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Surface Photovoltage-Induced Ultralow Work Function Material for Thermionic Energy Converters
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Pore Surface Engineering with Controlled Loadings of Functional Groups via Click Chemistry in Highly Stable Metal–Organic Frameworks
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Restoration of the covariant gauge α in the initial field of gravity in de Sitter spacetime
The gravitational field generated by a mass term and the initial surface through covariant retarded Green's function for linearized gravity in de Sitter spacetime was studied recently [4, 5] with the covariant gauges set to β = 2/3 and α = 5/3. In this paper we extend the work to restore the gauge parameter α in the field coming from the initial data using the method of shifting the parameter. The α terms in the initial field cancels exactly with the one coming from the source term. Consequently, the correct field configuration, with two equal mass points moving in its geodesic, one located at the North pole and another one located at the South pole, is reproduced in the whole manifold of de Sitter spacetime.
Dissociation of trimethylgallium on the ZrB{sub 2}(0001) surface
X-ray photoelectron spectroscopy and reflection absorption infrared spectroscopy (RAIRS) have been used to study the dissociative adsorption of trimethylgallium (TMG) on the ZrB{sub 2}(0001) surface. Spectra were obtained as a function of annealing temperature following TMG exposure at temperatures of 95 and 300 K, and also as a function of TMG exposure for a surface temperature of 300 K. After annealing above 220 K, a significant decrease in the relative concentration of carbon and gallium occurred accompanied by a shift of ∼0.2 eV in the Ga 2p{sub 3/2} binding energy. The RAIR spectra show that after annealing to ∼220 K, only one CH{sub 3} deformation band at 1196 cm{sup −1} remains, the intensity of which is considerably decreased indicating loss of at least one methyl group from TMG. Further annealing leads to the sequential loss of the other methyl groups. The first methyl desorbs while the last two dissociate to deposit two C atoms per TMG molecule onto the ZrB{sub 2} surface.
Vacuum thermionic work functions of polycrystalline Nb, Mo, Ta, W, Re, Os, and Ir.
Vacuum thermionic work function for well-outgassed polycrystalline surfaces, noting techniques for accurate measurement of current, area and temperature values
Pressure correlation for a cylinder in a diffuse sound field.
Surface pressure spatial correlation function for rigid infinitely long cylinder in three- dimensional diffuse sound field
Spectrophotometric studies of the photometric function, composition, and distribution of the surface materials of Mars.
Results of a program of mapping the surface of Mars carried out at a spatial resolution of 300 to 500 km during the 1969 opposition at IR (0.60 to 2.27 microns). Spectral albedo curves were obtained for 150 mare and desert areas. These curves fall into two well-defined and fairly uniform color-albedo groups corresponding to mare and desert units. The lack of areas with color and albedo that are distinctively different from those of these groups is interpreted as an indication that the surface of Mars consists of basically only two types of materials. Laboratory comparison data support a model of the Martian regolith that suggests that the general color of these surface units is due to a limonite stain coating the particles of lithic soils. Features in the spectral albedo curves at 1.6 and 2.1 microns are interpreted as being due to the H2O ice on the surface or in the Martian atmosphere.
Computer program for supersonic Kernel-function flutter analysis of thin lifting surfaces
This report describes a computer program (program D2180) that has been prepared to implement the analysis described in (N71-10866) for calculating the aerodynamic forces on a class of harmonically oscillating planar lifting surfaces in supersonic potential flow. The planforms treated are the delta and modified-delta (arrowhead) planforms with subsonic leading and supersonic trailing edges, and (essentially) pointed tips. The resulting aerodynamic forces are applied in a Galerkin modal flutter analysis. The required input data are the flow and planform parameters including deflection-mode data, modal frequencies, and generalized masses.
Surface temperatures and glassy state investigations in tribology, part 1
The research in this report is divided into two categories: (1) lubricant rheological behavior, and (2) thermal behavior of a simulated elastohydrodynamic contact. The studies of the lubricant rheological behavior consists of high pressure, low shear rate viscosity measurements, viscoelastic transition measurements, by volume dilatometry, dielectric transitions at atmospheric pressure and light scattering transitions. Lubricant shear stress-strain behavior in the amorphous glassy state was measured on several fluids. It appears clear from these investigations that many lubricants undergo viscoplastic transitions in typical EHD contacts and that the lubricant has a limiting maximum shear stress it can support which in turn will determine the traction in the contact except in cases of very low slide-roll ratio. Surface temperature measurements were made for a naphthenic mineral oil and a polyphenyl ether. The maximum surface temperature in these experiments was approximately symmetrical about the zero slide-roll ration except for absolute values of slide-roll ratio greater than about 0.9. Additional surface temperature measurements were made in contacts with rough surfaces where the composite surface roughness was approximately equal to the EHD film thickness. A regression analysis was done to obtain a predictive equation for surface temperatures as a function of pressure, sliding speed, and surface roughness. A correction factor for surface roughness effects to the typical flash temperature analysis was found.
Parametric results for heat transfer across honeycomb sandwich panels
The problem of heat transfer across honeycomb sandwich panels is theoretically investigated. The basic objective is to predict the rear surface temperature as a function of time when the front surface is exposed to a prescribed heat flux; the faces are bounded by planar sheets so that the air circulation in the honeycomb cells is bounded and contained. The influence of the air circulation on convective heat transfer is explicitly included. Drawing upon previous investigators' results that indicated various relations for the Nusselt numbers vs Rayleigh numbers in different regimes of the aspect ratio (defined as the ratio of the cell height to cell width), parametric calculations are performed to predict the rear surface temperatures. Chemical degradation of the material, especially the glue holding the face material on the end, is important but has not yet been included. The results indicate that decreasing the cell width, increasing the cell wall thickness and increasing the cell height all have beneficial effects upon the heat transfer; i.e., all of these variations reduce rear surface temperature for a given time for a prescribed heat flux on the front surface.
The diffusivity of hydrogen in Nb stabilized stainless steel
The evolution of hydrogen from 347 stainless steel has been studied by using a real time dynamic technique under ultrahigh vacuum conditions. Auger electron spectroscopy was used to determine the surface composition as a function of time and temperature. The surface film on the electropolished samples was found to be approximately 15 A thick and consisted of a carbon-oxygen complex and a metal oxide (FexOy). Upon heating to 400 C, the carbon-oxygen complex desorbed as CO and the remaining oxygen and carbon began to incorporate. Also at this temperature sulfur began to diffuse out of the bulk to the surface and at approximately 800 C formed a complete monolayer. At 900 C, carbon and oxygen virtually disappeared, leaving the monolayer of sulfur as the only surface contaminant. The hydrogen diffusivity was found to follow closely the equation D = 7.01 x 10 to the -7th exp(-48.0/RT) sq m per second over the entire temperature range studied, thus indicating that hydrogen evolution is not significantly affected by the changing surface composition. The somewhat higher value of the diffusivity obtained in this work compared to past measurements in austenitic stainless steels may indicate the importance of sample preprocessing and ultrahigh vacuum conditions in minimizing the effects of surface layers.
Light Scattered from Polished Optical Surfaces: Wings of the Point Spread Function
Random figure errors from the polishing process plus particles on the main mirrors in a telescope cause an extended point spread function (PSF) declining approximately as the inverse square of the sine of the angle from a star from about 100 micro-rad to a right angle. The decline in at least one case, and probably in general, proceeds as the inverse cube at smaller angles where the usual focal plane aperture radius is chosen. The photometric error due to misalignment by one Airy ring spacing with an aperture of n rings depends on the net variance in the figure. It is approximately 60/(n+1)(3) when using the data of Kormendy (1973). A typical value is 6 x 10 to the -5th power per ring of misalignment with n = 100 rings. The encircled power may be modulated on a time scale of hours by parts per thousand in a wavelength dependent manner due to relative humidity effects on mirror dust. The scattering according to an inverse power law is due to a random walk in aberration height caused by a multitude of facets and slope errors left by the polishing process. A deviation from such a law at grazing emergence may permit monitoring the dust effects.
Error trends in SASS winds as functions of atmospheric stability and sea surface temperature
Wind speed measurements obtained with the scatterometer instrument aboard the Seasat satellite are compared equivalent neutral wind measurements obtained from ship reports in the western N. Atlantic and eastern N. Pacific where the concentration of ship reports are high and the ranges of atmospheric stability and sea surface temperature are large. It is found that at low wind speeds the difference between satellite measurements and surface reports depends on sea surface temperature. At wind speeds higher than 8 m/s the dependence was greatly reduced. The removal of systematic errors due to fluctuations in atmospheric stability reduced the r.m.s. difference from 1.7 m/s to 0.8 m/s. It is suggested that further clarification of the effects of fluctuations in atmospheric stability on Seasat wind speed measurements should increase their reliability in the future.
The algorithms for rational spline interpolation of surfaces
Two algorithms for interpolating surfaces with spline functions containing tension parameters are discussed. Both algorithms are based on the tensor products of univariate rational spline functions. The simpler algorithm uses a single tension parameter for the entire surface. This algorithm is generalized to use separate tension parameters for each rectangular subregion. The new algorithm allows for local control of tension on the interpolating surface. Both algorithms are illustrated and the results are compared with the results of bicubic spline and bilinear interpolation of terrain elevation data.
Adatom diffusion and adatom-ledge interaction on the Si(111) surface using a semiempirical potential energy function
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Kink-site formation energies on the Si(111) surface using a semiempirical potential energy function
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