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NASA NTRS1985

Quantitative determination of mineral types and abundances from reflectance spectra using principal components analysis

A procedure was developed for analyzing remote reflectance spectra, including multispectral images, that quantifies parameters such as types of mineral mixtures, the abundances of mixed minerals, and particle sizes. Principal components analysis reduced the spectral dimensionality and allowed testing the uniqueness and validity of spectral mixing models. By analyzing variations in the overall spectral reflectance curves, the type of spectral mixture was identified, mineral abundances quantified and the effects of particle size identified. The results demonstrate an advantage in classification accuracy over classical forms of analysis that ignore effects of particle-size or mineral-mixture systematics on spectra. The approach is applicable to remote sensing data of planetary surfaces for quantitative determinations of mineral abundances.

Smith, M. O.↗

NASA NTRS1985

Quantitative analysis of planetary reflectance spectra with principal components analysis

A technique is presented for quantitative analysis of planetary reflectance spectra as mixtures of particles on microscopic and macroscopic scales using principal components analysis. This technique allows for determination of the endmembers being mixed, their abundance, and the scale of mixing, as well as other physical parameters. Eighteen lunar telescopic reflectance spectra of the Copernicus crater region, from 600 nm to 1800 nm in wavelength, are modeled in terms of five likely endmembers: mare basalt, mature mare soil, anorthosite, mature highland soil, and clinopyroxene. These endmembers were chosen from a similar analysis of 92 lunar soil and rock samples. The models fit the data to within 2 percent rms. It is found that the goodness of fit is marginally better for intimate mixing over macroscopic mixing.

Johnson, P. E.↗

NASA NTRS1984

Prepreg cure monitoring using diffuse reflectance-FTIR

An in situ diffuse reflectance-Fourier transform infrared technique was developed to determine infrared spectra of graphite fiber prepregs as they were being cured. A bismaleimide, an epoxy, and addition polyimide matrix resin prepregs were studied. An experimental polyimide adhesive was also examined. Samples were positioned on a small heater at the focal point of diffuse reflectance optics and programmed at 15 F/min while FTIR spectra were being scanned, averaged, and stored. An analysis of the resulting spectra provided basic insights into changes in matrix resin molecular structure which accompanied reactions such as imidization and crosslinking. An endo-exothermal isomerization involving reactive end-caps was confirmed for the addition polyimide prepregs. The results of this study contribute to a fundamental understanding of the processing of composites and adhesives. Such understanding will promote the development of more efficient cure cycles.

Young, P. R.↗

NASA NTRS1985

Venus global radar reflectivity and correlations with elevation

A geological analysis of the global radar reflectivity data for Venus is presented. The statistical and map pattern distribution of the radar reflectivity rho is first analyzed in the context of the porosity structure of the surface. Rho is then correlated with elevation in order to examine the degree of topographic control on material properties which could depend on PT-sensitive chemical weathering phenomena. Comparison of the rms slope alpha and rho correlations with elevation demonstrates that there are distinct topographic zones defined on the basis of the rho and alpha trends. Finally, hierarchical clustering analysis is applied to the global rho, alpha, and 100-km baseline regional slope data sets in order to define radar property-related subregions.

Garvin, J. B.↗

NASA NTRS1985

Colors of reflection nebulae. I - Phase function effects in the Merope nebula

The subject of color differences between reflection nebulae and their illuminating stars is reexamined in the light of developments of observational techniques, permitting accurate surface-brightness photometry over an expanded spectral region from the UV to the IR. Color-color diagrams for reflection nebulae can yield useful information about the wavelength dependence of the scattering properties of nebular dust without excessive sensitivity to the specific nebular geometry or the presence of multiple scattering, resulting in considerable savings in computational efforts. As an illustration, the color-difference method was applied to existing data for the Merope nebula, covering the spectral region 1550-5500 A. Strong evidence for a monotonically changing phase function of scattering at wavelengths less than or equal to 3500 A is found. The result is interpreted in the context of a plausible geometry for the Merope environment as providing support for a bimodal size distribution of nebular dust grains.

Witt, A. N.↗

NASA NTRS1985

Reflection and emission models for clouds derived from Nimbus 7 earth radiation budget scanner measurements

Statistical results from 2.8 million pairs of broadband shortwave and longwave radiance measurements were used to develop reflectance and emittance models for low, middle, and high water clouds and high ice clouds. The reflectance model was a function of the sum and product of the cosine of solar and viewing zenith angles, and the emittance model was related by a power law of the cosine of the viewing zenith angle.

Staylor, W. F.↗

NASA NTRS1985

Reflectance Modeling

The overall goal of this work has been to develop a set of computational tools and media abstractions for the terrain bidirectional reflectance problem. The modeling of soil and vegetation surfaces has been emphasized with a gradual increase in the complexity of the media geometries treated. Pragmatic problems involved in the combined modeling of soil, vegetation, and atmospheric effects have been of interest and one of the objectives has been to describe the canopy reflectance problem in a classical radiative transfer sense permitting easier inclusion of our work by other workers in the radiative transfer field.

Smith, J. A.↗

NASA NTRS1983

Spectral reflectance of surface soils: Relationships with some soil properties

Using a published atlas of reflectance curves and physicochemical properties of soils, a statistical analysis was carried out. Reflectance bands which correspond to five of the wavebands used by NASA's Thematic Mapper were examined for relationships to specific soil properties. The properties considered in this study include: Sand Content, Silt Content, Clay Content, Organic Matter Content, Cation Exchange Capacity, Iron Oxide Content and Moisture Content. Regression of these seven properties on the mean values of five TM bands produced results that indicate that the predictability of the properties can be increased by stratifying the data. The data was stratified by parent material, taxonomic order, temperature zone, moisture zone and climate (combined temperature and moisture). The best results were obtained when the sample was examined by climatic classes. The middle Infra-red bands, 5 and 7, as well as the visible bands, 2 and 3, are significant in the model. The near Infra-red band, band 4, is almost as useful and should be included in any studies. General linear modeling procedures examined relationships of the seven properties with certain wavebands in the stratified samples.

Kiesewetter, C. H.↗

NASA NTRS1986

Methane oxidation behind reflected shock waves: Ignition delay times measured by pressure and flame band emission

Ignition delay data were recorded for three methane-oxygen-argon mixtures (phi = 0.5, 1.0, 2.0) for the temperature range 1500 to 1920 K. Quiet pressure trances enabled us to obtain delay times for the start of the experimental pressure rise. These times were in good agreement with those obtained from the flame band emission at 3700 A. The data correlated well with the oxygen and methane dependence of Lifshitz, but showed a much stronger temperature dependence (phi = 0.5 delta E = 51.9, phi = 1.0 delta = 58.8, phi = 2.0 delta E = 58.7 Kcal). The effect of probe location on the delay time measurement was studied. It appears that the probe located 83 mm from the reflecting surface measured delay times which may not be related to the initial temperature and pressure. It was estimated that for a probe located 7 mm from the reflecting surface, the measured delay time would be about 10 microseconds too short, and it was suggested that delay times less than 100 microsecond should not be used. The ignition period was defined as the time interval between start of the experimental pressure rise and 50 percent of the ignition pressure. This time interval was measured for three gas mixtures and found to be similar (40 to 60 micro sec) for phi = 1.0 and 0.5 but much longer (100 to 120) microsecond for phi = 2.0. It was suggested that the ignition period would be very useful to the kinetic modeler in judging the agreement between experimental and calculated delay times.

Brabbs, T. A.↗

NASA NTRS1985

Modeling canopy reflectance and microwave backscattering coefficient

Various approaches to model canopy reflectance (CR) in the visible/infrared region and backscattering coefficient (BSC) in the microwave region are compared and contrasted. It is noted that BSC can be related to CR in the source direction (the 'hot spot' direction). By assuming a frequency dependent leaf reflectance and transmittance it is shown that the observed dependence of BSC on leaf area index, leaf angle distribution, angle of incidence, soil moisture content, and frequency can be simulated by a CR model. Thus both BSC and CR can, in principle, be calculated using a single model which has essentially the same parameters as many CR models do.

Goel, N. S.↗

NASA NTRS1984

Electro-optical terrain reflectance modeling - A perspective

Electro-optical terrain reflectance modeling is one of the components required in the overall capability to simulate remote sensing measurement systems as an aid to the sensor or information processing designer. Given that sensor fields-of-view may vary from a few centimeters to several meters and that measurement devices may be placed at varying heights above the terrain surface, modeling of complex combinations of terrain classes or media with respect to both vertical and horizontal scales may be required. This paper addresses the issue of combining modeling approaches for different classes of materials in the optical regime and recommends a more formal approach to the radiative characterization of media properties as well as the calculation of the bidirectional reflectance distribution functions.

Smith, J. A.↗

NASA NTRS1986

Light interception and leaf area estimates from measurements of grass canopy reflectance

Grassland is a major component of the earth's available land. The vast area and remoteness of this ecosystem makes it difficult to assess its condition and monitor productivity by traditional methods. Remote sensing potentially offers a rapid nondestructive approach for monitoring such ecosystems. A study was carried out in a tallgrass prairie site near Manhattan, Kansas, during the 1983 and 1984 seasons to investigate the feasibility of estimating light interception and green leaf area index (LAI) from measurements of canopy multispectral reflectance. Greenness (Gn) index was found to be strongly correlated with intercepted photosynthetically active radiation (PAR). Two methods, a direct regression (RGR) and an indirect approach (IND), were used to estimate LAI from Gn index. The LAI values estimated by RGR method were consistently lower than the measured ones; however, good agreement was obtained between the LAI values estimated by IND method and the measured LAI. This suggests that Gn transformation of canopy spectral reflectance is more closely related to the fraction of intercepted PAR by green foliage than the quantity of green LAI.

Asrar, G.↗

NASA NTRS1986

Directional reflectance distributions of a hardwood and pine forest canopy

A hand-held radiometer with AVHRR bands 1 and 2 was used to measure the directional reflectance distributions for both a hardwood and a pine forest canopy from a helicopter platform; canopy characteristics were also measured on the ground. The reflectance distributions obtained are compared with the scattering behavior of agricultural and natural grassland canopies. In addition, the Kimes (1983) three-dimensional radiative transfer model is used to document the unique radiant transfers that occur in forest canopies in virtue of their geometric structure. Both the measurements and the model calculations show that dense forest canopy scattering is similar to that for crops and grasslands. Attention is given to the effects of sparse forest canopies.

Kimes, D. S.↗

NASA NTRS1985

Near infrared leaf reflectance modeling

Near infrared leaf reflectance modeling using Fresnel's equation (Kumar and Silva, 1973) and Snell's Law successfully approximated the spectral curve for a 0.25-mm turgid oak leaf lying on a Halon background. Calculations were made for ten interfaces, air-wax, wax-cellulose, cellulose-water, cellulose-air, air-water, and their inverses. A water path of 0.5 mm yielded acceptable results, and it was found that assignment of more weight to those interfaces involving air versus water or cellulose, and less to those involving wax, decreased the standard deviation of the error for all wavelengths. Data suggest that the air-cell interface is not the only important contributor to the overall reflectance of a leaf. Results also argue against the assertion that the near infrared plateau is a function of cell structure within the leaf.

Parrish, J. B.↗

NASA NTRS1986

The motion of ions specularly reflected off a quasi-parallel shock in the presence of large-amplitude, monochromatic MHD waves

A model is used to examine the motion of specularly reflected ions in the presence of large-amplitude, monochromatic, transverse MHD waves. The calculations of ion trajectories are described. The heating downstream from the quasi-parallel bow shock is analyzed. The relationship between the specularly reflected ions and their gyrospeeds and guiding center speeds is studied. The data reveal that the characteristics of the motion depend on the frequency, wavelength, phase, and amplitude of the wave that is converted into the shock.

Fuselier, S. A.↗

NASA NTRS1986

Influence of process parameter variation on the reflectivity of sputter-deposited W-C multilayer diffraction gratings

Multilayer W-C diffraction gratings with nominal d spacings of 35 A have been fabricated by magnetron sputter deposition. The peak and integrated reflectivities of these films have been measured with Al K-alpha X-rays and compared to theoretical values. The rms surface roughness has been evaluated. The influence of several sputtering-system process parameters on the reflectivities has been investigated.

Sager, B.↗

NASA NTRS1987

Surface bidirectional reflectance properties of two southwestern Arizona deserts for wavelengths between 0.4 and 2.2 micrometers

Surface bidirectional reflectance characteristics are presented for the Sonora Desert and the Mohawk Valley at solar zenith angles of 13, 31, and 57 degs at wavelengths between 0.4 and 1.6 microns. Nadir reflectance values are presented for wavelengths between 0.4 and 2.2 microns for solar zenith angles of 13, 17.5, 27, 31, 45, 57, and 62 degs. Data were taken from a helicopter during May l985 in support of an Earth Radiation Budget Experiment (ERBE), a Stratospheric Aerosol Gas Experiment (SAGE II), and an Advanced Very High Resolution Radiometer (AVHRR) satellite validation experiment.

Whitlock, Charles H.↗

NASA NTRS1987

Reflectance spectra of mafic silicates and phyllosilicates from .6 to 4.6 microns

The results of spectral measurements for mafic silicates are given. The study provided valuable spectral reflectance information about mafic silicates and phyllosilicates in the 2.5 to 4.6 micron wavelength region. It was shown that the reflectance of these materials is strongly affected by the presence of H2O and OH. Therefore, the identification of these absorbing species is greatly enhanced.

Roush, Ted L.↗