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At least 1,387 records · Page 77

Fabrication of Bi-2212 Canted-Cosine-Theta Dipole Prototypes

The U.S. Magnet Development Program (MDP) is exploring the possibility of combining low-and higherature superconductor technologies, using cosine-theta and canted-cosine-theta (CCT) Nb3Sn dipole magnets together with Bi-2212 CCT inserts, with the ultimate goal of constructing a 20-T dipole. The MDP short-term goal is a Bi-2212 CCT insert capable of reaching 5 T in the bore when operating as a stand-alone and 3 T when operating under a background field of 15 T. This paper reports on the fabrication of our BIN4 dipole magnet and our BIN5a and BIN5b coils, designed and built at the Lawrence Berkeley National Laboratory to address potential fabrication issues of Bi-2212 coils and verify the design of our 18-20-T dipole magnet. BIN4 is a two-layer 50-cm-long CCT magnet that uses a nine-strand Rutherford cable made with 0.8-mm-diameter Bi-2212 strands. Its goal is to investigate critical current, insulation integrity, manufacturing challenges, and quench protection issues after heat treating both layers together under oxygen at standard atmosphere (1 bar). BIN5a and BIN5b are two identical coils, similar to the outer layer of BIN4, with the difference that the length is 39 cm, and they will undergo 50-bar overpressure processing heat treatment. Finally, BIN5 coils are made from the state-of-the-art strand with an engineering critical current density of 1150 A/mm 2 at 4.2 K and 5 T.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Machine learning analysis of RB-TnSeq fitness data predicts functional gene modules in Pseudomonas putida KT2440

ABSTRACT There is growing interest in engineering Pseudomonas putida KT2440 as a microbial chassis for the conversion of renewable and waste-based feedstocks, and metabolic engineering of P. putida relies on the understanding of the functional relationships between genes. In this work, independent component analysis (ICA) was applied to a compendium of existing fitness data from randomly barcoded transposon insertion sequencing (RB-TnSeq) of P. putida KT2440 grown in 179 unique experimental conditions. ICA identified 84 independent groups of genes, which we call fModules (“functional modules”), where gene members displayed shared functional influence in a specific cellular process. This machine learning-based approach both successfully recapitulated previously characterized functional relationships and established hitherto unknown associations between genes. Selected gene members from fModules for hydroxycinnamate metabolism and stress resistance, acetyl coenzyme A assimilation, and nitrogen metabolism were validated with engineered mutants of P. putida . Additionally, functional gene clusters from ICA of RB-TnSeq data sets were compared with regulatory gene clusters from prior ICA of RNAseq data sets to draw connections between gene regulation and function. Because ICA profiles the functional role of several distinct gene networks simultaneously, it can reduce the time required to annotate gene function relative to manual curation of RB-TnSeq data sets. IMPORTANCE This study demonstrates a rapid, automated approach for elucidating functional modules within complex genetic networks. While Pseudomonas putida randomly barcoded transposon insertion sequencing data were used as a proof of concept, this approach is applicable to any organism with existing functional genomics data sets and may serve as a useful tool for many valuable applications, such as guiding metabolic engineering efforts in other microbes or understanding functional relationships between virulence-associated genes in pathogenic microbes. Furthermore, this work demonstrates that comparison of data obtained from independent component analysis of transcriptomics and gene fitness datasets can elucidate regulatory-functional relationships between genes, which may have utility in a variety of applications, such as metabolic modeling, strain engineering, or identification of antimicrobial drug targets.

09 BIOMASS FUELS↗

Transient Simulation of the Multi-SERTTA Experiment with MAMMOTH

This work details the MAMMOTH reactor physics simulations of the Static Environment Rodlet Transient Test Apparatus (SERTTA) conducted at Idaho National Laboratory in FY-2017. TREAT static-environment experiment vehicles are being developed to enable transient testing of Pressurized Water Reactor (PWR) type fuel specimens, including fuel concepts with enhanced accident tolerance (Accident Tolerant Fuels, ATF). The MAMMOTH simulations include point reactor kinetics as well as spatial dynamics for a temperature-limited transient. The strongly coupled multi-physics solutions of the neutron flux and temperature fields are second order accurate both in the spatial and temporal domains. MAMMOTH produces pellet stack powers that are within 1.5% of the Monte Carlo reference solutions. Some discrepancies between the MCNP model used in the design of the flux collars and the Serpent/MAMMOTH models lead to higher power and energy deposition values in Multi-SERTTA unit 1. The TREAT core results compare well with the safety case computed with point reactor kinetics in RELAP5-3D. The reactor period is 44 msec, which corresponds to a reactivity insertion of 2.685% delta k/k$. The peak core power in the spatial dynamics simulation is 431 MW, which the point kinetics model over-predicts by 12%. The pulse width at half the maximum power is 0.177 sec. Subtle transient effects are apparent at the beginning insertion in the experimental samples due to the control rod removal. Additional difference due to transient effects are observed in the sample powers and enthalpy. The time dependence of the power coupling factor (PCF) is calculated for the various fuel stacks of the Multi-SERTTA vehicle. Sample temperatures in excess of 3100 K, the melting point UO$_2$, are computed with the adiabatic heat transfer model. The planned shaped-transient might introduce additional effects that cannot be predicted with PRK models. Future modeling will be focused on the shaped-transient by improving the control rod models in MAMMOTH and adding the BISON thermo-elastic models and thermal-fluids heat transfer.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Performance of two-pole bandpass filters photodefined on double-sided Y-Ba-Cu-O and Tl-Ba-Ca-Cu-O thin films

The performance of 7.3-GHz two-pole bandpass filters (5% bandwidth) fabricated on double-sided Y-Ba-Cu-O and Tl-Ba-Ca-Cu-O thin films deposited on LaAlO3 is discussed. At 77 K, the Tl-Ba-Ca-Cu-O and Y-Ba-Cu-O superconducting filters exhibited minimum passband insertion losses of 0.3 and 1.2 dB, respectively. An insertion loss of 3.4 dB was measured for an all-gold filter at 77 K.

TWO POLE BANDPASS FILTERS↗

A Methodology for the Measurement of Test Effectiveness

In developing a software system, we would like to estimate the total number of faults inserted in to the system, its residual fault content at any given time, and the efficacy of the testing activity in executing the code containing the newly inserted faults.

software reliability software faults software faul↗

First Results from NASA's Lunar Atmosphere and Dust Environment Explorer (LADEE)

As of early August, 2013, the Lunar Atmosphere and Dust Environment Explorer (LADEE) mission is scheduled for launch on a Minotaur V rocket from Wallops Flight Facility during a five-day launch period that opens on Sept. 6, 2013 (early Sept. 7 UTC). LADEE will address 40 year-old mysteries of the lunar atmosphere and the question of levitated lunar dust. It will also pioneer the next generation of optical space communications. LADEE will assess the composition of the lunar atmosphere and investigate the processes that control its distribution and variability, including sources, sinks, and surface interactions. LADEE will also determine whether dust is present in the lunar exosphere, and reveal its sources and variability. These investigations are relevant to our understanding of surface boundary exospheres and dust processes occurring at many objects throughout the solar system, address questions regarding the origin and evolution of lunar volatiles, and have potential implications for future exploration activities. Following a successful launch, LADEE will enter a series of phasing orbits, which allows the spacecraft to arrive at the Moon at the proper time and phase. This approach accommodates any dispersion in the Minotaur V launch injection. LADEE's arrival at the moon in early October. The spacecraft will approach the moon from its leading edge, travel behind the Moon out of sight of the Earth, and then re-emerge and execute a three-minute Lunar Orbit Insertion maneuver. This will place LADEE in an elliptical retrograde equatorial orbit with an orbital period of approximately 24 hours. A series of maneuvers is then performed to reduce the orbit to become nearly circular with a 156-mile (250- kilometer) altitude. Spacecraft checkout and science instrument commissioning will commence in early-October and will nominally span 30 days but can be extended for an additional 30 days in the event of contingencies. Following commissioning, the 100-day Science Phase is performed at an orbit with periapsis between 20-60 km. This orbit must be constantly managed due to the Moon's highly inhomogeneous gravity field. During the Science Phase, the moon will rotate more than three times underneath the LADEE orbit. LADEE employs a high heritage instrument payload: a Neutral Mass Spectrometer (NMS) from Goddard Space Flight Center, an Ultraviolet/Visible Spectrometer (UVS) from Ames Research Center, and a dust detection experiment (LDEX) from the University of Colorado/LASP. It will also carry the Lunar Laser Communications Demonstration (LLCD) as a technology demonstration. The LLCD is funded by the Human Exploration Operations Mission Directorate (HEOMD), managed by GSFC, and built by the MIT Lincoln Lab. Contingent upon LADEE's successful lunar orbit insertion and checkout, we will report the early results from the science investigations.

Moon↗

Galileo Preparing for Jupiter Arrival

The most critical events of the Galileo mission occur on Jupiter arrival day, December 7, 1995. In chronological order, these one-time events are: a 1000 km flyby of the innermost Galilean satellite Io, the 75-minute Atmospheric Entry Probe mission, and the Orbiter's Jupiter Orbit Insertion (JOI) maneuver. In addition, extensive, unique Orbiter science observations are planned because this is the only time Galileo will encounter Io, fly through the Io torus, and will be so close to Jupiter -- three times closer than at any of the perijove passes in the orbital mission. All of these events occur in what will be by far the most intense radiation environment Galileo will ever see. The focus of this paper is the extraordinary preparations being made to maximize the reliability of the most critical events in order to ensure a successful probe mission and Orbiter Insertion while also gathering unique arrival day Orbiter science. The paper also provides a mission status report including the return of the asteroid Ida data and the Galileo direct line-of-sight observations of Comet Shoemaker-Levy fragments impacting Jupiter in July 1994.

Galileo↗

Transient performance of accident tolerant fuel in design basis accidents

A set of transient analysis has been performed to assess the performance of candidate accident tolerant fuel (ATF) against reference UO{sub 2} fuel with Zircaloy cladding under design basis accident (DBA) conditions. This study examined two ATF options, U{sub 3}Si{sub 2} fuel with SiC cladding and UO{sub 2} fuel with APMT cladding. The accident analyses were conducted using the system code TRACE for a three-loop PWR plant. PARCS standalone full-core calculations were done for each fuel/cladding combination to provide inputs to the TRACE point-kinetics model. The design basis accidents analyzed were a reactivity insertion accident (RIA) and a large break loss-of-coolant accident (LBLOCA). The RIA was simulated by the insertion of a reactivity ramp of $1 (one dollar) in 0.1 s at hot full power (HFP) condition. The LBLOCA was a simulation of a double-ended pipe break in one of the cold legs of the primary loops. Differences in thermal responses of the fuel and the cladding are attributed to their thermal properties. The U{sub 3}Si{sub 2} fuel with its lower volumetric heat capacity and higher thermal conductivity (i.e. higher thermal diffusivity) generally results in a lower fuel temperature than the UO{sub 2} fuel and a correspondingly faster thermal response. Additional calculations for the U{sub 3}Si{sub 2} fuel shows that in a RIA the cladding material, SiC versus Zr, has little impact on the maximum fuel centerline temperature and the PCT (peak cladding temperature). An increase in the hot rod power factor is shown to raise the centerline fuel temperature in a RIA but has little impact on the PCT. The analysis results show that for a relatively fast decay heat driven transient, such as the LBLOCA, the thermal-hydraulics and fuel/cladding thermal properties dictate the overall response more so than the reactivity feedback. The results show that the PCTs in a LBLOCA are similar for all fuel/cladding combinations considered in this study. The LBLOCA analysis also notes the impact of the asymmetry in the system response. The fuel rods in the sector of the core connected to the hot leg of the broken loop (Sector 1 in the PWR model) is shown to have a much lower PCT than fuel rods in the other five sectors of the core. Results of this study indicate that for the two DBAs considered (RIA and LBLOCA) the transient behavior and the resulting peak cladding temperature of the two ATF options (U{sub 3}Si{sub 2} fuel with SiC cladding and UO{sub 2} fuel with APMT cladding) are similar to the standard light-water reactor fuel (UO{sub 2} fuel with Zircaloy cladding). (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A Machine Learning Based System Performance Prediction Model for Transportable FHR

A machine learning based system performance prediction model is currently created to support the development of autonomous control for small reactors, such as the Transportable Fluoride-salt-cooled High-temperature Reactor (TFHR), which has a 20 MWth compact core proposed by MIT for remote sites. The prediction model is constructed using support vector regression (SVR) with training data generated by RELAP5. A particle filtering framework is utilized to estimate and update model parameters with instrument measurements. Verifications of the prediction and filtering models have been carried out using TFHR reactivity insertion cases. Satisfactory performance in predicting the core behavior and in recognizing the inserted reactivity rate is concluded. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

High Resolution Measurements Reveal Transient Boiling Phenomena under Exponential Heat Inputs

Transient boiling heat transfer is important to the safety of nuclear reactors. Reactivity insertion accidents (RIA) in a nuclear reactor might result in a power excursion in which the heat generation in the fuel rises exponentially with time. The period of the exponential power excursion depends upon the magnitude of the reactivity insertion. The heat generated within the fuel is transferred to the water coolant which then starts to boil. The reactivity feedbacks caused by the heating (Doppler in the fuel and void in the coolant) represent an important mitigation mechanism for such accidents. The time delay between heat generation in the fuel and its transfer to the coolant is key to determining the outcome of the accident, in particular for experimental reactors using highly enriched fissile fuel with a very low Doppler effect. This time delay depends on conduction heat transfer within the fuel, single-phase convective heat transfer and eventually transient boiling heat transfer in the coolant. Although existing transient boiling databases form a highly valuable source of information, sometimes conclusions from different authors are quantitatively and qualitatively in disagreement with each other. This is likely due to differences in experimental setups and also limitations in the accuracy of diagnostics available in those experiments. In order to clarify these discrepancies and shed light on the mechanisms of transient boiling heat transfer, a new experimental study of both pool and flow boiling under exponential power input were carried out respectively. Exponential power escalation periods from 5 ms to 100 ms, bulk temperatures from saturation to 75 K of subcooling and Reynolds number from 25000 to 60000 have been explored at ambient pressure in both pool and flow boiling conditions. What makes this study unique is the use of synchronized state-of-the-art diagnostics such as IR thermometry and high speed video (HSV) which has improved the accuracy of measured quantities, and has provided a new and unique insights into the transient boiling heat transfer, including detection and modeling of the onset of nucleate boiling, better understanding of the transient boiling process and revelation of a new heat transfer mechanism that leads to higher CHF. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Comsol multiphysics simulation of the 1958 Y-12 criticality accident - 14654

This paper presents the simulation of the 1958 Y-12 criticality excursion using the commercial multiphysics code COMSOL Multiphysics. ICNC 2011 reported the initial effort to simulate the Y-12 accident power history using a fully coupled neutronic and computational fluid dynamic (CFD) approach with the Imperial College London FETCH code. That simulation included the initial spike and a subsequent power history 30 seconds afterwards. A time-dependent lumped parameter excursion model was later developed at Imperial in November 2014 and taken to 20 min. The COMSOL simulation is viewed as a hybrid treatment of these efforts. The use of COMSOL as a platform for criticality excursion simulation had been previously demonstrated with SILENE step reactivity insertion benchmarks. The Y-12 accident represented a unique time dependent reactivity insertion mechanism by dilution of the fissile concentration over time that facilitated the excursion termination. The COMSOL model includes a moving mesh vertical boundary, compartment radiolytic gas model, coupled turbulent fluid flow and conjugate heat transfer. The results are compared with both FETCH and lumped parameter simulations. The COMSOL power history results are in agreement with the reported and reconstructed initial spike fissions, power and total fissions over time. The simulated power trace shows explicit subsequent spikes approximately 10-20 seconds apart from the initial spike, over the first three minutes of the excursion. This result qualitatively confirms the radiation dose rate trace from a far field monitor located well beyond the affected facility. Additionally, the COMSOL model shows the onset of boiling after 3 minutes, as postulated in the literature. The combination of boiling and fissile solution dilution contributed to the shutdown mechanism. (authors)

42 ENGINEERING↗

Modulation-Doped Multiple Quantum Wells of Aligned Single-Wall Carbon Nanotubes

Heterojunctions, quantum wells, and superlattices with precise doping profiles are behind today's electronic and photonic devices based on III–V compound semiconductors such as GaAs. Currently, there is considerable interest in constructing similar artificial 3D architectures with tailored electrical and optical properties by using van der Waals junctions of low-dimensional materials. In this study, the authors have fabricated a novel structure consisting of multiple thin (≈20 nm) layers of aligned single-wall carbon nanotubes with dopants inserted between the layers. This “modulation-doped” multiple-quantum-well structure acts as a terahertz polarizer with an ultra-broadband working frequency range (from ≈0.2 to ≈200 THz), a high extinction ratio (20 dB from ≈0.2 to 1 THz), and a low insertion loss (<2.5 dB from ≈0.2 to 200 THz). The individual carbon nanotube films—highly aligned, densely packed, and large (2 in. in diameter)—were produced using vacuum filtration and then stacked together in the presence of dopants. This simple, robust, and cost-effective approach is applicable to the fabrication of a variety of devices relying on macroscopically 1D properties of aligned carbon nanotube assemblies.

36 MATERIALS SCIENCE↗

Investigation of Alkali-Ion (Li, Na, and K) Intercalation in K x VPO 4 F( x ~ 0) Cathode

This work compares the intercalation of K, Na, and Li in K x VPO 4 F (x~0). The K x VPO 4 F (x~0) cathode delivers reversible capacities of ≈90-100 mAh g -1 in K, Na, and Li cells, at an average voltage of ≈4.33 V for K, ≈3.98 V for Na, and ≈3.96 V for Li. This is so far the highest average voltage known for a K-intercalation cathode. The lower voltage of Li insertion compared to Na is attributable to undercoordinated Li ions in the K x VPO 4 F (x~0) framework. While the material shows high rate capability for all the alkali ions, Li migration in K x VPO 4 F (x~0) is more difficult than with Na and K. Here, this work suggests that a large cavity is not always good for insertion of alkali ions and cathode materials need to be suitably tailored to each intercalating ion species.

25 ENERGY STORAGE↗

Correction to: Investigation of Alkali-Ion (Li, Na, and K) Intercalation in K x VPO 4 F( x ~ 0) Cathode

This work compares the intercalation of K, Na, and Li in K x VPO 4 F (x~0). The K x VPO 4 F (x~0) cathode delivers reversible capacities of ≈90-100 mAh g -1 in K, Na, and Li cells, at an average voltage of ≈4.33 V for K, ≈3.98 V for Na, and ≈3.96 V for Li. This is so far the highest average voltage known for a K-intercalation cathode. The lower voltage of Li insertion compared to Na is attributable to undercoordinated Li ions in the K x VPO 4 F (x~0) framework. While the material shows high rate capability for all the alkali ions, Li migration in K x VPO 4 F (x~0) is more difficult than with Na and K. Here, this work suggests that a large cavity is not always good for insertion of alkali ions and cathode materials need to be suitably tailored to each intercalating ion species.

25 ENERGY STORAGE↗

Elastic Lattice Enabling Reversible Tetrahedral Li Storage Sites in a High-Capacity Manganese Oxide Cathode

The key to breaking through the capacity limitation imposed by intercalation chemistry lies in the ability to harness more active sites that can reversibly accommodate more ions (e.g., Li + ) and electrons within a finite space. However, excessive Li-ion insertion into the Li layer of layered cathodes results in fast performance decay due to the huge lattice change and irreversible phase transformation. Here, in this study, an ultrahigh reversible capacity is demonstrated by a layered oxide cathode purely based on manganese. Through a wealth of characterizations, it is clarified that the presence of low-content Li 2 MnO 3 domains not only reduces the amount of irreversible O loss; but also regulates Mn migration in LiMnO 2 domains, enabling elastic lattice with high reversibility for tetrahedral sites Li-ion storage in Li layers. This work utilizes bulk cation disorder to create stable Li-ion-storage tetrahedral sites and an elastic lattice for layered materials, with a reversible capacity of 600 mA h g –1 , demonstrated in th range 0.6–4.9 V versus Li/Li + at 10 mA g –1 . Admittedly, discharging to 0.6 V might be too low for practical use, but this exploration is still of great importance as it conceptually demonstrates the limit of Li-ions insertion into layered oxide materials.

25 ENERGY STORAGE↗

Low-Defect and Low-Porosity Hard Carbon with High Coulombic Efficiency and High Capacity for Practical Sodium Ion Battery Anode

Hard carbon is regarded as the most promising anode material for commercialization of Na ion batteries because of its high capacity and low cost. At present, the practical utilization of hard carbon anodes is largely limited by the low initial Coulombic efficiency (ICE). Na ions have been found to adopt an adsorption–insertion storage mechanism. In this paper a systematic way to control the defect concentration and porosity of hard carbon with similar overall architectures is shown. This study elucidates that the defects in the graphite layers are directly related to the ICE as they would trap Na ions and create a repulsive electric field for other Na ions so as to shorten the low-voltage intercalation capacity. The obtained low defect and porosity hard carbon electrode has achieved the highest ICE of 86.1% (94.5% for pure hard carbon material by subtracting that of the conductive carbon black), reversible capacity of 361 mA h g-1, and excellent cycle stability (93.4% of capacity retention over 100 cycles). This result sheds light on feasible design principles for high performance Na storage hard carbon: suitable carbon layer distance and defect free graphitic layers.

Xiao, Lifen↗