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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,387 records · Page 77

Experimental and numerical results on a shear layer excited by a sound pulse

The behavior of a sound in a jet was investigated. It is verified that the far-field acoustic power increased with flow velocity for the lower and medium frequency range. Experimentally, an attenuation at higher frequencies is also observed. This increase is found numerically to be due primarily to the interactions between the mean vorticity and the fluctuation velocities. Spectral decomposition of the real time data indicates that the power increase occurs in the low and middle frequency range, where the local instability waves have the largest spatial growth rate. The connection between this amplification and the local instability waves is discussed.

Maestrello, L.↗

Electron Beam Freeform Fabrication of Titanium Alloy Gradient Structures

Historically, the structural optimization of aerospace components has been done through geometric methods. A monolithic material is chosen based on the best compromise between the competing design limiting criteria. Then the structure is geometrically optimized to give the best overall performance using the single material chosen. Functionally graded materials offer the potential to further improve structural efficiency by allowing the material composition and/or microstructural features to spatially vary within a single structure. Thus, local properties could be tailored to the local design limiting criteria. Additive manufacturing techniques enable the fabrication of such graded materials and structures. This paper presents the results of a graded material study using two titanium alloys processed using electron beam freeform fabrication, an additive manufacturing process. The results show that the two alloys uniformly mix at various ratios and the resultant static tensile properties of the mixed alloys behave according to rule-of-mixtures. Additionally, the crack growth behavior across an abrupt change from one alloy to the other shows no discontinuity and the crack smoothly transitions from one crack growth regime into another.

Brice, Craig A.↗

Low power and privacy preserving sensor platform for occupancy detection

A low-cost, low-power, stand-alone sensor platform having a visible-range camera sensor, a thermopile array, a microphone, a motion sensor, and a microprocessor that is configured to perform occupancy detection and counting while preserving the privacy of occupants. The platform is programmed to extract shape/texture from images in spatial domain; motion from video in time domain; and audio features in frequency domain. Embedded binarized neural networks are used for efficient object of interest detection. The platform is also programmed with advanced fusion algorithms for multiple sensor modalities addressing dependent sensor observations. The platform may be deployed for (i) residential use in detecting occupants for autonomously controlling building systems, such as HVAC and lighting systems, to provide energy savings, (ii) security and surveillance, such as to detect loitering and surveil places of interest, (iii) analyzing customer behavior and flows, (iv) identifying high performing stores by retailers.

Velipasalar, Senem↗

A fast, matrix-based method to perform omnidirectional pressure integration

Abstract Experimentally-measured pressure fields play an important role in understanding many fluid dynamics problems. Unfortunately, pressure fields are difficult to measure directly with non-invasive, spatially resolved diagnostics, and calculations of pressure from velocity have proven sensitive to error in the data. Omnidirectional line integration methods are usually more accurate and robust to these effects as compared to implicit Poisson equations, but have seen slower uptake due to the higher computational and memory costs, particularly in 3D domains. This paper demonstrates how omnidirectional line integration approaches can be converted to a matrix inversion problem. This novel formulation uses an iterative approach so that the boundary conditions are updated each step, preserving the convergence behavior of omnidirectional schemes while also keeping the computational efficiency of Poisson solvers. This method is implemented in Matlab and also as a GPU-accelerated code in CUDA-C++. The behavior of the new method is demonstrated on 2D and 3D synthetic and experimental data. Three-dimensional grid sizes of up to 125 million grid points are tractable with this method, opening exciting opportunities to perform volumetric pressure field estimation from 3D PIV measurements.

42 ENGINEERING↗

Electron Energy-Loss Spectroscopy and Differential Phase Contrast Imaging with Active Decision in Multimodal Electron Microscopy: Isotopic detection at the atomic scale

Isotopic engineering provides a powerful route to control phonon behavior in crystalline solids, enabling fundamental studies of lattice dynamics and heat transport at the atomic scale. Here, we directly visualize isotope-dependent phonon propagation in epitaxial Cr 2 O 3 using aberration-corrected scanning transmission electron microscopy (STEM) combined with monochromated, high-energy-resolution electron energy-loss spectroscopy (EELS). Guided by ab initio phonon calculations, we demonstrate that optical phonon modes above 70 meV are predominantly oxygen-derived and exhibit measurable redshifts upon substitution of natural 16 O by enriched 18 O. Spatially resolved vibrational spectrum imaging reveals isotope-enriched tracer layers within Cr 2 O 3 thin films, correlating isotope concentration with phonon intensity variations and vibrational energy shifts. At the nanometer and atomic scales, vibrational EELS mapping uncovers coherent phonon propagation across isotopic interfaces, consistent with theoretical phonon density of states and dispersion relations. These results establish vibrational EELS as a quantitative probe for isotope-dependent phonon transport in materials, opening new possibilities for studying energy dissipation and lattice dynamics.

36 MATERIALS SCIENCE↗

A parametric study of electron multiharmonic instabilities in the magnetosphere

This paper presents numerical calculations of spatial growth rates of multiharmonic electron-cyclotron instabilities driven by a loss-cone energetic distribution, in the presence of colder electrons. When the cold electron density is comparable to the hot, nonconvective instability is possible in harmonic bands below or including the cold upper-hybrid frequency. When the cold electron density is larger than the hot, nonconvective instability is possible only in that band containing the cold upper-hybrid frequency. Increasing the cold electron temperature in relation to the hot eventually removes all nonconvective behavior. Convective instability is still possible above the cold upper-hybrid frequency.

Ashour-Abdalla, M.↗

High-resolution reflectance spectra of Mars in the 2.3-micron region - Evidence for the mineral scapolite

Spatially resolved reflectance spectra of Mars obtained from the Cooled Grating Array Spectrometer at the NASA Infrared Telescope Facility during August 26-30, 1988 were used to investigate the mineralogic origin of the 2.36-micron band that was revealed previously in Martian spectra. The new high-resolution data demonstrate that the absorption envelope centered near 2.36 microns has considerable spectral fine structure. It is shown that, while some of the observed absorption is due to CO in the Martian atmosphere, a significant amount of the observed spectral behavior is due to a solid mineral phase on the Martian surface. The solid-phase absorption features observed were found to match the spectral fine structure of minerals in the scapolite family. Scapolites of differing compositions were found which closely reproduce the regional spectral variations observed on Mars.

Clark, Roger N.↗

In Situ Monitoring of Crystal Growth Using Mephisto

Experiments were carried out to study the morphological stability of Bi-1atomic% Sn alloys using the MEPHISTO directional solidification apparatus aboard Space Shuttle Columbia (STS-87, launched November 19, 1997). The research program involved collaboration of the University of Florida, Centre National d'Etudes Spatiales (France), NASA/Glenn Research Center, the National Institute of Standards and Technology, and the University of New South Wales (Australia). The experiments made use of the Seebeck technique to measure the interface temperature, the resistance change across the sample for determination of the interface velocity, and Peltier current pulsing for demarcation of the interface shape. These data were obtained in real-time during various melting/solidification cycles, and the experiments were controlled via telecommands. The Seebeck signal and temperature measurements in the space experiments, as well as morphological behavior of the solid/liquid interface, were found to be significantly different than those obtained from ground-based studies. For the space-based experiments, interface breakdown was observed at growth velocities of 6.7, 27, and 40 micrometers/s, but not at 1.8 and 3.3 micrometers/s. The results further indicate that the morphological stability threshold for some grain orientations is significantly enhanced, resulting in a staggered planar to cellular transition front. This report summarizes some of these findings.

Abbaschian, Reza↗

Transient Effects in Atmosphere and Ionosphere Preceding the 2015 M7.8 and M7.3 Gorkha–Nepal Earthquakes

We analyze retrospectively/prospectively the transient variations of six different physical parameters in the atmosphere/ionosphere during the M7.8 and M7.3 earthquakes in Nepal, namely: 1) outgoing longwave radiation (OLR) at the top of the atmosphere (TOA); 2) GPS/TEC; 3) the very-low-frequency (VLF/LF) signals at the receiving stations in Bishkek (Kyrgyzstan) and Varanasi (India); 4) Radon observations; 5) Atmospheric chemical potential from assimilation models; and; 6) Air Temperature from NOAA ground stations. We found that in mid-March 2015, there was a rapid increase in the radiation from the atmosphere observed by satellites. This anomaly was located close to the future M7.8 epicenter and reached a maximum on April 21–22. The GPS/TEC data analysis indicated an increase and variation in electron density, reaching a maximum value during April 22–24. A strong negative TEC anomaly in the crest of EIA (Equatorial Ionospheric Anomaly) occurred on April 21, and a strong positive anomaly was recorded on April 24, 2015. The behavior of VLF-LF waves along NWC-Bishkek and JJY-Varanasi paths has shown abnormal behavior during April 21–23, several days before the first, stronger earthquake. Our continuous satellite OLR analysis revealed this new strong anomaly on May 3, which was why we anticipated another major event in the area. On May 12, 2015, an M7.3 earthquake occurred. Our results show coherence between the appearance of these pre-earthquake transient’s effects in the atmosphere and ionosphere (with a short time-lag, from hours up to a few days) and the occurrence of the 2015 M7.8 and M7.3 events. The spatial characteristics of the pre-earthquake anomalies were associated with a large area but inside the preparation region estimated by Dobrovolsky-Bowman. The preearthquake nature of the signals in the atmosphere and ionosphere was revealed by simultaneous analysis of satellite, GPS/TEC, and VLF/LF and suggest that they follow a general temporal-spatial evolution pattern that has been seen in other large earthquakes worldwide

Dimitar Ouzounov↗

Learning From User Behavior: A Survey-Assist Algorithm for Longitudinal Mobility Data Collection

GPS-based travel surveys are widely used in mobility studies to gather crucial qualitative data, like purpose, transportation mode and replaced mode. However, survey response still poses a burden to users, especially in long-term mobility studies, leading to response fatigue. We explore a survey-assist strategy to ease this burden by a novel, user-level modeling approach that leverages past responses from each user to predict responses for new trips, without relying on external data sources like GIS data. We investigate three main algorithms for predicting responses: (i) clustering trips and extrapolating responses for similar trips, (ii) using random forest classification, and (iii) clustering that uses a hybrid algorithm to determine spatial structure, which is then fed as input to a classic random forest classifier. The clustering approach can flexibly predict responses for even complex qualitative survey questions; it achieved F-scores of 65%. The random forest pipeline uses architecture that restricts it to predicting three predetermined survey questions: trip purpose, mode, and replaced mode. However, it achieved F-scores of 78%. While the survey-assist approach has been implemented by several proprietary systems, to our knowledge, this is the first exploration in the academic literature. It follows that this is also the first rigorous evaluation of multiple algorithms that can implement the approach. The evaluation uses a large scale, publicly available, longitudinal dataset consisting of ~ 92k trips from 235 users over a period of roughly one and a half years. With this approach, travel surveys can be pre-filled with the predicted responses for each trip, thus streamlining the survey process for users. Combined with an active learning system that requests user input on low-confidence predictions, models can be updated and improved over time to better support the long-term collection of longitudinal qualitative data.

clustering↗

Unravelling Magnetic Nanochain Formation in Dispersion for In Vivo Applications

Self-assembly of iron oxide nanoparticles (IONPs) into 1D chains is appealing, because of their biocompatibility and higher mobility compared to 2D/3D assemblies while traversing the circulatory passages and blood vessels for in vivo biomedical applications. In this work, parameters such as size, concentration, composition, and magnetic field, responsible for chain formation of IONPs in a dispersion as opposed to spatially confining substrates, are examined. In particular, the monodisperse 27 nm IONPs synthesized by an extended LaMer mechanism are shown to form chains at 4 mT, which are lengthened with applied field reaching 270 nm at 2.2 T. The chain lengths are completely reversible in field. Using a combination of scattering methods and reverse Monte Carlo simulations the formation of chains is directly visualized. The visualization of real-space IONPs assemblies formed in dispersions presents a novel tool for biomedical researchers. This allows for rapid exploration of the behavior of IONPs in solution in a broad parameter space and unambiguous extraction of the parameters of the equilibrium structures. Additionally, it can be extended to study novel assemblies formed by more complex geometries of IONPs.

36 MATERIALS SCIENCE↗

Scanning Electrochemical Microscopy: An Evolving Toolbox for Revealing the Chemistry within Electrochemical Processes

The parallel development of ultramicroelectrodes (UMEs) and groundbreaking scanning probe microscopy techniques in the late 1980s led to the development of the scanning electrochemical microscope. Scanning electrochemical microscopy (SECM) was born from the idea of using a tiny electrode to measure the local electrochemical behavior at operating electrodes. From its foundations, the technique displayed an inherent versatility in measuring sample properties beyond topography. It allowed experimenters to measure and map chemical reactions occurring at diverse interfaces, from inspecting the reversibility of redox mediators at metal electrodes, to detecting the hallmarks of cellular respiration on living plant leaves. Related but distinct electrochemical scanning probe techniques, such as electrochemical atomic force microscopy (EC-AFM), scanning ion conductance microscopy (SICM), and scanning electrochemical cell microscopy (SECCM) have developed in parallel. These techniques have demonstrated exquisite spatial resolution down to the nanoscale regime. However, it is the proposition of this review that SECM remains unmatched at revealing the chemical aspects of electrochemistry. Furthermore, it is our intention to review and demonstrate that the versatile architecture of SECM continues to evolve and address fundamental and emerging challenges in the fields of energy storage and conversion, chemical biology, materials science, and environmental chemistry, among others.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Intrinsic structural instabilities of domain walls driven by gradient coupling: Meandering antiferrodistortive-ferroelectric domain walls in BiFeO 3

Using the Landau-Ginzburg-Devonshire approach, we predict the intrinsic instability of the ferroelectric-ferroelastic domain walls in the multiferroic BiFeO 3 emerging from the interplay between the gradient terms of the antiferrodistortive and ferroelectric order parameters at the walls. These instabilities are the interface analog of the structural instabilities in the vicinity of phase coexistence in the bulk, and so they do not stem from incomplete polarization screening in thin films or its spatial confinement, electrostrictive or flexoelectric coupling. The effect of BiFeO 3 material parameters on the 71°, 109°, and 180° walls is explored, and it is shown that the meandering instability appears at 109° and 180° walls for small gradient energies, and the walls become straight and broaden for higher gradients. In contrast to the 180° and 109° domain walls, uncharged 71° walls are always straight, and their width increases with increasing the tilt gradient coefficient. As a result, the wall instability and associated intrinsic meandering provide insight into the behavior of morphotropic and relaxor materials, wall pinning, and mechanisms of interactions between order parameter fields and local microstructure.

36 MATERIALS SCIENCE↗

Observation of Fast Current Redistribution in an Imploding Plasma Column

Spectroscopic measurements of the magnetic field evolution in a Z-pinch throughout stagnation and with particularly high spatial resolution reveal a sudden current redistribution from the stagnating plasma (SP) to a low-density plasma (LDP) at larger radii, while the SP continues to implode. Based on the plasma parameters it is shown that the current is transferred to an increasing-conductance LDP outside the stagnation, a process likely to be induced by the large impedance of the SP. In conclusion, since an LDP often exists around imploding plasmas and in various pulsed-power systems, such a fast current redistribution may dramatically affect the behavior and achievable parameters in these systems.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Analysis of Viking infrared thermal mapping data of Mars. The effects of non-ideal surfaces on the derived thermal properties of Mars

The thermal interia of the surface of Mars varies spatially by a factor of eight. This is attributable to changes in the average particle size of the fine material, the surface elevation, the atmospheric opacity due to dust, and the fraction of the surface covered by rocks and fine material. The effects of these non-ideal properties on the surface temperatures and derived thermal inertias are modeled, along with the the effects of slopes, CO2 condensed onto the surface, and layering of fine material upon solid rock. The non-ideal models are capable of producing thermal behavior similar to that observed by the Viking Infrared Thermal Mapper, including a morning delay in the post-dawn temperature rise and an enhanced cooling in the afternoon relative to any ideal, homogeneous model. The enhanced afternoon cooling observed at the Viking-1 landing site is reproduced by the non-ideal models while that atop Arsia Mons volcano is not, but may be attributed to the observing geometry.

Muhleman, D. O.↗

The response of cylindrical panels fabricated from symmetrically and unsymmetrically laminated composite materials

Equations are developed which govern the deflection response of long cylindrical panels subjected to a line load. The line load is directed toward the center of curvature of the panel, is located at an arbitrary point along the arc length of the panel, and is included at an arbitrary angle relative to the radial direction. Only the geometrically linear problem is considered and the spatial dependence in the problem is reduced to one independent variable, specifically, the arc length along the panel. The problem is thus solvable in closed form. Both symmetrically laminated and the less common unsymmetrically laminated simply supported panels are studied. The unsymmetrically laminated case was considered because the natural shape of an unsymmetric laminate is cylindrical. Results are presented which show the influence of the location and inclination of the line load on panel deflection. Shallow and deep panels are considered. Both the symmetric and unsymmetric panels exhibit similar behavior, the unsymmetric configurations being less stiff. Limited experimental results are presented.

Carper, D. M.↗

Emergent Behavior at the Calcite–Water Interface during Reactive Transport in a Simple Microfluidic Channel

Geochemical reactive transport processes in natural mineral-fluid systems may produce a wide array of emergent phenomena that are difficult to predict from basic principles and to reproduce in model systems. In this study, we present experimental results obtained from a simple microfluidic system with which we explored the consequences of reacting the calcite (104) cleavage surface with an acidic Pb-bearing solution (pH = 3.5, [Pb] total = 5 mM) as a function of flow rate. This system is relevant to passive remediation systems for Pb-rich acid mine drainage. We observed periodic banding in the amounts of Pb sorption at flow velocities ≥ 926 μm s -1 , where the band spacing was spatially correlated with the amount of calcite dissolution and the development of micropyramidal topography on the calcite (104) surface. The equivalent coverage of Pb deposited in these Pb-rich bands was at least several monolayers per unit cell, yet there was no evidence for precipitation of any secondary Pb phase implying incorporation of Pb within the near-surface calcite lattice. We also observed spatial variations in nucleation and growth of euhedral secondary Pb-carbonate minerals hydrocerusite and cerussite at flow rates ≤ 278 μm s -1 ,. These findings demonstrate potential for exploiting the rich phenomenology afforded by the interplay among transport phenomena and chemical kinetics in experimental systems designed to yield deeper insights into geochemical self-organization.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗