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At least 1,369 records · Page 76

Low secondary electron yield engineered surface for electron cloud mitigation

Secondary electron yield (SEY or δ) limits the performance of a number of devices. Particularly, in high-energy charged particle accelerators, the beam-induced electron multipacting is one of the main sources of electron cloud (e-cloud) build up on the beam path; in radio frequency wave guides, the electron multipacting limits their lifetime and causes power loss; and in detectors, the secondary electrons define the signal background and reduce the sensitivity. The best solution would be a material with a low SEY coating and for many applications δ < 1 would be sufficient. We report on an alternative surface preparation to the ones that are currently advocated. Three commonly used materials in accelerator vacuum chambers (stainless steel, copper, and aluminium) were laser processed to create a highly regular surface topography. It is shown that this treatment reduces the SEY of the copper, aluminium, and stainless steel from δ{sub max} of 1.90, 2.55, and 2.25 to 1.12, 1.45, and 1.12, respectively. The δ{sub max} further reduced to 0.76–0.78 for all three treated metals after bombardment with 500 eV electrons to a dose between 3.5 × 10{sup −3} and 2.0 × 10{sup −2} C·mm{sup −2}.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Growth of cluster assembled ZnO film by nanocluster beam deposition technique

ZnO is considered as one of the most promising material for optoelectronic devices. The present work emphasizes production of cluster assembled ZnO films by a UHV nanocluster beam deposition technique where the nanoclusters were produced in a laser vaporization cluster source. The microstructural and the optical properties of the ZnO nanocluster film deposited were investigated. As the wet chemical processes are not compatible with current solid state methods of device fabrication, therefore alternative UHV technique described in the paper is the need of the hour.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Improving constraints on inflation with CMB delensing

Abstract The delensing of cosmic microwave background (CMB) maps will be increasingly valuable for extracting as much information as possible from future CMB surveys. Delensing provides many general benefits, including sharpening of the acoustic peaks, more accurate recovery of the damping tail, and reduction of lensing-inducedB-mode power. In this paper we present several applications of delensing focused on testing theories of early-universe inflation with observations of the CMB. We find that delensing the CMB results in improved parameter constraints for reconstructing the spectrum of primordial curvature fluctuations, probing oscillatory features in the primordial curvature spectrum, measuring the spatial curvature of the universe, and constraining several different models of isocurvature perturbations. In some cases we find that delensing can recover almost all of the constraining power contained in unlensed spectra, and it will be a particularly valuable analysis technique to achieve further improvements in constraints for model parameters whose measurements are not expected to improve significantly when utilizing only lensed CMB maps from next-generation CMB surveys. We also quantify the prospects of testing the single-field inflation tensor consistency condition using delensed CMB data; we find it to be out of reach of current and proposed experimental technology and advocate for alternative detection methods.

Astronomy & Astrophysics↗

Development of Lattice-Mismatched GaInAsP for Radiation Hardness

We develop lattice-mismatched GaInAsP as an alternative alloy to pure As-based alloys currently used in III-V multijunction solar cells. Increasing the alloy phosphorous and indium content while maintaining an optimal bandgap may allow high efficiency multijunction devices with increased radiation hardness. Here, 1.0-eV GaInAsP is developed and implemented into single and multijunction solar cell devices. The lattice-mismatched GaInAsP must be grown strain free, and the subcell thickness must be maintained below the thickness where surface-driven phase separation occurs. As observed in transmission electron microscopy and cathodoluminescence imaging, phase separation strengthens in the GaInAsP layer and leads to interfacial defect formation when the cell thickness is too great. We show single junction 1.0-eV Ga 0.5 In 0.5 As 0.7 P 0.3 with excellent carrier collection and a bandgap-voltage offset of 0.40 V. This material quality approaches that of 1.0-eV Ga 0.7 In 0.3 As used in inverted metamorphic multijunction devices, but has increased phosphorus content and consequently is expected to have a higher radiation resistance. We incorporate the 1.0-eV GaInAsP subcell into a 3-junction inverted metamorphic solar cell to test the performance of the subcell in a multijunction. No additional loss is observed upon integration into a multijunction cell: both the carrier collection and voltage of the GaInAsP subcell are unchanged from single junction devices. While further materials development and radiation testing is still required, these preliminary results indicate that lattice-mismatched GaInAsP can be effectively used in multijunction solar cells to replace radiation-soft materials.

14 SOLAR ENERGY↗

Controllable Reset Behavior in Domain Wall–Magnetic Tunnel Junction Artificial Neurons for Task-Adaptable Computation

Neuromorphic computing with spintronic devices has been of interest due to the limitations of CMOS-driven von Neumann computing. Domain wall–magnetic tunnel junction (DW-MTJ) devices have been shown to be able to intrinsically capture biological neuron behavior. Edgy-relaxed behavior, where a frequently firing neuron experiences a lower action potential threshold, may provide additional artificial neuronal functionality when executing repeated tasks. In this letter, we demonstrate that this behavior can be implemented in DW-MTJ artificial neurons via three alternative mechanisms: shape anisotropy, magnetic field, and current-driven soft reset. Using micromagnetics and analytical device modeling to classify the Optdigits handwritten digit dataset, we show that edgy-relaxed behavior improves both classification accuracy and classification rate for ordered datasets while sacrificing little to no accuracy for a randomized dataset. This letter establishes methods by which artificial spintronic neurons can be flexibly adapted to datasets.

42 ENGINEERING↗

Neutrons against cancer

The review is devoted to the analysis and generalization of the research carried out during recent years in industrially advanced countries on the use of fast, epithermal, and thermal neutrons for therapy of malignant tumors. Basic facilities for neutron production used for cancer treatment are presented. Optimal parameters of therapeutic beams are described. Techniques using neutrons of different energy regions are discussed. Results: and medical treatment efficiency are given. Comparison of the current state of neutron therapy of tumors and alternative treatments with beams of protons and carbon ions has been conducted. Main attention is given to the possibility of the practical use of accumulated experience of application of neutron beams for cancer therapy.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Combinatorial DNA Damage Pairing Model Based on X-Ray-Induced Foci Predicts the Dose and LET Dependence of Cell Death in Human Breast Cells

In contrast to the classic view of static DNA double-strand breaks (DSBs) being repaired at the site of damage, we hypothesize that DSBs move and merge with each other over large distances (m). As X-ray dose increases, the probability of having DSB clusters increases as does the probability of misrepair and cell death. Experimental work characterizing the X-ray dose dependence of radiation-induced foci (RIF) in nonmalignant human mammary epithelial cells (MCF10A) is used here to validate a DSB clustering model. We then use the principles of the local effect model (LEM) to predict the yield of DSBs at the submicron level. Two mechanisms for DSB clustering, namely random coalescence of DSBs versus active movement of DSBs into repair domains are compared and tested. Simulations that best predicted both RIF dose dependence and cell survival after X-ray irradiation favored the repair domain hypothesis, suggesting the nucleus is divided into an array of regularly spaced repair domains of ~;;1.55 m sides. Applying the same approach to high-linear energy transfer (LET) ion tracks, we are able to predict experimental RIF/m along tracks with an overall relative error of 12percent, for LET ranging between 30 350 keV/m and for three different ions. Finally, cell death was predicted by assuming an exponential dependence on the total number of DSBs and of all possible combinations of paired DSBs within each simulated RIF. Relative biological effectiveness (RBE) predictions for cell survival of MCF10A exposed to high-LET showed an LET dependence that matches previous experimental results for similar cell types. Overall, this work suggests that microdosimetric properties of ion tracks at the submicron level are sufficient to explain both RIF data and survival curves for any LET, similarly to the LEM assumption. Conversely, high-LET death mechanism does not have to infer linear-quadratic dose formalism as done in the LEM. In addition, the size of repair domains derived in our model are based on experimental RIF and are three times larger than the hypothetical LEM voxel used to fit survival curves. Our model is therefore an alternative to previous approaches that provides a testable biological mechanism (i.e., RIF). In addition, we propose that DSB pairing will help develop more accurate alternatives to the linear cancer risk model (LNT) currently used for regulating exposure to very low levels of ionizing radiation.

59 BASIC BIOLOGICAL SCIENCES↗

Assessment of the Impact of a New Guanidine Suppressor In NGS on F/H Laboratory Analyses For DWPF and Saltstone MCU Transfers

Implementation of the Next Generation Solvent (NGS) in the Modular Caustic-Side Solvent Extraction Unit (MCU) will now proceed with a new suppressor compound, 1,2,3-tris(3,7-dimethyloctyl)guanidine (TiDG), replacing the originally planned suppressor for NGS, 1,3-dicyclohexyl-2-(11-methyldodecyl) guanidine (DCiTG). The Savannah River National Laboratory (SRNL) was tasked with evaluating the potential impact to F/H Laboratory analyses supporting the Defense Waste Processing Facility (DWPF) Waste Acceptance Criteria (WAC) used to qualify transfers of MCU Strip Effluent (SE) into the facility and the Saltstone WAC used to qualify transfers of Tank 50 containing Decontaminated Salt Solution (DSS) from MCU into Saltstone. This assigned scope is covered by a Task Technical and Quality Assurance Plan (TTQAP). Previous impact evaluations were conducted when the DCiTG suppressor was planned for NGS and concluded that there was no impact to either the determination of MCU SE pH nor the analysis of Isopar ® L carryover in the MCU SE and DSS streams. SRNL reported on this series of cross-check studies between the SRNL and F/H Laboratories. The change in suppressor from DCiTG to TiDG in the NGS should not impact the measurement of Isopar ® L or pH in SE or DSS necessary to satisfy DWPF and Saltstone WAC (Tank 50) criteria, respectively. A statistical study of the low bias observed in Isopar ® L measurements in both SRNL and F/H Laboratories may be necessary now that the final NGS composition is fixed in order to quantify the low bias so that a proper correction can be applied to measurements critical to the DWPF and Saltstone WACs. Depending upon the final DWPF WAC requirement put in place for SE pH, it could become necessary to implement an alternative ICP-AES measurement of boron. The current blended solvent system testing in SRNL should address any impacts to Isopar ® L carryover into either the DSS or the SE. It is recommended that SRNL monitor the current blended solvent work underway with simulants in SRNL as well as any DWPF CPC testing done with the new SE stream to ascertain whether any need develops that could result in modification of any currently planned F/H Laboratory testing protocols.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Streak camera meeting summary

Streak cameras are important for high-speed data acquisition in single event experiments, where the total recorded information (I) is shared between the number of measurements (M) and the number of samples (S). Topics of this meeting included: streak camera use at the national laboratories; current streak camera production; new tube developments and alternative technologies; and future planning. Each topic is summarized in the following sections.

47 OTHER INSTRUMENTATION↗

Scattering Solar Thermal Concentrators

This program set out to explore a scattering-based approach to concentrate sunlight with the aim of improving collector field reliability and of eliminating wind loading and gross mechanical movement through the use of a stationary collection optic. The approach is based on scattering sunlight from the focal point of a fixed collection optic into the confined modes of a sliding planar waveguide, where it is transported to stationary tubular heat transfer elements located at the edges. Optical design for the first stage of solar concentration, which entails focusing sunlight within a plane over a wide range of incidence angles (>120 degree full field of view) at fixed tilt, led to the development of a new, folded-path collection optic that dramatically out-performs the current state-of-the-art in scattering concentration. Rigorous optical simulation and experimental testing of this collection optic have validated its performance. In the course of this work, we also identified an opportunity for concentrating photovoltaics involving the use of high efficiency microcells made in collaboration with partners at the University of Illinois. This opportunity exploited the same collection optic design as used for the scattering solar thermal concentrator and was therefore pursued in parallel. This system was experimentally demonstrated to achieve >200x optical concentration with >70% optical efficiency over a full day by tracking with <1 cm of lateral movement at fixed latitude tilt. The entire scattering concentrator waveguide optical system has been simulated, tested, and assembled at small scale to verify ray tracing models. These models were subsequently used to predict the full system optical performance at larger, deployment scale ranging up to >1 meter aperture width. Simulations at an aperture widths less than approximately 0.5 m with geometric gains ~100x predict an overall optical efficiency in the range 60-70% for angles up to 50 degrees from normal. However, the concentrator optical efficiency was found to decrease significantly with increasing aperture width beyond 0.5 m due to parasitic waveguide out-coupling loss and low-level absorption that become dominant at larger scale. A heat transfer model was subsequently implemented to predict collector fluid heat gain and outlet temperature as a function of flow rate using the optical model as a flux input. It was found that the aperture width size limitation imposed by the optical efficiency characteristics of the waveguide limits the absolute optical power delivered to the heat transfer element per unit length. As compared to state-of-the-art parabolic trough CPV system aperture widths approaching 5 m, this limitation leads to an approximate factor of order of magnitude increase in heat transfer tube length to achieve the same heat transfer fluid outlet temperature. The conclusion of this work is that scattering solar thermal concentration cannot be implemented at the scale and efficiency required to compete with the performance of current parabolic trough CSP systems. Applied within the alternate context of CPV, however, the results of this work have likely opened up a transformative new path that enables quasi-static, high efficiency CPV to be implemented on rooftops in the form factor of traditional fixed-panel photovoltaics.

14 SOLAR ENERGY↗

Investigations into Alternative Desorption Agents for Amidoxime-Based Polymeric Uranium Adsorbents

Amidoxime-based polymeric braid adsorbents that can extract uranium (U) from seawater are being developed to provide a sustainable supply of fuel for nuclear reactors. A critical step in the development of the technology is to develop elution procedures to selectively remove U from the adsorbents and to do so in a manner that allows the adsorbent material to be reused. This study investigates use of high concentrations of bicarbonate along with targeted chelating agents as an alternative means to the mild acid elution procedures currently in use for selectively eluting uranium from amidoxime-based polymeric adsorbents.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

NEK5000 Assessment Milestone Report: Single-Phase Natural Circulation using Direct Numerical Simulation (DNS) & Large Eddy Simulation (LES) Methods

This study evaluates the capabilities of the NEK5000 open-source code as an alternative to the commercially available software that is currently heavily relied upon. The first three case studies initiated the author with (1) the syntax and flow of the program, (2) varying initial and boundary conditions and (3) geometries of greater complexity & dimension. Case 1 studies transient conjugate heat transfer in the entry region of a pipe. Cases 2 & 3 simulate the natural convection flow in an enclosed differentially heated cavity (DHC) of two and three dimensions, respectively. The final case study, Case 4, produces three-dimensional single-phase natural convective flow using the Boussinesq approximation within a simplified representation of an aqueous homogeneous reactor system. The Boussinesq flow in Case 4 clearly depicts both Rayleigh-Taylor and Kelvin-Helmholtz instabilities qualitatively during post-processing analysis. Further analysis of Case 4, up to the point of a quasi-steady state (i.e. thermal-equilibrium condition), is done using the LES solver method in NEK5000. The volume-averaged solution temperatures, when compared between solvers, showed no significant difference. Due to its minimal compromise in fidelity of solution resolution and inexpensive computing cost, compared to the DNS solver, the LES solver is recommended for the current application. Methodology development for the four case studies are reported and a preliminary optimization study with different polynomial resolutions for Case 4 is addressed as a resource when performing future simulations using NEK5000. Hence, this report can be used as a reference starting point to the end user of NEK5000 for natural circulation phenomena in nuclear reactor safety applications.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Enabling a Flexible Grid with Increased Penetration of DER: Techno-economic Analysis of Metal Hydride Thermochemical Energy Storage Integrated with Stirling Engine for Grid Energy Storage Applications

This report summarizes the results of a techno-economic assessment of the capital and operational expenses for 3 scenarios utilizing a TES/Stirling engine system which is charged by an electric heater to provide grid power and energy storage. While there are several integration possibilities and material choices that could be utilized in such systems, three difference scenarios were chosen for this assessment to reflect an anticipated deployment of the technology where each might require different TES system configurations. Additionally, an enhanced version of the HTMH is considered to demonstrate the expected impact on costs with further technology development. The predicted capital and operational LCOS for the system configurations range from $0.0198/kWhr e - $0.0734/kWhr e which compare positively to the LCOS for lithium ion battery storage ranging from $0.087/kWhr e – $0.329/kWhr e . The key drivers for cost improvements to the system are material property enhancements in the HTMH primarily related to reducing the costs associated with the HTMH vessel and heat exchangers. This analysis demonstrates the potential benefits and flexibility of integrating a Stirling engine with a metal hydride-based TES system and suggests that the MH TES technology, at its current level of development, provides a highly competitive alternative to lithium ion batteries for large scale grid energy storage applications.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Interfaces in Halide Perovskites: Passivating Defects and Probing Grain Structure

In this talk we describe the role of interfaces, surface defects, and strain on non-radiative recombination losses in hybrid perovskite semiconductors. Using combinations of scanning-probe, electron backscatter diffraction (EBSD), and time-resolved photoluminescence microscopy and spectroscopy, we explore the microscopic origins of non-radiative recombination in both archetypal methylammonium lead tri-iodide (MAPI), and more advanced mixed-cation perovskites. Using EBSD, we image local grain orientation and strain, and correlate surface strain with increased non-radiative recombination in MAPI. We explore the interface between the perovskite and various common charge extraction layers, combining experiment and simulation to show that surface recombination at the charge extraction layers is a limitation in current perovskite solar cell architectures. Finally, we explore alternative passivation and extraction layers to propose ways to more routinely approach the theoretical voltage limits in perovskite photovoltaic using scalable process chemistry.

14 SOLAR ENERGY↗

Allosteric control of electron transfer in nitrogenase and nitrogenase-like enzymes (Final Report)

More than a third of all known proteins to date are either oxidoreductases or metalloproteins. The diversity of metal cofactors and redox centers in these proteins make them attractive candidates for engineering protein-based biocatalysts, biosensors, and biofuel cells, among other necessary tools for the bioeconomy. Many of these enzymes function as large multi-subunit complexes arranged as symmetric or asymmetric assemblies, and the purpose of this architecture is unclear. The goal of the project was to address this fundamental question by investigating the mechanism of action of two oxidoreductases: Nitrogenase and DPOR (Dark-Operative Protochlorophyllide Oxidoreductase, a nitrogenase-like oxidoreductase). Nitrogenase and DPOR play key roles in nitrogen fixation and photosynthesis, processes essential to sustaining life. Both proteins are arranged as two symmetrical halves with each half capable of substrate reduction. For more than half a century, substrate reduction by nitrogenase has been presumed to occur independently within the two identical halves. Funded by this DOE grant we have now shown that both nitrogenase and DPOR function asymmetrically. Electron transfer in one half suppresses activity in the other. Thus, we have demonstrated that the two halves do not function in an independent manner; rather, catalytic events in one-half allosterically suppress activity and electron transfer (ET) in the other. This alternating-site mechanism has significant implications on our current understanding of substrate reduction by these enzymes and offers a new mechanistic paradigm for the reactions they catalyze. Our work now provides a mechanistic map of the how the two symmetric catalytic halves work together to establish and maintain the sequential-site mechanism through multiple ET cycles to achieve substrate reduction. There is substantive need for bio-inspired tools that enable reduction of nitrogen and other substrates, as well as photosynthesis, for energy and food production. Understanding the workings of enzymes like nitrogenase and DPOR that mediate multi-electron redox chemistry is vital for designing such synthetic tools. The timing of our research coincides with the biotechnological breakthrough of light-driven artificial N2 reduction by nitrogenase, achieved using the native enzyme with both halves arranged in a mirror-like architecture as catalyst. Together with such discoveries, our research now reveal unknown facets of the reaction mechanism and hold promise for designing more effective catalysts.

59 BASIC BIOLOGICAL SCIENCES↗

Muckleshoot Indian Tribe-Energy Deployment (MITED) Project

The Muckleshoot Indian Tribe (MIT) collaborated with our Project Partner, GRID Alternatives (GRID), to install 132 kilowatts of direct current (kW-DC) of rooftop solar on three Tribal facilities. The three facilities are the Tribe’s Youth Drop-In Center, Canoe Shed, and Water Treatment Facility. The solar PV systems were originally anticipated to offset approximately 45% of the aggregate annual electricity usage of the three buildings. A major aspect of the MIT-ED project was providing hands-on paid training to five Muckleshoot Building Maintenance workers in solar PV installations, operations, and maintenance. The scope of work aligns with the Tribe’s goals of building local capacity and providing real world work experience and potential career opportunities in solar PV to its citizens. The Building Maintenance Department committed five of its current FTE employees to the project. GRID provided guidance for the MIT project team on identifying paid trainees as well as end goals of skill development through training, including a long-term Operations and Maintenance (O&M) plan tailored to the Tribe’s goals of local capacity building and stewardship of natural resources.

14 SOLAR ENERGY↗

An overview of NASA research on positive displacement type general aviation engines

The paper surveys the current status of the aviation positive displacement engine programs underway at the NASA Lewis Research Center. The program encompasses conventional, lightweight diesel, and rotary combustion engines. Attention is given to topics such as current production type engine improvement, cooling drag reduction, fuel injection, and experimental and theoretical combustion studies. It is shown that the program's two major technical thrusts are directed toward lean operation of current production type spark ignition engines and advanced alternative engine concepts. Finally, an Otto cycle computer model is also covered.

Kempke, E. E.↗