Search NASA⌕ Search

SEARCH · Search NASA

Results for “Layered structures”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,387 records · Page 77
All sourcesNASA NTRSDOE OSTI
DOE OSTI2015

How the method of synthesis governs the local and global structure of zinc aluminum layered double hydroxides

A series of zinc aluminum layered double hydroxides (ZnAl LDHs), [Zn1-xAlx (OH)2Ax,nH2O with A = NO3-, Cl- or CO3] were prepared by the urea and co-precipitation synthesis methods, which allowed for a detailed investigation on how synthesis parameters such as pH, metal ion concentration and post synthesis treatment influence the local and global structure of the LDH product. Information about sample composition, purity, defects and other structural aspects of the LDH products were obtained from powder X-ray diffraction, transmission electron microscopy, micro-Raman, and elemental analysis, as well as solid state 1H, 27Al and 67Zn NMR spectroscopy. Our results show that the urea method results in LDHs, which on the global scale are highly crystalline LDHs, whereas solid state NMR shows the different local environments indicating local disorder most likely linked to the presence of Al-rich phases. However, these Alrich phases are not detected by global range techniques, as they either defects within the LDH particles or separate phase(s) associated with LDHs. In contrast, samples prepared by coprecipitation especially synthesized under careful pH control and subsequently hydrothermal treated have high local order and good crystallinity (particle size). Our results show that both molecular level and macroscopic techniques are needed to assess the composition of LDHs, as the conventional PXRD and TEM analysis of LDHs failed to identify the many structural defects and/or amorphous phases.

Environmental Molecular Sciences Laboratory↗
DOE OSTI2019

Effect of Perforation on the Thermal and Electrical Breakdown of Self-Rolled-Up Nanomembrane Structures

Strain-induced self-rolled-up membranes (S-RuM) are structures formed spontaneously by releasing a strained layer or layer stacks from its mechanical support, with unique applications in passive photonics, electronics, and bioengineering. Depending on the thermal properties of the strained layers, these structures can experience various thermally induced deformations. These deformations can be avoided and augmented with the addition of strategically placed perforations in the membrane. This study reports on the use of perforations to modify the thermal effects on strained silicon nitride S-RuM structures. Finally, a programmable fuse with well-defined thermal threshold, ultrasmall footprint, and 2-3 V voltage rating is demonstrated, which can potentially serve as an on-chip sensing device for power electronic circuits.

36 MATERIALS SCIENCE↗
NASA NTRS1989

Stochastic estimation of coherent structures in turbulent boundary layers

The stochastic estimation provides a means of estimating conditional averages from unconditional statistics, namely, the two-point correlation tensor. This technique is applied to three-dimensional data obtained in a fully turbulent boundary layer. The results of linear and nonlinear estimates are compared to the corresponding conditional averages and the agreement is found to be excellent, with little improvement for nonlinear estimates. Extensions of the technique to space-time estimates of one- and two-point conditional averages are also presented, the latter providing a means to examine structures associated with a given length scale.

Guezennec, Y. G.↗
NASA NTRS2004

First Atmospheric Science Results from the Mars Exploration Rovers Mini-TES

Thermal infrared spectra of the martian atmosphere taken by the Miniature Thermal Emission Spectrometer (Mini-TES) were used to determine the atmospheric temperatures in the planetary boundary layer and the column-integrated optical depth of aerosols. Mini-TES observations show the diurnal variation of the martian boundary layer thermal structure, including a near-surface superadiabatic layer during the afternoon and an inversion layer at night. Upward-looking Mini-TES observations show warm and cool parcels of air moving through the Mini-TES field of view on a time scale of 30 seconds. The retrieved dust optical depth shows a downward trend at both sites.

Mars↗
DOE OSTI2020

Investigating Liquid Water Transport in Different Pore Structure of Gas Diffusion Layers for PEMFC Using Lattice Boltzmann Method

Proton exchange membrane fuel cells (PEMFC) require a gas diffusion layer (GDL) to aid in the transport of liquid fuel to the catalyst layer. In this work, direct modeling using the Lattice Boltzmann Method (LBM) was applied to X-ray CT scans of four different carbon gas diffusion layers to understand the mass transport properties through the samples. Three injection orientations were used to study local saturation levels, water evolution through the sample, and mass transport behavior at breakthrough conditions. The LBM, combined with computational fluid dynamic modeling techniques, can accurately predict liquid saturation at the macro and micro scale, which provides more insight into the mass transport phenomena through the GDL. The change of pore structure and orientation in both the in-plane and through-plane determines the path that liquid water must take, which could aid or impact PEMFC performance. The outcomes from this work will also benefit any research that needs knowledge of internal mass transport qualities of gas diffusion media.

Sepe, M.↗
DOE OSTI2019

Specific Features of Nonlinear Spin Wave Localization in a Layered Ferromagnet under the Action of the Magnetic Anisotropy of Layers

A trilayer structure model has been investigated, in which uniaxial ferromagnetic layers and thin-film interfaces between them are characterized by the magnetic anisotropy. The magnetization perturbation induced in this structure is described by the nonlinear Schrödinger equation with a nonlinear potential, which simulates the interfaces between ferromagnetic layers. It is shown that, in this structure, two types of nonlinear spin waves can propagate along the layers, which are induced by the nonlinearity of the interfaces caused by their magnetic anisotropy. The frequencies of such localized stationary states of spin waves have been obtained in the explicit analytical form. The conditions for the existence of these states, depending on the characteristics of the layers and interfaces between them, have been established.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2015

Direct observation of electrothermal instability structures in the skin layer of an intensely Ohmically heated conductor

Magnetically driven implosions (MDIs) on the Z Facility assemble high-energy-density plasmas for radiation effects and ICF experiments. MDIs are hampered by the Magneto-Rayleigh-Taylor (MRT) instability, which can grow to large amplitude from a small seed perturbation, limiting achievable stagnation pressures and temperatures. The metallic liners used in Magnetized Liner Inertial Fusion (MagLIF) experiments include astonishingly small (-10 nm RMS) initial surface roughness perturbations; nevertheless, unexpectedly large MRT amplitudes are observed in experiments. An electrothermal instability (ETI) may provide a perturbation which exceeds the initial surface roughness. For a condensed metal resistivity increases with temperature. Locations of higher resistivity undergo increased Ohmic heating, resulting in locally higher temperature, and thus still higher resistivity. Such unstable temperature (and pressure) growth produces density perturbations when the locally overheated metal changes phase, providing the seed perturbation for MRT growth. ETI seeding of MRT on thick conductors carrying current in a skin layer has thus far only been inferred by evaluating MRT amplitude late in the experiment. A direct observation of ETI is vital to ensure our simulation tools are accurately representing the seed of the deleterious MRT instability. In this LDRD project, ETI growth was directly observed on the surface of 1.0-mm-diameter solid Al rods which were pulsed with 1 MA of current in 100 ns. Fine structures resulting from ETI-driven temperature variations were observed directly through high resolution gated optical imaging. Data from two Aluminum alloys (6061 and 5N) and a variety fabrication techniques (conventional machining, single-point diamond turned, electropolished) enable evaluation of which imperfections provide a seed for ETI growth and subsequent plasma initiation. Data is relevant to the early stages of MagLIF liner implosions, when the ETI seed of MRT may be initiated, and provides a fundamentally new dataset with which to test our state-of-the-art simulation tools.

42 ENGINEERING↗
DOE OSTI2025

Layers Can Be Deceiving: A Hopping Model for Small Molecule Diffusion in TATB Crystal

Sorption of small molecule gases in materials can play a significant role in their long‐term stability and compatibility within multi‐material assemblies. While many material properties of the insensitive high explosive TATB (1,3,5‐triamino‐2,4,6‐trinitrobenzene) are well understood, very little is known regarding its permeability to gases. TATB crystal exhibits a graphitic‐like layered packing structure that evokes a mental schema in which the layers form nanoscopic channels, but it is unclear whether this structure promotes gas transport. Here, we use molecular dynamics (MD) simulations to predict transport of small molecules through TATB single crystal. An approach to fit classical force fields is developed to model TATB interactions with H 2 O, He, Ne, and Ar, which is then combined with steered MD to probe gas transport along selected directions in the crystal. We find that small molecule transport occurs via a hopping mechanism that exhibits distinct jumps between interstitial sites and is substantially faster normal to the layers as compared to through them. This result stems from the finding that intralayer junctions between adjacent TATB molecules are the most stable interstitial sites and that energetic barriers are lower for hopping between adjacent layers. An empirical model for diffusion rate based on the MD data shows that the rate decays exponentially with increasing molecular radius and is negligibly small for all molecules larger than He, including common atmospheric gases. These findings have implications for the interpretation of experiments that measure surface area, material response to extreme conditions, and are expected to help constrain models for material aging.

36 MATERIALS SCIENCE↗
DOE OSTI2018

P-n heterostructured TiO2/NiO double-shelled hollow spheres for the photocatalytic degradation of papermaking wastewater

Highlights: • P-n heterostructured TiO{sub 2}/NiO double-shelled hollow spheres were prepared. • A cubic-structured NiO layer is grown on surface of anatase TiO{sub 2} hollow sphere. • TiO{sub 2}/NiO show high photocatalytic activity for papermaking wastewater degradation. • The COD{sub Cr} removal rate of wastewater reaches 98.1% after 6 h of photodegradation. - Abstract: P-n heterostructured TiO{sub 2}/NiO double-shelled hollow spheres were prepared through sol–gel and hydrothermal processes. TiO{sub 2}/NiO nanomaterials were comprehensively characterized, and the results reveal that a cubic-structured NiO layer is successfully grown on the surface of the anatase TiO{sub 2} hollow sphere to achieve a p-n heterostructure. The thickness of TiO{sub 2} shell is ∼20 nm, and that of NiO shell is 10–25 nm. Compared with the pure TiO{sub 2} hollow spheres, the prepared p-n heterostructures display a considerably higher photocatalytic activity for papermaking wastewater degradation under UV light irradiation. The chemical oxygen demand removal rate of papermaking wastewater reaches 98.1% after 6 h of photodegradation with DSTN2 as the photocatalyst. The enhanced photocatalytic activity is due to the synergetic effects of p-n heterostructures and the large specific surface area of the catalyst; these effects may promote the separation of photogenerated electron–hole pairs.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2018

The Investigation of the Toughening Mechanism of PHBV/PBAT with a Novel Hyperbranched Ethylenediamine Triazine Polymer Based Modifier: The Formation of the Transition Layer and the Microcrosslinking Structure

A new type of designed hyperbranched ethylenediamine trazine polymer (HBETP) is successfully synthesized and characterized based upon NMR and GPC. The prepared HBETP is used to modify the poly(hydroxybutyrate-co-hydroxyvalerate) (PHBV)/poly(butylene adipate-co-terephthalate) (PBAT) blends. The effect of HBETP on the microstructure, mechanical properties and thermal properties of the blends is studied. The results indicate that upon addition of 1.0 wt% of HBETP, the impact strength of the PHBV/PBAT blends is increased by 47.1%; ∆T{sub g} of the blends decreases from 53.2 to 49.9 °C. These results, together with the morphology analysis of the fractured surface of the blends, conclude the formation of the transition layer between PHBV and PBAT. Also, the XRD result shows that the addition of HBETP can limit the growth of the PHBV crystals and causes the decrease of both the crystallinity and the grain crystalline size. The DSC result demonstrates that the addition of HBETP mainly affects the crystallization of the HB-HV binary eutectic region within PHBV. The mechanism of PHBV/PBAT toughening is due to the formation of the strong physical hydrogen bonding and the chemical micro-crosslinking between HBETP and PHBV/PBAT, which is proposed based on XPS characterization.

77 NANOSCIENCE AND NANOTECHNOLOGY↗
DOE OSTI2016

Structure of a magnetic flux annihilation layer formed by the collision of supersonic, magnetized plasma flows

We present experiments characterizing the detailed structure of a current layer, generated by the collision of two counter-streaming, supersonic and magnetized aluminum plasma flows. The anti parallel magnetic fields advected by the flows are found to be mutually annihilated inside the layer, giving rise to a bifurcated current structure—two narrow current sheets running along the outside surfaces of the layer. Measurements with Thomson scattering show a fast outflow of plasma along the layer and a high ion temperature (T i ~¯ZT e , with average ionization ¯Z=7). Lastly, analysis of the spatially resolved plasma parameters indicates that the advection and subsequent annihilation of the in-flowing magnetic flux determines the structure of the layer, while the ion heating could be due to the development of kinetic, current-driven instabilities.

42 ENGINEERING↗
DOE OSTI2017

Formation and properties of the buried isolating silicon-dioxide layer in double-layer “porous silicon-on-insulator” structures

The oxidation of mesoporous silicon in a double-layer “macroporous silicon–mesoporous silicon” structure is studied. The morphology and dielectric properties of the buried insulating layer are investigated using electron microscopy, ellipsometry, and electrical measurements. Specific defects (so-called spikes) are revealed between the oxidized macropore walls in macroporous silicon and the oxidation crossing fronts in mesoporous silicon. It is found that, at an initial porosity of mesoporous silicon of 60%, three-stage thermal oxidation leads to the formation of buried silicon-dioxide layers with an electric-field breakdown strength of E{sub br} ~ 10{sup 4}–10{sup 5} V/cm. Multilayered “porous silicon-on-insulator” structures are shown to be promising for integrated chemical micro- and nanosensors.

36 MATERIALS SCIENCE↗
NASA NTRS1996

Modeling of Sound Transmission through Shell Structures with Turbulent Boundary Layer Excitation

The turbulent boundary layer (TBL) pressure field is an important source of cabin noise during cruise of high subsonic and supersonic commercial aircraft. The broadband character of this excitation field results in an interior noise spectrum that dominates the overall sound pressure level (SPL) and speech interference metrics in the forward and midcabins of many aircraft. In the authors' previous study, sound transmission through an aircraft fuselage, modeled by two concentric cylindrical sandwich shells and excited by a TBL statistical model was investigated analytically. An assessment of point and global structural vibration levels and resulting interior noise levels was obtained for different TBL models, flight conditions and fuselage structural designs. However, due to the complication of the shell structure, the important noise transmission mechanisms were difficult to discern. Previous experience has demonstrated that a fundamental understanding of the range of modes (or wavenumbers) generated by the TBL source both in the structure and the acoustic cavity is key to the development of both active and passive control technologies. In an initial effort to provide this insight, the objective of this paper is to develop an analytical model of sound transmission through a simple unstiffened cylindrical aluminum shell excited by a TBL pressure field. The description of the turbulent pressure field is based on the Corcos formulation for the cross-spectral density (CSD) of the pressure fluctuations. The coupled shell and interior and exterior acoustic equations are solved for the structural displacement and the interior acoustic response using a Galerkin approach to obtain analytical solutions. Specifically, this study compares the real part of the normalized CSD of the TBL excitation field, the structural displacement and the interior acoustic field. Further the modal compositions of the structural and cavity response are examined and some inference of the dominant mechanism of noise transmission is made.

Tang, Yvette Y.↗
DOE OSTI2018

Localization of Excitations near a Thin Structured Spacer between Linear and Nonlinear Crystals

It has been shown that localized and semi-localized stationary states exist near a thin structured defect layer between a linear medium and a Kerr nonlinear medium. Localized states are described by a monotonically decreasing amplitude of the field on the both sides of the interface between the media. Semilocalized states are characterized by the field that has the form of a standing wave in the linear medium and decreases monotonically in the nonlinear medium. Kerr media with self-focusing and defocusing are considered. The proposed model is described by a system of the linear and nonlinear Schrödinger equations with a specific potential simulating a thin structured defect layer. It has been shown that localized and semi-localized states exist in different energy ranges in the case of contact of the linear medium with the self-focusing medium. In the case of contact of the linear medium with the defocusing medium, two types of localized and semi-localized states differing in energy and field profile can exist in different energy ranges. In particular cases, expressions for energies of states of these types have been obtained and conditions of their applicability have been indicated.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2018

Seeded growth of single-crystal two-dimensional covalent organic frameworks

Polymerizing monomers into periodic two-dimensional (2D) networks provides structurally precise, layered macromolecular sheets that exhibit desirable mechanical, optoelectrotronic, and molecular transport properties. 2D covalent organic frameworks (COFs) offer broad monomer scope but are generally isolated as powders comprised of aggregated nanometer-scale crystallites. Here we control 2D COF formation using a two-step procedure, in which monomers are added slowly to pre-formed nanoparticle seeds. The resulting 2D COFs are isolated as single-crystalline, micron-sized particles. Transient absorption spectroscopy of the dispersed COF nanoparticles provides two to three orders of magnitude improvement in signal quality relative to polycrystalline powder samples and suggests exciton diffusion over longer length scales than those obtained through previous approaches. These findings will enable a broad exploration of synthetic 2D polymer structures and properties.

Evans, Austin M. (ORCID:0000000235972454)↗
DOE OSTI2021

Importance of Superstructure in Stabilizing Oxygen Redox in P3‐Na 0.67 Li 0.2 Mn 0.8 O 2

Abstract Activation of oxygen redox represents a promising strategy to enhance the energy density of positive electrode materials in both lithium and sodium‐ion batteries. However, the large voltage hysteresis associated with oxidation of oxygen anions during the first charge represents a significant challenge. Here, P3‐type Na 0.67 Li 0.2 Mn 0.8 O 2 is reinvestigated and a ribbon superlattice is identified for the first time in P3‐type materials. The ribbon superstructure is maintained over cycling with very minor unit cell volume changes in the bulk while Li ions migrate reversibly between the transition metal and Na layers at the atomic scale. In addition, a range of spectroscopic techniques reveal that a strongly hybridized Mn 3d–O 2p favors ligand‐to‐metal charge transfer, also described as a reductive coupling mechanism, to stabilize reversible oxygen redox. By preparing materials under three different synthetic conditions, the degree of ordering between Li and Mn is varied. The sample with the maximum cation ordering delivers the largest capacity regardless of the voltage windows applied. These findings highlight the importance of cationic ordering in the transition metal layers, which can be tuned by synthetic control to enhance anionic redox and hence energy density in rechargeable batteries.

36 MATERIALS SCIENCE↗
NASA NTRS1990

Quasi-coherent structures in the turbulent boundary layer. I - Status report on a community-wide summary of the data

A review is presented of the approach, motivation and early results of a reevaluation of the knowledge collected by the research community during thirty years of research on the structure of turbulent boundary layers. Four distinctions or criteria concerning the need to improve the practices in this field are discussed: data versus inferences, possible versus actual versus significant events, one structure versus many, and one or two flows versus the totality of data. Attention given to the known quasi-coherent structures show that three factors significantly reduce the information available from laboratory data as a basis for forming a complete model of the quasi-coherent structure in the turbulent boundary layer: (1) the necessity to ensemble average probe output with resulting loss of phase information, (2) the inability to see more than one or two of the various types of structures simultaneously, and (3) the inability to see the spatial relations between the various quasi-coherent structures resulting from (1) and (2).

Kline, S. J.↗
DOE OSTI2016

Interfacial Atomic Structure of Twisted Few-Layer Graphene

A twist in bi- or few-layer graphene breaks the local symmetry, introducing a number of intriguing physical properties such as opening new bandgaps. Therefore, determining the twisted atomic structure is critical to understanding and controlling the functional properties of graphene. Combining low-angle annular dark-field electron microscopy with image simulations, we directly determine the atomic structure of twisted few-layer graphene in terms of a moiré superstructure which is parameterized by a single twist angle and lattice constant. This method is shown to be a powerful tool for accurately determining the atomic structure of two-dimensional materials such as graphene, even in the presence of experimental errors. Using coincidence-site-lattice and displacement-shift-complete theories, we show that the in-plane translation state between layers is not a significant structure parameter, explaining why the present method is adequate not only for bilayer graphene but also a few-layered twisted graphene.

36 MATERIALS SCIENCE↗