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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,351 records · Page 75

Adaptive relay autotuning under static and non-static disturbances with application to friction stir welding

When a traditional relay feedback test is biased, asymmetry is induced, erroneous system identification occurs, and the test may stop oscillating. Adaptive methods which restore symmetry to the relay test are developed, and additional methods are presented to detect and recover from a non-oscillation condition. This is demonstrated both in simulation and in a process with significant transients and disturbances - friction stir welding (FSW). In testing, it is shown that the adaptive method is able to restore symmetry even in the presence of severe and changing disturbances, including after the weld plunge where temperature gradients change rapidly. Finally, these improvements enable system identification of systems such as FSW in a more robust and accurate manner.

42 ENGINEERING↗

Simultaneously achieved large reversible elastocaloric and magnetocaloric effects and their coupling in a magnetic shape memory alloy

Large reversible caloric effects covering a broad temperature region are essential for high-efficiency and environment-friendly solid-state caloric refrigeration that can potentially replace the traditional vaporcompression-based cooling technology. Here, we report the simultaneously achieved large reversible magnetocaloric and elastocaloric effects in a Ni 43 Co 6 Mn 40 Sn 11 magnetic shape memory alloy. A reversible near-room-temperature magnetic entropy change Δ S m of as high as 19.3 J kg –1 K –1 under 5 T was experimentally obtained and the corresponding adiabatic temperature change Δ T ad was estimated to be 7.7 K. Meanwhile, a large reversible elastocaloric effect with a directly measured Δ T ad up to 7.1 K was attained. The elastocaloric effect exhibits high cyclic stability with no apparent degradation during 380 cycles of loading and unloading. Furthermore, we propose and demonstrate the utilization of the multicaloric approach under the coupled uniaxial stress and magnetic field to enlarge the refrigeration temperature region of reversible caloric effects. By combining the reversible magnetocaloric and elastocaloric effects and the reversible multicaloric effect under the coupling of uniaxial stress and magnetic field in the hysteresis region, large reversible caloric effects covering a broad temperature region from 257 K to 383 K can be obtained. Finally, this study may pave the way for designing advanced caloric materials with cyclically stable and reversible large caloric effects and wide refrigeration temperature region for solid-state refrigeration.

36 MATERIALS SCIENCE↗

The chemical and radiative effects of the Mount Pinatubo eruption

To clarify the mechanisms leading to effects on stratospheric ozone, time-dependent stratospheric aerosol and gas experiment II (SAGE II) and cryogenic limb array elaton spectrometer (CLAES) aerosol optical extinction data and SAGE II surface area density are used as parameters in a two-dimensional (2-D) zonally averaged chemical radiative transport model. The model was integrated with time from before the eruption through December 1993. The modeled impact on global ozone results from increased rates of heterogeneous reactions on sulfate aerosols and from the increased radiative heating and scattering caused by these aerosols. When the aerosol heating is allowed to modify the temperature distribution, the maximum change calculated in equatorial column ozone is -1.6%. The calculated equatorial temperature change and peak local ozone change in October 1991 are +6K and -4%, respectively. When aerosol heating perturbs the circulation in the model, the maximum change in equatorial column ozone is -6%. Increased heterogeneous processing on sulfate aerosols is calculated to have changed equatorial column ozone in late 1991 by -1.5%. Global column ozone in the model in 1992 and 1993 changed by -2.8% and -2.4%, respectively. The relationship of ozone-controlling processes in the lower stratosphere is altered as well; HO(x) becomes the most important catalytic cycle, followed by ClO(x) and NO(x). This is driven by significant changes in trace gas concentrations. In October 1991, lower stratospheric, equatorial NO(x) decreased by 40%, ClO(x) increased by 60%, and HO(x) increased by 25%. When the effect of heterogeneous chemical processing on sulfate aerosols is combined with aerosol heating, modifying either circulation or temperature, dramatically different ozone fingerprints with time and latitude are predicted. Model-derived changes in the equatorial region in column ozone best represented the observed data when perturbed circulation was combined with heterogeneous chemical effects. However, at high latitudes, the increased ozone production from the strengthening of the mean circulation tends to cancel the heterogeneous reduction of ozone. This is not in good agreement with observed data, especially in 1992 and 1993. When the circulation is held fixed and the temperature allowed to change, and heterogeneous chemical effects are included, the equatorial ozone decrease predicted was too small for 1991. However, the mid- to high-latitude decrease in 1992 and 1993 is in better agreement with observed data.

Kinneson, Douglas E.↗

Dynamics of the lignin glass transition

The dynamics of lignin, a complex and heterogeneous major plant cell-wall macromolecule, is of both fundamental and practical importance. Lignin is typically heated to temperatures above its glass transition to facilitate its industrial processing. Here, we performed molecular dynamics simulations to investigate the segmental (α) relaxation of lignin, the dynamical process that gives rise to the glass transition. It is found that lignin dynamics involves mainly internal motions below T g , while segmental inter-molecular motions are activated above T g . The segments whose mobility is enhanced above T g consist of 3–5 lignin monomeric units. The temperature dependence of the lignin segmental relaxation time changes from Arrhenius below T g to Vogel–Fulcher–Tamman above T g . This change in temperature dependence is determined by the underlying energy landscape being restricted below T g but exhibiting multiple minima above T g . The Q-dependence of the relaxation time is found to obey a power-law up to Q max , indicative of sub-diffusive motion of lignin above T g . Temperature and hydration affect the segmental relaxation similarly. Increasing hydration or temperature leads to: (1) the α process starting earlier, i.e. the beta process becomes shortened, (2) Q max decreasing, i.e. the lengthscale above which subdiffusion is observed increases, and (3) the number of monomers constituting a segment increasing, i.e. the motions that lead to the glass transition become more collective. The above findings provide molecular-level understanding of the technologically important segmental motions of lignin and demonstrate that, despite the heterogeneous and complex structure of lignin, its segmental dynamics can be described by concepts developed for chemically homogeneous polymers.

09 BIOMASS FUELS↗

How transient effects can change the inferred plasma temperatures when using K-shell sulfur line ratios in a time dependent iron sulfide plasma

This paper describes how the steady state atomic kinetics approximation can underestimate the electron temperature determined from K-shell lines in ps-time-scale transient plasmas. In particular, we model the temperature determination of solid FeS targets used in opacity experiments at the Orion laser facility from the ratio of sulfur He-α to Ly-α lines. Such experiments use short-pulse lasers to heat a thin microdot of FeS buried in a plastic target to temperatures of more than 1 keV and densities of approximately 1–2 g/cm 3 . Using atomic kinetics calculations based on a temperature history from a radiation hydrodynamic simulation of the target evolution, the peak temperature inferred from the sulfur line ratios is 1.29 keV at 3.1 ps as compared with the input peak temperature of 1.41 keV at 2.0 ps. There is a time lag of 1.2 ps at the peak, and an overall 0.5 ps time lag in the temporal history of the temperature as the plasma cools over the next 10 ps.

Rilloraza, Francisco↗

A sub-picosecond digital clock monitoring system

We describe a low-cost system designed to monitor wander in digital clocks with a precision of ≤ 1 ps. With this system we have shown that it is possible to track phase variations at the sub-picosecond level by adding noise to a reference clock. As in many cases where a clock is part of a complex distribution network small changes in temperature and other effects can lead to small changes in the clock's phase. As a further demonstration of the system, we have used it to measure the phase changes induced in optical signals in fibers.

47 OTHER INSTRUMENTATION↗

A Change in the Debye Temperature of a Single-Component Substance upon Amorphization

A method for calculating the Debye temperature of a single-component substance in the amorphous state is proposed based on a nonlinear dependence of first coordination number k{sub n} of the given structure on its packing factor k{sub p} as established previously. Proceeding from previously defined parameters of the Mie–Lennard-Jones potential, the Debye temperatures have been calculated for some pure crystalline and amorphous metals, diamond, silicon, and germanium, which are in good agreement with estimations reported by other researchers. It is shown that a minimum specific Helmholtz free energy is attained at k{sub p} = 0.45556, which means that this packing corresponds to a thermodynamically stable amorphous structure.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Millimeter-wave atmospheric loss prediction method

Relationship between atmospheric attenuation and the ground temperature and humidity provides a reference from which changes in temperature and humidity will produce a corresponding atmospheric loss figure. Computer program computes atmospheric loss due to water content, given the measured loss and ground temperature and humidity.

Stelzried, C. T.↗

The detection of H2 in cool carbon stars

Spectra of several carbon stars in the two micron region are examined and compared with synthetic spectra from model atmospheres. Molecular hydrogen has been directly observed in carbon stars for the first time through the quadrupole 1-0 S(1) line at 4712.9/cm. It is definitely present in several Mira variables, and is definitely not present in several irregular variables and one Mira variable. A discrepancy between the predicted and observed line depths at different temperatures is shown. Resolution of the discrepancy by change of temperature alone would require an upward revision of the present effective temperature scale by at least 600 K. Several possible resolutions of the dilemma are briefly examined.

Goebel, J. H.↗

Recording Rapidly Changing Cylinder-wall Temperatures

The present report deals with the design and testing of a measuring plug suggested by H. Pfriem for recording quasi-stationary cylinder wall temperatures. The new device is a resistance thermometer, the temperature-susceptible part of which consists of a gold coating applied by evaporation under high vacuum and electrolytically strengthened. After overcoming initial difficulties, calibration of plugs up to and beyond 400 degrees C was possible. The measurements were made on high-speed internal combustion engines. The increasing effect of carbon deposit at the wall surface with increasing operating period is indicated by means of charts.

Meier, Adolph↗

Arctic Ocean

The Arctic Ocean is the smallest of the Earth's four major oceans, covering 14x10(exp 6) sq km located entirely within the Arctic Circle (66 deg 33 min N). It is a major player in the climate of the north polar region and has a variable sea ice cover that tends to increase its sensitivity to climate change. Its temperature, salinity, and ice cover have all undergone changes in the past several decades, although it is uncertain whether these predominantly reflect long-term trends, oscillations within the system, or natural variability. Major changes include a warming and expansion of the Atlantic layer, at depths of 200-900 m, a warming of the upper ocean in the Beaufort Sea, a considerable thinning (perhaps as high as 40%) of the sea ice cover, a lesser and uneven retreat of the ice cover (averaging approximately 3% per decade), and a mixed pattern of salinity increases and decreases.

Parkinson, Claire L.↗

Effects of Age on Temperature Responses During Exposure to Hypergravity

Rats subjected to centrifugation show a marked decrease in body temperature relating to gravity level. Several studies have indicated, that an initial response to centrifugation is followed by acclimation. To test for differences between young (Y; 2 months) and mature (M; 8 months) rats in their response in temperature, both groups were exposed to hypergravity induced by centrifugation. Thirty-six male rats were divided into four groups according to age and G-load (control (1.0G-Y and 1.0G-M), 2.0G-Y or 2.0G-M) and were housed in pairs in standard vivarium cages. During the 7-day period of centrifugation, temperature was measured every five minutes by surgically implanted telemeters. Body mass was measured daily. We found that initial body temperature in 2.0G-M was less than that of 2.0G-Y. Both hypergravity groups (2.0G-Y and 2.0G-M) showed a decrease in temperature at the onset of centrifugation, and the change in temperature (Delta = 0.5 C) remained the same between the groups. Significant differences persisted with 2.0G-Y recovering to control values in four days and 2.0G-M recovering in five days. These results indicate that the mature animals have a similar response as the younger animals, but take longer to acclimate.

Fung, C.K.↗

Interannual and Long-Term Changes in Middle Atmosphere Temperature from Haloe

Radiative models of the middle atmosphere indicate that the largest temperature response due to steadily increasing amounts of atmospheric CO2 should occur at pressure altitudes between 1 and 0.1 hPa (about 48 to 64 km) and be of the order of 0.5 to 0.6 K/decade on a pressure surface . Such a rate assumes that there is no trend in ozone or in the dissipation of wave activity for that region of the middle atmosphere. This rate of cooling is only of the order of 0.20 to 0.25% per decade, which is a small trend to discern from observations. We have analyzed the 11-year, Version 19 (or V19) temperature versus pressure profile (or T(p)) time series from the UARS Halogen Occultation Experiment (HALOE) for such trends at selected pressure levels. The HALOE T(p) time series are being obtained using CO2 transmission data centered at 2.8 micrometers and from a single instrument that uses the limb solar occultation measurement geometry, which provides significant advantages for the calibration of its single profiles.

Remsbwerg, Ellis↗

Improvement of TOPEX/POSEIDON and Jason-1 Geophysical Data Record for Global Change Studies and Coastal Applications

The Earth's modem climate change has been characterized by interlinked changes in temperature, CO2, ice sheets and sea level. Global sea level change is a critical indicator for study of contemporary climate change. Sea level rise appears to have accelerated since the ice sheet retreats have stopped some 5000 years ago and it is estimated that the sea level rise has been approx. 15 cm over the last century. Contemporary radar altimeters represent the only technique capable of monitoring global sea level change with accuracy approaching 1 mm/yr and with a temporal scale of days and a spatial scale of 100 km or longer. This report highlights the major accomplishments of the TOPEX/POSEIDON (T/P) Extended Mission and Jason-1 science investigation. The primary objectives of the investigation include the calibration and improvement of T/P and Jason-1 altimeter data for global sea level change and coastal tide and circulation studies. The scientific objectives of the investigation include: (1) the calibration and improvement of T/P and Jason-1 data as a reference measurement system for the accurate cross-linking with other altimeter systems (Seasat, Geosat, ERS-1, ERS-2, GFO-1, and Envisat), (2) the improved determination and the associated uncertainties of the long-term (15-year) global mean sea level change using multiple altimeters, (3) the characterization of the sea level change by analyses of independent data, including tide gauges, sea surface temperature, and (4) the improvement coastal radar altimetry for studies including coastal ocean tide modeling and coastal circulation. Major accomplishments of the investigation include the development of techniques for low-cost radar altimeter absolute calibration (including the associated GPS-buoy technology), coastal ocean tide modeling, and the linking of multiple altimeter systems and the resulting determination of the 15-year (1985-1999) global mean sea level variations. The current rate of 15-year sea level rise observed by multiple satellite altimetry is +2.3 +/- 1.2 mm/yr, which is in general agreement with the analysis of sparsely distributed tide gauge measurements for the same data span, and represents the first such determination of sea level change in its kind.

Shum, C. K.↗