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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,333 records · Page 74
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Error Estimates for the Optimal Control of a Parabolic Fractional PDE

In this work, we consider the integral definition of the fractional Laplacian and analyze a linear-quadratic optimal control problem for the so-called fractional heat equation; control constraints are also considered. We derive existence and uniqueness results, first order optimality conditions, and regularity estimates for the optimal variables. To discretize the state equation we propose a fully discrete scheme that relies on an implicit finite difference discretization in time combined with a piecewise linear finite element discretization in space. We derive stability results and a novel $L^2(0,T;L^2(\Omega))$ a priori error estimate. On the basis of the aforementioned solution technique, we propose a fully discrete scheme for our optimal control problem that discretizes the control variable with piecewise constant functions, and we derive a priori error estimates for it. We illustrate the theory with one- and two-dimensional numerical experiments.

97 MATHEMATICS AND COMPUTING↗
NASA NTRS1997

Integrator Windup Protection-Techniques and a STOVL Aircraft Engine Controller Application

Integrators are included in the feedback loop of a control system to eliminate the steady state errors in the commanded variables. The integrator windup problem arises if the control actuators encounter operational limits before the steady state errors are driven to zero by the integrator. The typical effects of windup are large system oscillations, high steady state error, and a delayed system response following the windup. In this study, methods to prevent the integrator windup are examined to provide Integrator Windup Protection (IW) for an engine controller of a Short Take-Off and Vertical Landing (STOVL) aircraft. An unified performance index is defined to optimize the performance of the Conventional Anti-Windup (CAW) and the Modified Anti-Windup (MAW) methods. A modified Genetic Algorithm search procedure with stochastic parameter encoding is implemented to obtain the optimal parameters of the CAW scheme. The advantages and drawbacks of the CAW and MAW techniques are discussed and recommendations are made for the choice of the IWP scheme, given some characteristics of the system.

KrishnaKumar, K.↗
DOE OSTI2020

Quantification of the Radiative Effect of Aerosol–Cloud Interactions in Shallow Continental Cumulus Clouds

The indirect radiative effect of aerosol variability on shallow cumulus clouds is realized in nature with considerable concurrent meteorological variability. Large-eddy simulations constrained by observations at a continental site in Oklahoma are performed to represent the variability of different meteorological states on days with different aerosol conditions. The total radiative effect of this natural covariation between aerosol and other meteorological drivers of total cloud amount and albedo is quantified. The changes to these bulk quantities are used to understand the response of the cloud radiative effect to aerosol–cloud interactions (ACI) in the context of concurrent processes, as opposed to attempting to untangle the effect of individual processes on a case-by-case basis. Mutual information (MI) analysis suggests that meteorological variability masks the strength of the relationship between cloud drop number concentration and the cloud radiative effect. This is shown to be mostly due to variation in solar zenith angle and cloud field horizontal heterogeneity masking the relationship between cloud drop number and cloud albedo. By combining MI and more traditional differential analyses, a framework to identify important modes of covariation between aerosol, clouds, and meteorological conditions is developed. This shows that accounting for solar zenith angle variation and implementing an albedo bias correction increases the detectability of the radiative effects of ACI in simulations of shallow cumulus.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2017

Extreme Storms

Key Findings: 1. Human activities have contributed substantially to observed ocean-atmosphere variability in the Atlantic Ocean (medium confidence), and these changes have contributed to the observed upward trend in North Atlantic hurricane activity since the 1970s (medium confidence). 2. Both theory and numerical modeling simulations generally indicate an increase in tropical cyclone (TC) intensity in a warmer world, and the models generally show an increase in the number of very intense TCs. For Atlantic and eastern North Pacific hurricanes and western North Pacific typhoons, increases are projected in precipitation rates (high confidence) and intensity (medium confidence). The frequency of the most intense of these storms is projected to increase in the Atlantic and western North Pacific (low confidence) and in the eastern North Pacific (medium confidence). 3. Tornado activity in the United States has become more variable, particularly over the 2000s, with a decrease in the number of days per year with tornadoes and an increase in the number of tornadoes on these days (medium confidence). Confidence in past trends for hail and severe thunderstorm winds, however, is low. Climate models consistently project environmental changes that would putatively support an increase in the frequency and intensity of severe thunderstorms (a category that combines tornadoes, hail, and winds), especially over regions that are currently prone to these hazards, but confidence in the details of this projected increase is low. 4. There has been a trend toward earlier snowmelt and a decrease in snowstorm frequency on the southern margins of climatologically snowy areas (medium confidence). Winter storm tracks have shifted northward since 1950 over the Northern Hemisphere (medium confidence). Projections of winter storm frequency and intensity over the United States vary from increasing to decreasing depending on region, but model agreement is poor and confidence is low. Potential linkages between the frequency and intensity of severe winter storms in the United States and accelerated warming in the Arctic have been postulated, but they are complex, and, to some extent, contested, and confidence in the connection is currently low. 5. The frequency and severity of landfalling "atmospheric rivers" on the U.S. West Coast (narrow streams of moisture that account for 30 percent to 40 percent of the typical snowpack and annual precipitation in the region and are associated with severe flooding events) will increase as a result of increasing evaporation and resulting higher atmospheric water vapor that occurs with increasing temperature. (Medium confidence)

Kossin, J. P.↗
DOE OSTI2025

Impact of Different Thermal Gradients on the Dynamics of Cylindrical Lithium-ion Cells Subject to Accelerated Aging and on Module Performance

This study investigates the impacts of applying different thermal gradient patterns to cylindrical lithium-ion cells in a module on cell dynamics (temperatures, current flows, state of charge), module performance (evolution of resistance, capacity, and energy versus cycle number), and module lifetime. The thermal gradients were generated using cooling plates (CPs) with three different flow-field designs, namely, straight, perpendicular, and U-turn. The study uses computational fluid dynamics (CFD), the pseudo-two-dimensional (P2D) battery model, capacity loss and increased impedance due to the growth of a solid-electrolyte-interphase, and the electric current distribution from module terminals to cells that depends on the series-parallel electrical connections among the cells. The impact of the thermal gradient (resulting from the CP designs) on the variability in resistance, current, state of charge, and voltage among the cells was analyzed and linked to differences in the module's performance. Applying a thermal gradient to parallel-connected strings of series-connected cells led to variation in the current through each parallel string and an imbalance in the voltage of series-connected cells. Module performance is poorer when the thermal gradient causes a voltage imbalance than when it causes a current imbalance. Module performance becomes the worst when both current variation and voltage imbalance happen together. For instance, the module's lifetime (estimated as reaching 80% of its initial capacity) varied by 5% to 17.5%, depending on the magnitude and pattern of the imposed thermal gradient. As the relative orientation between thermal gradients and cells' electrical connectivity influences the module's performance, appropriate consideration should be given to the choice of the CP, especially if large thermal gradients are allowed.

Battery thermal management↗
NASA NTRS1980

Hyperstability in variable structure systems

A variable structure control law is a discontinuous feedback law whose coefficients switch on hypersurfaces defined in the state space. Feedback systems with variable structure control laws are often referred to as variable structure systems (VSS). The main feature of VSS is the sliding motion which can occur at the intersection of the switching surfaces. Demonstrating existence and reaching in the case of vector control in n-dimensional space is in general a problem in stability of nonlinear systems. The present investigation is concerned with the projection of motion on an m-dimensional subspace, taking into account aspects of the hyperstability concept in VSS design. The considered concepts are illustrated with the aid of an example.

Calise, A. J.↗
NASA NTRS1989

A weak Hamiltonian finite element method for optimal guidance of an advanced launch vehicle

A temporal finite-element method based on a mixed form of the Hamiltonian weak principle is presented for optimal control problems. The mixed form of this principle contains both states and costates as primary variables, which are expanded in terms of nodal values and simple shape functions. Time derivatives of the states and costates do not appear in the governing variational equation; the only quantities whose time derivatives appear therein are virtual states and virtual costates. Numerical results are presented for an elementary trajectory optimization problem; they show very good agreement with the exact solution along with excellent computational efficiency and self-starting capability. The feasibility of this approach for real-time guidance applications is evaluated. A simplified model for an advanced launch vehicle application that is suitable for finite-element solution is presented.

Hodges, Dewey H.↗
DOE OSTI2026

A coupled hydrologic-agroeconomic modeling framework to evaluate adaptive irrigation strategies under groundwater withdrawal restrictions

Growing groundwater scarcity requires integrated tools to capture interactions among hydrology, agricultural production, markets, and land use. This study presents an iterative modeling framework that couples hydrologic, crop-yield, and economic models to capture two-way feedback among water availability, agricultural production, and market responses under groundwater constraints. The primary goal of this paper is to describe the methodological development of the coupled framework and demonstrate the significance of iterative model interaction. Applied to the western United States, we evaluated adaptive responses to restricting groundwater use beyond recharge levels, represented through changes in irrigation management and expansion or shrinkage of crop markets through land reallocation. Results demonstrate that the iterative coupling converges to stable equilibrium responses within 10 iterations. At equilibrium, deficit irrigation emerges as the dominant adaptation strategy in California, with irrigation levels stabilizing at approximately 70% of full irrigation demand, while Arizona and New Mexico experience stronger yield sensitivities. Early iterations produce commodity price increases of up to 10% for fruit and vegetable crops; however, these responses moderate as land allocation and production patterns adjust across regions. Deficit irrigation and spatial reallocation of irrigated land partially offset production losses, with variability observed across different states: California maintains yields primarily via deficit irrigation, whereas Arizona and New Mexico will rely mainly on reducing irrigated area to absorb the shock. By capturing feedback between biophysical and economic processes, this approach highlights how irrigation strategies and land-use decisions evolve under water stress and provides a transferable platform for evaluating water management policies.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Recent Accelerated Decadal Shift in Winter North American Temperature Patterns Under Pacific‐Atlantic Decadal Variability

Global warming and internal climate variability have changed winter temperature extreme regimes in North America, affecting droughts and wildfires in the western United States. However, how internal climate variability influences North American winter temperature extreme patterns remains poorly understood. Here, we demonstrate that the recent winter North American surface air temperature (SAT) exhibits an accelerated decadal alternation between Warm West-Cold East (WWCE) and Cold West-Warm East (CWWE) dipoles because their variations show shorter decadal periods during 1990–2022 than during 1950–1989 and are regulated by the Pacific Decadal Oscillation (PDO) variability. While the winter WWCE dipole mainly linked to North Pacific blocking events exhibited a smaller mean amplitude during 1990–2022 than 1950–1989 due to the weakened positive PDO phase during 1990–2022 under the positive phase of the Atlantic Multidecadal Oscillation (AMO), the winter CWWE showed a larger mean amplitude during 1990–2022 due to the stronger negative PDO phase than during 1950–1989. Our results further suggest that the recent rapid decadal shift of North American winter temperatures is primarily attributed to the PDO variability likely due to anthropogenic warming under the positive AMO.

Atlantic Multidecadal Oscillation↗
NASA NTRS2005

Monitoring a Complex Physical System using a Hybrid Dynamic Bayes Net

The Reverse Water Gas Shift system (RWGS) is a complex physical system designed to produce oxygen from the carbon dioxide atmosphere on Mars. If sent to Mars, it would operate without human supervision, thus requiring a reliable automated system for monitoring and control. The RWGS presents many challenges typical of real-world systems, including: noisy and biased sensors, nonlinear behavior, effects that are manifested over different time granularities, and unobservability of many important quantities. In this paper we model the RWGS using a hybrid (discrete/continuous) Dynamic Bayesian Network (DBN), where the state at each time slice contains 33 discrete and 184 continuous variables. We show how the system state can be tracked using probabilistic inference over the model. We discuss how to deal with the various challenges presented by the RWGS, providing a suite of techniques that are likely to be useful in a wide range of applications. In particular, we describe a general framework for dealing with nonlinear behavior using numerical integration techniques, extending the successful Unscented Filter. We also show how to use a fixed-point computation to deal with effects that develop at different time scales, specifically rapid changes occuring during slowly changing processes. We test our model using real data collected from the RWGS, demonstrating the feasibility of hybrid DBNs for monitoring complex real-world physical systems.

Lerner, Uri↗
DOE OSTI2015

Stochastic Liouville equations for femtosecond stimulated Raman spectroscopy

Electron and vibrational dynamics of molecules are commonly studied by subjecting them to two interactions with a fast actinic pulse that prepares them in a nonstationary state and after a variable delay period T, probing them with a Raman process induced by a combination of a broadband and a narrowband pulse. This technique, known as femtosecond stimulated Raman spectroscopy (FSRS), can effectively probe time resolved vibrational resonances. We show how FSRS signals can be modeled and interpreted using the stochastic Liouville equations (SLE), originally developed for NMR lineshapes. The SLE provide a convenient simulation protocol that can describe complex dynamics caused by coupling to collective bath coordinates at much lower cost than a full dynamical simulation. The origin of the dispersive features that appear when there is no separation of timescales between vibrational variations and the dephasing time is clarified.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

A time-parallel multiple-shooting method for large-scale quantum optimal control

Quantum optimal control plays a crucial role in quantum computing by providing the interface between compiler and hardware. Solving the optimal control problem is particularly challenging for multi-qubit gates, due to the exponential growth in computational complexity with the system's dimensionality and the deterioration of optimization convergence. To ameliorate the computational complexity of time-integration, this paper introduces a multiple-shooting approach in which the time domain is divided into multiple windows and the intermediate states at window boundaries are treated as additional optimization variables. Further, this enables parallel computation of state evolution across time-windows, significantly accelerating objective function and gradient evaluations. Since the initial state matrix in each window is only guaranteed to be unitary upon convergence of the optimization algorithm, the conventional gate trace infidelity is replaced by a generalized infidelity that is convex for non-unitary state matrices. Continuity of the state across window boundaries is enforced by equality constraints. A quadratic penalty optimization method is used to solve the constrained optimal control problem, and an efficient adjoint technique is employed to calculate the gradients in each iteration. We demonstrate the effectiveness of the proposed method through numerical experiments on quantum Fourier transform gates in systems with 2, 3, and 4 qubits, noting a speedup of 80x for evaluating the gradient in the 4-qubit case, highlighting the method's potential for optimizing control pulses in multi-qubit quantum systems.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2022

Tracking the Sun: Pricing and Design Trends for Distributed Photovoltaic Systems in the United States, 2022 Edition

Berkeley Lab’s annual Tracking the Sun report describes trends among grid-connected, distributed solar photovoltaic (PV) systems in the United States. The latest edition of the report focuses on systems installed through year-end 2021, and is based on data from roughly 2.5 million systems. New to the report this year is an expanded coverage of paired PV-plus-storage systems, including details on system design and pricing trends. The report describes trends related to: -Project characteristics, including system size, module efficiencies, prevalence of paired PV with storage, use of module-level power electronics, third-party ownership, mounting configurations, panel orientation, and non-residential customer segmentation ownership -Median installed-price trends, both nationally and by state, including preliminary data for first half of 2022 -Variability in pricing according to system size, state, installer, equipment type, and other factors, relying on both descriptive and econometric analysis

14 SOLAR ENERGY↗
DOE OSTI2023

Modeling dust mineralogical composition: sensitivity to soil mineralogy atlases and their expected climate impacts

Soil dust aerosols are a key component of the climate system, as they interact with short- and long-wave radiation, alter cloud formation processes, affect atmospheric chemistry and play a role in biogeochemical cycles by providing nutrient inputs such as iron and phosphorus. The influence of dust on these processes depends on its physicochemical properties, which, far from being homogeneous, are shaped by its regionally varying mineral composition. The relative amount of minerals in dust depends on the source region and shows a large geographical variability. However, many state-of-the-art Earth system models (ESMs), upon which climate analyses and projections rely, still consider dust mineralogy to be invariant. The explicit representation of minerals in ESMs is more hindered by our limited knowledge of the global soil composition along with the resulting size-resolved airborne mineralogy than by computational constraints. In this work we introduce an explicit mineralogy representation within the state-of-the-art Multiscale Online Nonhydrostatic AtmospheRe CHemistry (MONARCH) model. We review and compare two existing soil mineralogy datasets, which remain a source of uncertainty for dust mineralogy modeling and provide an evaluation of multiannual simulations against available mineralogy observations. Soil mineralogy datasets are based on measurements performed after wet sieving, which breaks the aggregates found in the parent soil. Our model predicts the emitted particle size distribution (PSD) in terms of its constituent minerals based on brittle fragmentation theory (BFT), which reconstructs the emitted mineral aggregates destroyed by wet sieving. Our simulations broadly reproduce the most abundant mineral fractions independently of the soil composition data used. Feldspars and calcite are highly sensitive to the soil mineralogy map, mainly due to the different assumptions made in each soil dataset to extrapolate a handful of soil measurements to arid and semi-arid regions worldwide. For the least abundant or more difficult-to-determine minerals, such as iron oxides, uncertainties in soil mineralogy yield differences in annual mean aerosol mass fractions of up to ~ 100 %. Although BFT restores coarse aggregates including phyllosilicates that usually break during soil analysis, we still identify an overestimation of coarse quartz mass fractions (above 2 µm in diameter). In a dedicated experiment, we estimate the fraction of dust with undetermined composition as given by a soil map, which makes up ~ 10 % of the emitted dust mass at the global scale and can be regionally larger. Changes in the underlying soil mineralogy impact our estimates of climate-relevant variables, particularly affecting the regional variability of the single-scattering albedo at solar wavelengths or the total iron deposited over oceans. All in all, this assessment represents a baseline for future model experiments including new mineralogical maps constrained by high-quality spaceborne hyperspectral measurements, such as those arising from the NASA Earth Surface Mineral Dust Source Investigation (EMIT) mission.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS2023

Modeling Dust Mineralogical Composition: Sensitivity to Soil Mineralogy Atlases and Their Expected Climate Impacts

Soil dust aerosols are a key component of the climate system, as they interact with short- and long-wave radiation, alter cloud formation processes, affect atmospheric chemistry and play a role in biogeochemical cycles by providing nutrient inputs such as iron and phosphorus. The influence of dust on these processes depends on its physicochemical properties, which, far from being homogeneous, are shaped by its regionally varying mineral composition. The relative amount of minerals in dust depends on the source region and shows a large geographical variability. However, many state-of-the-art Earth system models (ESMs), upon which climate analyses and projections rely, still consider dust mineralogy to be invariant. The explicit representation of minerals in ESMs is more hindered by our limited knowledge of the global soil composition along with the resulting size-resolved airborne mineralogy than by computational constraints. In this work we introduce an explicit mineralogy representation within the state-of-the-art Multiscale Online Nonhydrostatic AtmospheRe CHemistry (MONARCH) model. We review and compare two existing soil mineralogy datasets, which remain a source of uncertainty for dust mineralogy modeling and provide an evaluation of multiannual simulations against available mineralogy observations. Soil mineralogy datasets are based on measurements performed after wet sieving, which breaks the aggregates found in the parent soil. Our model predicts the emitted particle size distribution (PSD) in terms of its constituent minerals based on brittle fragmentation theory (BFT), which reconstructs the emitted mineral aggregates destroyed by wet sieving. Our simulations broadly reproduce the most abundant mineral fractions independently of the soil composition data used. Feldspars and calcite are highly sensitive to the soil mineralogy map, mainly due to the different assumptions made in each soil dataset to extrapolate a handful of soil measurements to arid and semi-arid regions worldwide. For the least abundant or more difficult-to-determine minerals, such as iron oxides, uncertainties in soil mineralogy yield differences in annual mean aerosol mass fractions of up to ∼ 100 %. Although BFT restores coarse aggregates including phyllosilicates that usually break during soil analysis, we still identify an overestimation of coarse quartz mass fractions (above 2 µm in diameter). In a dedicated experiment, we estimate the fraction of dust with undetermined composition as given by a soil map, which makes up ∼ 10 % of the emitted dust mass at the global scale and can be regionally larger. Changes in the underlying soil mineralogy impact our estimates of climate-relevant variables, particularly affecting the regional variability of the single-scattering albedo at solar wavelengths or the total iron deposited over oceans. All in all, this assessment represents a baseline for future model experiments including new mineralogical maps constrained by high-quality spaceborne hyperspectral measurements, such as those arising from the NASA Earth Surface Mineral Dust Source Investigation (EMIT) mission.

Soil dust↗
DOE OSTI2015

Cyanate groups in higher oxidation state metal cluster chemistry: Mixed-valence (II/III) Mn 16 and Mn 18 clusters

Here, the employment of cyanato (OCN - ) group in high oxidation state manganese cluster chemistry, in conjunction with carboxylate ions and the organic chelating/bridging ligand 2-(hydroxymethyl)pyridine (hmpH), is reported. The syntheses, crystal structures, and magnetochemical characterization are described for [Mn 16 O 8 (OR) 4 (OCN) 4 (O 2 CMe) 12 (hmp) 6 (ROH) 2 ] (R = Me (1), Et (2)) and [Mn 18 O 14 (O 2 CR) 18 (hmp) 4 (hmpH) 2 (H 2 O) 2 ] (R = Me (3), Et (4)). The 2:1:1:1 reactions of Mn(O 2 CMe) 2 ·4H 2 O, hmpH, NaOCN and NEt 3 in solvent MeOH or EtOH afford the isostructural complexes [Mn 16 O 8 (OR) 4 (OCN) 4 (O 2 CMe) 12 (hmp) 6 (ROH) 2 ] (R = Me (1), Et (2)). The [Mn 16 (μ 4 -O) 4 (μ 3 -O) 4 (μ-OMe) 4 (μ 3 -OR) 6 (μ-OR) 6 ] 10+ core of representative complex 1 comprises a Mn II 4 Mn III 4 double-cubane subunit attached on either side to two symmetry-related Mn II Mn III 3 defective dicubanes. A similar reaction of Mn(O 2 CR) 2 ·4H 2 O, hmpH, NaOCN and NEt 3 , but in solvent MeCN, led instead to the formation of [Mn 18 O 14 (O 2 CR) 18 (hmp) 4 (hmpH) 2 (H 2 O) 2 ] (R = Me (3), Et (4)). Compounds 3 and 4 are very similar to each other and can be described as a central [Mn III 4 (μ-O) 6 ] rodlike subunit attached on either side to two symmetry-related [Mn 7 O 9 ] subunits. Variable-temperature, solid-state dc and ac magnetic susceptibility studies revealed the presence of predominant antiferromagnetic exchange interactions in all compounds, and possible S = 2 or 1 (for 1 and 2) and S = 0 (for 3 and 4) ground state spin values. The combined results demonstrate the ability of cyanato groups to facilitate the formation of new polynuclear Mn II/III complexes with structures different than these obtained from the use of the related azides.

2-(Hydroxymethyl)pyridine↗
NASA NTRS2022

Midwest Water Resources II: Evaluating Evapotranspiration with NASA Earth Observations and In Situ Observations to Understand Water Balance in Midwest Agriculture

Seasonal water variability in the midwestern United States extensively affects the agricultural community, as it impacts irrigation schedules, growing seasons, and overall ecosystem function. Evapotranspiration (ET) is a critical climatic variable in the water cycle and is used to evaluate spatiotemporal trends in drought and flood conditions. The NASA DEVELOP team partnered with the United States Department of Agriculture (USDA) Midwest Climate Hub, the Minnesota Department of Agriculture, the Illinois State Water Survey, and Michigan State University to compare remotely sensed ET products with in situ observations from January 2001 through December 2020. Remotely sensed actual ET (aET) data were sourced from NASA’s Terra Moderate Resolution Imaging Spectroradiometer (MODIS), and reference ET (refET) data were derived from the Gridded Surface Meteorological (gridMET) dataset. For in situ comparison, aET data were downloaded from the AmeriFlux database while refET data were collected from the Illinois Climate Network and Michigan State University’s Enviro-weather database. For a holistic assessment of ET, this project generated comparisons between remotely sensed and in situ observations, calculated descriptive statistics for validation between refET datasets, and spatially produced statistical validation maps regarding in situ sites. The temporal and spatial gaps of AmeriFlux data limited aET analysis. This comparative assessment of ET products across the Midwest can be used by project partners to assess regional water trends and guide future land management decisions.

Addison Pletcher↗