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At least 1,351 records · Page 75

Strain-rate dependence of ramp-wave evolution and strength in tantalum

We have conducted molecular dynamics (MD) simulations of quasi-isentropic ramp-wave compression to very high pressures over a range of strain rates from 10 11 down to 10 8 1/s. Using scaling methods, we collapse wave profiles from various strain rates to a master profile curve, which shows deviations when material response is strain-rate dependent. Thus, we can show with precision where, and how, strain-rate dependence affects the ramp wave. We find that strain rate affects the stress-strain material response most dramatically at strains below 20%, and that above 30% strain the material response is largely independent of strain rate. We show good overall agreement with experimental stress-strain curves up to approximately 30% strain, above which simulated response is somewhat too stiff. We postulate that this could be due to our interatomic potential or to differences in grain structure and/or size between simulation and experiment. Strength is directly measured from per-atom stress tensor and shows significantly enhanced elastic response at the highest strain rates. As a result, this enhanced elastic response is less pronounced at higher pressures and at lower strain rates.

36 MATERIALS SCIENCE↗

Theory of finite disturbances in a centrifugal compression system with a vaneless radial diffuser

A previous small perturbation analysis of circumferential waves in circumferential compression systems, assuming inviscid flow, is shown to be consistent with observations that narrow diffusers are more stable than wide ones, when boundary layer displacement effect is included. The Moore-Greitzer analysis for finite strength transients containing both surge and rotating stall in axial machines is adapted for a centrifugal compression system. Under certain assumptions, and except for a new second order swirl, the diffuser velocity field, including resonant singularities, can be carried over from the previous inviscid linear analysis. Nonlinear transient equations are derived and applied in a simple example to show that throttling through a resonant value of flow coefficient must occur in a sudden surge-like drop, accompanied by a transient rotating wave. This inner solution is superseded by an outer surge response on a longer time scale. Surge may occur purely as result of circumferential wave resonance. Numerical results are shown for various parametric choices relating to throttle schedule and the characteristic slope. A number of circumferential modes considered simultaneously is briefly discussed.

Moore, F. K.↗

Evolution of anisotropy with saturation and its implications for the elastoplastic responses of clay rocks

Many clay rocks have distinct bedding planes. Experimental studies have shown that their mechanical properties evolve with the degree of saturation (DOS), often with higher stiffness and strength after drying. For transversely isotropic rocks, the effects of saturation can differ between the bed-normal (BN) and bed-parallel (BP) directions, which gives rise to saturation-dependent stiffness and strength anisotropy. Accurate prediction of the mechanical behavior of clay rocks under partially saturated conditions requires numerical models that can capture the evolving elastic and plastic anisotropy with DOS. In this study, we present an anisotropy framework for coupled solid deformation-fluid flow in unsaturated elastoplastic media. Here we incorporate saturation-dependent strength anisotropy into an anisotropic modified Cam-Clay (MCC) model and consider the evolving anisotropy in both the elastic and plastic responses. The model was calibrated using experimental data from triaxial tests to demonstrate its capability in capturing strength anisotropy at various levels of saturation. Through numerical simulations, we demonstrate the role of evolving stiffness and strength anisotropy in the mechanical behavior of clay rocks. Plane strain simulations of triaxial compression tests were also conducted to demonstrate the impacts of material anisotropy and DOS on the mechanical and fluid flow responses.

36 MATERIALS SCIENCE↗

Hot Deformation Behavior of Aluminum Alloys AA7010 and AA7075

The hot deformation behavior of high-strength aluminum alloys AA7010 and 5 was studied through hot isothermal compression testing in the temperature regime of 623-723 K (at an interval of 25 K) and at varying strain rates (0.001 to 10 s{sup −1}). The safe zone of hot workability of both the alloys was determined using the instability criteria and correlating with the microstructure evolution. Zener–Hollomon parameters were calculated, and constitutive equations were also derived. Common characteristics observed in both the alloys were adiabatic shear band formation at a temperature of 623 K and strain rate of 10 s{sup −1} and flow localization at combination of all temperatures and high strain rate of 10 s{sup −1} with evolution of very fine recrystallized (DRX) grains. High-temperature resistance to deformation, large extent of recrystallization and relatively larger zone of stable deformation and higher activation energy in Al alloy AA7010 were observed as compared to AA7075. Considering the role of precipitates, dynamic recrystallization was found to have significant role in governing the hot deformation behavior of the alloys. Prediction of constitutive equations was found to be more accurate at higher temperatures and at moderate-to-high strain rates with relatively less error in AA7075 alloy as compared to AA7010 alloy.

36 MATERIALS SCIENCE↗

Atomic structure and melting of Ni and Fe 36 Ni up to 400 GPa

Iron, nickel and its alloys are critically important materials for industrial and technological applications due to their unique magnetic properties, strength, and thermal expansion. In this study, lasers were used to compress and heat Fe 36 Ni alloy (36 wt% Ni) and pure nickel up to the melting temperature using a combination of shock and ramp compression. The structure was measured using nanosecond in-situ x-ray diffraction, and simultaneous velocimetry was used to measure the pressure up to 454 GPa. A mixed face-centered-cubic (fcc) solid–liquid phase in Fe 36 Ni at 311 GPa provides experimental evidence that, compared to pure iron, the incorporation of nickel expands the stability field of the fcc phase to the melting curve. At lower temperatures, a mixed fcc and hexagonal-close-packed (hcp) phase is observed in ramp-compressed Fe 36 Ni at 278 GPa. At the higher compressions, a structure inconsistent with fcc, hcp, and body-centered cubic (bcc) is observed. In the case of pure Ni, the fcc phase is stable under ramp compression up to 402 GPa.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

As a Matter of Force—Systematic Biases in Idealized Turbulence Simulations

Many astrophysical systems encompass very large dynamical ranges in space and time, which are not accessible by direct numerical simulations. Thus, idealized subvolumes are often used to study small-scale effects including the dynamics of turbulence. These turbulent boxes require an artificial driving in order to mimic energy injection from large-scale processes. In this paper, we show and quantify how the autocorrelation time of the driving and its normalization systematically change the properties of an isothermal compressible magnetohydrodynamic flow in the sub- and supersonic regime and affect astrophysical observations such as Faraday rotation. For example, we find that δ-in-time forcing with a constant energy injection leads to a steeper slope in kinetic energy spectrum and less-efficient small-scale dynamo action. In general, we show that shorter autocorrelation times require more power in the acceleration field, which results in more power in compressive modes that weaken the anticorrelation between density and magnetic field strength. Thus, derived observables, such as the line-of-sight (LOS) magnetic field from rotation measures, are systematically biased by the driving mechanism. Finally, we argue that δ-in-time forcing is unrealistic and numerically unresolved, and conclude that special care needs to be taken in interpreting observational results based on the use of idealized simulations.

79 ASTRONOMY AND ASTROPHYSICS↗

Analysis of three-point-bend test for materials with unequal tension and compression properties

An analysis capability is described for the three-point-bend test applicable to materials of linear but unequal tensile and compressive stress-strain relations. The capability consists of numerous equations of simple form and their graphical representation. Procedures are described to examine the local stress concentrations and failure modes initiation. Examples are given to illustrate the usefulness and ease of application of the capability. Comparisons are made with materials which have equal tensile and compressive properties. The results indicate possible underestimates for flexural modulus or strength ranging from 25 to 50 percent greater than values predicted when accounting for unequal properties. The capability can also be used to reduce test data from three-point-bending tests, extract material properties useful in design from these test data, select test specimen dimensions, and size structural members.

Chamis, C. C.↗

Soft electrons as a possible heat source for Jupiter's thermosphere

The 850 K exospheric temperature inferred for Jupiter from the radio-occultation experiments on Pioneers 10 and 11 is shown to imply a heat input of 0.25-0.5 erg/sq cm/sec. One possible source of this energy is precipitation of electrons from a warm plasma (temperature corresponding to energies of the order of 30-500 eV). A mechanism is suggested wherein the presence of this plasma can be accounted for by centrifugal acceleration and adiabatic compression of ionospheric electrons and protons. Present ideas of the source strength of ionospheric plasma, however, give heating rates that are too small by one to two orders of magnitude, although inferences from direct plasma measurements suggest that the required plasma is indeed present.

Hunten, D. M.↗

Ionospheric projections of magnetospheric regions under low and high solar wind pressure conditions

The projection of magnetospheric regions into the dayside ionosphere as determined by particle precipitation characteristics was studied for dependence on solar wind parameters. It was found that the solar wind kinetic pressure p dramatically affected the map of magnetospheric projections. Under the constraint that p greater than or equal 4 nPa(yielding (p) = 5.9 nPa), the area of the cusp (magnetic latitude times magnetic local time extent) was 4.83 degree-hours; whereas under the constraint that p greater than or equal 2 nPa (yielding (p) = 1.5 nPa), the cusp area was only 1.01 degree-hours. The ionospheric footprint of the low-latitude boundary layer was similarly affected. Various possible correlations of p with other solar wind variables, including n, v, and absolute value of B(sub z), proved unable to account for the pressure effect. Because one criterion for identifying the cusp is high fluxes, the effect of nv was investigated with particular care, both in examples and statistically. Again, p itself had by far the most striking effect. Thus we concluded that some physical mechanism is needed to account for the pressure effect. One possibility is that increased direct solar wind plasma penetration of the magnetopause occurs under high-p conditions in the manner suggested by various proponents of impulsive penetration models. An alternative, which we find promising, is that, regardless of the original interplanetary magnetic field (IMF) strength, a high-p solar wind leads to a large compression factor for the magnetosheath field, which is the field actually in contact with the magnetosphere. From this latter viewpoint, the chief effect of high particle pressure is simply to enhance the effectiveness of the interaction of the IMF with the magnetosphere.

Newell, Patrick T.↗

Polymer-Oxygen Compatibility Testing: Effect of Oxygen Aging on Ignition and Combustion Properties

The oxygen compatibility of six polymers used in oxygen service was evaluated after exposure for 48 hours to oxygen pressures ranging from 350 to 6200 kPa (50 to 900 psia), and temperatures ranging from 50 to 250 C (122 to 302 F). Three elastomers were tested: CR rubber (C873-70), FKM fluorocarbon rubber (Viton A), and MPQ silicone rubber (MIL-ZZ-765, Class 2); and three thermoplastics were tested: polyhexamethylene adipamide (Zytel 42), polytetrafluoroethylene (Teflon TFE), and polychlorotrifluoroethylene (Neoflon CTFE M400H). Post-aging changes in mass, dimensions, tensile strength, elongation at break, and durometer hardness were determined. Also, the compression set was determined for the three elastomers. Results show that the properties under investigation were more sensitive to oxygen pressure at low to moderate temperatures, and more sensitive to temperature at low to moderate oxygen pressures. Inspection of the results also suggested that both chain scissioning and cross-linking processes were operative, consistent with heterogeneous oxidation. Attempts are underway to verify conclusively the occurrence of heterogeneous oxidation using a simple modulus profiling technique. Finally, the effect of aging at 620 kpa (90 psia) and 121 C (250 F) on ignition and combustion resistance was determined. As expected, aged polymers were less ignitable and combustible (had higher AlTs and lower heats of combustion). Special attention was given to Neoflon CTFE. More specifically, the effect of process history (compression versus extrusion molding) and percent crystallinity (quick- versus slow-quenched) on the AIT, heat of combustion, and impact sensitivity of Neoflon CTFE was investigated. Results show the AIT, heat of combustion, and impact sensitivity to be essentially independent of Neoflon CTFE process history and structure.

Waller, Jess M.↗

Autofrettage to Counteract Coefficient of Thermal Expansion Mismatch in Cryogenic Pressurized Pipes with Metallic Liners

Composite feedlines with metal liners have the potential to reduce weight/cost while providing the same level of permeation resistance and material compatibility of all-metal feedlines carrying cryogenic propellants in spacecraft. The major technical challenges are the large difference in Coefficient of Thermal Expansion between the liner and the composite, and the manufacturing method required to make a very thin liner with the required strength and dimensional tolerance. This study investigates the use of autofrettage (compressive preload) to counteract Coefficient of Thermal Expansion when pre-pressurization procedures cannot be used to solve this problem. Promising materials (aluminum 2219, Inconel 718, nickel, nickel alloy) and manufacturing techniques (chemical milling, electroplating) are evaluated to determine the best liner candidates. Robust, autofrettaged feedlines with a low Coefficient of Thermal Expansion liner (Inconel 718 or nickel alloy) are shown to successfully counteract mismatch at LOX temperature. A new concept, autofrettage by temperature, is introduced for high Coefficient of Thermal Expansion materials (aluminum and pure nickel) where pressure cannot be used to add compressive preload.

Wen, Ed↗

Hot Flow Anomalies at Venus

We present a multi-instrument study of a hot flow anomaly (HFA) observed by the Venus Express spacecraft in the Venusian foreshock, on 22 March 2008, incorporating both Venus Express Magnetometer and Analyzer of Space Plasmas and Energetic Atoms (ASPERA) plasma observations. Centered on an interplanetary magnetic field discontinuity with inward convective motional electric fields on both sides, with a decreased core field strength, ion observations consistent with a flow deflection, and bounded by compressive heated edges, the properties of this event are consistent with those of HFAs observed at other planets within the solar system.

Venusian↗

Producing Zirconium Diboride Components with Complex, Near-Net Shape Geometries by Aqueous Room-Temperature Injection Molding

Room-temperature injection molding is proposed as a novel, low-cost and more energy efficient manufacturing process capable of forming complex-shaped zirconium diboride (ZrB2) parts. This innovative processing method utilized aqueous suspensions with high powder loading and a minimal amount (5 vol.) of water-soluble polyvinylpyrrolidone (PVP), which was used as a viscosity modifier. Rheological characterization was performed to evaluate the room-temperature flow properties of ZrB2-PVP suspensions. ZrB2 specimens were fabricated with high green body strength and were machinable prior to binder removal despite their low polymer content. After binder burnout and pressureless sintering, the bulk density and microstructure of specimens were characterized using Archimedes technique and scanning electron microscopy. X-Ray Diffraction was used to determine the phase compositions present in sintered specimens. Ultimate strength of sintered specimens will be determined using ASTM C1323-10 compressive C-ring test.

Near-Net Shape Forming↗

I n s i t u observation of a phase transition in silicon carbide under shock compression using pulsed x-ray diffraction

The behavior of silicon carbide (SiC) under shock compression is of interest due to its applications as a high-strength ceramic and for general understanding of shock-induced polymorphism. Here we use the Matter in Extreme Conditions beamline of the Linac Coherent Light Source to carry out a series of time-resolved pump-probe x-ray diffraction measurements on SiC laser-shocked to as high as 206 GPa. Experiments on single crystals and polycrystals of different polytypes show a transformation from a low-pressure tetrahedral phase to the high-pressure rocksalt-type (B1) structure. We directly observe coexistence of the low- and high-pressure phases in a mixed-phase region and complete transformation to the B1 phase above 200 GPa. The densities measured by x-ray diffraction are in agreement with both continuum gas-gun studies and a theoretical B1 Hugoniot derived from static-compression data. Time-resolved measurements during shock loading and release reveal a large hysteresis upon unloading, with the B1 phase retained to as low as 5 GPa. The sample eventually reverts to a mixture of polytypes of the low-pressure phase at late times. Our study demonstrates that x-ray diffraction is an effective means to characterize the time-dependent structural response of materials undergoing shock-induced phase transformations at megabar pressures.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Fiber/matrix debonding evaluation of SiCf/SiC composites using micropillar compression technique

Third-generation silicon carbide (SiC) composites reinforced by SiC fibers (Hi-Nicalon S [HNS] and Tyranno SA3 [SA3]) are attractive for use in next generation reactors owing to their high strength and chemical inertness at high temperatures, as well as enhanced radiation tolerance under neutron irradiation environments. To optimize composite performance, the interfacial mechanical properties of chemical vapor–infiltrated (CVI) SiC f /SiC composites are investigated in this effort by using a slant interface micropillar compression testing procedure. The micropillar test specimens, containing an inclined pyrolytic carbon (PyC) interphase, are prepared using a focused ion beam. The novel microcompression testing successfully quantifies the debond shear strength and internal friction coefficient of micropillar test samples by using the Mohr-Coulomb formulation. Furthermore, according to four types of SiCf/SiC composite microcompression test results, interfacial properties and debond mechanisms are significantly affected by the PyC layer thickness, the local bonding mechanism of the PyC interphase on the SiC fiber surface, and the surface roughness of fibers. Regardless of PyC thicknesses, SA3-reinforced CVI SiC f /SiC composites are found to have much higher debond shear strengths than HNS-reinforced SiC f /SiC CVI composites. By using this micropillar compression technique alongside analytical methods, we uncover new understandings of PyC interface properties. Additionally, the micropillar test results obtained are correlated with macroscopic mechanical properties of neutron-irradiated CVI SiCf/SiC composites.

42 ENGINEERING↗

Feeding properties and behavior of hammer- and knife-milled pine

This work reports the rheological characterization of hammer and knife-milled lodgepole pine materials as a function of grind size and moisture content. Characterizations included particle size and shape distributions, bulk density, compressibility at 10 kPa uniaxial pressure, elastic recovery from 10 kPa uniaxial pressure, shear strength, effective angle of internal friction, arching in a custom hopper, and feeding performance in volumetric and gravimetric auger feeders. Particle analysis indicates that the width and length distributions of the 3 mm hammer-milled and the 6 mm knife-milled materials are quite similar, and that all the materials have relatively short aspect ratios (< 4). Compressibility and elastic recovery both increased with increasing moisture content with both values increasing more than 10% and the effect being most severe for the 3 mm grind. Adding 3 kPa of pressure increased the critical arching width for all hopper arching tests, except for the 25 mm grind material with 20% MC, for which the critical arching width actually decreased with increased pressure. Interestingly, for materials with smaller particle sizes, the volumetric feed rate tends to decrease as moisture increases even though the density of the material increases with moisture content and the auger speeds are the same. Time variability of volumetric feed rate increased dramatically with increasing particle size but the impact of moisture content was not as clear. For nearly all tests, gravimetric auger feeding resulted in better feeding control and substantially decreased time variability in the material feed rate. These tests show that material feed rate and volumetric auger feed rate variability are dependent upon material shear strength, bulk density, and particle size. Shear tests indicate that material strength generally decreased with increasing particle size, although the impact of moisture was not entirely consistent.

09 BIOMASS FUELS↗

Mechanical properties of metal-ceramic nanolaminates: Effect of constraint and temperature

Al/SiC nanolaminates with equal nominal thicknesses of the Al and SiC layers (10, 25, 50 and 100 nm) were manufactured by magnetron sputtering. The mechanical properties were measured at 25 °C and 100 °C by means of nanoindentation and micropillar compression tests and the deformation mechanisms were analyzed by in situ micropillar compression tests in the transmission electron microscope. In addition, finite element simulations of both tests were carried out to ascertain the role played by the strength of the Al layers and by the elastic constraint of the ceramic layers on the plastic flow of Al in the mechanical response. It was found that the mechanical response was mainly controlled by the constraint during nanoindentation or micropillar compression tests of very thin layered (≈10 nm) laminates, while the influence of the strength of Al layers was not as critical. This behavior was reversed, however, for thick layered laminates (100 nm). Here, these mechanisms point to the different effects of layer thickness during nanoindentation and micropillar compression, at both temperatures, and showed the critical role played by constraint on the mechanical response of nanolaminates made of materials with a very large difference in the elasto-plastic properties.

36 MATERIALS SCIENCE↗

Solvent-Free Preparation of High Energy, Binder-Free Electrodes Enabled by Dry Compressible Holey Graphene

Graphene is an atomically thick sheet consisting of a graphitic carbon network with excellent mechanical strength, electrical and thermal conductivity, and chemical stability. Holey graphene, a structural derivative of graphene, has an array of through-the-thickness holes across the lateral surface of the nanosheet. The presence of these holes has minimal detrimental effect on the graphene properties and leads to enhanced performance in applications such as electronics, sensors, and energy storage. For example, these holes allow more facile cross-plane ion and gas transport than intact graphene, making holey graphene an ideal electrode material for electrochemical energy storage. This presentation will focus on the ability of holey graphene to be compression molded into robust articles or architectures under solvent-free conditions without the need for potentially parasitic binders. The unique dry compressibility of holey graphene has enabled facile fabrication of high mass loading electrodes with both high density and high porosity, which have found use in supercapacitors and various high-energy battery systems such as lithium-oxygen, lithium-sulfur, and lithium-selenium batteries.

Yi Lin↗