal↗

ScAIN etch mask for highly selective etching

A fabrication process employing the use of ScAlN as an etch mask is disclosed. The ScAlN etch mask is chemically nonvolatile in fluorine-based etch chemistries and has a low sputter yield, resulting in greater etch mask selectivity and reduced surface roughness for silicon and other semiconductor materials. The ScAlN etch mask has an etch mask selectivity of greater than 200,000:1 relative to silicon compared to an etch mask selectivity of less than 40,000:1 for a prior art AlN etch mask relative to silicon. Further, due to reduced sputtering of the ScAlN etch mask, and thus reduced micromasking, the ScAlN etch mask yielded a surface roughness of 0.6 μm compared to a surface roughness of 2.8 μm for an AlN etch mask.

36 MATERIALS SCIENCE↗

Deposition of Ti{sub 2}AlC Thin Film

Future nuclear fission and fusion reactor designs require materials that can withstand long-term operation in extreme environments of high temperature, corrosion intermedia, plasma and fast neutron fluences. MAX phase materials have composition of the form M{sub n+1}AX{sub n} (n = 1-6) where M is an early transition metal, A is often an A-group element, mostly IIIA or IVA, and X is either carbon or nitrogen. They belong to a class of hexagonal structure ternary-layered materials. The main characteristic of the MAX phases is their structure which composes the stacking of n 'ceramic' M-X planes interposed with a 'metallic' A layer. Because of the 'mixed' structure, the MAX phases exhibit a combination of excellent properties of both ceramics and metals: high decomposition temperature, elastic stiffness, high oxidation resistance from ceramics as well as high thermal shock resistance, high thermal and electrical conductivities, and good machinability from metals. MAX phases also show great potential in tolerating radiation damage with both high irradiation tolerance and good self-healing abilities because of its unique structure. MAX phase thin films and coatings have been investigated in recent years. In particular, Ti{sub 2}AlC films have attracted attention because they possess great elastic properties, high temperature oxidation tolerance and excellent corrosion behavior. Therefore, Ti{sub 2}AlC films have been fabricated by several researchers. However, in the deposition of Ti{sub 2}AlC coatings, problems have arisen related to phase purity during sputtering from three elements (Ti, Al, C) targets onto substrates at a high temperature. Recent reports on reactive sputtering deposition of MAX phase carbides and nitrides show that the pure phase films (Ti{sub 2}AlC and Ti{sub 2}AlN) could be deposited at relatively low temperatures.

36 MATERIALS SCIENCE↗

On the Life Expectance of High-power CW Magnetrons for SRF Accelerators

Modern CW or pulse Superconducting RF (SRF) accelerators require efficient RF sources controllable in phase and power with a reduced cost. Therefore, utilization of the high-power CW magnetrons as RF sources in SRF accelerator projects was proposed in a number of works, e.g., [1, 2]. But typically, the CW magnetrons are designed as RF sources for industrial heating, and the lifetime of the tubes is not the first priority as it is required for high-energy accelerators. The high-power industrial CW magnetrons use the cathodes made of pure tungsten. The emission properties of the tungsten cathodes are not deteriorated much by electron and ion bombardments, but the latter causes sputtering of the cathode in the magnetron crossed fields. The sputtered cathode material covers the magnetron interior. This leads to sparks and discharges that limit the life of the magnetrons. We considered an analysis of magnetron failure modes vs. output power [3]. We developed a model of ionization of the residual gas in the magnetrons interaction space and simulated the spattering of the cathode in 100 kW CW magnetrons to estimate the life expectancy. Basing on results we proposed ways to increase the CW magnetrons longevity for SRF accelerators.

43 PARTICLE ACCELERATORS↗

TOF-SIMS analysis of decoherence sources in superconducting qubits

Superconducting qubits have emerged as a potentially foundational platform technology for addressing complex computational problems deemed intractable with classical computing. Despite recent advances enabling multiqubit designs that exhibit coherence lifetimes on the order of hundreds of μs, material quality and interfacial structures continue to curb device performance. Two-level system defects in the thin superconducting film and adjacent dielectric regions introduce stochastic noise and dissipate electromagnetic energy at the cryogenic operating temperatures. In this study, we utilize time-of-flight secondary ion mass spectrometry to understand the role specific fabrication procedures play in introducing such dissipation mechanisms in these complex systems. We interrogated Nb thin films and transmon qubit structures fabricated through slight modifications in the processing and vacuum conditions. We find that when the Nb film is sputtered onto the Si substrate, oxide and silicide regions are generated at various interfaces. We also observe that impurity species, such as niobium hydrides and carbides, are incorporated within the niobium layer during the subsequent lithographic patterning steps. The formation of these resistive compounds likely impacts the superconducting properties of the Nb thin film. Additionally, we observe the presence of halogen species distributed throughout the patterned thin films. We conclude by hypothesizing the source of such impurities in these structures in an effort to intelligently fabricate superconducting qubits and extend coherence times moving forward.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Ferroelectricity of wurtzite Al 1−x Hf x N heterovalent alloys

Thin films of aluminum hafnium nitride (Al1−xHfxN) were synthesized via reactive magnetron sputtering for Hf contents up to x = 0.13. X-ray diffraction showed a single c-axis oriented wurtzite phase for all films. Hard x-ray photoelectron spectroscopy demonstrated homogeneous Al:Hf distribution through the thin films and confirmed their insulating character. A collection of complementary tests showed unambiguous polarization inversion, and thus ferroelectricity in multiple samples. Current density vs electric field hysteresis measurements showed distinct ferroelectric switching current peaks, the piezoelectric coefficient d 33,f,meas measured using a double beam laser interferometer (DBLI) showed a reversal in sign with similar magnitude, and anisotropic wet etching confirmed field-induced polarization inversion. This demonstrates the possibility of using tetravalent–and not just trivalent–alloying elements to enable ferroelectricity in AlN-based thin films, highlighting the compositional flexibility of ferroelectricity in wurtzites and greatly expanding the chemistries that can be considered for future devices.

36 MATERIALS SCIENCE↗

Nb 3 Sn coating of SRF cavity by cosputtering from a composite target

Here, we deposited an Nb 3 Sn film on the inner surface of a 2.6 GHz Nb superconducting radio frequency cavity by cosputtering using a composite of Nb and Sn tube targets in a DC cylindrical magnetron sputtering system, followed by the thermal annealing of the coated cavity. An aluminum mockup cavity, replicating a 2.6 GHz Nb SRF cavity geometry, was utilized to optimize deposition parameters, resulting in cosputtered Nb–Sn films with an Sn content of 32–42 at. % on the beam tubes and equator positions. Several annealing conditions were investigated to improve the surface homogeneity of the Nb 3 Sn film. The best cosputtered Nb–Sn film was achieved after annealing at 600 °C for 6 h, followed by annealing at 950 °C for 1 h. The best process was applied to a Nb cavity, which was RF tested in a cryogenic dewar. RF testing of the Nb 3 Sn-coated cavity demonstrated a superconducting transition temperature of 17.78 K. The Nb 3 Sn cavity underwent light Sn recoating, followed by additional RF testing, resulting in the enhancement of the RF performance, primarily due to the improved surface homogeneity of the Nb 3 Sn coating.

Nb3Sn film↗

Structure and Cathodoluminescent Properties of Y{sub 2}O{sub 3}:Eu Thin Films at Different Activator Concentrations

The surface structure and cathodoluminescence (CL) spectra of thin films of Y{sub 2}O{sub 3}:Eu obtained by HF ion plasma sputtering were investigated by varying the activator concentration in the range of 1.0–7.5 mole%. The possibility of creating irregular solutions of yttrium and europium oxides and the structural features of the small and large crystallites that form the Y{sub 2}O{sub 3}:Eu film were demonstrated on the basis of the shape of the CL spectra at different activator concentrations. The critical distance for interaction between the Eu{sup 3+} ions at nodes with C{sub 2} and C{sub 3i} point symmetry was estimated, and a mechanism of energy migration between these centers was proposed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Taking into Account Interelement Interference in X-Ray Fluorescence Analysis of Thin Two-Layer Ti/V Systems

We propose a new method for determining the thickness of layers in x-ray fluorescence analysis of two-layer Ti/V systems, using easily fabricated standardized film layers obtained by sputter deposition of titanium on a polymer film substrate. We have calculated correction factors taking into account the level of attenuation for the intensity of the primary emission from the x-ray tube and the analytical line for the element of the bottom layer in the top layer, and the enhancement of the fluorescence intensity for the top layer by the emission of atoms in the bottom layer.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Role of Perpendicular Anisotropy in the Zigzag Domain Wall Structure in Thin Magnetic Films

We investigate apparently zigzag domain walls in ultrathin magnetic films and calculate the total energy in zero applied field considering anisotropies in the second-order approximation. We discuss the change in zigzag wall morphology and scale as a function of the dipolar length and the total energy depend on film parameters exclusively anisotropy constants, crystallographic orientation and film thickness for a given dipolar length. We explain also the role of the second-order anisotropy in the total energy and the dynamics response of the in-plane magnetization for a given dipolar length. We use some constants in connection with experimental data reported for amorphous TbCo films grown in external in-plane magnetic field by high-frequency ion sputtering and for MnAs on GaAs films.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Study of Electrical Transport and Magnetic Properties of Nd{sub 0.7}Sr{sub 0.3}MnO{sub 3}/Nd{sub 0.8}Na{sub 0.2}MnO{sub 3} Bilayer Thin Films

Bilayer films of Nd{sub 0.7}Sr{sub 0.3}MnO{sub 3}/Nd{sub 0.8}Na{sub 0.2} MnO{sub 3} were grown on 001-orientated LaAlO{sub 3} substrate by using RF magnetron sputtering. The thickness of the Nd{sub 0.8}Na{sub 0.2}MnO{sub 3} (NNMO) film was kept fixed at 120 nm while that of the Nd{sub 0.7}Sr{sub 0.3}MnO{sub 3} (NSMO) film was varied from 12 to 100 nm. X-ray diffraction patterns confirm the growth of films along the (001) direction, and the out-of-plane lattice constant of the NSMO film decreases with an increase in film thickness. The bilayer films are found to undergo out-of-plane tensile strain, and the lattice strain is found to decrease with an increase in film thickness. The ferromagnetic transition temperature is found to increase with an increase in the NSMO film thickness. M–H loops recorded at 50 K show a systematic increase in saturation magnetisation with an increase in film thickness. Metal–insulator transition has been observed for the film thickness of 30 nm and above, and the transition temperature is found to increase with an increase in film thickness. The electrical resistivity data in the metallic region were explained based on electron–electron and electron–magnon scattering mechanism by including a weak localisation effect at low temperature. The electrical resistivity data in the insulating region follow the Mott-variable range hopping model.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Transverse Tunable Magneto-Plasmonic Kerr Effect in Large Area Micro-Patterned Au/Co/Au Structures

By sputtering the sequence of Au/Co/Au layers on ordered microspheres, two-dimensional plasmonic arrays with sufficient angular tunability and enhanced transverse magneto-plasmonic Kerr effect are fabricated. For confirmation of enhanced optical properties, we simulated the fabricated sample using the finite difference time domain method. In order to investigate the effect of rotation speed on the anisotropy of the samples and their magneto-plasmonic responses, these patterned structures are fabricated under dissimilar holder rotation speeds for inner cobalt layer deposition (i.e., Au (10 rpm)/Co (30 rpm)/Au (10 rpm) and Au (10 rpm)/Co (10 rpm)/Au (10 rpm) structures). Our results show that the transverse magneto-plasmonic Kerr effect measurements can provide unique and useful information about the structure and quality of the fabricated samples. In addition, the ability of the samples as a tunable magnetic field sensor has been investigated.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Influence of Thickness on Structural and Magnetic Properties of Co-rich Bi{sub 10}Co{sub 16}O{sub 38} Sillenite Thin Films

The effect of thickness on structural and magnetic properties of Co-rich Bi{sub 10}Co{sub 16}O{sub 38} (BCO) sillenite thin films is investigated systematically. BCO thin films are deposited using a simultaneous evaporation of Bi{sub 2}O{sub 3}, Co targets with RF-DC magnetron sputtering along with post-annealing procedure. The magnetic studies reveal an ordered magnetic nature below film thicknesses of 100 nm. Further, the temperature-dependent and field-dependent magnetic data is evaluated to comprehend the microstructure impact on to the magnetic nature of Co-rich sillenite thin films.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Investigation on the Current Transport Characteristics of SrTiO{sub 3}/YBa{sub 2}Cu{sub 3}O{sub 7−x} Heterostructure

By the combined use of the sol-gel and pulsed laser deposition methods, the SrTiO{sub 3}/YBa{sub 2}Cu{sub 3}O{sub 7−x} (STO/YBCO) heterostructure was prepared on a LaAlO{sub 3} substrate. XRD results and φ scanning test showed that the prepared STO/YBCO heterostructure had good biaxial texture. Moreover, a Pt electrode was sputtered on the STO/YBCO heterostructure to investigate the current density-voltage (J − V) characteristic curves of STO/YBCO in the 50–300 K temperature range. The results showed that the STO/YBCO heterostructure had good rectifying characteristics. With an applied positive bias voltage smaller than 3.7 V, the current density of the STO/YBCO heterostructure decreased with the decrease of temperature; for higher voltages, on the contrary, the current density increased with the decrease of temperature. When the YBCO experienced superconducting transition, the turn-on voltage (V{sub t}) changed suddenly due to the sudden opening of the superconducting energy gap of YBCO. The V{sub t} variation obtained from the experiment was essentially consistent with the known value of the YBCO superconducting energy gap.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Preferred Orientation Enhancement in FeCo/SiO{sub 2} Nanocomposite Films Induced by Cu Underlayer

We prepared FeCo/SiO{sub 2} thin films through depositng initial materials on various thickness Cu seed layers by sol-gel spin-coating and magnetron-sputtering methods. As-prepared composite films were reduced in hydrogen to induce texture growth. Structure, magnetic property, and surface topography of the films were characterized by X-ray diffraction (XRD), vibrating sample magnetometer (VSM), and atomic force microscopy (AFM). These experimental data indicate that the ratio values of I{sub (200)}/I{sub (110)} of the thin films are all larger than 1 for all the samples, indicating that FCC-copper is in favor of promoting (200) FeCo texture, but more thickness will reduce this advantage. Cu underlayers can also promote the out-of-plane magnetic anisotropy of the films.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Effect of RF Power on Structural, Magnetic, and Optical Properties of CoFe{sub 2}O{sub 4} Thin Films

The thin films of CoFe{sub 2}O{sub 4} were deposited on glass substrates by radio-frequency (RF) sputtering. The effect of RF power variation from 60–120 W on the structure, magnetic, and optical properties of the as-deposited films and films annealed at 500 °C was studied. The magnetic parameters of the film, i.e., in-plane coercivity (H{sub c}), saturation magnetization (M{sub s}), and remanence (M{sub r}) increase as RF power is increased from 60 to 80 W followed by a decreasing trend with further increase in RF power to 120 W. Annealing of the film significantly improves the magnetic properties. The largest grain size and the best crystallinity of the film are obtained for the film deposited at 80 W of RF power. The thin films exhibited 70–80% optical transmittance. Optical band gap (E{sub g}) depends on the RF power and grain size, and it varies between 2.08 and 2.16 eV for the as-deposited films and between 2.16 and 2.30 eV for the annealed films. The study shows that RF power used for depositing the film has strong effect on the microstructure and properties of the film.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗