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All sourcesNASA NTRSDOE OSTI
DOE OSTI2023

SAS4A/SASSYS-1 Validation with EBR-II Tests Performed During the SHRT Testing Program (Rev. 2)

The EBR-II sodium-cooled fast reactor supported a wide range of fast reactor research activities. The final fifteen years of operations at EBR-II were used for experiments and tests to demonstrate the importance of passive safety in liquid metal reactors and the capability of such systems to provide strong passive responses during off-normal conditions. The Shutdown Heat Removal Test program at EBR-II provided test data supporting the validation of computer codes for design, licensing, and operation of LMRs, among other objectives. The program included nearly sixty tests, most of which were protected and unprotected loss of flow and loss of heat sink tests run at various initial powers and flow rates. This report documents the results of modeling and simulation of tests from the Shutdown Heat Removal Test program to support validation of Argonne’s SAS4A/SASSYS-1 fast reactor safety analysis code. SHRT-17 and SHRT-6 were protected loss of flow tests where a loss of electrical power to all sodium coolant pumps was simulated to demonstrate the effectiveness of natural circulation cooling characteristics. SHRT-45R, SHRT-39, and SHRT-43R were unprotected loss of flow tests where the control rod scram function of the plant protection system was disabled to demonstrate the effectiveness of EBR-II’s passive reactivity feedbacks. BOP-301 and BOP-302R were unprotected loss of heat sink tests that demonstrated how reactivity feedback effects driven by changes to the core inlet temperature can shut down the fission process. PICT-5/6 demonstrated how core power could be increased and decreased via changes in the intermediate sodium and feedwater flow rates. This validation activity leverages modeling and simulation efforts that originated under an International Atomic Energy Agency Coordinated Research Project for benchmark analysis of the EBR-II Shutdown Heat Removal Tests. The SAS4A/SASSYS-1 models originally developed for the CRP have been modernized to utilize new code features and modeling practices. Differences between the predicted and measured test data were explored and the causes of these differences were identified as being due to modeling approximations, uncertainty in transient component behavior, and instrumentation uncertainties. Overall, it was concluded that for all tests simulated there was good agreement between the flow, power, and temperature predictions and the measured data.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2018

Immobilization of Organic Liquid Radioactive Waste (LWR) in a Sulfur Composite Matrix at the BN-350 Fast Neutron Reactor Site, Kazakhstan - 18031

The immobilization treatment and final disposition of all forms of organic radioactive liquids, such as pump oil, spent solvent, tri-butyl-phosphate (TBP) and scintillation fluids, remain a significant challenge for nuclear waste generators and national regulators. The majority of nuclear nations have instituted regulations that require some form of encapsulation of treated organic liquid, notwithstanding LLW organic liquids that can be safely incinerated. In most cases cement is the designated material for encapsulation; however, cement can pose certain problems with the containment of treated organic liquids. In 2013, with funding from the U.S. Department of Energy - National Nuclear Security Administration through its Global Initiative for Proliferation Prevention Program (GIPP), a proven U.S. technology for the treatment of radioactive organic liquids was introduced at the BN-350 fast neutron reactor facility in Aktau, Kazakhstan. As the facility was undergoing full decommissioning, one hundred and sixty cubic meters of contaminated pump oil (including Cs-137, Sr-90 and U-235/238) contained in large above ground tanks had to be treated for final disposal. As a result of the research conducted over a two-year period, a new 2-step treatment process was invented by combining the U.S. solidification technology with a newly developed inorganic filler and molecular sulfur, referred to as radiation-resistant composite (RRC) to fully encapsulate the waste oil. The outcome of extensive test program indicates that the final form can reach up to 60 wt.% with a compressive strength of about 100 kg/cm{sup 2}. Preliminary conclusions indicate that RRC outperforms cement as an encapsulation form for final waste treatment which meets U.S. Nuclear Regulatory requirements for final disposal. This paper examines the preliminary experimental work that was conducted in Kazakhstan with the U.S. polymer technology and radioactive pump oil, and the subsequent secondary process of combining the solidified material into a homogeneous final form utilizing RRC. Topics covered in the paper include: - Kazakhstan's regulatory requirements for attaining an achievable waste form for acceptance, which led to the RRC invention; - Technical objectives for the application of polymer technology and RRC materials to radioactive liquid waste; - Polymer solidification with radioactive oil and the result; step one of the RRC process; - Description of RRC materials, their origin and chemical characteristics; - Process of combining the solidified polymer mass with RRC materials into a solid, homogeneous matrix; step two of the RRC process; - Experimental results including leaching data, waste loading estimates and heat process calculations to create the matrix; - Cost advantages of the RRC process over cementation; - Limitations of the RRC process; - Next steps to verify conformance of the RRC technology to the U.S. requirements. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2015

Center for Electrocatalysis, Transport Phenomena, and Materials (CETM) for Innovative Energy Storage - Final Report

EFRC vision. The direct use of organic hydrides in fuel cells as virtual hydrogen carriers that generate stable organic molecules, protons, and electrons upon electro-oxidation and can be electrochemically charged by re-hydrogenating the oxidized carrier was the major focus of the Center for Electrocatalysis, Transport Phenomena and Materials for Innovative Energy Storage (EFRC-ETM). Compared to a hydrogen-on-demand design that includes thermal decomposition of organic hydrides in a catalytic reactor, the proposed approach is much simpler and does not require additional dehydrogenation catalysts or heat exchangers. Further, this approach utilizes the advantages of a flow battery (i.e., separation of power and energy, ease of transport and storage of liquid fuels) with fuels that have system energy densities similar to current hydrogen PEM fuel cells. EFRC challenges. Two major EFRC challenges were electrocatalysis and transport phenomena. The electrocatalysis challenge addresses fundamental processes which occur at a single molecular catalyst (microscopic level) and involve electron and proton transfer between the hydrogen rich and hydrogen depleted forms of organic liquid fuel and the catalyst. To form stable, non-radical dehydrogenation products from the organic liquid fuel, it is necessary to ensure fast transport of at least two electrons and two protons (per double bond formation). The same is true for the reverse hydrogenation reaction. The transport phenomena challenge addresses transport of electrons to/from the electrocatalyst and the current collector as well as protons across the polymer membrane. Additionally it addresses prevention of organic liquid fuel, water and oxygen transport through the PEM. In this challenge, the transport of protons or molecules involves multiple sites or a continuum (macroscopic level) and water serves as a proton conducting medium for the majority of known sulfonic acid based PEMs. Proton transfer in the presence of prospective organic liquid fuels was studied. During EFRC program various types of electrocatalysts, classes of fuels, and membranes have been investigated.

25 ENERGY STORAGE↗
DOE OSTI2021

Institutional and Policy Landscape for Solar-Plus-Storage Deployment by Electric Cooperatives

As co-location with battery storage has become a significant solar project-design trend across the United States, policies at all levels have started to adjust. Generally, these policies address battery storage development in major, urban markets, served by large investor-owned utilities (IOUs). Yet all kinds of utilities nationwide are seeking ways to tap into the fast-growing battery storage market, and they are all stakeholders in the federal, state, and local policies that impact the storage market's development. The electric cooperative sector, which includes some 830 distribution utilities and 63 generating and transmission (G&T) utilities across a mostly rural landscape, is no exception. It is impacted by federal, state, and local government policy requirements and incentives, as well as by policies that are controlled by the sector's own institutions. The objective of this paper is to identify and discuss the various policy and institutional factors that are relevant to the electric cooperative sector, and especially to local, distribution-level electric cooperatives (co-ops) that may be interested in procuring energy storage. Given this, the paper is largely written from the local co-op perspective. It also may be useful to wholesale G&T cooperatives. Other parties that may find the paper useful include storage developers, who are often unfamiliar with co-ops; local and state policymakers addressing policy options for this sector, and local renewable or storage stakeholders, who wish to understand the policy landscape affecting their local utility. Although co-op energy storage programs may tap customer-side batteries, this examination is focused on utility-side "front of the meter" projects and the policy issues they raise.

14 SOLAR ENERGY↗
DOE OSTI2013

Sensor Network Demonstration for In Situ Decommissioning - 13332

Florida International University's (FIU's) Applied Research Center is currently supporting the Department of Energy's (DOE) Environmental Management Office of D and D and Facility Engineering program. FIU is supporting DOE's initiative to improve safety, reduce technical risks, and limit uncertainty within D and D operations by identifying technologies suitable to meet specific facility D and D requirements, assessing the readiness of those technologies for field deployment, and conducting feasibility studies and large scale demonstrations of promising technologies. During FY11, FIU collaborated with Savannah River National Laboratory in the development of an experimental test site for the demonstration of multiple sensor systems for potential use in the in situ decommissioning process. In situ decommissioning is a process in which the above ground portion of a facility is dismantled and removed, and the underground portion is filled with a cementious material such as grout. In such a scenario, the question remains on how to effectively monitor the structural health of the grout (cracking, flexing, and sinking), as well as track possible migration of contaminants within and out of the grouted monolith. The right types of sensors can aid personnel in better understanding the conditions within the entombed structure. Without sensors embedded in and around the monolith, it will be very difficult to estimate structural integrity and contaminant transport. Yet, to fully utilize the appropriate sensors and the provided data, their performance and reliability must be evaluated outside a laboratory setting. To this end, a large scale experimental setup and demonstration was conducted at FIU. In order to evaluate a large suite of sensor systems, FIU personnel designed and purchased a pre-cast concrete open-top cube, which served as a mock-up of an in situ DOE decommissioned facility. The inside of the cube measures 10 ft x 10 ft x 8 ft. In order to ensure that the individual sensors would be immobilized during the grout pouring activities, a set of nine sensor racks were designed. The 270 sensors provided by Idaho National Laboratory (INL), Mississippi State University (MSU), University of Houston (UH), and University of South Carolina (USC) were secured to these racks based on predetermined locations. Once sensor racks were installed inside the test cube, connected and debugged, approximately 32 cubic yards of special grout material was used to entomb the sensors. MSU provided and demonstrated four types of fiber loop ring-down (FLR) sensors for detection of water, temperature, cracks, and movement of fluids. INL provided and demonstrated time differenced 3D electrical resistivity tomography (ERT), advanced tensiometers for moisture content, and thermocouples for temperature measurements. University of Houston provided smart aggregate (SA) sensors, which detect crack severity and water presence. An additional UH sensor system demonstrated was a Fiber Bragg Grating (FBG) fiber optic system measuring strain, presence of water, and temperature. USC provided a system which measured acoustic emissions during cracking, as well as temperature and pH sensors. All systems were connected to a Sensor Remote Access System (SRAS) data networking and collection system designed, developed and provided by FIU. The purpose of SRAS was to collect and allow download of the raw sensor data from all the sensor system, as well as allow upload of the processed data and any analysis reports and graphs. All this information was made available to the research teams via the Deactivation and Decommissioning Knowledge Management and Information Tool (D and D KM-IT). As a current research effort, FIU is performing an energy analysis, and transferring several sensor systems to a Photovoltaic (PV) System to continuously monitor energy consumption parameters and overall power demands. Also, One final component of this research is focusing on developing an integrated data network to capture, log and analyze sensor system data in near real time from a single interface. FIU personnel and DOE Fellows monitored the progress and condition of the sensors for a period of six months. During this time, the sensors recorded data pertaining to strain, compression, temperature, crack detection, moisture presence, fluid mobility, shock resistance, monolith movement, and electrical resistivity. In addition, FIU regularly observed the curing process of the grout and documented the cube condition via the nine racks of sensors. The sensors held up throughout the curing process, withstood the natural elements for six months, and monitored the integrity of the grout. The large scale experiment and demonstration conducted at FIU was the first of its kind to demonstrate the feasibility of state of the art sensors for in situ decommissioning applications. These efforts successfully measured the durability, performance, and precision of the sensors in question as well as monitored and recorded the curing process of the selected grout material under natural environmental conditions. The current energy analysis work is resulting in data on the constraints placed by some of the sensor systems on a power network that requires high reliability and low losses. In addition, a sensor system demonstration has determined that it is feasible to develop an integrated data network where data can be accessed in near real-time from all systems, thereby allowing for larger-scale integrated system testing to be performed. Information collected during the execution of this research project will aid decision makers in the identification of sensors to be used in nuclear facilities selected for in situ decommissioning. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2016

Final Scientific/Technical Report (DOE F 241.3) Next-Generation LED Package Architectures Enabled by Thermally Conductive Transparent Encapsulants

The objective of this program is to generate novel LED package designs that would provide 30% improvement in lumen/$ output. This was to be achieved by improving thermal management in encapsulants/ phosphors to reduce their temperatures. Currently, the heat that is generated during down conversion of blue light to longer wavelengths by the phosphors dispersed in the encapsulant does not have optimum thermal pathways for dissipation due to poor thermal conductivity of the encapsulant material. Additionally, high temperature in the encapsulant during operation is one of the primary failure modes in LED luminaires resulting in much shorter than expected life. The thermal issues manifest in color instability (yellowing, browning), cracking and hot spots in the encapsulant leading to failures. This work explored boron nitride (hBN) as thermal fillers in encapsulants to improve thermal conductivity while minimally impacting optical properties. Various approaches to Boron Nitride (BN) were evaluated and over 380 samples were generated to down select appropriate BN morphologies. We developed a range or BN materials for enabling thermal properties while attempting to minimally impact to optical properties.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2020

Advanced Anode for Internal Reforming and Thermal Management in Solid Oxide Fuel Cells

Solid oxide fuel cell (SOFC) is an efficient and clean electrical power generation system compared to conventional combustion based technologies with energy efficiency reaching as high as 85-90% in co-generation mode (electricity and heat). Other advantages of SOFCs are hybridization, modularity of construction, small CO 2 foot print per kWh of generated electricity and fuel flexibility. Hydrocarbons present in the gaseous fuel is utilized in SOFCs by internal or external reforming. There are two different internal reforming concepts: Direct Internal Reforming (DIR) and Indirect Internal Reforming (IIR). For DIR operation, the endothermic reforming reaction and the exothermic reaction from the oxidation reaction are operated together in the single unit eliminating the requirement for a separate fuel reformer. This configuration also simplifies the overall system design, making SOFC more attractive and efficient means of producing electrical power. The main advantage of the DIR type of operation is that the H 2 or CO consumption by the electrochemical reaction could directly promote the conversion of methane at the anode side of the fuel cell resulting in high conversion and high efficiency. The DIR operation, however, requires an anode material that has desired dual catalytic (hetero and electro) properties for reforming reaction and electrochemical reactions. The anode materials also need to remain resistant to carbon formation at the operating temperature and atmosphere with stable cell performance. Another requirement is to match the reforming reactions and electrochemical reactions to avoid local cooling or overheating, which can result in mechanical failure due to thermally induced stresses. Direct internal reforming (DIR) of hydrocarbon fuels simplifies the overall SOFC system design making it more attractive and efficient for producing electrical power. Low cost alloy anodes for distributed internal reforming of methane and other hydrocarbon fuels offer increased fuel-flexibility, reliability, and long term performance stability of solid oxide fuel cells (SOFC). The research program examined modification of the chemical compositions and microstructure of high entropy alloy (HEA) anode materials using thermochemical calculations and process simulation and modeling to achieve distributed reforming over the entire anode to eliminate hot zones. Cell fabrication and testing of the HEA anodes using button cell configuration has been performed to demonstrate the advantages of new anode over traditional Ni-YSZ anodes for distributed reforming and carbon free operation. Technical accomplishments include identification and synthesis of HEA carbon-resistant anode, demonstration of reduction in reforming rate confirmed by GC and modelling data validating effectiveness for thermal management in cell/stacks, electrochemical testing of HEA anode in single cell (HEA-GDC||YSZ||LSM-YSZ) and Characterization of pretest and posttest anode materials by TEM and SEM-EDS confirming carbon-free operation.

30 DIRECT ENERGY CONVERSION↗
DOE OSTI2013

Hanford River Protection Project Life cycle Cost Modeling Tool to Enhance Mission Planning - 13396

The Life cycle Cost Model (LCM) Tool is an overall systems model that incorporates budget, and schedule impacts for the entire life cycle of the River Protection Project (RPP) mission, and is replacing the Hanford Tank Waste Operations Simulator (HTWOS) model as the foundation of the RPP system planning process. Currently, the DOE frequently requests HTWOS simulations of alternative technical and programmatic strategies for completing the RPP mission. Analysis of technical and programmatic changes can be performed with HTWOS; however, life cycle costs and schedules were previously generated by manual transfer of time-based data from HTWOS to Primavera P6. The LCM Tool automates the preparation of life cycle costs and schedules and is needed to provide timely turnaround capability for RPP mission alternative analyses. LCM is the simulation component of the LCM Tool. The simulation component is a replacement of the HTWOS model with new capability to support life cycle cost modeling. It is currently deployed in G22, but has been designed to work in any full object-oriented language with an extensive feature set focused on networking and cross-platform compatibility. The LCM retains existing HTWOS functionality needed to support system planning and alternatives studies going forward. In addition, it incorporates new functionality, coding improvements that streamline programming and model maintenance, and capability to input/export data to/from the LCM using the LCM Database (LCMDB). The LCM Cost/Schedule (LCMCS) contains cost and schedule data and logic. The LCMCS is used to generate life cycle costs and schedules for waste retrieval and processing scenarios. It uses time-based output data from the LCM to produce the logic ties in Primavera P6 necessary for shifting activities. The LCM Tool is evolving to address the needs of decision makers who want to understand the broad spectrum of risks facing complex organizations like DOE-RPP to understand how near-term programmatic decisions affect life cycle costs and commitments. (authors)

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2015

The conduct of the united states department of energy nuclear criticality safety program hands-on training and education courses - 14621

The United States Department of Energy (DOE) Nuclear Criticality Safety Program (NCSP), funded and managed by the National Nuclear Security Administration (NNSA), offers courses to educate nuclear criticality safety (NCS) engineers, process supervisors, and others, and to provide experimental, hands-on training addressing important characteristics of neutron multiplying systems. This training satisfies the American National Standard Institute/American Nuclear Society (ANSI/ANS)-8.26-2007 requirement for participating in hands-on experiments with fissionable materials and provides awareness and understanding of DOE Orders, Guides and Rules, ANS standards, and hazard identification techniques, as well as control design, implementation, and maintenance in criticality safety evaluations. Since the pilot course was developed in 2011, a variety of courses have been developed for NCS practitioners and process supervisors. Attendees have come from several US and international sites. Through NCSP international collaborations and relationships, students from the Atomic Weapons Establishment (AWE) in the United Kingdom, Atomic Energy of Canada, and the Institute for Radiation Protection and Nuclear Safety in France have participated in these courses in the US. Manager courses are available for process supervisors and operations managers with NCS responsibilities in their daily jobs. Manager courses are taught at Sandia National Laboratory (SNL) and the National Criticality Experiments Research Center (NCERC); they offer a combination of hands-on experiments and classroom discussions. A two-week course is also offered for NCS practitioners, with a week of classroom instruction at Los Alamos National Laboratory (LANL) focused on generation of NCS evaluations, and a week of hands-on training utilizing the critical assemblies at either SNL or NCERC. Cleared students can attend the hands-on training at either SNL or NCERC, and uncleared students can attend at SNL. Courses continue to evolve and continuously improve as important elements of NCS evaluations (e.g., human factors, non-destructive assay (NDA) techniques, process criticality accident lessons-learned, and hand calculation methods) are integrated with criticality safety evaluation exercises. Courses include tours of process operations at SNL, NCERC, and LANL, and interaction with instructors experienced in conducting critical experiments and working in NCS. The NNSA NCSP provides management, funding, and technical direction for these courses and makes them available with no tuition cost to NCS practitioners. This paper provides a status report to the NCS community on the conduct of these courses and how they will likely evolve in the future. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗
DOE OSTI2016

Convective Heat Transfer in Decay Heat Exchanger of Sodium-cooled Fast Reactor

Sodium-to-sodium heat exchangers such as the decay heat exchanger (DHX) are key components of the prototype generation [V sodium-cooled fast reactor (PGSFR). The DHX transfers the decay heat generated in the reactor core to the decay heat removal loop after a reactor shutdown. Shell-and-tube type with straight tube arrangement has been widely adopted for the sodium-to-sodium heat exchanger of the sodium-cooled fast reactor. Thus liquid metal heat transfer characteristics inside the tube and around the tube bundle have to be fully understood to design the sodium-to-sodium heat exchanger and evaluate its thermal performance accurately. Plenty of studies on the convective heat transfer of the liquid metals were conducted to present the Nusselt number (Nu) correlations with respect to the Peclet number (Pe). However, those correlations still deviated from each other considerably and few of correlations for low Pe range (less than 100) have been reported. Accordingly, it is difficult for a design code developer to choose a proper heat transfer coefficient correlation for the sodium-to-sodium heat exchanger particularly in a low flow rate range. Recently, a separate effect test for the DHX has been completed using the STELLA-1 facility at KAERI according to the STELLA program which aims at establishment of separate and integral test database (DB) for the design of the PGSFR. The heat transfer performance test of the DHX was successfully conducted under major operating conditions. The objective of this work is to suggest proper convective heat transfer correlations for tube- and shell-sides of the sodium-to-sodium heat exchanger based on the test DB obtained from STELLA-1. The Pe range of the analyzed experimental data is concentrated on less then 100. The adequacy of the suggested correlations is evaluated by applying to the DHX design code, SHXSA. Based on the DHX test DB of the STELLA-1, the proper convective heat transfer correlations for the tube- and shell-side of sodium-to-sodium heat exchangers were suggested. Two correlation combinations for each side were proposed and turned out to be reasonable through the evaluation using the SHXSA design code: Suggestion no. 1: - Lyon correlation (constant = 4) for tube-side; - Lubarsky-Kaufman correlation for shell-side. Suggestion no. 2: - Modified Lyon correlation (constant = 1.45) for tube-side; - Schad-modified correlation for shell-side The Pe ranges of the DHX test DB were 53 - 225 for the tube-side and 45 - 148 for the shell-side, but most of test conditions were concentrated on the Pe range of less than 100. Two correlation suggestions can be practically used for the design of sodium-to-sodium heat exchangers. However, by utilizing more test DB, it needs to be verified which one is closer to real phenomena. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2013

Predicting Backdrafting and Spillage for Natural-Draft Gas Combustion Appliances: Validating VENT-II

VENT-II is a computer program designed to provide detailed analysis of natural draft and induced draft combustion appliance vent-systems (i.e., furnace or water heater). This program is capable of predicting house depressurization thresholds that lead to backdrafting and spillage of combustion appliances; however, validation reports of the program being applied for this purpose are not readily available. The purpose of this report is to assess VENT-II’s ability to predict combustion gas spillage events due to house depressurization by comparing VENT-II simulated results with experimental data for four appliance configurations. The results show that VENT-II correctly predicts depressurizations resulting in spillage for natural draft appliances operating in cold and mild outdoor conditions, but not for hot conditions. In the latter case, the predicted depressurizations depend on whether the vent section is defined as part of the vent connector or the common vent when setting up the model. Overall, the VENTII solver requires further investigation before it can be used reliably to predict spillage caused by depressurization over a full year of weather conditions, especially where hot conditions occur.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2015

Electricity market design for generator revenue sufficiency with increased variable generation

Here, we present a computationally efficient mixed-integer program (MIP) that determines optimal generator expansion decisions, and hourly unit commitment and dispatch in a power system. The impact of increasing wind power capacity on the optimal generation mix and generator profitability is analyzed for a test case that approximates the electricity market in Texas (ERCOT). We analyze three market policies that may support resource adequacy: Operating Reserve Demand Curves (ORDC), Fixed Reserve Scarcity Prices (FRSP) and fixed capacity payments (CP). Optimal expansion plans are comparable between the ORDC and FRSP implementations, while capacity payments may result in additional new capacity. The FRSP policy leads to frequent reserves scarcity events and corresponding price spikes, while the ORDC implementation results in more continuous energy prices. Average energy prices decrease with increasing wind penetration under all policies, as do revenues for baseload and wind generators. Intermediate and peak load plants benefit from higher reserve prices and are less exposed to reduced energy prices. All else equal, an ORDC approach may be preferred to FRSP as it results in similar expansion and revenues with less extreme energy prices. A fixed CP leads to additional new flexible NGCT units, but lower profits for other technologies.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2013

Lights, Camera, Action ... and Cooling - The case for centralized low carbon energy at Fox Studios

Fox Studios partnered with the U.S. Department of Energy (DOE) to develop and implement solutions to retrofit two production stages and one of its central cooling plants, to reduce energy consumption by at least 30% as part of DOE’s Commercial Building Partnerships (CBP) Program. Although this case study reports expected savings arising from proposed design recommendations for a unique building type and the unusual load characteristics associated with its use, the EEMs implemented for the central plant are applicable to any large campus, office and higher education facility. The intent is that by making the energy-efficiency measures (EEMs) set that were assessed as cost-effective from this project applicable to a larger number of buildings on the campus Fox Studios will be able to implement an integrated campus-wide energy strategy for the long term. The significant challenges for this project in the design phase included identifying how to assess and analyze multiple system types, develop a coherent strategy for assessment and analysis, implement the measurement and verification activities to collect the appropriate data (in terms of capturing ‘normal’ operating characteristics and granularity) and determine the best approach to providing cooling to the site buildings based on the nature of existing systems and the expected improvement in energy performance of the central cooling plant. The analytical framework adopted provides a blueprint for similar projects at other large commercial building campuses.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2014

Investigating Deformation and Failure Mechanisms in Nanoscale Multilayer Metallic Composites

Over the history of materials science there are many examples of materials discoveries that have made superlative materials; the strongest, lightest, or toughest material is almost always a goal when we invent new materials. However, often these have been a result of enormous trial and error approaches. A new methodology, one in which researchers design, from the atoms up, new ultra-strong materials for use in energy applications, is taking hold within the science and engineering community. This project focused on one particular new classification of materials; nanolaminate metallic composites. These materials, where two metallic materials are intimately bonded and layered over and over to form sheets or coatings, have been shown over the past decade to reach strengths over 10 times that of their constituents. However, they are not yet widely used in part because while extremely strong (they don’t permanently bend), they are also not particularly tough (they break relatively easily when notched). Our program took a coupled approach to investigating new materials systems within the laminate field. We used computational materials science to explore ways to institute new deformation mechanisms that occurred when a tri-layer, rather than the more common bi-layer system was created. Our predictions suggested that copper-nickel or copper-niobium composites (two very common bi-layer systems) with layer thicknesses on the order of 20 nm and then layered 100’s of times, would be less tough than a copper-nickel-niobium metallic composite of similar thicknesses. In particular, a particular mode of permanent deformation, cross-slip, could be activated only in the tri-layer system; the crystal structure of the other bi-layers would prohibit this particular mode of deformation. We then experimentally validated this predication using a wide range of tools. We utilized a DOE user facility, the Center for Integrated Nanotechnology (CINT), to fabricate, for the first time, these tri-layer composites. CINT formed nanolaminate composites were tested in tension, with bulge testing, using nanoindentation, and using micro-compression testing to demonstrate that the tri-layer films were indeed tougher and hardened more during deformation (they got stronger as we deformed them) than equivalent bi-layers. The seven graduate students, 4 post-docs and research faculty, and the two faculty co-PI’s were able to create a collaborated computational prediction and experimental validation team to demonstrate the benefits of this class of materials to the community. The computational work crossed from atomistic to bulk simulations, and the experiments coupled form nm-scale to the mm scale; closely matching the simulations. The simulations provided viable mechanisms that explained the observed results, and new experimental results were used to push the boundaries of the simulation tools. Over the life of the 7 years of this program we proved that tri-layer nanolaminate metallic composite systems exceeded the mechanical performance of bi-layer systems if the right materials were chosen, and that the mechanism responsible for this was tied to the cross slip of dislocations. With 30 journal publications resulting from this work we have broadly disseminated this family of results to the scientific community.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Alstom’s Limestone Chemical Looping Gasification Process for High Hydrogen Syngas Generation

Alstom Power Inc., a wholly owned subsidiary of the General Electric Company (GE), is developing Limestone-based Chemical Looping (LCL™) Processes, utilizing limestone derived calcium sulfate as an oxygen carrier to transport oxygen from air to the fuel. The LCL™ process is a breakthrough technology with the potential to capture CO 2 and SO 2 from new and existing coal-fired power plants at reduced costs while maintaining high plant power generation efficiency. Chemical looping is a next generation advancement to oxy-combustion which would not require the significant investment in a cryogenic distillation type oxygen production plant. Instead of the energy-consuming oxygen plant, chemical looping uses a benign material to directly remove oxygen from the air and bring that oxygen into contact with the fuel. This "game changing" technology is the lowest cost-of-electricity technical approach that GE Power has identified to date for coal power with carbon capture. The technology has significantly lower capital costs compared to a conventional steam power plant with first generation carbon capture technologies. This new power plant concept is based on a hybrid combustion-gasification process utilizing high temperature chemical and thermal looping technology. In the air reactor, a solid oxygen carrier picks up oxygen from air through an oxidation reaction and leaves nitrogen behind. The hot oxygen-carrying solid carrier is then transported to a fuel reactor, where it releases oxygen. The released oxygen then converts the coal in the fuel reactor into combustion gases. The solid carrier is recycled back to the air reactor for regeneration completing the “chemical loop.” The regeneration step produces heat from which steam is produced for power generation while the process results in a concentrated carbon dioxide stream in which the carbon is captured for use or sequestration (CCUS). Limestone as a precursor for the oxygen carrier is abundant, benign, low cost, and is used in CFB and PC boilers for sulfur control. Challenges associated with this carrier include a complex reaction mechanism with possible side reactions leading to the release of SO 2 . The development of the Limestone Chemical Looping Gasification (LCL-G™) technology was co-funded by the Department of Energy under the DOE/NETL Cooperative Agreement No. DE- FE0023497, in parallel with the collaborative combustion (LCL-C™) program. In this report, the LCL-G™ experimental testing from the electrically-heated, once-through, 100 kW Pilot-Scale Test Facility (PSTF) is analysed and reviewed. The PSTF Oxidizer is a 50-foot tall, 100-mm diameter transport reactor, while the PSTF Reducer reactor is based upon a bubbling-bed design. The experimental data from four (4) test campaigns (denoted “Weeks”) are reviewed and discussed. The LCL-G™ (DE-FE0023497) project objectives for gasification are >90% carbon gasified in the Reducer and a H 2 :CO molar generation ratio of 2:1. These project performance metrics were not met by a single coal test, but they were individually approached in two separate tests.

01 COAL, LIGNITE, AND PEAT↗
DOE OSTI2018

Final Report to the National Energy Technology Laboratory on FY14- FY15 Cooperative Research with the Consortium for Electric Reliability Technology Solutions

The Power System Engineering Research Center (PSERC) engages in technological, market, and policy research for an efficient, secure, resilient, adaptable, and economic U.S. electric power system. PSERC, as a founding partner of the Consortium for Electric Reliability Technology Solutions (CERTS), conducted a multi-year program of research for U.S. Department of Energy (DOE) Office of Electricity Delivery and Energy Reliability (OE) to develop new methods, tools, and technologies to protect and enhance the reliability and efficiency of the U.S. electric power system as competitive electricity market structures evolve, and as the grid moves toward wide-scale use of decentralized generation (such as renewable energy sources) and demand-response programs. Phase I of OE’s funding for PSERC, under cooperative agreement DE-FC26-09NT43321, started in fiscal year (FY) 2009 and ended in FY2013. It was administered by DOE’s National Energy Technology Laboratory (NETL) through a cooperative agreement with Arizona State University (ASU). ASU provided sub-awards to the participating PSERC universities. This document is PSERC’s final report to NETL on the activities for OE, conducted through CERTS, from September 2015 through September 2017 utilizing FY 2014 to FY 2015 funding under cooperative agreement DE-OE0000670. PSERC is a thirteen-university consortium with over 30 industry members. Since 1996, PSERC has been engaged in research and education efforts with the mission of “empowering minds to engineer the future electric energy system.” Its work is focused on achieving: • An efficient, secure, resilient, adaptable, and economic electric power infrastructure serving society • A new generation of educated technical professionals in electric power • Knowledgeable decision-makers on critical energy policy issues • Sustained, quality university programs in electric power engineering. PSERC core research is funded by industry, with a budget supporting approximately 30 principal investigators and some 70 graduate students and other researchers. Its researchers are multi-disciplinary, conducting research in three principal areas: power systems, power markets and policy, and transmission and distribution technologies. The research is collaborative; each project involves researchers typically at two universities working with industry advisors who have expressed interest in the project. Examples of topics for recent PSERC research projects include grid integration of renewables and energy storage, new tools for taking advantage of increased penetration of real-time system measurements, advanced system protection methods to maintain grid reliability, and risk and reliability assessment of increasingly complex cyber-enabled power systems. A PSERC’s objective is to proactively address the technical and policy challenges of U.S. electric power systems. To achieve this objective, PSERC works with CERTS to conduct technical research on advanced applications and investigate the design of fair and transparent electricity markets; these research topics align with CERTS research areas 1 and 2: Real-time Grid Reliability Management (Area 1), and Reliability and Markets (Area 2). The CERTS research areas overlap with the PSERC research stems: Power Systems, Power Markets, and Transmission and Distribution Technologies, as described on the PSERC website (see http://www.pserc.org/research/research_program.aspx). The performers were with Arizona State University (ASU), Cornell University (CU), University of California at Berkeley (UCB), and University of Illinois at Urbana-Champaign (UIUC). PSERC research activities in the area of reliability and markets focused on electric market and power policy analyses. The resulting studies suggest ways to frame best practices using organized markets for managing U.S. grid assets reliably and to identify highest priority areas for improvement. PSERC research activities in the area of advanced applications focused on mid- to long-term software research and development, with anticipated outcomes that move innovative ideas toward real-world application. Under the CERTS research area of Real-time Grid Reliability Management, PSERC has been focused on Advanced Applications Research and Development (AARD), a subgroup of activities that works to develop advanced applications and tools to more effectively operate the electricity delivery system, by enabling advanced analysis, visualization, monitoring and alarming, and decision support capabilities for grid operators.

24 POWER TRANSMISSION AND DISTRIBUTION↗
DOE OSTI2019

Equation-based object-oriented modeling and simulation for data center cooling: A case study

© 2019 Elsevier B.V. Data center cooling accounts for about 1% of electricity usage in the United States. Computer models are pivotal in designing and operating energy-efficient cooling systems. Compared to conventional building performance simulation programs, the equation-based object-oriented modeling language Modelica is an emerging approach that can enable fast prototyping and dynamic simulation of cooling systems. In this case study, we first modeled the cooling and control systems of an actual data center located in Massachusetts using the open-source Modelica Buildings library, and then calibrated a baseline model based on measurement data. The simulation of the baseline model identified several operation-related issues in the cooling and control systems, such as degraded cooling coils, improper dead band in control settings, and simultaneous cooling and heating in air handlers. Afterwards, we used a sequential search technique as well as an optimization scheme to investigate the energy saving potentials for different energy efficiency measures aiming to address the abovementioned issues. Simulation results show potential energy savings up to 24% by resolving identified control-related issues and optimizing the supply air temperature.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2016

SEE Action Guide for States: Energy Efficiency as a Least-Cost Strategy to Reduce Greenhouse Gases and Air Pollution and Meet Energy Needs in the Power Sector

This guide is designed to provide information to state decision makers and staff on options to advance energy efficiency through strategies designed or implemented at the state and local levels of government and in the private sector.1 The information in this guide is intended to be useful to a wide variety of partners and stakeholders involved in energy-related discussions and decision-making at state and local levels. These energy efficiency options, or “pathways” as they are identified in this guide, can assist states in using energy efficiency to meet air pollution reduction and other policy objectives such as energy affordability and reliability. A pathway is a set of interdependent actions that results in measurable energy savings streams and associated avoided air emissions and other benefits over a period of time. These activities can include state, local, or private sector regulations, policies, programs and other activities. For each of five broad pathways that offer sizable cost-effective energy savings, the guide addresses likely questions policy makers and regulators face when screening for the best opportunities to advance energy efficiency in their state.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗