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A Statistical Testing Approach for Quantifying Software Reliability; Application to an Example System

The U.S. Nuclear Regulatory Commission (NRC) encourages the use of probabilistic risk assessment (PRA) technology in all regulatory matters, to the extent supported by the state-of-the-art in PRA methods and data. Although much has been accomplished in the area of risk-informed regulation, risk assessment for digital systems has not been fully developed. The NRC established a plan for research on digital systems to identify and develop methods, analytical tools, and regulatory guidance for (1) including models of digital systems in the PRA's of nuclear power plants (NPPs), and, (2) incorporating digital systems in the NRC's risk-informed licensing and oversight activities. Under NRC's sponsorship, Brookhaven National Laboratory (BNL) explored approaches for addressing the failures of digital instrumentation and control (I and C) systems in the current NPP PRA framework. Specific areas investigated included PRA modeling digital hardware , development of a philosophical basis for defining software failure , and identification of desirable attributes of quantitative software reliability methods . Based on the earlier research, statistical testing is considered a promising method for quantifying software reliability. It is widely recognized that software failures are due to the triggering of pre-existing defects by the software's operational environment. Software defects can arise from errors made in user requirements or coding errors introduced during the developmental process. The software's operational environment includes factors such as the time history of digital system inputs, communication interfaces, the internal state of the digital system, and external conditions. Thus, software reliability is a function of both the number of pre-existing defects and the presence of a triggering condition caused by the manner in which the software is used. In this paper, we describe a statistical software-testing approach for quantifying software reliability and applied it to the loop-operating control system (LOCS) of an experimental loop of the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL). The work involved collaboration between BNL and INL. The objectives of the study include: (1) Development of a statistical testing approach for estimating software failure probability on demand, the results of which are suitable for including in a probabilistic risk assessment (PRA); and, (2) Application of the approach to the LOCS to estimate its failure probability, and obtain insights into the feasibility, practicality, and usefulness of the estimation in models of digital systems for inclusion in nuclear power plants' PRAs. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Geodesic Models of Quasi-periodic-oscillations as Probes of Quadratic Gravity

Future very-large-area X-ray instruments (for which the effective area is larger than >3 m{sup 2}) will be able to measure the frequencies of quasi-periodic oscillations (QPOs) observed in the X-ray flux from accreting compact objects with sub-percent precision. If correctly modeled, QPOs can provide a novel way to test the strong-field regime of gravity. By using the relativistic precession model and a modified version of the epicyclic resonance model, we develop a method to test general relativity against a generic class of theories with quadratic curvature corrections. With the instrumentation being studied for future missions such as eXTP, LOFT, or STROBE-X, a measurement of at least two QPO triplets from a stellar mass black hole can set stringent constraints on the coupling parameters of quadratic gravity.

79 ASTRONOMY AND ASTROPHYSICS↗

Author Contribution to the Pu Handbook II: Chapter 37 LLNL Integrated Sample Preparation Glovebox (TEM) Section

The development of our Integrated Actinide Sample Preparation Laboratory (IASPL) commenced in 1998 driven by the need to perform transmission electron microscopy studies on naturally aged plutonium and its alloys looking for the microstructural effects of the radiological decay process (1). Remodeling and construction of a laboratory within the Chemistry and Materials Science Directorate facilities at LLNL was required to turn a standard radiological laboratory into a Radiological Materials Area (RMA) and Radiological Buffer Area (RBA) containing type I, II and III workplaces. Two inert atmosphere dry-train glove boxes with antechambers and entry/exit fumehoods (Figure 1), having a baseline atmosphere of 1 ppm oxygen and 1 ppm water vapor, a utility fumehood and a portable, and a third double-walled enclosure have been installed and commissioned. These capabilities, along with highly trained technical staff, facilitate the safe operation of sample preparation processes and instrumentation, and sample handling while minimizing oxidation or corrosion of the plutonium. In addition, we are currently developing the capability to safely transfer small metallographically prepared samples to a mini-SEM for microstructural imaging and chemical analysis. The gloveboxes continue to be the most crucial element of the laboratory allowing nearly oxide-free sample preparation for a wide variety of LLNL-based characterization experiments, which includes transmission electron microscopy, electron energy loss spectroscopy, optical microscopy, electrical resistivity, ion implantation, X-ray diffraction and absorption, magnetometry, metrological surface measurements, high-pressure diamond anvil cell equation-of-state, phonon dispersion measurements, X-ray absorption and emission spectroscopy, and differential scanning calorimetry. The sample preparation and materials processing capabilities in the IASPL have also facilitated experimentation at world-class facilities such as the Advanced Photon Source at Argonne National Laboratory, the European Synchrotron Radiation Facility in Grenoble, France, the Stanford Synchrotron Radiation Facility, the National Synchrotron Light Source at Brookhaven National Laboratory, the Advanced Light Source at Lawrence Berkeley National Laboratory, and the Triumph Accelerator in Canada.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Development of Bismuth and Platinum Bi-Metallic Nanoparticles to Enhance Melt Wire Temperature Resolution

Advanced manufacturing (AM) based on direct-write (DW) technologies has emerged as the predominant enabler for the fabrication of active and passive sensors to be deployed in harsh operating environments seen in a nuclear reactor. Recently, Idaho National Laboratory and Boise State University have recently established capabilities to incorporate advanced manufacturing (AM) methods to accelerate, modernize and enhance functionality of nuclear sensors and instrumentation to achieve the goal of enhancing the safety and efficiency of nuclear reactors. A significant thrust of this work includes the development of nuclear relevant feedstock materials compatible with a variety of direct-write processes for the development, fabrication and testing of AM sensors for peak temperature detection and neutron flux monitoring. For this report, bismuth and bismuth/platinum (BiPt) bi-metallic nanoparticles were synthesized using wet chemical approaches to develop bi-metallic feedstock materials to enhance the sensitivity of melt wires for peak temperature detection. Nanoparticle characterization was performed with Transmission Electron Microscopy (TEM) for nanoparticle composition and size, Transmission X-Ray Diffraction Fluorescence (TXRF) for nanoparticle composition, and Differential Scanning Calorimetry to elucidate the melting point of BiPt bi-metallic nanoparticles. Preliminary results indicate bi-metallic BiPt nanoparticles as a viable pathway for fabricating high resolution AM melt wires.

36 MATERIALS SCIENCE↗

Ultra low background time projection alpha particle detector ( Phase II Final Scientific/Technical Report)

When alpha particles are emitted into a gas they create an ionization track of gas ions and electrons. In our commercial UltraLo instrument we apply a voltage between a planar sample and an anode, integrate the anode signal as it collects the electrons, and distinguish between alphas emitted from the sample and elsewhere (anode, sidewalls) by the duration and shape of the resultant signal. The major contributors limiting the instrument’s lower detection limit are cosmic rays that pass through the detector close to the sample and Rn decays that produce charge tracks the originate in the gas and end on the sample. In this work we proposed to identify and reject these events by converting the anode into a multi-pixel array and operating in time projection mode. Cosmic rays would be eliminated by generating charge on many pixels, while charge collection asymmetry would distinguish between sample events (Bragg curve up) and Rn events (Bragg curve down). We therefore proposed to modify an UltraLo by pixilating its anode, developing low noise, low power multiplexed electronics to track each pixel’s signal individually, and develop analysis software to make the required discriminations.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

A Smart System for the Contactless Measurement of Energy Expenditure

Energy Expenditure (EE) (kcal/day), a key element to guide obesity treatment, is measured from CO 2 production, VCO 2 (mL/min), and/or O 2 consumption, VO 2 (mL/min). Current technologies are limited due to the requirement of wearable facial accessories. A novel system, the Smart Pad, which measures EE via VCO 2 from a room’s ambient CO 2 concentration transients was evaluated. Resting EE (REE) and exercise VCO 2 measurements were recorded using Smart Pad and a reference instrument to study measurement duration’s influence on accuracy. The Smart Pad displayed 90% accuracy (±1 SD) for 14–19 min of REE measurement and for 4.8–7.0 min of exercise, using known room’s air exchange rate. Additionally, the Smart Pad was validated measuring subjects with a wide range of body mass indexes (BMI = 18.8 to 31.4 kg/m2), successfully validating the system accuracy across REE’s measures of ~1200 to ~3000 kcal/day. Furthermore, high correlation between subjects’ VCO 2 and λ for CO 2 accumulation was observed (p < 0.00001, R = 0.785) in a 14.0 m3 sized room. This finding led to development of a new model for REE measurement from ambient CO 2 without λ calibration using a reference instrument. The model correlated in nearly 100% agreement with reference instrument measures (y = 1.06x, R = 0.937) using an independent dataset (N = 56).

47 OTHER INSTRUMENTATION↗

Nuclear Energy Infrastructure Database Fitness and Suitability Review

In 2014, the Deputy Assistant Secretary for Science and Technology Innovation (NE-4) initiated the Nuclear Energy-Infrastructure Management Project by tasking the Nuclear Science User Facilities (NSUF) to create a searchable and interactive database of all pertinent NE supported or related infrastructure. This database will be used for analyses to establish needs, redundancies, efficiencies, distributions, etc. in order to best understand the utility of NE’s infrastructure and inform the content of the infrastructure calls. The NSUF developed the database by utilizing data and policy direction from a wide variety of reports from the Department of Energy, the National Research Council, the International Atomic Energy Agency and various other federal and civilian resources. The NEID contains data on 802 R&D instruments housed in 377 facilities at 84 institutions in the US and abroad. A Database Review Panel (DRP) was formed to review and provide advice on the development, implementation and utilization of the NEID. The panel is comprised of five members with expertise in nuclear energy-associated research. It was intended that they represent the major constituencies associated with nuclear energy research: academia, industry, research reactor, national laboratory, and Department of Energy program management. The Nuclear Energy Infrastructure Database Review Panel concludes that the NSUF has succeeded in creating a capability and infrastructure database that identifies and documents the major nuclear energy research and development capabilities across the DOE complex. The effort to maintain and expand the database will be ongoing. Detailed information on many facilities must be gathered from associated institutions added to complete the database. The data must be validated and kept current to capture facility and instrumentation status as well as to cover new acquisitions and retirements.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

The ALS OSMS: Optical Surface Measuring System for high accuracy two-dimensional slope metrology with state-of-the-art x-ray mirrors

We report that to preserve the brightness and coherence of x-rays produced by diffraction-limited-storage-ring (DLSR) and free-electron laser (FEL) light sources, beamline optics must have unprecedented quality. For example, in the case of the most advanced beamlines for the DLSR source under development at the Advanced Light Source (ALS), the ALS-U, we need highly curved x-ray mirrors with surface slope tolerances better than 50-100 nrad (root-mean-square, rms). At the ALS X-Ray Optics Lab (XROL), we are working on the development of a new Optical Surface Measuring System (OSMS) with the required measurement accuracy. The OSMS is capable for the two-dimensional (2D) surface slope metrology over the spatial range from the sub-mm scale to the clear aperture. Usage of different arrangements of the OSMS sensors allows measuring the mirrors in the face-up or side-facing orientation, corresponding to the beamline application. The OSMS translation system and data acquisition software are designed to support multi scan measurement runs optimized for automatic suppression and compensation of instrumental drifts and major angular and spatial systematic errors. Here, we discuss the recent results of the OSMS research and development project. We provide details of the OSMS design and describe results of experimental performance tests of the gantry system. In particular, we show that the system is capable for measurement repeatability with strongly curved mirrors on the level of 20 nrad (rms). The high angular resolution of the OSMS rotational tip-tilt stage is adequate for implementation of instrumental calibration with using the mirror under test as a reference. The achieved measuring accuracy is demonstrated via comparison to metrology with the carefully calibrated Developmental Long Trace Profiler, also available at the XROL.

47 OTHER INSTRUMENTATION↗

Integrating ORNL’s HPC and Neutron Facilities with a Performance-Portable CPU/GPU Ecosystem

We explore the development of a performance-portable CPU/GPU ecosystem to integrate two of the US Department of Energy’s (DOE’s) largest scientific instruments, the Oak Ridge Leadership Computing facility and the Spallation Neutron Source (SNS), both of which are housed at Oak Ridge National Laboratory. We select a relevant data reduction workflow use-case to obtain the differential scattering cross-section from data collected by SNS’s CORELLI and TOPAZ instruments. We compare the current CPU-only production implementation using the Garnet Python multiprocess package based on the Mantid C++ framework against our proposed CPU/GPU implementation that uses the LLVM-based, just-in-time Julia scientific language and the JACC.jl performance-portable package. Two proxy apps were developed: (i) an app for extracting relevant Mantid kernels (MDNorm) in C++ and (ii) the Julia MiniVATES.jl miniapp. We present performance results for NVIDIA A100 and AMD MI100 GPUs and AMD EPYC 7513 and 7662 CPUs. The results provide insights for future generations of data reduction software that can embrace performance portability for an integrated research infrastructure across DOE’s experimental and computational facilities.

Hahn, Steven↗

Neutron time-of-flight reflectometer GRAINS with horizontal sample plane at the IBR-2 reactor: Possibilities and prospects

A new time-of-flight neutron reflectometer GRAINS with a horizontal sample plane (vertical scattering plane) has recently been put into operation at the pulsed reactor IBR-2 (JINR, Dubna). The scattering geometry applied makes it possible to carry out complex studies of nanostructured interfaces in solid and liquid states by measuring the specular reflectivity and the intensity of diffuse scattering of thermal neutrons from open surfaces and hidden interlayer boundaries, including solid-liquid interfaces, over a wide momentum transfer range. The classical analysis of specular reflectivity allows one to determine the scattering length density profile in the object under study in a direction perpendicular to the interface for a thickness of ~100 nm with a resolution of 1 nm. The analysis of off-specular (diffuse) neutron scattering makes it possible to characterize lateral correlations on surfaces and interlayer boundaries. The paper summarizes the first experience in the operation of the GRAINS reflectometer. The instrument characteristics are presented together with the possibilities for experiments with solid and liquid samples illustrated with simple systems. Further steps for the development of the reflectometer are discussed.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Model Development and Analysis of a High-Fidelity Neutron Transport Sensor: The Quadrupole Detector Concept for Measurement of the Neutron Flux Gradient

Accurate reconstruction of the neutron flux distribution within a reactor core is essential for safe and efficient reactor operation. Traditional power shape synthesis in Light Water Reactors relies on hundreds of in-core detectors. However, this approach becomes impractical for Advanced Reactors and Microreactors due to limited space and harsh environments. To address this challenge, we propose a data-driven methodology that combines high-fidelity modeling with real-time ex-core sensor measurements, enabling the reconstruction of core power distribution while minimizing the reliance on intrusive in-core instrumentation. This project began in FY24 and achieved two initial milestones: (1) the definition of a three-year development plan for a Digital Twin framework and (2) the development of high-fidelity neutronics models of the Purdue University Reactor One (PUR-1) using both MCNP6 and OpenMC. The PUR-1 reactor, a zero-power facility, was selected due to its suitability for neutronics-focused modeling and the availability of experimental data for validation. Both models were benchmarked using neutron flux measurements obtained from irradiated gold foils, which were strategically placed within the core during a dedicated campaign in July 2024. This report marks the continuation and completion of those foundational tasks. The OpenMC model has been refined (improved geometric accuracy, expanded cross-section libraries, and refined sampling) and validated using additional experimental data. An updated sensor design—based on quadrupole configuration—was designed to measure both ex-core flux and its spatial gradient. These measurements will serve as inputs to a neural network-based reconstruction algorithm. Finally, the methodology was demonstrated on a two-dimensional test case representative of the heterogeneous material composition of the PUR-1 reactor core. A neural network implementation of the Kirchhoff-Helmholtz integral equation was employed to solve the boundary value problem using peripheral sensor measurements. The preliminary results confirm the strong potential of the proposed approach for accurate and minimally invasive neutron flux reconstruction.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Development of a hybrid neural network and transfer learning model for optimized ICP-MS/MS operation

Correct function and calibration of instrumentation is a crucial assumption for any scientific experiment. One such instrument, tandem inductively coupled plasma mass spectrometer (ICP-MS/MS), has in-depth calibration settings that range across 30+ different parameters, making it difficult to determine optimal conditions without expertise and some degree of trial and error. Often, these settings are hand-tuned, a time-intensive process prone to local maxima and human error. While some automation is available, the automation also may favor local optimizations over a global optimum. In addition to these difficulties, day to day instrument variability can further complicate the calibration process. We propose a solution to this problem as a machine learning (ML) algorithm that learns how each parameter helps determine the calibration sensitivity across several elements, and re-weights parameters over time as instrument variability changes (e.g., a global neural network (NN) with a time-dependent transfer learning (TL) component). This model would be able to generate a surface of predicted calibration sensitivities and their respective parameters, and a simple multivariate algorithm would be able to pull out the optimum results with the settings associated with them. Here-in, we describe our initial findings in working towards this goal, including data extraction from historical files, exploratory data analysis, and some initial model building to better describe the data and the feasibility of our goal.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Development of a High-Rate Front-End ASIC for X-Ray Spectroscopy and Diffraction Applications

We developed a new front-end application-specific integrated circuit (ASIC) to upgrade the Maia X-ray microprobe. The ASIC instruments 32 configurable channels that perform either positive or negative charge amplification, pulse shaping, peak amplitude, and time extraction along with buffered analog storage. At a gain of 3.6 V/fC, 1-μs peaking time, and a temperature of 248 K, an electronic resolution of 13 and 10 e- rms was measured with and without a silicon drift detector (SDD) sensor, respectively. A spectral resolution of 170-eV full-width at half-maximum (FWHM) at 5.9 keV was obtained with an 55Fe source. The channel linearity was better than ± 1% with rate capabilities up to 40 kcps. The ASIC was fabricated in a commercial 250-nm process with a footprint of 6.3 mm × 3.9 mm and dissipates 167 mW of static power.

Vernon, Emerson↗

Instrumentation for Assessing DC Electrical Distribution Systems in Buildings

Direct current (DC) distribution systems is emerging as a favorable option over alternating current in buildings due to its energy and non-energy benefits (e.g., efficiency, resilience, safety). However, limited guidelines exist to evaluate the DC electrical distribution infrastructure. This paper aims to fill that gap by detailing our experience with metering a building-level electrical DC distribution system. Our case study is a DC microgrid at the Direct Energy Partners Research & Development facility located in Charlotte, North Carolina. This paper presents our approach, technical challenges, and lessons learned with DC metering and instrumentation.

buildings↗

Improving Elemental Ratio Measurements on Uranyl Fluoride with NanoSIMS

Measurements on samples of calcined uranyl fluoride (UO 2 F 2 ) using Raman spectroscopy, electron microscopy with elemental analysis, and secondary ion mass spectrometry (SIMS) indicate four facts. First, UO 2 F 2 undergoes a previously unreported oxidation reaction beginning around 350 °C in air. The resulting oxidation compound is likely similar to U 3 O 8 /UO 3 , but presently represents a novel chemical species. Second, variations in F/U ratio across samples as measured by electron microscopy with x-ray spectroscopy correlate with variations in F/U ratio as measured with the NanoSIMS 50L instrument. Third, simple mixed powders of LaF 3 +U 3 O 8 are not sufficiently homogeneous to act as a high F+U content standard material. Fourth, additional method development for determining the bulk F/U ratio using an alternative technique is necessary to further develop analytical standards.

36 MATERIALS SCIENCE↗

An Advanced Extreme-Environment Wireless Telemetry System for Turbine Blade Instrumentation

As advanced natural gas power generation systems evolve, the thrust for increased efficiencies and reduced emissions results in increasingly harsh conditions inside the turbine environment. These high temperatures, pressures, and corrosive atmospheres result in accelerated rates of degradation, leading to failure of turbine materials and components. Wolfspeed, A Cree Company, Siemens Energy, and Siemens Corporate Technology, in collaboration with the Department of Energy (DOE)'s National Energy Technology Laboratory, are developing a reliable and long-term monitoring capability in the turbine hot gas path in the form of novel ceramic-based thermocouples and wide bandgap instrumentation electronics that will contribute to the overall reliability of gas turbines. When equipped with better monitoring and controls, power plants can operate with increased fuel-burning efficiency, improved process dynamics and gas concentrations, and increased overall longevity of the power plant components. This will result in increased turbine availability and a reduction in outages and maintenance costs. The technology being developed in this program is based on advanced techniques and innovations in nearly every aspect of high-temperature electronics, including materials, semiconductor devices, subcomponents, electronic packaging, and system integration. The environment in which this wireless system must operate has continuous centrifugal loads with a gravitation force on the order of 16,000 times the force of gravity (16,000 g) and temperatures exceeding 400°C. This article will specifically discuss the background and motivation for the high-temperature instrumentation system and will explain the high-level electrical system, the construction of the instrumentation package, the techniques used for integration onto rotating components, as well as the wireless power and data transmission systems. In addition to the electrical and mechanical design, this article will also discuss results from laboratory bench testing as well as heated spin rig testing. Lastly, this article will highlight the future direction of the instrumentation system evolution, with a final objective of insertion into Siemens natural gas turbine power plants.

47 OTHER INSTRUMENTATION↗

SU-F-T-06: Development of a Formalism for Practical Dose Measurements in Brachytherapy in the German Standard DIN 6803

Purpose: In the steep dose gradients in the vicinity of a radiation source and due to the properties of the changing photon spectra, dose measurements in Brachytherapy usually have large uncertainties. Working group DIN 6803-3 is presently discussing recommendations for practical brachytherapy dosimetry incorporating recent theoretical developments in the description of brachytherapy radiation fields as well as new detectors and phantom materials. The goal is to prepare methods and instruments to verify dose calculation algorithms and for clinical dose verification with reduced uncertainties. Methods: After analysis of the distance dependent spectral changes of the radiation field surrounding brachytherapy sources, the energy dependent response of typical brachytherapy detectors was examined with Monte Carlo simulations. A dosimetric formalism was developed allowing the correction of their energy dependence as function of source distance for a Co-60 calibrated detector. Water equivalent phantom materials were examined with Monte Carlo calculations for their influence on brachytherapy photon spectra and for their water equivalence in terms of generating equivalent distributions of photon spectra and absorbed dose to water. Results: The energy dependence of a detector in the vicinity of a brachytherapy source can be described by defining an energy correction factor kQ for brachytherapy in the same manner as in existing dosimetry protocols which incorporates volume averaging and radiation field distortion by the detector. Solid phantom materials were identified which allow precise positioning of a detector together with small correctable deviations from absorbed dose to water. Recommendations for the selection of detectors and phantom materials are being developed for different measurements in brachytherapy. Conclusion: The introduction of kQ for brachytherapy sources may allow more systematic and comparable dose measurements. In principle, the corrections can be verified or even determined by measurement in a water phantom and comparison with dose distributions calculated using the TG43 dosimetry formalism. Project is supported by DIN Deutsches Institut fuer Normung.

60 APPLIED LIFE SCIENCES↗

Development of a systematic approach for safety assessment of PLD based equipment of I and C systems - 354

Nuclear power plants (NPPs) increasingly apply digital equipment for instrumentation and control (I and C) systems. During the life cycle of NPPs the operators, designers and manufactures are facing the need to replace or upgrade obsolete equipment or to implement new digital I and C systems. A relatively new challenge in this area is the deployment of programmable logic devices (PLDs) for the equipment of I and C systems. Regulatory approval for safety and safety related I and C systems demands confirmation of evidence that design as well as verification and validation (V and V) processes have ensured that the application of new equipment will fulfil safety and reliability requirements and its intended design function. The objective of the recent research project of GRS is developing a systematic approach for the assessment of PLD-based equipment in safety and safety-related I and C systems regarding the fulfilment of regulatory requirements and identification of undesired failure effects. A generic approach for the safety-oriented assessment of PLD-based equipment has been developed, based on the principles of a Plan-Do-Check-Act (PDCA) cycle. The approach comprises planning of the assessment, predefined analysis steps and methodologies, as well as required input information, criteria for decision making process, the tasks concerning identification of improvement potential and determining documentation. (authors)

22 GENERAL STUDIES OF NUCLEAR REACTORS↗