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At least 1,405 records · Page 78

Soft X-ray emission from laser-irradiated gold foils

Here, this paper reports measurements of soft-x-ray emission from gold foils irradiated by 6 ns laser pulses, and analysis and simulations of the observations. These foils can be used as x-ray sources to drive a wide range of experiments. A multichannel, photodiode array measured the time-resolved, soft-x-ray emission. A soft-x-ray framing camera imaged the emission in selected energy bands. Foil thicknesses were from 0.5 to 1.5 μm. The imaging data show that the region emitting soft x-rays grows throughout the laser drive, on both the front and rear surfaces. Analysis of the emitted radiation flux from the rear surface, taking the time-dependent spot size into account, showed that the peak effective temperature of 0.5-μm-thick foils is near 88 eV, while that of 0.75-μm-thick foils is near 78 eV. A Monte Carlo method was used to evaluate the component of the uncertainty in the effective temperature introduced by variations in signal voltages and by uncertainty in the size of the emitting spot. This was found to be near ±2 eV in most cases. Simple theoretical considerations explain the main features of the observations. The Florence code, working with atomic physics from sophisticated models, proved able to reproduce the main features of the observed spectra with 1D simulations in which the laser energy flux was adjusted on the basis of the observed lateral spreading of energy.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Measurements toward refined methane emission factors from industrial and commercial natural gas meters

The methane emission factors used in the U.S. EPA Greenhouse Gas Inventory (GHGI) for several categories of equipment in the natural gas supply chain currently have large uncertainties. The purpose of this project was to focus on one of those categories, industrial/commercial customer meters. The potential effect of the uncertainty for this category could be large due to the 5.6 million meters nationwide. We divided the country into six regions and worked extensively with local natural gas distribution companies to gain access to the meters. Ten weeks of measurements were conducted with an additional three weeks spent later revisiting the first sites. Sites were selected pseudo-randomly, by first randomly selecting a location then driving to as many meters as possible during that day, then randomly selecting another starting meter for the next day. At each site, every component was scanned with a combustible gas indicator (CGI), all components were counted, and all leaks with indications above 100ppm were logged. For 3 of the 10 weeks of measurements all leaks above 100ppm were quantified and for the remaining seven only leaks with an indication concentration above 22,500 ppm (45% of lower explosive limit) were quantified. Leaks were quantified using an enclosure, a vacuum pump, and methane sensor (either a CGI or Los Gatos Research Greenhouse Gas Analyzer). Through the initial visits 18,934 components were scanned, resulting in 1,170 leak indications above 100ppm, 351 leaks quantified at 174 different meter sets. The data was collected in a way so that it could be stratified by region, meter type, and component type. The largest number of components scanned were valves (4908) and flanges (4571). Very preliminary analysis of the data indicates that the mean leak size (not by meter) by region was Southeast (0.78 ± 2.2 lpm) Southwest (0.63 ± 1.5 lpm), Rocky Mountain (0.54 ± 1.3 lpm) Northeast (0.14 ± 0.56 lpm), Midwest (0.14 ± 0.56 lpm), and Pacific (0.07 ± 0.56 lpm). We also have determined that of the component types logged, roughly 2 – 5% of all components leaked. Our results are only preliminary, but initial indications are that based on data from this study, the current emission factors could increase by a factor of 5 to 10. Data analysis is ongoing to verify.

03 NATURAL GAS↗

Commercially Fabricated Low Loss Superconducting Resonators Integrated With Detectors for Frequency Domain Multiplexing Readout of Future Cosmic Microwave Background Experiments

Planned Stage-IV cosmic microwave background (CMB) experiments call for telescopes with the order of 500 000 transition edge sensor (TES) bolometers. Such large arrays would benefit from detector multiplexing, as well as miniaturization and integration of readout components. Additionally, fabrication of micro-fabricated devices at a commercial foundry could potentially boost production rate and reduce overall cost. To this end, HYPRES, Inc., LBNL, and U.C. Berkeley are developing low loss, superconducting LC resonators integrated with antenna coupled TES bolometers for frequency multiplexing readout. The resonators are fabricated on the same wafer and are in the same process flow as the TES detectors, reducing size, weight, and wiring complexity of a detector module compared to the conventional design, where each component is fabricated separately. We have fabricated and tested resonators from 0.6 to 70 MHz, both as standalone devices and integrated with TES bolometers, all fabricated on 150- mm wafers. Finally, we discuss the design and fabrication of these devices and present measurements of the standalone resonators.

47 OTHER INSTRUMENTATION↗

Diversifying Composition Leads to Hierarchical Composites with Design Flexibility and Structural Fidelity

Although significant progress has been made in the self-assembly of nanostructures, present successes heavily rely on precision in building block design, composition, and pair interactions. These requirements fundamentally limit our ability to synthesize macroscopic materials where the likelihood of impurity inclusion escalates and, more importantly, to access molecular-to-nanoscopic-to-microscopic-to-macroscopic hierarchies, since the types and compositions of building blocks vary at each stage. Inspired by biological blends and high-entropy alloys, we hypothesize that diversifying the blend’s composition can overcome these limitations. Increasing the number of components increases mixing entropy, leading to the dispersion of different components and, as a result, enhances interphase miscibility, weakens the dependence on specific pair interactions, and enables long-range cooperativity. This hypothesis is validated in complex blends containing small molecules, block copolymer-based supramolecules, and nanoparticles/colloidal particles. Hierarchically structured composites can be obtained with formulation flexibility in the filler selection and blend composition. It is worth noting that, by adding small molecules, we can solve the size constraint that plagues traditional block copolymer/nanoparticle blends. Detailed characterization and simulation further confirm that each component is distributed to locally mediate unfavorable interactions, cooperatively mitigate composition fluctuations, and retain structural fidelity. Furthermore, the blends have sufficient mobility to access tunable microstructures without compromising the order of the nanostructure. Besides establishing a kinetically viable pathway to release current constraints in the composite design and to navigate uncertainties during structure formation over multiple length scales, the present study demonstrates that entropy-driven behaviors can be realized in systems beyond high-entropy alloys despite inherent differences between metal alloys and organic/inorganic hybrids.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Pore Aperture Control Toward Size‐Exclusion‐Based Hydrocarbon Separations

Metal–organic frameworks (MOFs) have been proposed as a promising material for non-thermal chemical separations owing to their high structural diversity and tunability. Here, we report the synthesis of a zinc-based MOF containing a three-dimensional (3D) linker, bicyclo[2.2.2]octane-1,4-dicarboxylic acid, with high thermal stability towards the separation of hexane isomers. The incorporation of the 3D linker enhances the structural stability and provides well-defined pore apertures/channels with sub-Ångstrom precision. This precision allowed for the separation of similarly sized hexane isomers based on subtle differences in their kinetic diameters. Multi-component liquid phase batch experiments confirmed the separation of hexanes mixture into linear, monobranched, and dibranched isomers. This work represents a significant milestone in the construction of stable Zn-based MOFs and the incorporation of 3D linkers as a potential solution to challenging separations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

A hierarchical analysis of the impact of methodological decisions on statistical downscaling of daily precipitation and air temperatures

Despite the widespread application of statistical downscaling tools, uncertainty remains regarding the role of model formulation in determining model skill for daily maximum and minimum temperature (Tmax and Tmin), and precipitation occurrence and intensity. Impacts of several key aspects of statistical transfer function form on model skill are evaluated using a framework resistant to model overspecification. We focus on: (a) model structure: simple (generalized linear models, GLMs) versus complex (artificial neural networks, ANNs) models. (b) Predictor selection: Fixed number of predictors chosen a priori versus stepwise selection of predictors and inclusion of grid point values versus predictors derived from application of principal components analysis (PCA) to spatial fields. We also examine the influence of domain size on model performance. For precipitation downscaling, we consider the role of the threshold used to characterize a wet day and apply three approaches (Poisson and Gamma distributions in GLM and ANN) to downscale wet-day precipitation amounts. While no downscaling formulation is optimal for all predictands and at 10 locations representing diverse U.S. climates, and due to the exclusion of variance inflation all of the downscaling formulations fail to reproduce the range of observed variability, models with larger suites of prospective predictors generally have higher skill. For temperature downscaling, ANNs generally outperform GLM, with greater improvements for T min than T max . Furthermore, use of PCA-derived predictors does not systematically improve model skill, but does improve skill for temperature extremes. Model skill for precipitation occurrence generally increases as the wet-day threshold increases and models using PCA-derived predictors tend to outperform those based on grid cell predictors. Each model for wet-day precipitation intensity overestimates annual total precipitation and underestimates the proportion derived from extreme precipitation events, but ANN-based models and those with larger predictor suites tend to have the smallest bias.

54 ENVIRONMENTAL SCIENCES↗

Response of 14YWT alloys under neutron irradiation: A complementary study on microstructure and mechanical properties

Nanostructured ferritic alloys (NFAs) having sub-micron grain size with a high density of nano-oxides (NOs) (size of ~2-3 nm) are one of the best candidates for structural components in Generation IV nuclear systems. In this study, 14YWT NFA cladding tubes were irradiated in BOR60 reactor up to 7 dpa at 360-370 °C. Detailed microstructural analysis has been conducted using bright field transmission electron microscopy, bright field scanning transmission electron microscopy, energy filtered transmission electron microscopy, energy dispersive X-ray spectroscopy, electron energy loss spectroscopy and transmission Kikuchi diffraction techniques. This revealed cavities, <100> and <111> type dislocation loops, and α' precipitates forming after irradiation with relationships between cavities and NOs, and α' precipitates and NOs. Cavities mostly form on the NOs; whereas, α' precipitates form between the NOs where the point defect concentration is high. Moreover, α' precipitates are distributed homogenously on and around the dislocation loops which is consistent with the observation that there is no Cr segregation on dislocation loops. Grain boundaries were found to be mostly depleted in Cr; however, the characteristics of each grain boundary determines the Cr behavior and the α' denuded zone around the grain boundaries. Mechanical properties of the irradiated tubes have been determined by using both low force and high force nanoindentation techniques, resulting in 1.03±0.33 GPa and 0.82±0.20 GPa hardening, respectively. Dispersed barrier hardening calculations and nanoindentation measurements are in good agreement. In this paper, 14YWT NFA has been systematically studied after neutron irradiation to better understand its superior performance: low α' concentration, low swelling and low radiation-induced hardening.

36 MATERIALS SCIENCE↗

Improvement of Oxygen Reduction Performance in Alkaline Media by Tuning Phase Structure of Pd–Bi Nanocatalysts

Tuning the crystal phase of bimetallic nanocrystals offers an alternative avenue to improving their electrocatalytic performance. Herein, we present a facile and one-pot synthesis approach that is used to enhance the catalytic activity and stability toward oxygen reduction reaction (ORR) in alkaline media via control of the crystal structure of Pd-Bi nanocrystals. By merely altering the types of Pd precursors under the same conditions, the monoclinic structured Pd 5 Bi 2 and conventional face-centered cubic (fcc) structured Pd 3 Bi nanocrystals with comparable size and morphology can be precisely synthesized, respectively. Interestingly, the carbon-supported monoclinic Pd 5 Bi 2 nanocrystals exhibit superior ORR activity in alkaline media, delivering a mass activity (MA) as high as 2.05 A/mg Pd . After 10,000 cycles of ORR durability test, the monoclinic structured Pd 5 Bi 2 /C nanocatalysts still remain a MA of 1.52 A/mg Pd , which is 3.6 times, 16.9 times, and 21.7 times as high as those of the fcc Pd 3 Bi/C counterpart, commercial Pd/C, and Pt/C electrocatalysts, respectively. Moreover, structural characterizations of the monoclinic Pd 5 Bi 2 /C nanocrystals after the durability test demonstrate the excellent retention of the original size, morphology, composition, and crystal phase, greatly alleviating the leaching of the Bi component. Overall, this work provides new insight for the synthesis of multimetallic catalysts with a metastable phase and demonstrates phase-dependent catalytic performance.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Dual curved photonic crystal ring resonator based channel drop filter using two-dimensional photonic crystal structure

In this paper channel drop filter (CDF) is designed using dual curved photonic crystal ring resonator (PCRR). The photonic band gap (PBG) is calculated by plane wave expansion (PWE) method and the photonic crystal (PhC) based on two dimensional (2D) square lattice periodic arrays of silicon (Si) rods in air structure have been investigated using finite difference time domain (FDTD) method. The number of rods in Z and X directions is 21 and 20 respectively with lattice constant 0.540 nm and rod radius r = 0.1 µm. The channel drop filter has been optimized for telecommunication wavelengths λ = 1.591 µm with refractive indices 3.533. In the designed structure further analysis is also done by changing whole rods refractive index and it has been observed that this filter may be used for filtering several other channels also. The designed structure is useful for CWDM systems. This device may serve as a key component in photonic integrated circuits. The device is ultra compact with the overall size around 123 µm{sup 2}.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Experimental and theoretical comparison of Sb, As, and P diffusion mechanisms and doping in CdTe

Fundamental material doping challenges have limited CdTe electro-optical applications. In this work, the As atomistic diffusion mechanisms in CdTe are examined by spatially resolving dopant incorporation in both single-crystalline and polycrystalline CdTe over a range of experimental conditions. Density-functional theory calculations predict experimental activation energies and indicate As diffuses slowly through the Te sublattice and quickly along GBs similar to Sb. Because of its atomic size and associated defect chemistry, As does not have a fast interstitial diffusion component similar to P. Experiments to incorporate and activate P, As, and Sb in polycrystalline CdTe are conducted to examine if ex-situ Group V doping can overcome historic polycrystalline doping limits. The distinct P, As, and Sb diffusion characteristics create different strategies for increasing hole density. Because fast interstitial diffusion is prominent for P, less aggressive diffusion conditions followed by Cd overpressure to relocate the Group V element to the Te lattice site is effective. For larger atoms, slower diffusion through the Te sublattice requires more aggressive diffusion, however further activation is not always necessary. Based on the new physical understanding, we have obtained greater than 10^16 cm^-3 hole density in polycrystalline CdTe films by As and P diffusion.

14 SOLAR ENERGY↗

Neutrinos from Earth-bound dark matter annihilation

Abstract A sub-component of dark matter with a short collision length compared to a planetary size leads to efficient accumulation of dark matter in astrophysical bodies. We analyze possible neutrino signals from the annihilation of such dark matter and conclude that in the optically thick regime for dark matter capture, the Earth provides the largest neutrino flux. Using the results of the existing searches, we consider two scenarios for the neutrino flux, from stopped mesons and prompt higher-energy neutrinos. In both cases we exclude some previously unexplored parts of the parameter space (dark matter mass, its abundance, and the scattering cross section on nuclei) by recasting the existing neutrino searches.

Astronomy & Astrophysics↗

The AMACStar ASIC for the HL-LHC ATLAS ITk Strip detector: design, verification, testing, and quality assurance

For the high-luminosity upgrade to the LHC (HL-LHC), the ATLAS detector at CERN requires an all-new inner detector, the Inner Tracker (ITk). The ITk Strip subdetector is made up of silicon modules, which include three types of radiation-hard ASICs. One of these is the Autonomous Monitor and Control (AMAC). The AMAC is manufactured by Global Foundries using 130 nm CMOS8RF DM technology and is approximately 3 by 5 mm in size. This ASIC autonomously monitors the temperatures, voltages, and currents in the module components while controlling critical values in order to prevent these quantities from reaching dangerous levels. The final design, AMACStar, was verified, tested, and ensured to perform all necessary functions. A quality control procedure using an in-house probe station set-up was developed in order to ensure that every individual chip on each wafer of AMACStars required by the ITk Strip project met performance requirements. The average per wafer yield of usable AMACStars is 92.33%, exceeding the design-specific 90% yield estimated for project costing. This estimate was based on actual yields for similar designs in this process.

Analogue electronic circuits↗

Hybrid MEMS-CMOS ion traps for NISQ computing

Surging interest in engineering quantum computers has stimulated significant and focused research on technologies needed to make them manufacturable and scalable. In the ion trap realm this has led to a transition from bulk three-dimensional macro-scale traps to chip-based ion traps and included important demonstrations of passive and active electronics, waveguides, detectors, and other integrated components. At the same time as these technologies are being developed the system sizes are demanding more ions to run noisy intermediate scale quantum (NISQ) algorithms, growing from around ten ions today to potentially a hundred or more in the near future. To realize the size and features needed for this growth, the geometric and material design space of microfabricated ion traps must expand. In this paper we describe present limitations and the approaches needed to overcome them, including how geometric complexity drives the number of metal levels, why routing congestion affects the size and location of shunting capacitors, and how RF power dissipation can limit the size of the trap array. Finally, we also give recommendations for future research needed to accommodate the demands of NISQ scale ion traps that are integrated with additional technologies.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Diffusion Monte Carlo study of strongly interacting two-dimensional Fermi gases

Ultracold atomic Fermi gases have been a popular topic of research, with attention being paid recently to two-dimensional (2D) gases. In this work, we perform T=0 ab initio diffusion Monte Carlo calculations for a strongly interacting two-component Fermi gas confined to two dimensions. We first go over finite-size systems and the connection to the thermodynamic limit. After that, we illustrate pertinent 2D scattering physics and properties of the wave function. We then show energy results for the strong-coupling crossover, in between the Bose-Einstein condensation (BEC) and Bardeen-Cooper-Schrieffer (BCS) regimes. Our energy results for the BEC-BCS crossover are parametrized to produce an equation of state, which is used to determine Tan's contact. We carry out a detailed comparison with other microscopic results. Lastly, we calculate the pairing gap for a range of interaction strengths in the strong coupling regime, following from variationally optimized many-body wave functions.

74 ATOMIC AND MOLECULAR PHYSICS↗

Atacama Cosmology Telescope: Constraints on prerecombination early dark energy

The early dark energy (EDE) scenario aims to increase the value of the Hubble constant (H0) inferred from cosmic microwave background (CMB) data over that found in the standard cosmological model (Λ CDM ), via the introduction of a new form of energy density in the early Universe. The EDE component briefly accelerates cosmic expansion just prior to recombination, which reduces the physical size of the sound horizon imprinted in the CMB. Previous work has found that nonzero EDE is not preferred by Planck CMB power spectrum data alone, which yield a 95% confidence level (C.L.) upper limit f EDE < 0.087 on the maximal fractional contribution of the EDE field to the cosmic energy budget. In this paper, we fit the EDE model to CMB data from the Atacama Cosmology Telescope (ACT) data release 4. We find that a combination of ACT, large-scale Planck TT (similar to WMAP), Planck CMB lensing, and BAO data prefers the existence of EDE at >99.7 % C .L . : f EDE = 0.091$^{+0.020}_{-0.036}$, with H 0 = 70.9$^{+1.0}_{-2.0}$ km/s/Mpc (both 68% C.L.). From a model-selection standpoint, we find that EDE is favored over Λ CDM by these data at roughly 3 σ significance. In contrast, a joint analysis of the full Planck and ACT data yields no evidence for EDE, as previously found for Planck alone. We show that the preference for EDE in ACT alone is driven by its TE and EE power spectrum data. The tight constraint on EDE from Planck alone is driven by its high-ℓ TT power spectrum data. Understanding whether these differing constraints are physical in nature, due to systematics, or simply a rare statistical fluctuation is of high priority. Here, the best-fit EDE models to ACT and Planck exhibit coherent differences across a wide range of multipoles in TE and EE, indicating that a powerful test of this scenario is anticipated with near-future data from ACT and other ground-based experiments.

79 ASTRONOMY AND ASTROPHYSICS↗

Variance components in confocal scanning laser tomography measurements of neuro‐retinal rim area and the effect of repeated measurements on the power to detect loss over time

Abstract Purpose To estimate the variation in measurements of neuro‐retinal rim area (NRA) determined by confocal scanning laser tomography and consequences for clinical follow‐up. Methods Altogether, 24 healthy subjects were randomized on –320 μ m, Moorfields and Standard NRA plane strategies. Additionally, NRA was measured in 32 glaucoma subjects. Variance components for subjects, visits and measurements were estimated with analysis of variance. Sample sizes required to detect a 6.0 × 10 −2 mm 2 NRA change were estimated assuming a significance level of 0.05 and a power of 0.8. Consequences for independent group, and paired comparison design, respectively, were analysed. Further, precision in estimates within subjects over time was investigated. Results The variation of NRA among subjects was considerably larger than the variation among visits and measurements. For glaucoma subjects, the variation among visits and measurements were of the same order but larger than in healthy subjects. It was found that independent group comparisons require inconveniently large sample sizes. Within‐subject paired comparisons over time require sample sizes of below 15 subjects. The estimated variations for glaucoma subjects imply that 54 months of follow‐up is required for detection of change from baseline. Conclusions The variance for subjects is substantial in relation to those for visits and measurements. Cross‐sectional independent group comparisons of levels of NRA are unsuitable, due to considerable subject variation. Levels of NRA differences within subjects between visits can be estimated with acceptable precision. Neuro‐retinal rim area (NRA) measurement can be used for long‐term follow‐up of glaucoma progression.

Sandberg Melin, Camilla↗

ASDFL: An adaptive super‐pixel discriminative feature‐selective learning for vehicle matching

Abstract There are a large number of cameras in modern transportation system that capture numerous vehicle images continuously. Therefore, automatic analysis of these vehicle images is helpful for traffic flow management, criminal investigations and vehicle inspections. Vehicle matching, which aims to determine whether two input images depict an identical vehicle, is one of the core tasks in vehicle analysis. Recent relevant studies have focused on local feature extraction instead of global extraction, since local details can provide crucial cues to distinguish between cars. However, these methods do not select local features; that is, they do not assign weights to local features. Therefore, in this research, we systematically study the vehicle matching task, and present a novel annotation‐free local‐based deep learning method called Adaptive super‐pixel discriminative feature‐selective learning (ASDFL) to address this issue. In ASDFL, vehicle images are segmented into clusters of super‐pixels of similar size by considering the location and colour similarities of pixels without using any component‐level annotation. These super‐pixels are deemed to be the virtual components of vehicles. Moreover, a convolutional neural network is used to extract the deep features of these virtual components. Thereafter, an instance‐specific mask generation module driven by the extracted global features is enhanced to produce a mask to select the most distinctive virtual components of each vehicle image pair in the feature space. Finally, the vehicle matching task is accomplished by classifying the selected virtual component features of each imaged vehicle pair. Extensive experiments on two popular vehicle identification benchmarks demonstrate that our method is 1.57% and 0.8% more accurate than the previous baselines in a vehicle matching task on the VeRi and VehicleID datasets, respectively, which demonstrates the effectiveness of our method.

Qin, Rong↗

Phase measurements of EUV mask defects

Extreme Ultraviolet (EUV) Lithography mask defects were examined on the actinic mask imaging system, SHARP, at Lawrence Berkeley National Laboratory. Also, a quantitative phase retrieval algorithm based on the Weak Object Transfer Function was applied to the measured through-focus aerial images to examine the amplitude and phase of the defects. The accuracy of the algorithm was demonstrated by comparing the results of measurements using a phase contrast zone plate and a standard zone plate. Using partially coherent illumination to measure frequencies that would otherwise fall outside the numerical aperture (NA), it was shown that some defects are smaller than the conventional resolution of the microscope. We found that the programmed defects of various sizes were measured and shown to have both an amplitude and a phase component that the algorithm is able to recover.

42 ENGINEERING↗