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At least 1,387 records · Page 77

Benchmarking of activation rate in special core in LR-0 reactor

The experiments focused on the determination of activation reaction rates of selected IRDFF materials activated in a well-defined special core assembled in the LR-0 reactor are presented in the paper. The used core is designed and verified for IRDFF library testing by reactivity characterization, fission rates distribution and also neutron spectra measurement at the center of the core. {sup 23}Na(n,2n), {sup 75}As(n,2n), {sup 89}Y(n,2n) and {sup 90}Zr(n,2n) reaction cross sections were measured in this special core. The presented neutron cross sections were derived from experimentally determined reaction rates of irradiated samples of NaF, As{sub 2}O{sub 3}, Y{sub 2}O{sub 3}, and ZrO{sub 2}. These reaction rates are derived from gamma activities of the activation products of studied activation reactions. Net Peak Areas (NPA) of photons accompanying decay were measured using a semiconductor High Purity Germanium (HPGe) detector. Despite the fact that mentioned reactions have a threshold above 10 MeV, where the neutron spectrum in the special LR-0 core is nearly undistinguishable from {sup 235}U prompt fission neutron spectrum, the measured integral cross sections averaged in LR-0 spectrum were corrected for spectral shift. The obtained values of {sup 235}U spectral average cross section are: (3.84 ± 0.19) μb for {sup 23}Na(n,2n); (0.320 ± 0.015) mb for {sup 75}As(n,2n); (0.171 ± 0.006) mb for {sup 89}Y(n,2n); (0.107 ± 0.005) mb for {sup 90}Zr(n,2n). (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

EVOLUTION OF THE MASS-METALLICITY RELATIONS IN PASSIVE AND STAR-FORMING GALAXIES FROM SPH-COSMOLOGICAL SIMULATIONS

We present results from SPH-cosmological simulations, including self-consistent modeling of supernova feedback and chemical evolution, of galaxies belonging to two clusters and 12 groups. We reproduce the mass-metallicity (ZM) relation of galaxies classified in two samples according to their star-forming (SF) activity, as parameterized by their specific star formation rate (sSFR), across a redshift range up to z = 2. The overall ZM relation for the composite population evolves according to a redshift-dependent quadratic functional form that is consistent with other empirical estimates, provided that the highest mass bin of the brightest central galaxies is excluded. Its slope shows irrelevant evolution in the passive sample, being steeper in groups than in clusters. However, the subsample of high-mass passive galaxies only is characterized by a steep increase of the slope with redshift, from which it can be inferred that the bulk of the slope evolution of the ZM relation is driven by the more massive passive objects. The scatter of the passive sample is dominated by low-mass galaxies at all redshifts and keeps constant over cosmic times. The mean metallicity is highest in cluster cores and lowest in normal groups, following the same environmental sequence as that previously found in the red sequence building. The ZM relation for the SF sample reveals an increasing scatter with redshift, indicating that it is still being built at early epochs. The SF galaxies make up a tight sequence in the SFR-M{sub *} plane at high redshift, whose scatter increases with time alongside the consolidation of the passive sequence. We also confirm the anti-correlation between sSFR and stellar mass, pointing at a key role of the former in determining the galaxy downsizing, as the most significant means of diagnostics of the star formation efficiency. Likewise, an anti-correlation between sSFR and metallicity can be established for the SF galaxies, while on the contrary more active galaxies in terms of simple SFR are also metal-richer. Finally, the [O/Fe] abundance ratio is presented too: we report a strong increasing evolution with redshift at given mass, especially at z {approx}> 1. The expected increasing trend with mass is recovered when only considering the more massive galaxies. We discuss these results in terms of the mechanisms driving the evolution within the high- and low-mass regimes at different epochs: mergers, feedback-driven outflows, and the intrinsic variation of the star formation efficiency.

79 ASTRONOMY AND ASTROPHYSICS↗

Supernova siblings and their parent galaxies in the Zwicky Transient Facility Bright Transient Survey

ABSTRACT Supernova (SN) siblings – two or more SNe in the same parent galaxy – are useful tools for exploring progenitor stellar populations as well as properties of the host galaxies such as distance, star-formation rate, dust extinction, and metallicity. Since the average SN rate for a Milky Way-type galaxy is just one per century, a large imaging survey is required to discover an appreciable sample of SN siblings. From the wide-field Zwicky Transient Facility (ZTF) Bright Transient Survey (which aims for spectroscopic completeness for all transients which peak brighter than r < 18.5 mag) we present 10 SN siblings in five parent galaxies. For each of these families, we analyse the SN’s location within the host and its underlying stellar population, finding agreement with expectations that SNe from more massive progenitors are found nearer to their host core and in regions of more active star formation. We also present an analysis of the relative rates of core collapse and thermonuclear SN siblings, finding a significantly lower ratio than past SN sibling samples due to the unbiased nature of the ZTF.

Graham, Melissa L. (ORCID:0000000291543136)↗

The Impact of Nuclear Reaction Rate Uncertainties on the Evolution of Core-collapse Supernova Progenitors

We review properties of core-collapse supernova progenitors with respect to the composite uncertainties in the thermonuclear reaction rates by coupling the probability density functions of the reaction rates provided by the STARLIB reaction rate library with MESA stellar models. We evolve 1000 models of 15${M}_{\odot }$ from the pre-main sequence to core O-depletion at solar and subsolar metallicities for a total of 2000 Monte Carlo stellar models. For each stellar model, we independently and simultaneously sample 665 thermonuclear reaction rates and use them in a MESA in situ reaction network that follows 127 isotopes from 1 H to 64 Zn. With this framework we survey the core mass, burning lifetime, composition, and structural properties at five different evolutionary epochs. At each epoch we measure the probability distribution function of the variations of each property and calculate Spearman rank-order correlation coefficients for each sampled reaction rate to identify which reaction rate has the largest impact on the variations on each property. We find that uncertainties in the reaction rates of ${}^{14}{\rm{N}}{({\rm{p}},\gamma )}^{15}{\rm{O}}$, triple-α, ${}^{12}{\rm{C}}{(\alpha ,\gamma )}^{16}{\rm{O}}$, 12 C( 12 C,p) 23 Na, 12 C( 16 O, p) 27 Al, 16 O( 16 O,n) 31 S, 16 O( 16 O, p) 31 P, and 16 O( 16 O,α) 28 Si dominate the variations of the properties surveyed. We find that variations induced by uncertainties in nuclear reaction rates grow with each passing phase of evolution, and at core H-, He-depletion they are of comparable magnitude to the variations induced by choices of mass resolution and network resolution. Yet, at core C-, Ne-, and O-depletion, the reaction rate uncertainties can dominate the variation, causing uncertainty in various properties of the stellar model in the evolution toward iron core-collapse.

79 ASTRONOMY AND ASTROPHYSICS↗

Advanced probabilistic risk analysis using RAVEN and RELAP-7

RAVEN, under the support of the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program [1], is advancing its capability to perform statistical analyses of stochastic dynamic systems. This is aligned with its mission to provide the tools needed by the Risk Informed Safety Margin Characterization (RISMC) path-lead [2] under the Department Of Energy (DOE) Light Water Reactor Sustainability program [3]. In particular this task is focused on the synergetic development with the RELAP-7 [4] code to advance the state of the art on the safety analysis of nuclear power plants (NPP). The investigation of the probabilistic evolution of accident scenarios for a complex system such as a nuclear power plant is not a trivial challenge. The complexity of the system to be modeled leads to demanding computational requirements even to simulate one of the many possible evolutions of an accident scenario (tens of CPU/hour). At the same time, the probabilistic analysis requires thousands of runs to investigate outcomes characterized by low probability and severe consequence (tail problem). The milestone reported in June of 2013 [5] described the capability of RAVEN to implement complex control logic and provide an adequate support for the exploration of the probabilistic space using a Monte Carlo sampling strategy. Unfortunately the Monte Carlo approach is ineffective with a problem of this complexity. In the following year of development, the RAVEN code has been extended with more sophisticated sampling strategies (grids, Latin Hypercube, and adaptive sampling). This milestone report illustrates the effectiveness of those methodologies in performing the assessment of the probability of core damage following the onset of a Station Black Out (SBO) situation in a boiling water reactor (BWR). The first part of the report provides an overview of the available probabilistic analysis capabilities, ranging from the different types of distributions available, possible sampling strategies, and post processing analysis capabilities. The first part of the report provides an extensive description of two major developments introduced this year: adaptive sampling for limit surface sampling and multi variate distributions. The document concludes with a description of the demo case (BWR-SBO) and a discussion of the results obtained.

97 MATHEMATICS AND COMPUTING↗

Modeling Specular Exchange Between Concentric Cylinders in a Radiative Shielded Furnace

The objective of this research is to develop and validate mathematical models to characterize the thermal performance of a radiative shielded furnace, the University of Alabama in Huntsville (UAH) Isothermal Diffusion Oven. The mathematical models are validated against experimental data obtained from testing the breadboard oven in a terrestrial laboratory environment. It is anticipated that the validation will produce math models capable of predicting the thermal performance of the furnace over a wide range of operating conditions, including those for which no experimental data is available. Of particular interest is the furnace core temperature versus heater power parametric and the transient thermal response of the furnace. Application to a microgravity environment is not considered, although it is conjectured that the removal of any gravity dependent terms from the math models developed for the terrestrial application should yield adequate results in a microgravity environment. The UAH Isothermal Diffusion Oven is designed to provide a thermal environment that is conducive to measuring the diffusion of high temperature liquid metals. In addition to achieving the temperatures required to melt a sample placed within the furnace, reducing or eliminating convective motions within the melt is an important design consideration [1]. Both of these influences are reflected in the design of the furnace. Reducing unwanted heat losses from the furnace is achieved through the use of low conductivity materials and reflective shielding. As evidenced by the highly conductive copper core used to house the sample within the furnace, convective motions can be greatly suppressed by providing an essentially uniform thermal environment. An oven of this design could ultimately be utilized in a microgravity environment, presumably as a experiment payload. Such an application precipitates other design requirements that limit the resources available to the furnace such as power, mass, volume, and possibly even time. Through the experimental and numerical results obtained, the power requirements and thermal response time of the breadboard furnace are quantified.

Schunk, Richard Gregory↗

Petrographic and spectral study of hydrothermal mineralization in drill core from Hawaii: A potential analog to alteration in the martian subsurface

Abstract Continuous rock core was collected for 1764 m (5786’) on the Pohakuloa Army Training base near the center of the big island of Hawaii. The core traverses basaltic lava flows from the volcano's shield-building phase, and perched aquifers and higher temperature groundwaters were encountered. The collected samples record water-rock interactions of basaltic materials in a setting that may be a model for groundwater interactions on Mars. We collected visible and infrared point spectra of materials in the lowest portion of the core, where alteration was noted to become more prominent. We identified three types of phyllosilicate spectral signatures and three types of zeolites. The phyllosilicates show similarity to those identified on Mars using data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). Based on the field survey, 25 depths were selected for sampling and petrographic analysis of thin sections. The spectral data and thin section work have a strong agreement in the types of materials identified by the two different techniques. Both the spectral and petrographic data indicate low to moderate temperature geothermal alteration occurred in the lower half of the core. The field spectra are a useful reconnaissance tool for selecting mineralogic diversity for subsequent higher resolution and more time-consuming laboratory analysis.

Geochemistry & Geophysics↗

Development of Material Studies at the LANL UCN Facility Focusing on Actinide Hydriding and Fission Damage

The aging of as-built actinide surfaces in static and dynamic environments is a complex problem of high importance to LANL’s core mission. Many standard material science tools used to study this problem are ideal for highly controlled, lab-made samples. The goal of this work is to use ultracold neutrons to bridge the gap between lab made and as-built surface aging studies. This capability is unique to LANL and will support our core mission.

36 MATERIALS SCIENCE↗

Re-Evaluation of HSE DATA in Light of High P-T Partitioning Data: Late Chondritic Addition to Inner Solar System Bodies Not Always Required for HSE

Studies of terrestrial peridotite and martian and achondritic meteorites have led to the conclusion that addition of chondritic material to growing planets or planetesimals, after core formation, occurred on Earth, Moon, Mars, asteroid 4 Vesta, and the parent body of the angritic meteorites. One study even proposed that this was a common process in the final stages of growth. These conclusions are based al-most entirely on the 8 highly siderophile elements (HSE; Re, Au, Pt, Pd, Rh, Ru, Ir, Os), which have been used to argue for late accretion of chondritic material to the Earth after core formation was complete. This idea was originally proposed because the D(metal/silicate) values for the HSE are very high (greater than 10,000), yet their concentration in the terrestrial mantle is too high to be consistent with such high Ds. The HSE in the terrestrial mantle also are present in chondritic relative abundances and hence require similar Ds if this was the result of core-mantle equilibration. The conclusion that late chondritic additions are required for all five of these bodies is based on the chondritic relative abundances of the HSE, as well as their elevated concentrations in the samples. An easy solution is to call upon addition of chondritic material to the mantle of each body, just after core formation; however, in practice this means similar additions of chondritic materials to each body just after core formation which ranges from approximately 4-5 Ma after T(sub 0) for 4 Vesta and the angrites, to 10-25 Ma for Mars, to 35 to 60 Ma for Moon and perhaps the Earth. Since the work of there has been a realization that high PT conditions can lower the partition coefficients of many siderophile elements, indicating that high PT conditions (magma ocean stage) can potentially explain elevated siderophile element abundances. However, detailed high PT partitioning data have been lacking for many of the HSE to evaluate whether such ideas are viable for all four bodies. Re-cent partitioning studies have covered P, T, fO2, and compositional ranges that allow values to be predicted at conditions relevant to these five inner solar system bodies. Because the D(HSE) metal/silicate are lowered substantially at higher PT conditions and natural com-positions (FeNi metallic liquids and peridotites) it is natural to re-examine the role of core formation on the HSE patterns in a variety of inner solar system bodies. Here I will discuss other processes (including high PT core formation for Mars, Moon and Earth) that can produce the observed HSE patterns, and demonstrate that there are viable hypotheses other than the "one size fits all" hypothesis of late chondritic additions.

Righter, K.↗

Comparing western (Megascops kennicottii) and whiskered (M. trichopsis) screech-owl microbiomes in southern Arizona using a novel 16S rRNA sequencing method

Microbiomes are essential to a host’s physiology and health. Despite the overall importance of microbiomes to animal health, they remain understudied in wildlife. Microbiomes function as physical barriers to invading pathogens, and changes in the diversity or composition of microbes within a host may disrupt this barrier. In order to use microbiomes in wildlife ecology, knowledge of the natural variation within and among species is essential. We compare the diversity and composition of two avian species that share the same habitat and niche in our study area, the western screech-owl (Megascops kennicottii) and the whiskered screech-owl (M. trichopsis). We used a targeted 16S sequencing method to improve the taxonomic resolution of microbiomes. We found similar measures of alpha diversity between species and sample types (cloacal samples vs. fecal samples). However, there were significant differences in bacterial species richness among nestlings from different nest boxes, and the composition differed between the two bird species and among nestlings from different nest boxes. Western screech-owls had more variation in alpha diversity and composition and had fewer bacterial species in their core microbiome than whiskered screech-owls. Siblings are likely to yield similar findings for microbiomes; thus, sampling nestlings from different nests may be most informative for monitoring population-level changes.

59 BASIC BIOLOGICAL SCIENCES↗

Enhanced Oxygen Reduction Reaction Activity on Pt-Monolayer-Shell PdIr/Ni-Core Catalysts

Platinum monolayer oxygen reduction reaction catalysts offer the most promising possibility of reducing the Pt content without sacrificing its fuel cell performance. Here, we present a facile way of preparing Pt monolayer shell on PdIr-based core catalysts with and without Ni sub-core. They showed much higher activity for oxygen reduction reaction than commercial Pt/C catalyst. Among tested samples, PtMLPd2Ir/Ni/C performs the best having Pt mass activity 14 times and Platinum Group Metal mass activity 0.8 times higher than that of Pt/C. In addition, accelerated durability test indicates its excellent durability, which was demonstrated by a 7.5% decrease in Platinum Group Metal mass activity compared to 64% for the commercial Pt/C catalyst. As a result, the role of Ni sub-core in oxygen reduction reaction activity and durability of PtML on PdIr-based catalysts was also elucidated.

25 ENERGY STORAGE↗

Post-igneous redistribution of components in eucrites

In our analyses, we utilize a microdrilling technique that removes 40 to 100 micron diameter cores from mineral grains in thin sections analyzed by microprobe. The cores are then analyzed by INAA using the technique of Lindstrom. Three eucrites were selected for application of this analytical technique: monomict breccias Pasamonte and Stannern and unbrecciated EET90020. Pasamonte is among the most unequilibrated of the eucrites on the basis of zoning in pyroxenes and is considered to be an igneous rock not significantly affected by metamorphism. Stannern has igneous texture but its pyroxenes indicate some re-equilibration, although little, if any, recrystallization. EET90020 has a granulite texture and has been substantially recrystallized. Our sample of Pasamonte contains several clasts of different grain sizes ranging from glass to fine grained with diabasic texture containing lathy plagioclase, unexsolved pigeonite, and mesostasis. Cores were taken of the glass and from minerals and mesostases in six lithic clasts which normally allowed sampling of more than one phase per clast. Our sample of Stannern is also a breccia but with little difference in grain size between clasts and matrix. The plagioclase and pigeonite are blocky, twinned, and exsolved and coexist with a bit of mesostasis. Cores were taken of plagioclase and pigeonite with no attempt to distinguish separate clasts. EET90020 is a granular mixture of twinned plagioclase and pigeonite having rather uniform size and many triple junctions. Several cores were taken of both phases. Both clear and cloudy grains of plagioclase and pyroxene were sampled in all three eucrites.

Phinney, W. C.↗

A Combined SAXS/SANS Study for the in Situ Characterization of Ligand Shells on Small Nanoparticles: The Case of ZnO

ZnO nanoparticles (NPs) have great potential for their use in, e.g., thin film solar cells due to their electro-optical properties adjustable on the nanoscale. Therefore, the production of well-defined NPs is of major interest. For a targeted production process, the knowledge of the stabilization layer of the NPs during and after their formation is of particular importance. For the study of the stabilizer layer of ZnO NPs prepared in a wet chemical synthesis from zinc acetate, only ex situ studies have been performed so far. An acetate layer bound to the surface of the dried NPs was found; however, an in situ study which addresses the stabilizing layer surrounding the NPs in a native dispersion was missing. By the combination of small angle scattering with neutrons and X-rays (SANS and SAXS) for the same sample, we are now able to observe the acetate shell in situ for the first time. In addition, the changes of this shell could be followed during the ripening process for different temperatures. With increasing size of the ZnO core (d core ) the surrounding shell (d shell ) becomes larger, and the acetate concentration within the shell is reduced. For all samples, the shell thickness was found to be larger than the maximum extension of an acetate molecule with acetate concentrations within the shell below 50 vol %. Furthermore, there is not a monolayer of acetate molecules that covers the NPs but rather a swollen shell of acetate ions. This shell is assumed to hinder the growth of the NPs to larger macrostructures. In addition, we found that the partition coefficient μ between acetate in the shell surrounding the NPs and the total amount of acetate in the solution is about 10% which is in good agreement with ex situ data determined by thermogravimetric analysis.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Acetate concentrations and oxidation in salt marsh sediments

Acetate concentrations and rates of acetate oxidation and sulfate reduction were measured in S. alterniflora sediments in New Hampshire and Massachusetts. Pore water extracted from cores by squeezing or centrifugation contained in greater than 0.1 mM acetate and, in some instances, greater than 1.0 mM. Pore water sampled nondestructively contained much less acetate, often less than 0.01 mM. Acetate was associated with roots, and concentrations varied with changes in plant physiology. Acetate turnover was very low whether whole core or slurry incubations were used. Radiotracers injected directly into soils yielded rates of sulfate reduction and acetate oxidation not significantly different from core incubation techniques. Regardless of incubation method, acetate oxidation did not account for a substantial percentage of sulfate reduction. These results differ markedly from data for unvegetated coastal sediments where acetate levels are low, oxidation rate constants are high, and acetate oxication rates greatly exceed rates of sulfate reduction. The discrepancy between rates of acetate oxidation and sulfate reduction in these marsh soils may be due either to the utilization of substrates other than acetate by sulfate reducers or artifacts associated with measurements of organic utilization by rhizosphere bacteria. Care must be taken when interpreting data from salt marsh sediments since the release of material from roots during coring may affect the concentrations of certain compounds as well as influencing results obtained when sediment incubations are employed.

Source record↗

Relativistic beaming and the nuclei of double-lobed radio quasars

A complete sample of double-lobed 3CR quasars with minimal orientation bias is defined. Properties of these objects on the greater than kpc scale are consistent with the simple beaming model for their nuclei. VLBI maps of six nuclei reveal 'core-jet' structures. Both nuclei mapped at multiple epochs are modestly superluminal. The distribution of apparent velocities in this sample will provide a stringent test of beaming.

Hough, D. H.↗

Evidence of parsec-scale jets in low-luminosity active galactic nuclei

The nuclear radio emission of low-luminosity active galactic nuclei (LLAGNs) is often associated with unresolved cores. In this paper we show that most LLAGNs present extended jet radio emission when observed with sufficient angular resolution and sensitivity. They are thus able to power, at least, parsec-scale radio jets. To increase the detection rate of jets in LLAGNs, we analyze subarcsecond resolution data of three low-ionization nuclear emission regions. This yields the detection of extended jet-like radio structures in NGC 1097 and NGC 2911 and the first resolved parsec-scale jet of NGC 4594 (Sombrero). The three sources belong to a sample of nearby LLAGNs for which high-spatial-resolution spectral energy distribution of their core emission is available. This allows us to study their accretion rate and jet power (Q {sub jet}) without drawing on (most) of the ad hoc assumptions usually considered in large statistical surveys. We find that those LLAGNs with large-scale radio jets (>100 pc) have Q {sub jet} > 10{sup 42} erg s{sup –1}, while the lowest Q {sub jet} correspond to those LLAGNs with parsec-scale (≤100 pc) jets. The Q {sub jet} is at least as large as the radiated bolometric luminosity for all LLAGN, in agreement with previous statistical studies. Our detection of parsec-scale jets in individual objects further shows that the kinematic jet contribution is equally important in large- or parsec-scale objects. We also find that the Eddington-scaled accretion rate is still highly sub-Eddingtonian (<10{sup –4}) when adding the Q {sub jet} to the total emitted luminosity (radiated plus kinetic). This indicates that LLAGNs are not only inefficient radiators but that they also accrete inefficiently or are very efficient advectors.

79 ASTRONOMY AND ASTROPHYSICS↗

Siderophile Element Depletion in the Angrite Parent Body (APB) Mantle: Due to Core Formation?

The origin of angrites has evaded scientists due in part to unusual mineralogy, oxidized character, and small numbers of samples. Increased interest in the origin of angrites has stemmed from the recovery of approximately 10 new angrites in the past decade. These new samples have allowed meteoriticists to recognize that angrites are compositionally diverse, old, and record very early differentiation. Also, a magma ocean has been proposed to have been involved in APB early differentiation, but this remains untested for siderophile elements which are commonly cited as one of the main lines of evidence for magma oceans on the early Earth, Moon, Mars and eucrite parent body (e.g., [6]). And recent suggestions that angrites may or may not be from Mercury have also peaked interest in these achondrites. Given all of this background, a detailed understanding of the early differentiation process is desired. Previous efforts at examining siderophile element (SE) concentrations with respect to core formation processes in the APB have not resulted in any definite conclusions regarding segregation of a metallic core. The goal of this study is to summarize what is known about SE concentrations in the suite, estimate depletions of SE compared to chondrites, and apply metal/silicate experimental partition coefficients to assess whether the APB had a core.

Righter, K.↗

Structural analysis of Fe–Mn–O nanoparticles in glass ceramics by small angle scattering

Magnetic nanocrystals containing Fe and Mn were obtained by annealing of silicate glasses with the composition 13.6Na{sub 2}O–62.9SiO{sub 2}–8.5MnO–15.0Fe{sub 2}O{sub 3−x} (mol%) at 580 °C for different periods of time. Here, we present Small Angle Neutron Scattering using Polarized neutrons (SANSPOL) and Anomalous Small Angle X-ray Scattering (ASAXS) investigation on these glass ceramic samples. Analysis of scattering data from both methods reveals the formation of spherical core–shell type of nanoparticles with mean sizes between 10 nm and 100 nm. ASAXS investigation shows the particles have higher concentration of iron atoms and the shell like region surrounding the particles is enriched in SiO{sub 2}. SANSPOL investigation shows the particles are found to be magnetic and are surrounded by a non-magnetic shell-like region. - Graphical abstract: Magnetic spherical core–shell nanoparticles in glass ceramics: SANSPOL and ASAXS investigations. - Highlights: • Formation and growth mechanisms of magnetic nanoparticles in silicate glass. • SANSPOL and ASAXS methods employed to evaluate quantitative information. • Analyses showed formation of nanoparticles with spherical core–shell structures. • Core of the particle is magnetic and surrounded by weak magnetic shell like region.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗