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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,405 records · Page 78

Radiation in Space and Its Control of Equilibrium Temperatures in the Solar System

The problem of determining equilibrium temperatures for reradiating surfaces in space vacuum was analyzed and the resulting mathematical relationships were incorporated in a code to determine space sink temperatures in the solar system. A brief treatment of planetary atmospheres is also included. Temperature values obtained with the code are in good agreement with available spacecraft telemetry and meteorological measurements for Venus and Earth. The code has been used in the design of space power system radiators for future interplanetary missions.

Juhasz, Albert J.↗

Josephson Thermal Memory

In this work, we propose a superconducting thermal memory device that exploits the thermal hysteresis in a flux-controlled temperature-biased superconducting quantum-interference device (SQUID). This system reveals a flux-controllable temperature bistability, which can be used to define two well-distinguishable thermal logic states. We discuss a suitable writing-reading procedure for these memory states. The time of the memory writing operation is expected to be on the order of approximately 0.2 ns for a Nb-based SQUID in thermal contact with a phonon bath at 4.2 K. We suggest a noninvasive readout scheme for the memory states based on the measurement of the effective resonance frequency of a tank circuit inductively coupled to the SQUID. The proposed device paves the way for a practical implementation of thermal logic and computation. The advantage of this proposal is that it represents also an example of harvesting thermal energy in superconducting circuits.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Chemical control of nadimide cure temperature and rate

Polyimide resins suitable for use as composite matrix materials are formed by copolymerization of maleic and norbornenyl endcapped monomers and oligomers. The copolymers can be cured at temperatures under about 300 C by controlling the available concentration of the maleic end-capped reactant. This control can be achieved by adding sufficient amounts of said maleic reactant, or by chemical modification of either copolymer, so as to either increase Diels-Alder retrogression of the norbornenyl capped reactant and/or holding initiation and polymerization to a rate compatible with the availability of the maleic-capped reactant.

Lauver, R. W.↗

Wireless Temperature Sensing Using Permanent Magnets for Nonlinear Feedback Control of Exothermic Polymers

Epoxies and resins can require careful temperature sensing and control in order to monitor and prevent degradation. To sense the temperature inside a mold, it is desirable to utilize a small, wireless sensing element. In this paper, we describe a new architecture for wireless temperature sensing and closed-loop temperature control of exothermic polymers. This architecture is the first to utilize magnetic field estimates of the temperature of permanent magnets within a temperature feedback control loop. We further improve performance and applicability by demonstrating sensing performance at relevant temperatures, incorporating a cure estimator, and implementing a nonlinear temperature controller. This novel architecture enables unique experimental results featuring closed-loop control of an exothermic resin without any physical connection to the inside of the mold. In this paper we describe each of the unique features of this approach including magnetic field-based temperature sensing, Extended Kalman Filtering (EKF) for cure state estimation, and nonlinear feedback control over time-varying temperature trajectories. We use experimental results to demonstrate how low-cost permanent magnets can provide wireless temperature sensing up to ~90°C. In addition, we use a polymer curecontrol test-bed to illustrate how internal temperature sensing can provide improved temperature control over both short and long time-scales. In conclusion, this wireless temperature sensing and control architecture holds value for a range of manufacturing applications.

47 OTHER INSTRUMENTATION↗

An analytical investigation of shape control of large space structures by applied temperatures

An analytical procedure for the static shape control of flexible space structures subjected to thermal distortions is developed which is based on prescribing temperatures in control elements having much higher coefficients of thermal expansion than the main structure. The temperatures at the control elements are defined so as to minimize the overall thermal distortion of the structure from its ideal shape, and a matrix equation is obtained which can be solved for the set of optimum control temperatures. A formulation of the procedure for continuous structures governed by differential equations and a formulation for discrete (finite element modeled) structures governed by matrix equations are presented. The equations from the continuous formulation are employed for the shape control of a simple beam distorted by nonuniform heating, and the discrete formulation is applied in a general purpose finite-element structural analysis computer program for the shape control of a 750 m radiometer antenna reflector dish subjected to orbital heating. A reduction in thermal distortion by a factor of nearly 50 was obtained with the use of only seven control elements. Results for four different sets of control locations for the antenna are presented in which reductions in distortion of up to a factor of four were obtained.

Haftka, R. T.↗

Separate sensible and latent cooling: Carnot limits and system taxonomy

Energy efficiency and thermal comfort can be improved by independent control of temperature and humidity. In recent work, an emerging class of cooling systems known as separate sensible and latent cooling (SSLC) systems have demonstrated 14 to 47% energy savings, while simultaneously providing better comfort control than conventional air conditioning. In this work, SSLC is defined as using two or more cooling processes with unequal sensible heat ratio (SHR) to control temperature and humidity independently and dynamically. Fundamental efficiency limits of SSLC systems are developed for the first time, demonstrating that the Carnot efficiency for SSLC is higher than that of conventional systems. It is revealed that SSLC has particularly high potential for moderate outdoor temperatures, high sensible building loads, and drier indoor conditions. Additionally, this work proposes a classification scheme for SSLC systems, revealing an enormous number of feasible cycle permutations. This provides a framework for the important research task of developing SSLC systems that will save energy, be practical to construct, and be controllable.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Performance of MODIS Thermal Emissive Bands On-orbit Calibration Algorithms

Two nearly identical copies of the Moderate Resolution Imaging Spectroradiometer (MODIS) are currently operated on-board the Terra and Aqua spacecrafts, launched in December 1999 and May 2002, respectively. Together, they have produced an unprecedented amount of science data products, which are widely used for the studies of changes in the Earth's system of land, oceans, and atmosphere. MODIS is a cross-track scanning radiometer, which uses a two-sided scan mirror and collects data continuously over a wide scan angle range (+/-55 degree relative to the instrument nadir) each scan of 1.47 seconds. It has 36 spectral bands with wavelengths ranging from visible (VIS) to long-wave infrared (LWIR). MODIS bands 1-19 and 26 are the reflective solar bands (RSB) and bands 20-25 and 27-36 are the thermal emissive bands (TEB). MODIS was developed and designed with improvements made over its heritage sensors (such as AVHRR and Landsat) and, in particular, with more stringent calibration requirements. Because of this, MODIS was built with a set of state-of-art on-board calibrators (OBC), which include a solar diffuser (SD), a solar diffuser stability monitor (SDSM), a blackbody (BB), a spectroradiometric calibration assembly (SRCA), and a space view (SV) port. With the exception of view angle differences, MODIS OBC measurements and the Earth View (EV) observations are made via the same optical path. MODIS TEB have a total of 160 individual TEB detectors (10 per band), which are located on two cold focal plane assemblies (CFPA). For nominal on-orbit operation, the CFPA temperature is controlled at 83K via a passive radiative cooler. For the TEB, the calibration requirements at specified typical scene radiances are less than or equal to 1% with an exception for the fire detection (low gain) band. MODIS TEB on-orbit calibration is performed on a scan-by-scan basis using a quadratic calibration algorithm, and data collected from sensor responses to the onboard BB and SV. The BB serves as the thermal calibration source and the SV provides measurements for the sensor's background and offsets. MODIS on-board BB is a v-grooved plate with its temperature measured using 12 platinum resistive thermistors (PRT) uniformly embedded in the BB substrate. All the BB thermistors were characterized pre-launch with reference to the NIST temperature standards. Unlike typical BB operations in many heritage sensors, which have no temperature control capability, the MODIS on-board BB can be operated at any temperatures between instrument ambient (about 270K) and 315K and can also be varied continuously within this range. This feature has significantly enhanced the MODIS' capability of tracking and updating the TEB nonlinear calibration coefficients over its entire mission. Following a brief description of MODIS TEB on-orbit calibration methodologies and its onboard BB operational activities, this paper provides a comprehensive performance assessment of MODIS TEB quadratic calibration algorithm. It examines the scan-by-scan, orbit-by-orbit, daily, and seasonal variations of detector responses and associated impact due changes in the CFPA and instrument temperatures. Specifically, this paper will analyze the contribution by each individual thermal emissive source term (BB, scan cavity, and scan mirror), the impact on the Level 1 B data product quality due to pre-launch and on-orbit calibration uncertainties. A comparison of Terra and Aqua TEB on-orbit performance, lessons learned, and suggestions for future improvements will also be made.

Xiong, Xiaoxiong↗

Application of Artificial Neural Network Model for Optimized Control of Condenser Water Temperature Set-Point in a Chilled Water System

Here, in this study, real-time predictive control and optimization model based on an ANN (artificial neural network) was developed to evaluate the cooling energy saving performance of the optimized control of CndWT (condenser water temperature). For this purpose, the difference in TCEC (total cooling energy consumption) between the conventional control strategy when the CndWT produced by the cooling tower is fixed and the optimized control strategy when real-time control of the CndWT through the optimal ANN model is applied was compared and analyzed. For the modeling of the building to be simulated, the co-simulation of EnergyPlus and MATLAB was built through the middleware Building Controls Virtual Test Bed. For the prediction of TCEC, an ANN model was developed through MATLAB's neural network toolbox. The model accuracy of the ANN was examined through Cv(RMSE) index and as a result, Cv(RMSE) of the optimized ANN model turned out to be approximately 25 %. More importantly, the predictive control technique was able to save TCEC by 5.6 % compared to the conventional control method constantly fixing CndWT set-point to 30 °C. These results showed that the CndWT needs to be dynamically controlled using artificial intelligence technique such as ANN model and that significant energy savings were achievable compared to the conventional fixed control.

42 ENGINEERING↗

Torsional and biaxial (tension-torsion) fatigue damage mechanisms in Waspaloy at room temperature

Strain controlled torsional and biaxial (tension-torsion) low cycle fatigue behavior of Waspaloy was studied at room temperature as a function of heat treatment. Biaxial tests were conducted under proportional and nonproportional cyclic conditions. The deformation behavior under these different cyclic conditions was evaluated by slip trace analysis. For this, a Schmidt-type factor was defined for multiaxial loading conditions, and it was shown that when the slip deformation is predominant, nonproportional cycles are more damaging than proportional or pure axial or torsional cycles. This was attributed to the fact that under nonproportional cyclic conditions, deformation was through multiple slip, as opposed to single slip for other loading conditions, which gave rise to increased hardening. The total life for a given test condition was found to be independent of heat treatment. This was interpreted as being due to the differences in the cycles to initiation and propagation of cracks.

Jayaraman, N.↗

Coatings for CSP Lifetime

The feasibility and performance of tower-technology-based concentrated solar power (CSP) is highly dependent on the efficiency of the energy transformation from sun to heat at the receiver. The higher the solar absorptivity of the receiver coating, the higher the efficiency of the plant as a whole. BrightSource Energy (BSE) has developed a series of High-Performance Coating (HPC) systems in order to achieve high absorptivity over the plant lifetime (25-35 years). This requires stable coatings that are easily applicable on the large receiver surface and will maintain their optical properties under intense solar flux and thousands of heating and cooling cycles in desert conditions. Different coating formulations are required according to the differing plant conditions: receiver materials, operating conditions (temperatures, daily cycles, etc.), and environmental conditions. BSE also developed a coating for the next generation of CSP receivers, such as those being under DOE’s CSP Gen3 program, which will be operated with high temperature heat transfer fluids at temperatures of up to 800°C, which is significantly hotter than the operating temperature of current systems. Once the coating is formulated, the next challenge is evaluating its lifetime properties. BSE has found several independent failure modes that impact HPC absorptivity degradation: • Decrease in HPC optical properties due to oxidation in the receiver tubes surface below the HPC; • HPC film deterioration due to cycling of temperatures and humidity due to daily operation startup and shutdown as well as changing ambient conditions; • Mechanical degradation due to erosion by sand and wind. Existing test methods examine various aspects independently, but do not provide a combined accelerated lifetime result. Creating such a combined test suite, with a way to interpret the results to predict the coating’s projected lifetime, was the ultimate goal of this project. The project was divided into three major workstreams: lab testing (individual failure mode tests and combined failure mode tests); developing a theoretical model for aging; and validation of the test apparatus via on-sun testing in near real-world conditions at CIEMAT-PSA. Developing a test apparatus that accurately controlled the temperature while also introducing the desired solar flux proved more challenging than expected. While in the end we did succeed in creating a test apparatus that can control temperature, solar flux, and humidity, the results did not appear to accelerate the lifetime of the samples as desired. We suspect that to properly accelerate the samples we must also subject the samples to increased amounts of oxygen. Similarly, while we successfully created a combined model that is publicly available, we were unable to validate it sufficiently to feel comfortable recommending it as a general guideline.

14 SOLAR ENERGY↗

Improving Flexibility and Performance of Staged Pressurized Oxy-Combustion

Staged pressurized oxy-combustion (SPOC) is a novel coal combustion power technology being developed by Washington University in St. Louis (WUSTL) that offers the potential to deliver low-carbon power at a reduced cost. Oxy-combustion plants operate by removing most of the nitrogen contained in air prior to combustion, thereby burning fuel in a near-pure oxygen stream instead of air. This combustion produces a flue gas containing primarily carbon dioxide (CO 2 ) and water vapor that allows relatively straightforward CO 2 capture. First-generation, atmospheric oxy-combustion technology relies on a flue gas recycle (FGR) diluent to reduce the peak temperatures achieved and the resulting high thermal radiation levels that would otherwise occur in a fuel/oxygen only flame. In contrast, by staging the combustion in several steps, SPOC reduces the peak temperatures of combustion without resorting to a high degree of FGR to control flame temperatures. The SPOC process operates by utilizing two or more pressurized boiler modules connected in series to produce fuel staging; hence, only a portion of the fuel is combusted in any given combustion module. Subsequently the thermal energy released at each stage can be captured and removed from the gases prior to subsequent stages, when more fuel is introduced. This allows the SPOC process to operate with minimal FGR, avoiding the associated efficiency losses and additional costs. While the staging controls the heat release profile in SPOC, operating in a pressurized condition yields a more compact system, reducing modular boiler size and delivering enhanced heat transfer. Additionally, operating at elevated pressures ensures that the latent heat of moisture available from moisture in the fuel and generated by the combustion of the hydrogen content in the fuel can be captured as useful thermal energy for steam turbine integration. This is possible due to elevated dew point from the high partial pressure of the moisture generated in this process, which allows substantial feedwater heater bypassing to be achieved. The inclusion of this thermal energy, normally lost to the atmosphere in traditional combustion processes or to cooling systems in atmospheric oxy-combustion, allows the resultant net efficiency of the SPOC system to be up to 6 percentage points greater than first-generation systems. To begin the process of developing this technology for full-scale application, the Electric Power Research Institute, Inc. teamed up with WUSTL, American Air Liquide, Doosan Babcock, and the U.S. Department of Energy to investigate a practical and workable boiler design concept that would minimize process risks where possible. The SPOC system offers unique process flexibility opportunities due to the staged nature of the combustion, making it a prime candidate for future primary energy delivery where the ability to operate at reduced load in an efficient manner and ramp rapidly will be valuable for balancing intermittent renewable electricity generation. The efficiency of traditional coal-fired power plants is lower at reduced loads below the steam temperature control range due to the challenges in balancing the heat pickup between radiative and convective superheater and reheater surface. Introducing additional heating surface for optimal extended controlled low load operation will likely lead to excessive attemperation at high loads, ultimately leading to a poorer overall cycle efficiency. The SPOC process can facilitate the adjustment of fuel firing rates between stages, targeting heat pickup to where it is most needed and potentially can shut down stages for low-load operation, facilitating an increased steam temperature control range on turndown. The boiler design concept assessment is being carried out to identify the maximum permissible compactness of the SPOC boiler heating surfaces. The assessment will determine the minimum overall height that will deliver appropriate tube operating metal temperatures at full load and achieve rated reheat steam temperatures at low operating loads, balanced against the needs of efficient coal combustion, and the potential resultant slagging and ash environments. The design parameters are being validated by combustion testing in the 100-kWth pressurized combustion test rig at WUSTL. Parameters being investigated include flame stability, fuel burnout, ash composition, radiative heat flux, and temperature profiles. These are being carried out for a range of inlet gas conditions and compositions and at multiple load conditions to investigate combustion stability at reduced load. The results of this testing inform the modeling of the large-scale system, that was sized at 550 MWe to allow direct comparison with the National Energy Technology Laboratory baseline cases for atmospheric oxy-combustion, air firing, and air firing with post-combustion capture.

20 FOSSIL-FUELED POWER PLANTS↗

Apparatus for Measuring Total Emissivity of Small, Low-Emissivity Samples

An apparatus was developed for measuring total emissivity of small, lightweight, low-emissivity samples at low temperatures. The entire apparatus fits inside a small laboratory cryostat. Sample installation and removal are relatively quick, allowing for faster testing. The small chamber surrounding the sample is lined with black-painted aluminum honeycomb, which simplifies data analysis. This results in the sample viewing a very high-emissivity surface on all sides, an effect which would normally require a much larger chamber volume. The sample and chamber temperatures are individually controlled using off-the-shelf PID (proportional integral derivative) controllers, allowing flexibility in the test conditions. The chamber can be controlled at a higher temperature than the sample, allowing a direct absorptivity measurement. The lightweight sample is suspended by its heater and thermometer leads from an isothermal bar external to the chamber. The wires run out of the chamber through small holes in its corners, and the wires do not contact the chamber itself. During a steady-state measurement, the thermometer and bar are individually controlled at the same temperature, so there is zero heat flow through the wires. Thus, all of sample-temperature-control heater power is radiated to the chamber. Double-aluminized Kapton (DAK) emissivity was studied down to 10 K, which was about 25 K colder than any previously reported measurements. This verified a minimum in the emissivity at about 35 K and a rise as the temperature dropped to lower values.

Tuttle, James↗

Implementation of a Model Predictive Control Strategy to Regulate Temperature Inside Plug-Flow Solar Reactor With Countercurrent Flow

Abstract Solar-driven thermochemical energy storage systems are proven to be promising energy carriers (solar fuels) to utilize solar energy by using reactive solid-state pellets. However, the production of solar fuel requires a quasi-steady-state process temperature, which represents the main challenge due to the transient nature of solar power. In this work, an adaptive model predictive controller (MPC) is presented to regulate the temperature inside a tubular solar reactor to produce solid-state solar fuel for long-term thermal storage systems. The solar reactor system consists of a vertical tube heated circumferentially over a segment of its length by concentrated solar power, and the reactive pellets (MgMn2O4) are fed from the top end and flow downwards through the heated tube. A countercurrent flowing gas supplied from the lower end interacts with flowing pellets to reduce it thermochemically at a temperature range of 1000—1500 °C. A low-order physical model was developed to simulate the dynamics of the solar reactor including the reaction kinetics, and the proposed model was validated numerically by using a 7-kW electric furnace. The numerical model then was utilized to design the MPC controller, where the control system consists of an MPC code linked to an adaptive system identification code that updates system parameters online to ensure system robustness against external disturbances (sudden change in the flow inside the reactor), model mismatches, and uncertainty. The MPC controller parameters are tuned to enhance the system performance with minimum steady-state error and overshoot. The controller is tested to track different temperature ranges between 500 °C and 1400 °C with different particles/gas mass flowrates and ramping temperature profiles. Results show that the MPC controller successfully regulated the reactor temperature within ± 1 °C of its setpoint and maintained robust performance with minimum input effort when subjected to sudden changes in the amount of flowing media and the presence of chemical reaction.

Engineering↗