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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

BER-Myriant Succinic Acid Biorefinery

Myriant Corporation (Myriant) has successfully produced the bioproduct succinic acid by the fermentation of glucose at a commercial scale operation in Lake Providence, Louisiana. The MySAB facility (Myriant Succinic Acid Biorefinery) came on stream in May 2013 and has been producing product since then. The MySAB facility is a demonstration-scale plant, capable of utilizing sorghum grits and commercially available dextrose, to ferment glucose into succinic acid. A downstream processing train has demonstrated the ability to produce an industrial, a standard and a polymer grade product. It consists of cell separation, membrane filtration, continuous chromatography, polishing to remove ionic and color bodies impurities, and final evaporation and crystallization. A by-product of the process is ammonium sulfate which is sold as a liquid fertilizer product. Since 2007 when development work began in the Woburn, Massachusetts R&D laboratories, the succinic acid bio-process has evolved through: Process development (microbiology, fermentation, and downstream) – R&D development laboratories; Piloting efforts at Fermic S.A. de C.V., Mexico City, Mexico – upstream and downstream processes; Design, construction, commissioning, and commercial production operations at the MySAB facility Additionally, Myriant became a wholly-owned subsidiary of the PTT Global Chemical Plc., Thailand, in late 2015, their investment into and support of Myriant goes back to 2011. The support of PTT Global Chemical Plc. helped to improve the upstream and downstream processes, and produce significant metric ton quantities of high quality bio-based succinic acid. The product has gone into a number of commercial markets worldwide for customer applications, development and production. The experience base gained via operations at the MySAB facility since May 2013, along with continued R&D development efforts involving Microbiology, Fermentation, and Downstream processes, at both the Woburn, Massachusetts and PTT Global Chemical Plc. Thailand laboratories, positions the company well for future production at the plant and commercialization of new bio-based products. This will be especially important and valuable as the green chemistry business climate continues to take root and flourish.

09 BIOMASS FUELS↗
DOE OSTI2016

Community Anaerobic Digester: Powered by Students and Driving Practical Applications

The Vermont Tech Community Anaerobic Digester (VTCAD) was conceived and funded by a partnership of educational, agricultural, waste management and environmental groups to create a living laboratory demonstrating the value of recycling nutrients, renewable energy and agricultural co-products from organic wastes. VTCAD was constructed on the Randolph Center, Vermont campus of Vermont Tech, a public college offering engineering technology, agricultural, renewable energy education and workforce training. With funding from the U.S. Department of Energy (DOE), the Vermont State Colleges and others, construction was completed in early 2014 and the facility has been operational since April 2014. At full power, VTCAD uses 16,000 gallons of manure and organic residuals to produce 8,880 kilowatt hours (kWh) of electricity per day, ‘waste’ heat that will be used to heat four campus buildings, bedding material for the college dairy herds and recycled nutrients used as crop fertilizer. VTCAD uses a mixture of manure from co-managed farms and organic residuals collected from the community. Feedstock materials include brewery residuals, the glycerol by-product of biodiesel production from waste cooking oil, grease trap waste, and waste paper and, soon, locally collected pre- and post-consumer food residuals.

09 BIOMASS FUELS↗
DOE OSTI2012

Alfalfa variety selection for maximum fiber content, protein and nitrogen fixation

The fertile soils of Southern Minnesota are highly productive from both a natural and agricultural standpoint. We chose to examine potential feedstock in both of these settings as a focus for our study. In part one of this report we detail our findings examining potential feedstock in prairie and wetlands in the Mankato, MN area in 2009. We were able to familiarize ourselves with techniques used to isolate and quantify concentrations of cellulose, hemicellulose and lignin in both a classroom and laboratory setting. These techniques were then used for our experiments that examined the effects of harvest regime, irrigation and salinity on eight potential-feedstock varieties of alfalfa (Medicago sativa).

09 BIOMASS FUELS↗
DOE OSTI2017

Endomembrane Cation Transporters and Membrane Trafficking

Multicellular, as well as unicellular, organisms have evolved mechanisms to regulate ion and pH homeostasis in response to developmental cues and to a changing environment. The working hypothesis is that the balance of fluxes mediated by diverse transporters at the plasma membrane and in subcellular organelles determines ionic cellular distribution, which is critical for maintenance of membrane potential, pH control, osmolality, transport of nutrients, and protein activity. An emerging theme in plant cell biology is that cells respond and adapt to diverse cues through changes of the dynamic endomembrane system. Yet we know very little about the transporters that might influence the operation of the secretory system in plants. Here we focus on transporters that influence alkali cation and pH homeostasis, mainly in the endomembrane/ secretory system. The endomembrane system of eukaryote cells serves several major functions: i) sort cargo (e.g. enzymes, transporters or receptors) to specific destinations, ii) modulate the protein and lipid composition of membrane domains through remodeling, and iii) determine and alter the properties of the cell wall through synthesis and remodeling. We had uncovered a novel family of predicted cation/H + exchangers (CHX) and K + efflux antiporters (KEA) that are prevalent in higher plants, but rare in metazoans. We combined phylogenetic and transcriptomic analyses with molecular genetic, cell biological and biochemical studies, and have published the first reports on functions of plant CHXs and KEAs. CHX studied to date act at the endomembrane system where their actions are distinct from the better-studied NHX (Na/K-H + exchangers). Arabidopsis thaliana CHX20 in guard cells modulate stomatal opening, and thus is significant for vegetative survival. Other CHXs ensure reproductive success on dry land, as they participate in organizing pollen walls, targeting of pollen tubes to the ovule or promoting fertilization. Based on localization and mutant analyses, we conclude that CHXs modulate the ion balance, pH or both in micro-regions of endoplasmic reticulum, endosomes and prevacuolar compartment (PVC), and so influence membrane trafficking and signaling resulting in proper osmoregulation in guard cells and seed formation. We also demonstrated for the first time that AtKEA2 associates with chloroplasts, especially at the two poles of developing plastids. These results show that AtKEA1 and AtKEA2 transporters in specific microdomains of the inner envelope link local osmotic, ionic, and pH homeostasis to plastid division and thylakoid membrane formation. The first 3-D structure model of AtCHX was generated, and architecture-directed mutagenesis identified critical residues of the transport core giving insights to the transport mode of this family. Thus we have revealed for the first time crucial roles of an unknown K + /H + transport family on plant growth (KEA), gas exchange, pollen cell wall, and different phases of reproduction (CHXs). The dynamic endomembrane of plant cells is integral to cytokinesis, cell expansion, defense, and cell wall formation, thus these studies are directly relevant to the mission of the Department of Energy and to a better understanding of determinants for enhancing plant biomass and plant tolerance to abiotic stress.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

4th Penn State Bioinorganic Workshop

The research area of biological inorganic chemistry encompasses a wide variety of subfields, including molecular biology, biochemistry, biophysics, inorganic chemistry, analytical chemistry, physical chemistry, and theoretical chemistry, as well as many different methods, such as biochemical characterization of enzymes, reaction kinetics, a plethora of spectroscopic techniques, and computational methods. The above methods are combined to understand the formation, function, and regulation of the many metallo-cofactors found in Nature as well as to identify novel metallo-cofactors. Many metalloenzyme-catalyzed reactions are extremely complex, but are of fundamental importance to science and society. Examples include (i) the reduction of the chemically inert molecule, dinitrogen, to ammonia by the enzyme nitrogenase (this reaction is fundamental for the production of nitrogen fertilizers); (ii) the oxidation of water to dioxygen by the Mn4Ca cluster found in photosystem II; and (iii) myriad reactions in which aliphatic, inert C-H bonds are cleaved for subsequent functionalization of the carbon atoms (the latter reactions are important in the biosynthesis of many natural products). Because of the broad range of areas and techniques employed in this field, research in bioinorganic chemistry is typically carried out collaboratively between two or more research groups. It is of paramount importance that researchers working in this field have a good, basic, working knowledge of many methods and approaches employed in the field, in order to design and discuss experiments with collaborators. Therefore, the training of students working in bioinorganic chemistry is an important aspect of this field. Hugely successful “bioinorganic workshops” were offered in the 1990s at The University of Georgia. These workshops laid the foundation for many of the extant collaborative research efforts in this area today. The large and diverse group of bioinorganic chemists at The Pennsylvania State University and our unique laboratory space are well suited for the continuation of such training workshops. The co-principal investigators of this award lead these efforts. After a smaller “trial workshop” in 2010, the Penn State bioinorganic group, led by the co-PIs, offers these workshops biennially. The 2012, 2014, and 2016 workshops provided training to 123, 162, and 153 participants, respectively, by offering (i) a series of lectures given by faculty experts on the given topic, (ii) hands-on training in small groups by experts in the various methods, and (iii) sharing research results of the participants by oral and poster presentations. The centerpiece of the workshops is the hands-on training, in which approximately half of the participants from all ranks (undergraduate students to faculty) served as teachers. In this section, the traditional roles of teachers and students were sometimes reversed to the extent that undergraduate students taught faculty in the students' areas of specialty. We anticipate that these workshops will facilitate research in bioinorganic chemistry and will help establish future collaborations among “workshop alumni” to carry out cutting-edge research in bioinorganic chemistry that will address many important topics relevant to our society.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2017

The Effect of Airborne Contaminants on Fuel Cell Performance and Durability

The impact of contaminants on fuel cell performance was examined to document air filter specifications (prevention) and devise recovery procedures (maintenance) that are effective at the system level. Eight previously undocumented airborne contaminants were selected for detailed studies and characterization data was used to identify operating conditions that intensifying contamination effects. The use of many and complementary electrochemical, chemical and physical characterization methods and the derivation of several mathematical models supported the formulation of contamination mechanisms and the development of recovery procedures. The complexity of these contamination mechanisms suggests a shift to prevention and generic maintenance measures. Only two of the selected contaminants led to cell voltage losses after injection was interrupted. Proposed recovery procedures for calcium ions, a component of road de-icers, dessicants, fertilizers and soil conditioners, were either ineffective or partly effective, whereas for bromomethane, a fumigant, the cell voltage was recovered to its initial value before contamination by manipulating and sequencing operating conditions. However, implementation for a fuel cell stack and system remains to be demonstrated. Contamination mechanisms also led to the identification of membrane durability stressors. All 8 selected contaminants promote the formation of hydrogen peroxide, a known agent that can produce radicals that attack the ionomer and membrane molecular structure whereas the dehydrating effect of calcium ions on the ionomer and membrane increases their brittleness and favors the creation of pinholes under mechanical stresses. Data related to acetylene, acetonitrile and calcium ions are emphasized in the report.

33 ADVANCED PROPULSION SYSTEMS↗
DOE OSTI2017

Measurements and modeling of CO 2 concentration and isotopes to improve process-level understanding of Arctic and boreal carbon cycling. Final Report

The major goal of this project was to improve understanding of processes that control the exchanges of CO 2 between the atmosphere and the land biosphere on decadal and longer time scales. The approach involves measuring the changes in atmospheric CO 2 concentration and the isotopes of CO 2 ( 13 C/ 12 C and 18 O/ 16 O) at background stations and uses these and other datasets to challenge and improve numerical models of the earth system. The project particularly emphasized the use of these data to improve understanding of changes occurring in boreal and arctic ecosystems over the past 50 years and to seek from these data improved understanding of large-scale processes impacting carbon cycling, such as the responses to warming, CO 2 fertilization, and disturbance. The project also led to advances in the understanding of changes in water-use efficiency of land ecosystems globally based on trends in 13 C/ 12 C. The core element of this project was providing partial support for continuing measurements of CO 2 concentrations and isotopes from the Scripps CO 2 program, initiated by C. D. Keeling in the 1960s. The measurements included analysis of flasks collected at an array of ten stations distributed from the Arctic to the Antarctic. The project also supported modeling studies and interpretive work to help understand the origins of the large ~50% increase in the amplitude of the atmospheric CO 2 cycle detected at high northern latitudes between 1960 and present and to understand the long-term trend in carbon 13 C/ 12 C of CO 2 . The seasonal cycle work was advanced through collaborations with colleagues at MPI Jena and Imperial College

47 OTHER INSTRUMENTATION↗
DOE OSTI2018

A Microalgae-Based Platform for the Beneficial Re-use of Carbon Dioxide Emissions from Power Plants

This project sought to address the technical and economic barriers to carbon dioxide capture and utilization using microalgae. Operating data were collected in 2016 and 2017 during cultivation of Scenedesmus acutus at Duke Energy’s East Bend Station – a coal-fired power plant located in northern Kentucky – using flue gas as the CO 2 source. Algae were grown in a 1200 L “cyclic flow” photobioreactor (PBR) designed by the University of Kentucky. A key finding was that the harvested algae contained only very low concentrations of heavy metals (As, Cd, Hg, Se), consistent with heavy metals incorporation from the supplied nutrients. This indicates that algal biomass produced from coal-derived flue gas would be suitable for a variety of applications, including the production of bioplastics, use as fertilizer, etc. A lifecycle assessment showed that the UK-designed PBR employed in this work qualifies as a net CO 2 capture technology. Indeed, over a 30-year period, net CO 2 capture would equate to 43% of the targeted amount, i.e., the amount captured from the supplied flue gas. A techno-economic analysis indicated that the minimum production cost of Scenedesmus acutus biomass in the US is in the order of 875 USD/ton, excluding the cost of capital. While this figure is not too dissimilar to values reported for open raceway ponds in similar scenarios, it emphasizes that for current cultivation technology any pathway to economic viability will require applications for which algal boimass can be sold at prices in excess of 1,000 USD/ton. Currently, such applications represent relatively small markets, such as pigments (e.g., astaxanthin) and nutraceuticals (ω-3 unsaturated fatty acids), as well as nutritional supplements (whole algae) for human consumption and for use in pet food. Consequently, the commercialization of large-scale algae-based CO 2 capture and utilization will require the development of new technologies to reduce the cost of algae production and/or the development of new, high-value applications for algal biomass. One of the more promising applications for algal biomass is in the production of bioplastics. In this work, the potential for the algae grown in the East Bend PBR for the production of bioplastic with adequate mechanical properties was clearly shown. Positive features of the produced biomass included a high protein content and a composition that was generally more homogeneous than biomass grown in open ponds (in which many species may be present). The best candidate for further review, after incorporation into ethylene-vinyl acetate, was a lipid and sugar extracted material, which showed the highest extension values with comparable load values to other UK-derived samples. It also demonstrated extension benefits against the Algix Bloom product (currently offered commercially), even though it contained agglomerates which generally exert a negative effect on mechanical properties. This leads to speculation that with enhanced milling that exists on the commercial scale, the sugar and fat extracted product may be even more competitive. This, in turn, points to the need for additional work in order to assess the properties of such optimized algae-based plastics and the price point they can command.

09 BIOMASS FUELS↗
DOE OSTI2017

Nitrogenase Inspired Peptide-Functionalized Catalyst for Efficient, Emission-Free Ammonia Production

Ammonia production is one of the most important industrial processes in the world, as the major component of fertilizer to sustain higher food production. It is also one of the most energy intensive and carbon intensive chemical processes worldwide, primarily due to the steam methane reforming step to produce hydrogen for the reaction. Currently, ammonia is produced via the Haber Bosch process, which requires high temperature and pressure, and has low equilibrium efficiency. Due to these reaction conditions, the process is most economical at extremely large scale (100,000s of tons per day). In order to enable more distributed production scales which better match with renewable energy input and sustainable reactant sources, alternative methods of ammonia synthesis are needed, which scale more effectively and economically. One such approach is electrochemical synthesis based on ion exchange membrane cells. Peptide templating to form catalyst nanoparticles of controlled size, combined with peptide surface adsorbtion to model the nitrogenase active site, was used to develop novel catalyst materials and deposit them on electrodes.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

Lasers for Medicine Final Report CRADA No. TC-0436-93

This project is intended to advance the US position in laser diae~osis and treatment of disease in three thrust areas. A first laser system will advance the US position in photodynamic therapy whereby dyes are introduced into selected tissue and laser treatment with wavelena@ matching the dyes’ absorption band allows treatment of only the desired tissue. This effort will focus on the development and application of diode arrays delivering up to 10 watts at wavelengths of 657 nm, 675 nm and 695 nm with fiber optic delivery systems. This system would replace existing cumbersome systems with a compact diode array system. A second laser system is intended to advance the US position in the medical use of lasers in dermatology to remove port wine stains. The project will involve the development of a new all solid-state laser system to deliver light at 585 nm for the d~ect removal of port wine stains in human skin. This solid-state system would replace the currently used dye laser system with a compact, more efficient, less costly, environmentally benign solid-state laser system. Additionally this new laser system will offer new flexibility in the pulse format allowing treatment on a wider range of patients. A third laser system is targeted to develop a diode-pumped TrnYAG laser system operating at 1.9 pm to drill small holes in animal eggs with the goal of improving fertility. This system would replace the current excimer system at 308 nm, which has undesirable mutagenic problems

42 ENGINEERING↗
DOE OSTI2018

Expanding the breeder’s toolbox for perennial grasses

With the increase in world energy demand and the environmental impacts associated with continued fossil fuel use, there is a great need for the development of alternative and sustainable fuel sources. Switchgrass ( Panicum virgatum L. ), a perennial grass native to North America, is poised to become one of the first dedicated biomass crops deployed on a large scale in the United States in large part due to its inherent high yield, adaptability and perennial nature. Current ‘cultivars’ of switchgrass are essentially undomesticated wild selections from natural populations. Thus, there is considerable potential for improvement of this emerging energy crop. Traditional breeding approaches in switchgrass have been hampered by its self-incompatibility and sensitivity to inbreeding, therefore there is a significant need to develop new tools for improved switchgrass breeding. The proposed research uses a systems biology approach to accelerate switchgrass breeding, to develop its biotechnological improvement through the generation of stress-tolerant varieties, and to establish ways to minimize the potential impact of transgenes on ecosystems. In this proposal, we will develop new breeding tools for perennial grasses and apply these tools toward improving switchgrass. Specifically, we will employ two complementary approaches to overcome the difficulty of breeding a large, polyploid, self-incompatible plant. The first approach will accelerate conventional breeding by developing a method to rapidly create doubled haploid (homozygous) lines for breeding. This approach is based on altering CENH3, a centromere-specific histone, leading to the production of haploid offspring when the centromere mutant is crossed to wild type plants. Subsequent genome doubling results in fully homozygous individuals and overcomes one of the major limitations in breeding self-incompatibile crops. These homozygous lines would allow switchgrass breeders to apply a variety of breeding approaches that have been previously impossible. The second approach is to develop tools and reagents to accelerate the biotechnological improvement of switchgrass including: modules for improved stress tolerance, a test bed to evaluate transgenes in a perennial model grass and a robust gene containment system. In order to maintain a favorable energy balance and avoid competition with food crops, dedicated biomass crops must be grown with minimal inputs (fertilizer and water) on marginal lands that are unsuited to the traditional high input agriculture necessary to produce food. Thus, abiotic stress tolerance and efficient water and nutrient use are of paramount importance. Considerable basic research has been directed at these areas and this knowledge has been used to develop transgenic approaches to greatly improve water and nutrient use efficiency. By applying these approaches to switchgrass we will rapidly increase drought tolerance and nutrient use efficiency. This approach can rapidly introduce these traits in different cultivars allowing breeders to add these traits to their elite germplasm. Since biotechnologically improved switchgrass must ultimately be grown in open fields, they must be designed to minimize the potential impact of the transgenes on non-target ecosystems. The best way to do this is to minimize gene flow from the transgenic plants. Thus, we will develop technology to introduce sterility into the transgenic plants. We will then combine this technology with the stress resistance modules to create switchgrass lines with enhanced resistance to abiotic stresses.

09 BIOMASS FUELS↗
DOE OSTI2018

Expanding the Breeder’s Toolbox for Perennial Grasses

With the increase in world energy demand and the environmental impacts associated with continued fossil fuel use, there is a great need for the development of alternative and sustainable fuel sources. Switchgrass (Panicum virgatum L.), a perennial grass native to North America, is poised to become one of the first dedicated biomass crops deployed on a large scale in the United States in large part due to its inherent high yield, adaptability and perennial nature. Current ‘cultivars’ of switchgrass are essentially undomesticated wild selections from natural populations. Thus, there is considerable potential for improvement of this emerging energy crop. Traditional breeding approaches in switchgrass have been hampered by its self-incompatibility and sensitivity to inbreeding, therefore there is a significant need to develop new tools for improved switchgrass breeding. The proposed research uses a systems biology approach to accelerate switchgrass breeding, to develop its biotechnological improvement through the generation of stress-tolerant varieties, and to establish ways to minimize the potential impact of transgenes on ecosystems. In this proposal, we will develop new breeding tools for perennial grasses and apply these tools toward improving switchgrass. Specifically, we will employ two complementary approaches to overcome the difficulty of breeding a large, polyploid, self-incompatible plant. The first approach will accelerate conventional breeding by developing a method to rapidly create doubled haploid (homozygous) lines for breeding. This approach is based on altering CENH3, a centromere-specific histone, leading to the production of haploid offspring when the centromere mutant is crossed to wild type plants. Subsequent genome doubling results in fully homozygous individuals and overcomes one of the major limitations in breeding self-incompatibile crops. These homozygous lines would allow switchgrass breeders to apply a variety of breeding approaches that have been previously impossible. The second approach is to develop tools and reagents to accelerate the biotechnological improvement of switchgrass including: modules for improved stress tolerance, a test bed to evaluate transgenes in a perennial model grass and a robust gene containment system. In order to maintain a favorable energy balance and avoid competition with food crops, dedicated biomass crops must be grown with minimal inputs (fertilizer and water) on marginal lands that are unsuited to the traditional high input agriculture necessary to produce food. Thus, abiotic stress tolerance and efficient water and nutrient use are of paramount importance. Considerable basic research has been directed at these areas and this knowledge has been used to develop transgenic approaches to greatly improve water and nutrient use efficiency. By applying these approaches to switchgrass we will rapidly increase drought tolerance and nutrient use efficiency. This approach can rapidly introduce these traits in different cultivars allowing breeders to add these traits to their elite germplasm. Since biotechnologically improved switchgrass must ultimately be grown in open fields, they must be designed to minimize the potential impact of the transgenes on non-target ecosystems. The best way to do this is to minimize gene flow from the transgenic plants. Thus, we will develop technology to introduce sterility into the transgenic plants. We will then combine this technology with the stress resistance modules to create switchgrass lines with enhanced resistance to abiotic stresses.

09 BIOMASS FUELS↗
DOE OSTI2019

Mu*STAR ADSR Fuel Conversion Facility Evaluation and Cost Analysis

The purpose of the reported effort is the development of a conceptual process for conversion of used nuclear fuel (UNF) from light water reactors (LWRs) to a fluoride salt form to facilitate its use for power generation in a Mu*STAR Accelerator-driven Subcritical Reactor (ADSR). This document evaluates potential processes for converting UNF into a fluoride salt, evaluates the costs/benefits of using enriched lithium in the carrier salt, and analyzes comparable costs of similar facilities to make a rough order of magnitude estimate for the cost to design, construct, and commission a Mu*STAR ADSR fuel conversion facility. This document also makes a high-level comparison of the Mu*STAR ADSR fuel cycle with other important fuel cycles. The results of the cost analysis show that the Mu*STAR ADSR fuel conversion facility will cost more than $100M, possibly up to around $1B, to design and construct. The cost will depend on the size of the hot cell required, which will depend on the processing options chosen for converting the UNF to a molten salt. Operations and maintenance of the facility will be on the order of $10M per year. The design, fabrication, and installation of the remote process equipment to support the fuel conversion will be an additional cost of more than $50M. Cost surveys of Department of Energy hot cell designs and previous Department of Energy hot cell construction suggest that the cost variance may be large, and the risk of escalating costs may be high in the regulation-mandated atmosphere of nuclear facility design and construction. The molten salt for the Mu*STAR ADSR contains all of the nonvolatile isotopes in the UNF, and there is never a separation of the plutonium from the fission products. This makes this conversion process much more proliferation resistant than the reprocessing options used for other closed fuel cycles. When normalized to the amount of electricity produced, the Mu*STAR ADSR fuel cycle’s expected cost might be less than any reprocessing fuel cycle and possibly less than the once-through cycle now used. Simulations show that once the conversion to fluoride is made, that up to seven times as much energy can be extracted from the UNF than was produced by the LWR while making it [Bowman, 2010]. Using once-only, on-site conversion to fluoride means no mining, no enrichment, no manufacturing of fuel rods, and no transportation costs. Typically, the UNF was produced over a 40-year period in an LWR; it can potentially be used for 280 years in Mu*STAR, producing the same power as the LWR did, ultimately requiring disposal of approximately the same volume of material as the LWR generated. Mu*STAR burns most of the higher actinides, which could reduce both the cost of disposal and significantly reduce the longevity of its radiotoxicity. Mu*STAR ADSR’s ability to demonstrate unique and valuable peripheral benefits are additional arguments for this technology, including (1) turning UNF into a valuable commodity (thus, its disposal will not be such an immediate problem, so continued operation of existing LWRs will be more acceptable); (2) burning fissile or fertile fuel including excess weapons-grade plutonium in subcritical mode; and (3) providing high-temperature process heat to convert natural gas to synthetic diesel fuel, water to hydrogen, or for other process-heat applications.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
DOE OSTI2018

Determining the Drivers of Redox Sensitive Biogeochemistry in Humid Tropical Forests

Our objectives were to determine the spatial and temporal dynamics and drivers of soil O 2 availability and redox-sensitive biogeochemical processes using easily measured and modeled parameters. We used automated soil O 2 sensing coupled with measurements of soil chemical and physical properties, climate, and greenhouse gas concentrations and fluxes. These results are being used to derive quantitative relationships linking climate and soil physical properties to redox sensitive biogeochemical processes in tropical forests. We tested the hypothesis that hot spots and hot moments are driven primarily by high substrate availability using distributed sampling and field and lab fertilization experiments. To better model C and nutrient cycling and greenhouse gas fluxes in Earth system models we need to develop a more mechanistic understanding of the spatial and temporal dynamics and drivers of soil O 2 availability in tropical forest soils. In this study we used field and laboratory experiments to help develop a mechanistically derived redox component for the Community Land Model (CLM) module of the Community Earth System Model (CESM).

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2013

Greenhouse Gas Reductions in the Power Industry Using Domestic Coal and Biomass - Volume 1: IGCC

The objective of this study was to simulate biomass co-firing in a dry-fed, entrained-flow gasifier in an integrated gasification combined cycle (IGCC) power plant and examine the resulting performance, environmental response, and economic response. To develop a more complete understanding of the impact of co-feeding biomass, each case was examined using a limited life cycle greenhouse gas (GHG) analysis, which examines GHG emissions beyond the plant stack. Included in the limited life cycle GHG analysis were anthropogenic greenhouse gas emissions from the production, processing, transportation, and fertilization of biomass and from mining, transporting and handling coal.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2012

Corn Grain, Cultivation, Operation

This unit process includes operation of farming activities for cultivation of corn grain including diesel, fertilizers, herbicides and water use, as well as emissions from diesel combustion, criteria air pollutants, and water emissions. To access the model referenced in the report, please visit https://www.netl.doe.gov/energy-analysis/details?id=C5563FA6-3EF8-4E6B-A1A6-D278C05E054A

42 ENGINEERING↗
DOE OSTI2012

Corn Stover Cultivation, Operation

This unit process includes operation of farming activities for cultivation of corn stover, including diesel, fertilizers, herbicides and water use, as well as emissions from diesel combustion, criteria air pollutants, and water emissions. To access the model referenced in the report, please visit https://www.netl.doe.gov/energy-analysis/details?id=5278DC55-F203-4AB2-A1EE-88872B9EDD01

09 BIOMASS FUELS↗
DOE OSTI2012

Southern Pine Biomass Cultivation, Operation

This unit process includes operation period farming activities for cultivation of SRWC (from Southern Pine), including inputs of combusted diesel, fertilizers, herbicides and water use, as well as criteria air pollutants and water emissions. To access the model referenced in the report, please visit https://www.netl.doe.gov/energy-analysis/details?id=E56A9C71-D7FB-4657-8131-80424C9E7062

09 BIOMASS FUELS↗