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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,369 records · Page 76
All sourcesNASA NTRSDOE OSTI
NASA NTRS1973

Mechanical Attachment of Reusable Surface Insulation to Space Shuttle Primary Structure

Three methods of attaching surface insulation tiles to shuttle primary structure have been proposed: direct bond, mechanical attachment, and subpanels with standoffs. The direct bond approach is lightweight but is difficult to refurbish and inspect. The subpanel approach is heavier but allows for easy refurbishment since subpanels are easily removed and replaced. The mechanical attachment approach allows easy refurbishment and inspection and is lightweight when an efficient insulator is used between surface insulation tiles and primary structure.

Fleck, R. W.↗
DOE OSTI2016

Laser structuring of the diamond surface in the nanoablation regime

The possibility of using nanoablation (graphitisation-free photoinduced etching) for precise micro- and nanostructuring of the surface of a diamond single crystal has been experimentally investigated. The processing has been performed by femtosecond third-harmonic pulses of a Ti : sapphire laser (λ=266 nm). The specific features of the formation of a surface nanorelief (regularity of the newly formed structures and reduced nanoablation rate near craters) are discussed. The possibility of fabricating a diamond phase diffraction grating with a relief depth of ∼130 nm is demonstrated and the diffraction pattern recorded at λ=532 nm is compared with the results of theoretical analysis. (paper)

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2025

Iridium Nanocrystals Enriched with Defects and Atomic Steps to Enhance Oxygen Evolution Reaction Performance

The presence of defects can significantly improve catalytic activity and stability, as they influence the binding of the reactants, intermediates, and products to the catalyst. Controlling defects in the structures of nanocrystal catalysts is synthetically challenging. In this study, we demonstrate the ability to control the growth of Ir nanocrystals, enabling the tuning of both structural and surface defects. The Ir nanocrystals have unique structures that range from single crystals of a few nanometers to twinned nanoparticles and multiply twinned crystallites with a high density of atomic steps. Further, this approach of defect engineering enables us to understand their roles in enhancing the performance of the OER and producing an Ir catalyst with both high activity and stability. Our results show the importance of the concept of using synthetic control of structural and surface defects in metal nanoparticles as a strategy to improve catalytic performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2014

Structure of the near-surface layer of NiTi on the meso- and microscale levels after ion-beam surface treatment

Using the EBSD, SEM and TEM methods, the structure of surface layer of polycrystalline NiTi alloy samples was examined after the modification of material surface by the pulsed action of mean-energy silicon ion beam. It was found that the ion beam treatment would cause grain fragmentation of the near-surface layer to a depth 5÷50 μm; a higher extent of fragmentation was observed in grains whose close-packed planes were oriented approximately in the same direction as the ion beam was. The effect of high-intensity ion beam treatment on the anisotropic behavior of polycrystalline NiTi alloy and the mechanisms involved were also examined.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2026

Structured illumination for surface-resolved grazing-incidence X-ray scattering

Grazing-incidence (GI) scattering techniques are widely used to characterize thin films, offering high surface sensitivity and insight into morphology and structure. However, these approaches typically provide statistical averaged information due to elongated footprint or limited spatial resolution due to beam size. Here we introduce a method that combines structured illumination with GI X-ray scattering and leverages our computational imaging approach to resolve local structural details. We demonstrate that our method captures local features of an organic semiconductor thin film without the need for sample rotation as in tomography. The method expands GI techniques from statistical averaging to high-resolution imaging, thereby providing the capability for detailed analysis of local material properties, such as domain shape, orientation and polymorphism, which are critical for advancing material design towards more efficient and tailored materials.

97 MATHEMATICS AND COMPUTING↗
NASA NTRS1980

Surface flaw detection in structural ceramics by scanning photoacoustic spectroscopy

Laser-scanned photoacoustic spectroscopy has been used to detect tightly closed surface cracks in three structural ceramic materials: sintered silicon nitride, reaction-bonded silicon nitride, and sintered silicon carbide. It is found that the amplitude of the photoacoustic signal from the flaws is greater for the silicon nitrides than for silicon carbide, which is attributed to the lower thermal diffusivity of silicon nitride as well as differences in the grain size distribution and chemical composition. Signal amplitude, reproducibility, and signal-to-noise ratio are acceptable for effective flaw detection

Khandelwal, P. K.↗
DOE OSTI2023

Engineering Active Surface Oxygen Sites of Cubic Perovskite Cobalt Oxides toward Catalytic Oxidation Reactions

Unraveling the role of surface oxygen sites in transition metal oxides during catalytic reactions has always been the focus of environmental and energy chemistry research. For this work, active surface oxygen sites of cubic perovskite cobalt oxide were engineered to comprehend their crucial role and catalytic mechanism at the molecular level. By removing those inert Sr/La–O termination layers, active oxygen sites were exposed on the Co terminated surface of Sr 0.6 La 0.4 CoO 3–δ that furnished the dominant catalytic process of CO oxidation via the Mars–van Krevelen (MvK) mechanism. The fabrication of five-coordinate cobalt ions and the enhanced covalency of Co–O bonds not only optimize the surface electronic structure of Co 3d–O 2p, but also supply active surface oxygen sites, which effectively oxidizes CO to CO 2 with a significantly improved oxidation performance and stability as evidenced by soft/hard XAS, XPS, and O 2 -TPD. Furthermore, online isotopic 18 O 2 mass spectrometry, in situ DRIFTS, and theoretical simulation demonstrate that the activity of surface oxygen sites enhances the kinetics of the MvK reaction, while unsaturated coordination sites from five-coordinate cobalt ions primarily contribute to the activated oxygen molecules and the stable catalytic cycle. The results reported here provide a deep insight into the comprehension of the relationships among active oxygen sites, surface electronic structure, and the reaction mechanism of transition metal oxides necessary for catalytic oxidation reactions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2016

Spin-polarized surface resonances accompanying topological surface state formation

Topological insulators host spin-polarized surface states born out of the energetic inversion of bulk bands driven by the spin-orbit interaction. Here we discover previously unidentified consequences of band-inversion on the surface electronic structure of the topological insulator Bi 2 Se 3 . By performing simultaneous spin, time, and angle-resolved photoemission spectroscopy, we map the spin-polarized unoccupied electronic structure and identify a surface resonance which is distinct from the topological surface state, yet shares a similar spin-orbital texture with opposite orientation. Its momentum dependence and spin texture imply an intimate connection with the topological surface state. Calculations show these two distinct states can emerge from trivial Rashba-like states that change topology through the spin-orbit-induced band inversion. As a result, this work thus provides a compelling view of the coevolution of surface states through a topological phase transition, enabled by the unique capability of directly measuring the spin-polarized unoccupied band structure.

36 MATERIALS SCIENCE↗
NASA NTRS2007

Increased Alignment in Carbon Nanotube Growth

Method and system for fabricating an array of two or more carbon nanotube (CNT) structures on a coated substrate surface, the structures having substantially the same orientation with respect to a substrate surface. A single electrode, having an associated voltage source with a selected voltage, is connected to a substrate surface after the substrate is coated and before growth of the CNT structures, for a selected voltage application time interval. The CNT structures are then grown on a coated substrate surface with the desired orientation. Optionally, the electrode can be disconnected before the CNT structures are grown.

Delzeit, Lance D.↗
DOE OSTI2018

Distinct Turbulence Structures in Stably Stratified Boundary Layers With Weak and Strong Surface Shear

Turbulence structures and exchange of momentum and heat in the nocturnal stable boundary layer (SBL) show distinct features under different stability conditions prompting interest in their connection. Here eddy covariance data collected at four different heights on a 62-m meteorological tower over a large open flat terrain are used to characterize different SBL states and associated turbulence structures. In a SBL characterized by strong near-surface winds, turbulent eddy sizes scale with their observational heights and the SBL experiences enhanced turbulent mixing of momentum and heat throughout (a state hereafter referred to as a “coupled” state). Conversely, in a decoupled SBL, weak winds occur near the surface and turbulent eddies are depressed and detached from the boundary leading to suppressed vertical mixing and layered SBL profiles. Because the transport of momentum and heat to the surface across SBL layers is determined by turbulent eddies, cross-layer correlation and the aforementioned SBL coupling states can be delineated by distinct turbulence structures.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1993

(abstract) The SIR-C/X-SAR Mission

The Shuttle Imaging Radar-C and X-Band Synthetic Aperture Radar (SIR-C/X-SAR) is a cooperative experiment between the National Aeronautics and Space Administration (NASA), the German Space Agency (DARA), and the Italian Space Agency (ASI). The experiment is the next evolutionary step in NASA's Spaceborne Imaging Radar (SIR) program that began with the Seasat SAR in 1978, and continued with SAR -A in 1981 and SAR-B in 1984. The program will eventually lead to the Earth Observing System (EOS) SAR later in this decade. SIR-C will provide increased capability over Seasat, SIR-A, and SIR-B by acquiring polarimetric images simultaneously at two microwave frequencies: L-band (wavelength 24 cm) and C-band (wavelength 6 cm). X-SAR will operate at X-band (wavelength 3 cm) with VV polarization, resulting in a three-frequency capability. Because radar backscatter is most strongly influenced by objects comparable in size to the radar wavelength, this multifrequency capability will provide information about the Earth's surface over a wide range of scales not discernable with single-frequency experiments. The polarimetric data will yield quantitative information about the surface geometric structure, vegetation dielectric properties, and surface discontinuities. The first SIR-C/X-SAR flight is planned for early in 1994, with two subsequent flights in different seasons to enable data aquisition under different environmental conditions. SIR-C/X-SAR will collect data for a period of 6 to 9 days during each flight. The instrument will be flown in a 57(deg) inclination orbit with a nomimal orbit altitude of 215 km. This altitude will result in a slightly drifting orbit. The latest status of the SIR-C/X-SAR mission and instrument design, science activities, and expected results will be presented.

SIR-C/XSAR radar backscatter surface geometric str↗
DOE OSTI2019

Defect Formation under Nitrogen-Ion Implantation and Subsequent Annealing in GaAs Structures with an Uncovered Surface and a Surface Covered with an AlN Film

The concentration profiles of defects produced in structures upon the implantation of nitrogen ions into GaAs epitaxial layers with an uncovered surface and that covered with an AlN film and subsequent annealing are studied. The ion energies and the implantation doses are chosen so that the nitrogen-atom concentration profiles coincided in structures of both types. Rutherford proton backscattering spectra are measured in the random and channeling modes, and the concentration profiles of point defects formed are calculated for the samples under study. It is found that the implantation of nitrogen ions introduces nearly the same number of point defects into structures of both types, and the formation of an AlN film by ion-plasma sputtering is accompanied by the formation of an additional number of defects. However, the annealing of structures of both types leads to nearly the same concentrations of residual defects.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS1985

A cool anomaly off northern California - An investigation using IR imagery and in situ data

The OPTOMA (Ocean Prediction Through Observation, Modeling and Analysis) program is developing an ocean descriptive-predictive system for four-dimensional data assimilation. It is presently concerned with the mesoscale variability in the California Current System (CCS). The present paper has the objective to assess the relationship of surface temperature structure to subsurface temperature structure and flow fields. Surface temperature anomalies are related to the mesoscale horizontal advective and subsurface mass fields. The cool anomaly off northern California in summer 1982 is discussed, taking into account the temperature structure along transects, T-S variations and inferred water masses, variation of horizontal temperature patterns with depth, and synoptic information from IR data.

Rienecker, M. M.↗
DOE OSTI2014

Optimal packing size of non-ligated CdSe nanoclusters for microstructure synthesis

Structural and electrostatic properties of nanoclusters of CdSe of diameter 1–2 nm are studied with first principle calculations to determine the optimal size for synthesizing microstructures. Based on robustness of the core structure, i.e., the retention of tetrahedral geometry, hexagonal ring structure, and overall wu{sup ¨}rtzite structure to surface relaxations, we conclude that nanoclusters of ~2 nm diameter are the best candidates to form a dense microstructure with minimal interstitial space. Se-terminated surfaces retain a zigzag structure as Se atoms are pulled out and Cd atoms are pulled in due to relaxation, therefore, are best suited for inter-nanocluster formations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2021

Performance demonstration of vacuum microwave components critical for the operation of the ITER low-field side reflectometer

Final design studies in preparation for manufacturing have been performed for functional components of the vacuum portion of the ITER Low-Field Side Reflectometer (LFSR). These components consist of an antenna array, electron cyclotron heating (ECH) protection mirrors, phase calibration mirrors, and vacuum windows. Evaluation of these components was conducted at the LFSR test facility and DIII-D. The antenna array consists of six corrugated-waveguide antennas for simultaneous profile, fluctuation, and Doppler measurements. A diffraction grating, incorporated into the plasma-facing miter bend, provides protection of sensitive components from stray ECH at 170 GHz. For in situ phase calibration of the LFSR profile reflectometer, an embossed mirror is incorporated into the adjacent miter bend. Measurements of the radiated beam profile indicate that these components have a small, acceptable effect on mode conversion and beam quality. Baseline transmission characteristics of the dual-disk vacuum window are obtained and are used to guide ongoing developments. Preliminary simulations indicate that a surface-relief structure on the window surfaces can greatly improve transmission. The workability of real-time phase measurements was demonstrated on the DIII-D profile reflectometer. The new automated real-time analysis agrees well with the standard post-processing routine.

47 OTHER INSTRUMENTATION↗