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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,369 records · Page 76
All sourcesNASA NTRSDOE OSTI
NASA NTRS2015

An Assessment of Antarctic Circumpolar Current and Southern Ocean Meridional Overturning Circulation During 1958-2007 in a Suite of Interannual CORE-2 Simulations

In the framework of the second phase of the Coordinated Ocean-ice Reference Experiments (CORE-II), we present an analysis of the representation of the Antarctic Circumpolar Current (ACC) and Southern Ocean Meridional Overturning Circulation (MOC) in a suite of seventeen global ocean-sea ice models. We focus on the mean, variability and trends of both the ACC and MOC over the 19582007 period, and discuss their relationship with the surface forcing. We aim to quantify the degree of eddy saturation and eddy compensation in the models participating in CORE-II, and compare our results with available observations, previous fine-resolution numerical studies and theoretical constraints. Most models show weak ACC transport sensitivity to changes in forcing during the past five decades, and they can be considered to be in an eddy saturated regime. Larger contrasts arise when considering MOC trends, with a majority of models exhibiting significant strengthening of the MOC during the late 20th and early 21st century. Only a few models show a relatively small sensitivity to forcing changes, responding with an intensified eddy-induced circulation that provides some degree of eddy compensation, while still showing considerable decadal trends. Both ACC and MOC interannual variability are largely controlled by the Southern Annular Mode (SAM). Based on these results, models are clustered into two groups. Models with constant or two-dimensional (horizontal) specification of the eddy-induced advection coefficient show larger ocean interior decadal trends, larger ACC transport decadal trends and no eddy compensation in the MOC. Eddy-permitting models or models with a three-dimensional time varying show smaller changes in isopycnal slopes and associated ACC trends, and partial eddy compensation. As previously argued, a constant in time or space is responsible for a poor representation of mesoscale eddy effects and cannot properly simulate the sensitivity of the ACC and MOC to changing surface forcing. Evidence is given for a larger sensitivity of the MOC as compared to the ACC transport, even when approaching eddy saturation. Future process studies designed for disentangling the role of momentum and buoyancy forcing in driving the ACC and MOC are proposed.

Southern Ocean dynamics↗
DOE OSTI2014

Soil temperature, soil moisture and thaw depth, Utqiagvik (Barrow), Alaska, Ver. 1

This dataset consists of field measurements of soil properties made during 2012 and 2013 in areas A to D of Intensive Site 1 at the Next-Generation Ecosystem Experiments (NGEE) Arctic site near Utqiagvik (Barrow), Alaska. Included are i) weekly measurements of thaw depth, soil moisture, presence and depth of standing water and soil temperature made during the 2012 and 2013 growing seasons (June to September) and ii) half-hourly measurements of soil temperature logged continuously during the period June 2012 to September 2013. There are a total of 47 files in this dataset. Some data were originally provided in Excel workbooks, these files have been preserved as XLSX files within the zip "Original_Files" and also separated by plot ID, year, and/or depth into CSV files. Some functions, features, and formatting were lost during the transformation. Regarding "additional temperature" CSVs, data curators made their best attempt to label plot titles and measurements in those files. Additional documentation and information can be found in file(s) labelled as BEO_soil_properties_user_file.pdf.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research.The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska.Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Soil CO2 and CH4 Chamber Fluxes in Tussock Tundra, Council Road Mile Marker 71, Seward Peninsula, Alaska, 2016-2019

In August-September 2016, June-August 2017, June-August 2018, and June 2019, co-located measurements were made of surface CH4 and CO2 flux, soil temperature, moisture, and thaw depth. Measurements were made at 35 chamber locations at the Council Mile Marker 71 Site (CN_MM71) on the Seward Peninsula, Alaska. Chamber locations include upland moist acidic tussock tundra, thermo-erosional slopes, and periodically inundated lowland water channels. The dataset includes three *.csv data files with measurements using transparent and opaque chambers (CO2 and CH4 fluxes in light and dark) plus one *.pdf user guide.The Next-Generation Ecosystem Experiments: Arctic (NGEE Arctic), was a research effort to reduce uncertainty in Earth System Models by developing a predictive understanding of carbon-rich Arctic ecosystems and feedbacks to climate. NGEE Arctic was supported by the Department of Energy's Office of Biological and Environmental Research. The NGEE Arctic project had two field research sites: 1) located within the Arctic polygonal tundra coastal region on the Barrow Environmental Observatory (BEO) and the North Slope near Utqiagvik (Barrow), Alaska and 2) multiple areas on the discontinuous permafrost region of the Seward Peninsula north of Nome, Alaska. Through observations, experiments, and synthesis with existing datasets, NGEE Arctic provided an enhanced knowledge base for multi-scale modeling and contributed to improved process representation at global pan-Arctic scales within the Department of Energy's Earth system Model (the Energy Exascale Earth System Model, or E3SM), and specifically within the E3SM Land Model component (ELM).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2016

A radiation closure study of Arctic stratus cloud microphysical properties using the collocated satellite-surface data and Fu-Liou radiative transfer model

Retrievals of cloud microphysical properties based on passive satellite imagery are especially difficult over snow-covered surfaces because of the bright and cold surface. To help quantify their uncertainties, single-layered overcast liquid-phase Arctic stratus cloud microphysical properties retrieved by using the Clouds and the Earth's Radiant Energy System Edition 2 and Edition 4 (CERES Ed2 and Ed4) algorithms are compared with ground-based retrievals at the Atmospheric Radiation Measurement North Slope of Alaska (ARM NSA) site at Barrow, AK, during the period from March 2000 to December 2006. A total of 206 and 140 snow-free cases (Rsfc ≤ 0.3), and 108 and 106 snow cases (R sfc > 0.3), respectively, were selected from Terra and Aqua satellite passes over the ARM NSA site. The CERES Ed4 and Ed2 optical depth (τ) and liquid water path (LWP) retrievals from both Terra and Aqua are almost identical and have excellent agreement with ARM retrievals under snow-free and snow conditions. In order to reach a radiation closure study for both the surface and top of atmosphere (TOA) radiation budgets, the ARM precision spectral pyranometer-measured surface albedos were adjusted (63.6% and 80% of the ARM surface albedos for snow-free and snow cases, respectively) to account for the water and land components of the domain of 30 km × 30 km. Most of the radiative transfer model calculated SW↓ sfc and SW↑ TOA fluxes by using ARM and CERES cloud retrievals and the domain mean albedos as input agree with the ARM and CERES flux observations within 10 W m -2 for both snow-free and snow conditions. Sensitivity studies show that the ARM LWP and r e retrievals are less dependent on solar zenith angle (SZA), but all retrieved optical depths increase with SZA.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1995

Wind-Related Features and Processes on Venus Summary of Magellan Results

A search of Magellan synthetic aperture radar images covering about 98% of the venusian surface shows that aeolian features occur at all longitudes and latitudes. A global data base for wind streaks, the most common type of aeolian feature, was developed. For each of the 5970 streaks in the data base, information was compiled on location, streak type, radar backscatter, dimensions, azimuth, orientation with respect to local slope, and type of landform with which it is associated. In addition, streaks occurring in association with parabolic ejecta deposits were designated type P streaks, which constitute about 31% of the data base. Wind streak azimuths were analyzed to assess wind patterns at the time of their formation. Both hemispheres show strong westward and equatorward trends in azimuths, consistent with Hadley circulation and inferred upper atmospheric westward zonal winds. When type P streaks (those considered to result from transient impact events) were removed, the westward component was greatly reduced, suggesting that the upper zonal winds do not extend to the surface. The presence of equator-oriented streaks at high latitudes suggests that Hadley circulation extends to the poles. A field of possible yardangs found southwest of Mead Crater strikes NE-SW and occupies plains situated in a shallow topographic depression. Analysis of non-type P streaks in the area suggests that equatorward winds are funneled through the depression and are responsible for the erosion of the terrain to form the yardangs. Dune deposits are limited on Venus. Two dune fields were identified (Aglonice and Fortuna-Meshkenet) which total in area about 18,300 square km. Microdunes are proposed for some southern hemisphere areas which show distinctive radar reflectivities. Bragg scattering and/or subpixel reflections from the leeward faces of microdune bedforms could account for the unusual radar backscatter cross sections.

Greeley, Ronald↗
NASA NTRS1995

Wind-Related Features and Processes on Venus: Summary of Magellan Results

A search of Magellan synthetic aperture radar images covering approximately 98% of the venusian surface shows that aeolian features occur at all longitudes and latitudes. A global data base for wind streaks, the most common type of aeolian feature, was developed. For each of the 5970 streaks in the data base, information was compiled on location, streak type, radar backscatter, dimensions, azimuth, orientation with respect to local slope, and type of landform with which it is associated. In addition, streaks occurring in association with parabolic ejecta deposits were designated type P streaks, which constitute about 31% of the data base. Wind streak azimuths were analyzed to assess wind patterns at the time of their formation. Both hemispheres show strong westward and equatorward trends in azimuths, consistent with Hadley circulation and inferred upper atmospheric westward zonal winds. When type P streaks (those considered to result from transient impact events) were removed, the westward component was greatly reduced, suggesting that the upper zonal winds do not extend to the surface. The presence of equator-oriented streaks at high latitudes suggests that Hadley circulation extends to the poles. A field of possible yardangs found southwest of Mead Crater strikes NE-SW and occupies plains situated in a shallow topographic depression. Analysis of non-type P streaks in the area suggests that equatorward winds are funneled through the depression and are responsible for the erosion of the terrain to form the yardangs. Dune deposits are limited on Venus. Two dune fields were identified (Aglonice and Fortuna-Meshkenet) which total in area about 18,300 sq km. Microdunes are proposed for some southern hemisphere areas which show distinctive radar reflectivities. Bragg scattering and/or subpixel reflections from the leeward faces of microdune bedforms could account for the unusual radar backscatter cross sections.

Greeley, Ronald↗
DOE OSTI2018

Publisher Correction: High power surface emitting terahertz laser with hybrid second- and fourth-order Bragg gratings

A surface-emitting distributed feedback (DFB) laser with second-order gratings typically excites an antisymmetric mode that has low radiative efficiency and a double-lobed far-field beam. The radiative efficiency could be increased by using curved and chirped gratings for infrared diode lasers, plasmon-assisted mode selection for mid-infrared quantum cascade lasers (QCLs), and graded photonic structures for terahertz QCLs. Here, we demonstrate a new hybrid grating scheme that uses a superposition of second and fourth-order Bragg gratings that excite a symmetric mode with much greater radiative efficiency. The scheme is implemented for terahertz QCLs with metallic waveguides. Peak power output of 70 mW with a slope-efficiency of 993 mW A -1 is detected with robust single-mode single-lobed emission for a 3.4 THz QCL operating at 62 K. The hybrid grating scheme is arguably simpler to implement than aforementioned DFB schemes and could be used to increase power output for surface-emitting DFB lasers at any wavelength.

Jin, Yuan↗
DOE OSTI2020

Full Concentration Gradient-Tailored Li-Rich Layered Oxides for High-Energy Lithium-Ion Batteries

Lithium-rich layered oxides (LLOs) are prospective cathode materials for next-generation lithium-ion batteries (LIBs), but severe voltage decay and energy attenuation with cycling still hinder their practical applications. In this study, a series of full concentration gradient-tailored agglomerated-sphere LLOs are designed with linearly decreasing Mn and linearly increasing Ni and Co from the particle center to the surface. The gradient-tailored LLOs exhibit noticeably reduced voltage decay, enhanced rate performance, improved cycle stability, and thermal stability. Without any material modifications or electrolyte optimizations, the gradient-tailored LLO with medium-slope shows the best electrochemical performance, with a very low average voltage decay of 0.8 mV per cycle as well as a capacity retention of 88.4% within 200 cycles at 200 mA g –1 . These excellent findings are due to spinel structure suppression, electrochemical stress optimization, and Jahn-Teller effect inhibition. Further investigation shows that the gradient-tailored LLO reduces the thermal release percentage by as much as about 41% when the battery is charged to 4.4 V. This study provides an effective method to suppress the voltage decay of LLOs for further practical utilization in LIBs and also puts forward a bulk-structure design strategy to prepare better electrode materials for different rechargeable batteries.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Unraveling the relationship between physicochemical properties of NiFeReOx catalysts and the correlated performance toward electrochemical oxygen evolution reaction

NiFeO x catalysts with single site Re dopants exhibit much higher active and stability toward electrochemical oxygen evolution reaction (OER) compared to traditional NiFeO x catalysts. Nevertheless, the relationship between physicochemical properties of NiFeReO x catalysts and the correlated performance toward OER is unclear, which hampers to enhance the OER performance further. Herein, we prepared a series of NiFeReO x catalysts with different physicochemical properties by treating them at different temperatures (up to 350 °C) and then evaluated their performance toward OER. Here, the results show that heat treatment can convert all metal oxidation states to higher values as well as specific surface areas, which are believed to favor real active site generation and OER activity enhancement. A decrease in activity is observed with the temperature increase at the low current range, and the smallest overpotential of 248 mV at 10 mA cm −2 is achieved with the pristine NiFeReO x catalyst. In contrast, the heat-treated samples possess smaller Tafel slopes and lower charge transfer resistance likely due to enhanced intrinsic activity (from higher oxidation states) and conductivity, which facilitate the reaction kinetics and surpass the pristine sample at a large current density. Additionally, the sample treated at 350 °C exhibits a higher activity at 1000 mA cm −2 (1.68 V vs. RHE compared to pristine sample of 1.92 V vs. RHE); however, it manifests a poorer stability compared to the pristine one due to the imbalance of reconstruction/transformations that occurred on the catalyst surface during OER operation. Our work unravels the relationship between physicochemical properties of NiFeReO x catalysts and the correlated OER performance and provides valuable insights for designing NiFeReO x catalysts with high activity and durability.

Catalyst reconstruction↗
DOE OSTI2018

Highly Graphitic Mesoporous Fe,N-Doped Carbon Materials for Oxygen Reduction Electrochemical Catalysts

The synthesis, characterization, and electrocatalytic properties of mesoporous carbon materials doped with nitrogen atoms and iron are reported and compared for the catalyzed reduction of oxygen gas at fuel cell cathodes. Mixtures of common and inexpensive organic precursors, melamine, and formaldehyde were pyrolyzed in the presence of transition-metal salts (e.g., nitrates) within a mesoporous silica template to yield mesoporous carbon materials with greater extents of graphitization than those of others prepared from small-molecule precursors. In particular, Fe,N-doped carbon materials possessed high surface areas (~800 m 2 /g) and high electrical conductivities (~19 S/cm), which make them attractive for electrocatalyst applications. The surface compositions of the mesoporous Fe,N-doped carbon materials were postsynthetically modified by acid washing and followed by high-temperature thermal treatments, which were shown by X-ray photoelectron spectroscopy to favor the formation of graphitic and pyridinic nitrogen moieties. Such surface-modified materials exhibited high electrocatalytic oxygen reduction activities under alkaline conditions, as established by their high onset and half-wave potentials (1.04 and 0.87 V, respectively vs reversible hydrogen electrode) and low Tafel slope (53 mV/decade). These values are superior to many similar transition-metal- and N-doped carbon materials and compare favorably with commercially available precious-metal catalysts, e.g., 20 wt % Pt supported on activated carbon. As a result, the analyses indicate that inexpensive mesoporous Fe,N-doped carbon materials are promising alternatives to precious metal-containing catalysts for electrochemical reduction of oxygen in polymer electrolyte fuel cells.

36 MATERIALS SCIENCE↗
NASA NTRS1976

Degradation of small mare surface features

Ring-moat structures are interpreted as remnants of flow topography associated with mare emplacement. Measurements of narrow moats characterizing these small mare features reveal a contradiction between their inferred preservation and the degree of surface degradation predicted by theoretical erosional models. Moat widths smaller than 50 m are recorded in areas where erosional models predict that walls of craters three to four times as large should be degraded to slopes of 1 deg. Crater statistics in such regions provide estimates of equilibrium conditions for impact crater formation that are consistent with the degree of preservation of the narrow moats. Although relative ages determined by observation of crater wall slopes near 20 deg, may be appropriate, it is concluded that current erosional models are not valid down to impact-degraded slopes of 1 deg. Relative age estimates based on the inferred degraded state of highly subdued craters are believed to be invalid, particularly for late Eratosthenian-age and Copernican-age mare units. In regions displaying ring-moat structures, highly subdued craters larger than the average moat widths are intepreted as either endogenic features associated with the emplacement of mare flow units or degraded secondary craters, which are typically subdued at the outset.

Schultz, P. H.↗
NASA NTRS1977

Ocean current surface measurement using dynamic elevations obtained by the GEOS-3 radar altimeter

Remote Sensing of the ocean surface from the GEOS-3 satellite using radar altimeter data has confirmed that the altimeter can detect the dynamic ocean topographic elevations relative to an equipotential surface, thus resulting in a reliable direct measurement of the ocean surface. Maps of the ocean dynamic topography calculated over a one month period and with 20 cm contour interval are prepared for the last half of 1975. The Gulf Stream is observed by the rapid slope change shown by the crowding of contours. Cold eddies associated with the current are seen as roughly circular depressions.

Leitao, C. D.↗
NASA NTRS1979

Magnetopause surface fluctuations observed by Voyager 1

Moving out of the dawnside of the earth's magnetosphere, Voyager 1 crossed the magnetopause apparently seven times, despite the high spacecraft speed of 11 km/sec. Normals to the magnetopause and their associated error cones were estimated for each of the crossings using a minimum variance analysis of the internal magnetic field. The oscillating nature of the ecliptic plane component of these normals indicates that most of the multiple crossings were due to a wave-like surface disturbance moving tailward along the magnetopause. The wave, which was aperiodic, was modeled as a sequence of sine waves. The amplitude, wavelength, and speed were determined for two pairs of intervals from the measured slopes, occurrence times, and relative positions of six magnetopause crossings. The magnetopause thickness was estimated to lie in the range 300 to 700 km with higher values possible. The estimated amplitude of these waves was obviously small compared to their wavelengths.

Lepping, R. P.↗
NASA NTRS1981

A program to evaluate a control system based on feedback of aerodynamic pressure differentials. Part 2: Data report for phase 1 wind tunnel test

Wind tunnel test data are presented. The purpose of the test was to determine the sensor location for sensitivity to flap deflection and to determine the range required of the sensor. The calculations followed to correct the raw pressure measurements, the corrected measurements, which represent the static pressures along the airfoil surface, and the static pressures tabulated and in coefficient form are described. However, the chordwise locations of the upper and lower surface taps do not coincide. An interpolation routine is performed to find the lower surface pressure coefficients at the upper surface tap locations. The difference, C sub P(lower) - C sub P(upper), is calculated and listed and the data are reorganized with respect to each tap location. A numerical regression performed to quantify the slopes of the graphs allows more accurate comparison of sensitivity and linearity.

Hrabak, R. R.↗
NASA NTRS1982

A feedback model for the source of auroral kilometric radiation

It is noted that in order to compensate for the wave refraction inside the source, the boundary reflection surfaces must converge with altitude, and this implies that the most likely auroral kilometric radiation source would be a thin, local density enhancement, since the refractive index contours at its boundaries would be expected to slope inward. The ISEE observations of multiple spectral components, which are attributed to separate oscillations at different altitudes in the same enhancement, indicate a source thickness as small as 25 km and an internal wave growth threshold of roughly 40 dB, rather than the 70-120 dB previously believed necessary to account for auroral kilometric radiation without feedback. What is considered more significant is that the feedback model accounts for numerous aspects of the auroral kilometric radiation behavior, predicts emission at the wave growth saturation level, and leads to the conclusion that auroral kilometric radiation originates at many compact sites, each emitting a nearly monochromatic wave.

Calvert, W.↗
NASA NTRS2016

Nitrogen Dioxide Observations from the Geostationary Trace Gas and Aerosol Sensor Optimization (GeoTaso) Airborne Instrument: Retrieval Algorithm and Measurements During DISCOVER-AQ Texas 2013

The Geostationary Trace gas and Aerosol Sensor Optimization (GeoTASO) airborne instrument is a test bed for upcoming air quality satellite instruments that will measure backscattered ultraviolet, visible and near-infrared light from geostationary orbit. GeoTASO flew on the NASA Falcon aircraft in its first intensive field measurement campaign during the Deriving Information on Surface Conditions from Column and Vertically Resolved Observations Relevant to Air Quality (DISCOVER-AQ) Earth Venture Mission over Houston, Texas, in September 2013. Measurements of backscattered solar radiation between 420 and 465 nm collected on 4 days during the campaign are used to determine slant column amounts of NO2 at 250 m x 250 m spatial resolution with a fitting precision of 2.2 x 10(exp 15) molecules/sq cm. These slant columns are converted to tropospheric NO2 vertical columns using a radiative transfer model and trace gas profiles from the Community Multiscale Air Quality (CMAQ) model. Total column NO2 from GeoTASO is well correlated with ground-based Pandora observations (r = 0.90 on the most polluted and cloud-free day of measurements and r = 0.74 overall), with GeoTASO NO2 slightly higher for the most polluted observations. Surface NO2 mixing ratios inferred from GeoTASO using the CMAQ model show good correlation with NO2 measured in situ at the surface during the campaign (r = 0.85). NO2 slant columns from GeoTASO also agree well with preliminary retrievals from the GEO-CAPE Airborne Simulator (GCAS) which flew on the NASA King Air B200 (r = 0.81, slope = 0.91). Enhanced NO2 is resolvable over areas of traffic NOx emissions and near individual petrochemical facilities.

Aerosol Sensor Optimization↗
DOE OSTI2018

High power surface emitting terahertz laser with hybrid second- and fourth-order Bragg gratings

A surface-emitting distributed feedback (DFB) laser with second-order gratings typically excites an antisymmetric mode that has low radiative efficiency and a double-lobed far-field beam. The radiative efficiency could be increased by using curved and chirped gratings for infrared diode lasers, plasmon-assisted mode selection for mid-infrared quantum cascade lasers (QCLs), and graded photonic structures for terahertz QCLs. Here, we demonstrate a new hybrid grating scheme that uses a superposition of second and fourth-order Bragg gratings that excite a symmetric mode with much greater radiative efficiency. The scheme is implemented for terahertz QCLs with metallic waveguides. Peak power output of 170 mW with a slope-efficiency of 993 mW A -1 is detected with robust single-mode single-lobed emission for a 3.4 THz QCL operating at 62 K. Finally, the hybrid grating scheme is arguably simpler to implement than aforementioned DFB schemes and could be used to increase power output for surface-emitting DFB lasers at any wavelength.

36 MATERIALS SCIENCE↗
DOE OSTI2014

In situ anodization of aluminum surfaces studied by x-ray reflectivity and electrochemical impedance spectroscopy

We present results from the anodization of an aluminum single crystal [Al(111)] and an aluminum alloy [Al 6060] studied by in situ x-ray reflectivity, in situ electrochemical impedance spectroscopy and ex situ scanning electron microscopy. For both samples, a linear increase of oxide film thickness with increasing anodization voltage was found. However, the slope is much higher in the single crystal case, and the break-up of the oxide film grown on the alloy occurs at a lower anodization potential than on the single crystal. The reasons for these observations are discussed as are the measured differences observed for x-ray reflectivity and electrochemical impedance spectroscopy.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗