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At least 1,405 records · Page 78

Coherent structures in a turbulent mixing layer - A comparison between direct numerical simulations and experiments

An eduction scheme has been developed in an attempt to determine the characteristics of large-scale vortical structures in a turbulent mixing layer. This analysis scheme has been applied to a set of experimental data taken in a new, larger mixing layer facility designed to minimize boundary and resonance effects. A similar scheme has been developed to apply to the results of a direct numerical simulation of a temporally growing mixing layer. A comparison of the two approaches shows important similarities in the coherent structures. The numerical simulations indicate that low levels of coherent forcing can dramatically change the evolution of the mixing layer. In the absence of such forcing, the numerical simulations and experiments show a lack of regularity in the transverse position, spacing, amplitude, shape and spanwise coherence of the large-scale vortical structures.

Metcalfe, R. W.↗

Crystal Growth and Structure Characterization of Three Layered Uranyl Phosphates and Their Relation to the Phosphuranylite Family

Three new materials related to the phosphuranylite family were synthesized by using alkali chloride fluxes at 875 °C: CsNa 3 [(UO 2 ) 3 O 2 (PO 4 ) 2 ] ( 1 ), Cs 2 Na 4 [(UO 2 ) 5 O 5 (PO 4 ) 2 ] ( 2 ), and Rb 6 [(UO 2 ) 5 O 5 (PO 4 ) 2 ] ( 3 ). CsNa 3 [(UO 2 ) 3 O 2 (PO 4 ) 2 ] ( 1 ) crystallizes in the triclinic space group P 1 - with the lattice parameters, a = 6.9809(3) Å, b = 9.3326(4) Å, c = 12.9626(5) Å, α = 71.5620(10)°, β = 78.9430(10)°, and γ = 68.0840(1)°; Cs 2 Na 4 [(UO 2 ) 5 O 5 (PO 4 ) 2 ] ( 2 ) crystallizes in the triclinic space group P 1 - with the lattice parameters, a = 6.9890(3) Å, b = 12.9652(6) Å, c = 13.2086(6) Å, α = 96.224(2)°, β = 101.433(2)°, and γ = 105.459(2)°; and Rb 6 (PO 4 ) 2 [(UO 2 ) 5 O 5 ] crystallizes in the P 2 1 / m space group with the lattice parameters, a = 6.9255(3) Å, b = 24.773(1) Å, c = 7.07647(3) Å, and β = 90.741(1)°. The sheets of 1 are based on the phosphuranylite topology, while the sheets of 2 and 3 contain sheets based on the U 3 O 8 and uranophane topologies but differ in the orientation of the phosphate tetrahedra. The regions between the sheets contain the alkali cations and are not all identical in structures 1 and 2 . The geometrical isomers found in these sheet structures and their relationship to known sheet topologies are discussed.

nuclear, materials and chemistry by design, synthe↗

The effect of adhesive layers on the fracture of laminated structures

The effect of the thickness and the elastic properties of the adhesive layers in laminated structures is considered. The structure is assumed to consist of two sets of periodically arranged dissimilar layers which may contain cracks perpendicular to the interfaces. The crack problem is solved under the assumption of plane strain or generalized plane stress and by using two different models for the adhesive layers. In the first model the adhesive layer is approximated by a combination of tensile and shear springs. In the second the adhesive layer is considered to be an elastic continuum, hence involving no approximating assumptions. The results regarding the stress intensity and stress concentration factors obtained from these two models and that found by ignoring the adhesive layers are presented and some comparisons are made.

Gecit, M. R.↗

Minimizing Oxygen Permeability in Chitin/Cellulose Nanomaterial Coatings by Tuning Chitin Deacetylation

The demand for packaging materials with low gas permeabilities is increasing, but commonly used petroleum-derived single-use plastics are not renewable, biodegradable, or easy to recycle. Nanomaterials composed of chitin and cellulose, which are abundant in nature, have high crystallinities and low oxygen permeabilities (OP), providing a viable alternative. In this work, we explore how deacetylation conditions of crab shell chitin can be used to tune the charge and size of resulting chitin nanowhiskers (ChNWs) and the resulting OP of layered film structures. Three deacetylation factors, the concentration of sodium hydroxide (%NaOH), temperature (T), and reaction time, were explored using a three-factor three-level Taguchi design with an orthogonal array. Furthermore, the resulting ChNW suspensions were sequentially spray-coated with suspensions of cellulose nanocrystals (CNCs) onto cellulose acetate (CA) films to form a multilayer structure. We show that ChNWs prepared under more aggressive deacetylation conditions inside the original orthogonal array (higher %NaOH, T, and time) had shorter lengths but the surface charge was significantly influenced only by more aggressive deacetylation outside of the original design conditions. With only ~10% decrease in the ultimate tensile strength and no significant loss in failure strain, the ChNW-CNC coating resulted in ~20% decrease in WVTR in comparison to uncoated CA films. The optimization of process conditions resulted in CA-ChNW-CNC films with a 91-99% decrease in OP (132-16.7 cm 3 ∙μm/m 2 /day/kPa versus 1553 cm3∙μm/m2/day/kPa for uncoated CA).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Coherent structures in a turbulent boundary layer. I - Generation of 'artificial' bursts

In an effort to better understand the physics and structure of coherent events in a turbulent boundary layer, an attempt is made to produce 'artificial' bursts. These are generated in a turbulent boundary layer developed on a flat plate towed in an 18 m water channel and thus with negligible freestream turbulence. The burstlike events are produced by either withdrawing near-wall fluid from two minute holes separated in the spanwise direction or by pitching a miniature delta wing that is flush-mounted to the wall. Either of these two actions generates a hairpinlike vortex and low-speed streak that resemble naturally occurring structures. The resulting sequence of events that occur at a given location can be uniquely controlled, thus allowing detailed examination via phase-locked measurements and flow visualization. In this paper, the proof of concept of artificial burst generation is established by comparing the artificial events with natural, random bursts using flow visualization and hot-film signals.

Gad-El-hak, M.↗

Possible Topological Hall Effect above Room Temperature in Layered Cr 1.2 Te 2 Ferromagnet

Topological Hall effect (THE) has been used as a powerful tool to unlock spin chirality in novel magnetic materials. Recent focus has been widely paid to THE and possible chiral spin textures in two-dimensional (2D) layered magnetic materials. However, the room-temperature THE has been barely reported in 2D materials, which hinders its practical applications in 2D spintronics. In this paper, we report a possible THE signal featuring antisymmetric peaks in a wide temperature window up to 320 K in Cr 1.2 Te 2 , a new quasi-2D ferromagnetic material. The temperature, thickness, and magnetic field dependences of the THE lead to potential spin chirality origin that is associated with the spin canting under external magnetic fields. Furthermore, our work holds promise for practical applications in future chiral spin-based vdW spintronic devices.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Bi-Axial Load Testing of a Woven-Webbing Inflatable Space Habitat Restraint Layer Component

This report discusses testing of a bi-axial woven panel consisting of high-strength webbings that represent a portion of the structural restraint layer of an inflatable space structure. Inflatable softgoods vessels are being researched for human space missions as possible habitats, airlocks and tunnel elements. Understanding the complex behavior of the softgoods restraint layer and maturing finite element analysis capabilities to model these structures is critical to their successful implementation. The primary goal of this research is to study the load-up and load distribution in a weave of webbings, before and after the loss of tension in one of the webbings. In addition, a key objective is to evaluate the ability to convert strains measured via photogrammetry using digital image correlation to loads in the weave. The report gives an introduction and objectives for the test program and a description of the test fixture, setup and procedure. This is followed by a section focusing on the test data and associated discussion. To streamline presentation of the data, one focus case is detailed in the main text. (Comprehensive data set can be found in Appendix A for the three remaining test cases.) In addition to the load and time histories for one case, summary charts and tables that incorporate data from all four test cases are provided. The concluding remarks include major findings, lessons learned and recommendations for future work. Appendix B provides complementary full-field strain results when considering the existing woven webbing data as a fabric. These types of results could inform models intended for global representation. Appendix C contains a description from a series of exploratory instrumented hammer tap tests and results on the weave. These tests describe an area of research for the biaxial test fixture beyond the current testing studying the propagation and detection of vibrations in a tensioned weave that has applications in impact and damage detection.

Karen H Lyle↗

Metallic 2D Janus SNbSe layers driven by a structural phase change

Synthesis of 2D metallic Janus SNbSe and SeNbS in 1T phase from 1H-phase NbS 2 and NbSe 2 , respectively, is achieved through using a room temperature plasma-assisted technique that induces a structural phase transition.

Wu, Cheng-Lun [Materials Science and Engineering, ↗

Effects of nitrogen plasma treatment on the electrical property and band structure of few-layer MoS{sub 2}

Few-layer MoS{sub 2} prepared by the chemical vapor deposition method was treated with nitrogen plasma under different radio-frequency (rf) power conditions in order to experimentally study the change in the electrical property. Control of the rf power could change the work function of MoS{sub 2} from 5.40 eV to 5.06 eV. It is shown that the increased rf power leads to the increased (reduced) number of nitrogen (oxygen) atoms, increasing the electron concentration and shifting the Fermi level toward conduction band. The sensitivity of the work function to the rf power provides an opportunity to tune the work function of MoS{sub 2}.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Femtosecond laser patterning, synthesis, defect formation, and structural modification of atomic layered materials

This article summarizes recent research on laser-based processing of twodimensional (2D) atomic layered materials, including graphene and transition metal dichalcogenides (TMDCs). Ultrafast lasers offer unique processing routes that take advantage of distinct interaction mechanisms with 2D materials to enable extremely localized energy deposition. Experiments have shown that ablative direct patterning of graphene by ultrafast lasers can achieve resolutions of tens of nanometers, as well as single-step pattern transfer. Ultrafast lasers also induce non-thermal excitation mechanisms that are useful for the thinning of TMDCs to tune the 2D material bandgap. Laser-assisted site-specific doping was recently demonstrated where ultrafast laser radiation under ambient air environment could be used for the direct writing of high-quality graphene patterns on insulating substrates. This article concludes with an outlook towards developing further advanced laser processing with scalability, in situ monitoring strategies and potential applications.

36 MATERIALS SCIENCE↗