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DOE OSTI2015

Solar energy parking canopy demonstration project

The goal of this pilot/demonstration program is to measure the viability of using solar photovoltaic (PV) technology at three locations in a mountain community environment given the harsh weather conditions. An additional goal is to reduce long-term operational costs, minimize green house gas emissions, lower the dependency on energy produced from fossil fuels, and improve the working environment and health of city employees and residents.

14 SOLAR ENERGY↗

DOE OSTI2020

Innovative Approaches to the Decommissioning of a Redundant Plutonium Processing Facility - 20147

At Sellafield, in the North West of the United Kingdom (UK), there are a number of redundant plutonium processing facilities. Over the past three decades several decommissioning strategies have been deployed to clean up these redundant facilities. Whilst there have been many successes previously reported, there remain many challenges. As previously presented at WM2017 (Paper Ref 17081) some of these challenges have recently been addressed through a new approach which introduced a number of innovations. The purpose of these innovations is to seek ways to significantly reduce risks to both decommissioning personnel and the environment by minimising the extent of physical 'hands on' decommissioning activities and by simplifying the waste production process. This paper provides an update on the progress of these innovations since 2017. Additionally, the paper also provides details of the new decommissioning technologies which have been introduced over the past 2 years to enable the most challenging aspects of the redundant plutonium processing facility to be decommissioned. These new decommissioning technologies address challenges associated with the preparation of process vessels and pipework to enable their safe in-situ size reduction by remote means: - New decommissioning techniques have been introduced to allow penetrations to be remotely cut into process vessels and pipework to provide a means of accessing and controlling the venting of any potential hydrogen gas present. - Additionally, a new large scale bespoke remote diamond wire cutting machine has been designed and manufactured to enable the process vessels to be size reduced in situ. Both of these new cutting technologies have involved collaborative working with specialist equipment suppliers including extensive development, trialling demonstration and commissioning prior to bringing the equipment into operational service. Several years of work have now culminated in reaching the final stages of decommissioning of the redundant plutonium processing facility with decommissioning of the final process vessels now underway and completion expected by the end of 2019. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

DOE OSTI2022

Vertebrate and invertebrate competition for carrion in human‐impacted environments depends on abiotic factors

Abstract Human altered landscapes have caused declines in the diversity of wildlife where behaviorally plastic species (i.e., mesocarnivores and invasive species) tend to monopolize these areas and consume predictable and readily accessible food resources, such as human food waste and carrion. Increased consumption of carrion by vertebrates and invasive invertebrate species can alter population dynamics of native necrophagous insects relying on these resources. We tested the hypothesis that vertebrate scavengers and invasive species reduce blow fly (1) ability to use carrion and (2) reproduction in human‐impacted environments in central Texas, USA, with season, habitat (field and wooded landscapes), and carrion type (species of carrion and coat color) acting synergistically. Vertebrate scavengers in this habitat, of which 75% of the documented species were mesocarnivores and obligate scavengers, consumed 100% of carrion during the winter and 62% during summer despite having low species richness (2–5 species). Of the remaining carcasses available for arthropod activity during summer, the invasive red imported fire ant, Solenopsis invicta (Hymenoptera: Formicidae), monopolized 34%, and blow flies (e.g., Lucilia eximia and Chrysomya rufifacies [Diptera: Calliphoridae]) were only able to colonize 25%. Approximately 90% of carrion that was utilized by blow flies was co‐colonized by fire ants, and subsequent production of adult blow flies experienced up to a ninefold reduction in production compared with carcasses that were not scavenged by vertebrates or fire ants. Our results demonstrate oviposition resources used by blow flies in environments altered by human activity are reduced significantly by vertebrate scavengers and an invasive ant species. Future research should determine whether competitive interactions between vertebrate and invasive ant competitors for access to carrion resources have population‐level impacts to blow flies in human‐mediated ecosystems, or whether blow flies are able to shift to other resources to maintain sustainable populations and continue providing ecosystem services, such as pollination.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2023

Effects of Fe(III) (hydr)oxide mineralogy on the development of microbial communities originating from soil, surface water, groundwater, and aerosols

Microbial Fe(III) reduction is a key component of the iron cycle in natural environments. However, the susceptibility of Fe(III) (hydr)oxides to microbial reduction varies depending on the mineral's crystallinity, and the type of Fe(III) (hydr)oxide in turn will affect the composition of the microbial community. Here, we created microcosm reactors with microbial communities from four different sources (soil, surface water, groundwater, and aerosols), three Fe(III) (hydr)oxides (lepidocrocite, goethite, and hematite) as electron acceptors, and acetate as an electron donor to investigate the shaping effect of Fe(III) mineral type on the development of microbial communities. During a 10-month incubation, changes in microbial community composition, Fe(III) reduction, and acetate utilization were monitored. Overall, there was greater reduction of lepidocrocite than of goethite and hematite, and the development of microbial communities originating from the same source diverged when supplied with different Fe(III) (hydr)oxides. Furthermore, each Fe(III) mineral was associated with unique taxa that emerged from different sources. This study illustrates the taxonomic diversity of Fe(III)-reducing microbes from a broad range of natural environments.

58 GEOSCIENCES↗

NASA NTRS2002

Nutrition and renal stone disease in space

There is a growing body of evidence from the National Aeronautics and Space Administration and the Russian space program showing that humans exposed to the microgravity environment of space have a greater risk for developing renal stones. Increased bone resorption and the attendant hypercalciuria and hyperphosphaturia contribute significantly to raising the urinary state of saturation with respect to the calcium salts, namely calcium oxalate and calcium phosphate. In addition, other environmental and dietary factors may adversely affect urine composition and increase stone formation risk during space flight. For example, reductions in urinary volume, pH, and citrate contribute to raising stone formation risk. In addition to raising the risk for calcium stone formation, this metabolic profile is conducive to the formation of uric acid stones. Although observations to date have suggested that there may actually be a reduced food intake during the early phase of flight, crew members on longer-duration flights may increase food intake and be at increased risk for stone formation. Taken together, these findings support the use of nutritional recommendations for crew members that would serve to reduce the stone-forming propensity of the urinary environment. Pharmacologic intervention should be directed at raising urinary volumes, diminishing bone losses, and preventing reductions in urinary pH and citrate. Success in reducing the risk for stone formation in astronauts would also be of potential major benefit to the estimated 20 million Americans with nephrolithiasis.

Review↗

DOE OSTI2011

Morphological and Structural Changes during the Reduction and Reoxidation of CuO/CeO2 and Ce1-xCuxO2 Nanocatalysts: In Situ Studies with Environmental TEM XRD and XAS

We have studied the structural, morphological, and electronic properties of CuO/CeO{sub 2} and Ce{sub 1-x}Cu{sub x}O{sub 2} nanocatalysts during reduction/oxidation cycles using H2 and O2 as chemical probes. Time-resolved in situ characterization was performed by X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) as well as aberration-corrected environmental transmission electron microscopy (ETEM). We have found that both types of nanocatalysts reduce to a Cu/CeO{sub 2} biphase system with significant oxygen vacancies in CeO{sub 2}. Important variations are seen in the Cu particle size and metal dispersion depending on the initial state of the copper oxide-ceria systems. During subsequent in situ oxygen annealing, the Cu precipitated from the CuO/CeO{sub 2} system reoxidized to form CuO through a Cu2O intermediate phase as expected. However, the Cu precipitated from the Ce{sub 0.8}Cu{sub 0.2}O{sub 2} solid solution behaved rather differently under oxidizing conditions, and neither oxidized to form CuO nor fully returned to a bulk Ce{sub 0.8}Cu{sub 0.2}O{sub 2} phase in solid solution. We found that 50% of the Cu returned to a Ce{sub 1-x}Cu{sub x}O{sub 2} solid solution, while the remainder was observed by in situ ETEM to form an amorphous copper oxide phase with a Cu oxidation state similar to Ce{sub 1-x}Cu{sub x}O{sub 2}, but with a local bonding environment similar to CuO. The behavior of the reduced Ce{sub 0.8}Cu{sub 0.2}O{sub 2} reflects strong interactions between Cu and the ceria matrix and illustrates the advantages of working with solid solutions of mixed oxides.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

NASA NTRS2005

Flight Loads and Environments Initiative

A viewgraph presentation on the design of a lightweight non-intrusive force measurement device (FMD) to reduce the cost per effective payload (PL) mass into orbit (CPMO) by improving launch vehicle (LV) loads and environments.

Kaufman, Daniel↗

DOE OSTI2011

Morphological and Structural Changes During the Reduction and Reoxidation of CuO/CeO(2) and Ce(1-x)Cu(x)O(2) Nanocatalysts: In-situ Studies with Environmental TEM, XRD and XAS

We have studied the structural, morphological, and electronic properties of CuO/CeO{sub 2} and Ce{sub 1-x}Cu{sub x}O{sub 2} nanocatalysts during reduction/oxidation cycles using H{sub 2} and O{sub 2} as chemical probes. Time-resolved in situ characterization was performed by X-ray diffraction (XRD) and X-ray absorption spectroscopy (XAS) as well as aberration-corrected environmental transmission electron microscopy (ETEM). We have found that both types of nanocatalysts reduce to a Cu/CeO{sub 2} biphase system with significant oxygen vacancies in CeO{sub 2}. Important variations are seen in the Cu particle size and metal dispersion depending on the initial state of the copper oxide-ceria systems. During subsequent in situ oxygen annealing, the Cu precipitated from the CuO/CeO{sub 2} system reoxidized to form CuO through a Cu{sub 2}O intermediate phase as expected. However, the Cu precipitated from the Ce{sub 0.8}Cu{sub 0.2}O{sub 2} solid solution behaved rather differently under oxidizing conditions, and neither oxidized to form CuO nor fully returned to a bulk Ce{sub 0.8}Cu{sub 0.2}O{sub 2} phase in solid solution. We found that {approx} 50% of the Cu returned to a Ce{sub 1-x}Cu{sub x}O{sub 2} solid solution, while the remainder was observed by in situ ETEM to form an amorphous copper oxide phase with a Cu oxidation state similar to Ce{sub 1-x}Cu{sub x}O{sub 2}, but with a local bonding environment similar to CuO. The behavior of the reduced Ce{sub 0.8}Cu{sub 0.2}O{sub 2} reflects strong interactions between Cu and the ceria matrix and illustrates the advantages of working with solid solutions of mixed oxides.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

NASA NTRS1972

Design, fabrication and testing of two electrohydraulic vibration isolation systems for helicopter environments

Two electrohydraulic vibration isolation systems were designed and fabricated to reduce the vertical vibrations transmitted to the XH-51N research helicopter cabin at the blade passage frequency (18 Hz) and its first harmonic (36 Hz). Hydraulic power and electrical control are provided to two separate servoactuators from a common power supply and control electronics package located behind the pilot's seat. One servoactuator is installed between the cabin and fuselage and replaces an existing passive spring. A second servoactuator is mounted between the existing seat and cabin floor. Both servoactuators incorporate a mechanical failsafe design. The control electronics circuitry provides automatic tracking of the blade passage frequency. Results of laboratory, environmental and ground vibration tests employing an XH-51A stripped down helicopter fuselage show that the active cabin isolator reduces the vertical vibrations transmitted from the fuselage attachment point to the cabin attachment point at 18 and 36 Hz (or as an alternative, 6 Hz) by better than 90 percent.

Allen, R. E.↗

NASA NTRS1995

Report of the Space Shuttle Management Independent Review Team

At the request of the NASA Administrator a team was formed to review the Space Shuttle Program and propose a new management system that could significantly reduce operating costs. Composed of a group of people with broad and extensive experience in spaceflight and related areas, the team received briefings from the NASA organizations and most of the supporting contractors involved in the Shuttle Program. In addition, a number of chief executives from the supporting contractors provided advice and suggestions. The team found that the present management system has functioned reasonably well despite its diffuse structure. The team also determined that the shuttle has become a mature and reliable system, and--in terms of a manned rocket-propelled space launch system--is about as safe as today's technology will provide. In addition, NASA has reduced shuttle operating costs by about 25 percent over the past 3 years. The program, however, remains in a quasi-development mode and yearly costs remain higher than required. Given the current NASA-contractor structure and incentives, it is difficult to establish cost reduction as a primary goal and implement changes to achieve efficiencies. As a result, the team sought to create a management structure and associated environment that enables and motivates the Program to further reduce operational costs. Accordingly, the review team concluded that the NASA Space Shuttle Program should (1) establish a clear set of program goals, placing a greater emphasis on cost-efficient operations and user-friendly payload integration; (2) redefine the management structure, separating development and operations and disengaging NASA from the daily operation of the space shuttle; and (3) provide the necessary environment and conditions within the program to pursue these goals.

Source record↗

NASA NTRS1990

Clutter filter design considerations for Airborne Doppler radar detection of windshear

The problem of clutter rejection when processing down-looking Doppler radar returns from a low altitude airborne platform is a paramount problem. With radar as a remote sensor for detecting and predicting windshear in the vicinity of an urban airport, dynamic range requirements can exceed 50 dB because of high clutter to signal ratios. This presentation describes signal processing considerations in the presence of distributed and/or discrete clutter interference. Previous analyses have considered conventional range cell processing of radar returns from a rigidly mounted radar platform using either the Fourier or the pulse-pair method to estimate average windspeed and windspeed variation within a cell. Clutter rejection has been based largely upon analyzing a particular environment in the vicinity of the radar and employing a variety of techniques to reduce interference effects including notch filtering, Fourier domain line editing, and use of clutter maps. For the airborne environment the clutter characteristics may be somewhat different. Conventional clutter rejection methods may have to be changed and new methods will probably be required to provide useful signal to noise ratios. Various considerations are described. A major thrust has been to evaluate the effect of clutter rejection filtering upon the ability to derive useful information from the post-filter radar data. This analysis software is briefly described. Finally, some ideas for future analysis are considered including the use of adaptive filtering for clutter rejection and the estimation of windspeed spatial gradient directly from radar returns as a means of reducing the effects of clutter on the determination of a windshear hazard.

Baxa, Ernest G., Jr.↗

DOE OSTI2017

Enhanced oxidation resistance of active nanostructures via dynamic size effect

A major challenge limiting the practical applications of nanomaterials is that the activities of nanostructures (NSs) increase with reduced size, often sacrificing their stability in the chemical environment. Under oxidative conditions, NSs with smaller sizes and higher defect densities are commonly expected to oxidize more easily, since high-concentration defects can facilitate oxidation by enhancing the reactivity with O 2 and providing a fast channel for oxygen incorporation. Here, using FeO NSs as an example, we show to the contrary, that reducing the size of active NSs can drastically increase their oxidation resistance. A maximum oxidation resistance is found for FeO NSs with dimensions below 3.2 nm. Rather than being determined by the structure or electronic properties of active sites, the enhanced oxidation resistance originates from the size-dependent structural dynamics of FeO NSs in O 2 . We find this dynamic size effect to govern the chemical properties of active NSs.

36 MATERIALS SCIENCE↗

DOE OSTI2016

Degradation in PV Encapsulant Strength of Attachment: An Interlaboratory Study Towards a Climate-Specific Test

Reduced strength of attachment of the encapsulant resulting from the outdoor environment, including ultraviolet (UV) radiation, may decrease photovoltaic (PV) module lifetime by enabling widespread corrosion of internal components. To date, few studies exist showing how the adhesion of PV components varies with environmental stress. We have conducted an interlaboratory experiment to provide an understanding that will be used to develop climatic specific module tests. Factors examined in the study included the UV light source (lamp type), temperature, and humidity to be proposed for use in accelerated aging tests. A poly (ethylene-co-vinyl acetate) (EVA) formulation often used in veteran PV installations was studied using a compressive shear test - to quantify the strength of attachment at the EVA/glass interface. Replicate laminated glass/polymer/glass coupon specimens were weathered at 12 institutions using a variety of indoor chambers or field aging. Shear strength, shear strain, and toughness were measured using a mechanical load-frame for the compressive shear test, with subsequent optical imaging and electron microscopy of the separated surfaces.

14 SOLAR ENERGY↗

NASA NTRS2014

Lessons Learned in the First Year Operating Software Defined Radios in Space

Operating three unique software defined radios (SDRs) in a space environment aboard the Space Communications and Navigation (SCaN) Testbed for over one year has provided an opportunity to gather knowledge useful for future missions considering using software defined radios. This paper provides recommendations for the development and use of SDRs, and it considers the details of each SDRs approach to software upgrades and operation. After one year, the SCaN Testbed SDRs have operated for over 1000 hours. During this time, the waveforms launched with the SDR were tested on-orbit to assure that they operated in space at the same performance level as on the ground prior to launch to obtain an initial on-orbit performance baseline. A new waveform for each SDR has been developed, implemented, uploaded to the flight system, and tested in the flight environment. Recommendations for SDR-based missions have been gathered from early development through operations. These recommendations will aid future missions to reduce the cost, schedule, and risk of operating SDRs in a space environment. This paper considers the lessons learned as they apply to SDR pre-launch checkout, purchasing space-rated hardware, flexibility in command and telemetry methods, on-orbit diagnostics, use of engineering models to aid future development, and third-party software. Each SDR implements the SCaN Testbed flight computer command and telemetry interface uniquely, allowing comparisons to be drawn. The paper discusses the lessons learned from these three unique implementations, with suggestions on the preferred approach. Also, results are presented showing that it is important to have full system performance knowledge prior to launch to establish better performance baselines in space, requiring additional test applications to be developed pre-launch. Finally, the paper presents the issues encountered with the operation and implementation of new waveforms on each SDR and proposes recommendations to avoid these issues.

radio equipment↗

NASA NTRS2014

Lessons Learned in the First Year Operating Software Defined Radios in Space

Operating three unique software defined radios (SDRs) in a space environment aboard the Space Communications and Navigation (SCaN) Testbed for over one year has provided an opportunity to gather knowledge useful for future missions considering using software defined radios. This paper provides recommendations for the development and use of SDRs, and it considers the details of each SDR's approach to software upgrades and operation. After one year, the SCaN Testbed SDRs have operated for over 1000 hours. During this time, the waveforms launched with the SDR were tested on-orbit to assure that they operated in space at the same performance level as on the ground prior to launch to obtain an initial on-orbit performance baseline. A new waveform for each SDR has been developed, implemented, uploaded to the flight system, and tested in the flight environment. Recommendations for SDR-based missions have been gathered from early development through operations. These recommendations will aid future missions to reduce the cost, schedule, and risk of operating SDRs in a space environment. This paper considers the lessons learned as they apply to SDR pre-launch checkout, purchasing space-rated hardware, flexibility in command and telemetry methods, on-orbit diagnostics, use of engineering models to aid future development, and third-party software. Each SDR implements the SCaN Testbed flight computer command and telemetry interface uniquely, allowing comparisons to be drawn. The paper discusses the lessons learned from these three unique implementations, with suggestions on the preferred approach. Also, results are presented showing that it is important to have full system performance knowledge prior to launch to establish better performance baselines in space, requiring additional test applications to be developed pre-launch. Finally, the paper presents the issues encountered with the operation and implementation of new waveforms on each SDR and proposes recommendations to avoid these issues.

space communication↗

NASA NTRS2023

Ground-Based Capabilities for Lunar Infrastructure Testing

A focus of NASA’s Moon-to-Mars objectives is the development of the infrastructure on the lunar surface that will be needed to support broader lunar surface operations. This infrastructure is intended to support both United States and international partners to expand human presence on the lunar surface. As this lunar infrastructure is designed and established, it will be critical to ensure that the various hardware elements work together to both enable the capabilities and to avoid unintended actions. NASA’s Glenn Research Center (GRC) is establishing ground-based testing and emulation facilities to mimic the lunar environment that the surface power and communications infrastructure will operate in. These facilities are intended to represent power and communications providers, users, and interfaces to ensure that systems operate as intended to support the lunar economy. They will empower industry to rapidly evaluate new technologies under realistic conditions. In 2023 GRC is opening a new, state-of-the-art, Aerospace Communications Facility featuring hardware-in-the-loop and ground-to-orbit testbeds. The Multiple Asset Testbed for Research in Innovative Communications Systems (MATRICS) capability will emulate the lunar communications environment, enabling validation of mission concepts and technologies to reduce risk through performance and operations testing, training, and uncover potential issues in compatibility among communication systems providers and users. In addition to the communications testbed, GRC is also developing a full-scale power grid to reduce lunar mission risk. The Adaptable Surface Power Integration and Research (ASPIRE) project aims to reduce mission and hardware risk via high-fidelity integrated testing and pave the way for commercially supplied utility power on the lunar surface. The facility will be scalable and highly adaptable and will be available to NASA, Industry, Academia, and International Partners. ASPIRE will allow developers to integrate and demonstrate their power solutions in a relevant environment, and it will be able to characterize the lunar power performance in representative mission contexts.

ground-based testing↗

DOE OSTI2017

Genomics and Ecology of Novel N 2 O-Reducing Microorganisms

Microorganisms with the capacity to reduce the greenhouse gas nitrous oxide (N 2 O) to harmless dinitrogen gas are receiving increased attention due to increasing N 2 O emissions (and our need to mitigate climate change) and to recent discoveries of novel N 2 O-reducing bacteria and archaea. The diversity of denitrifying and nondenitrifying microorganisms with capacity for N 2 O reduction was recently shown to be greater than previously expected. A formerly overlooked group (clade II) in the environment include a large fraction of nondenitrifying N 2 O reducers, which could be N 2 O sinks without major contribution to N 2 O formation. Finally, we review the recent advances about fundamental understanding of the genomics, physiology, and ecology of N 2 O reducers and the importance of these findings for curbing N 2 O emissions.

59 BASIC BIOLOGICAL SCIENCES↗

DOE OSTI2016

Removal of TcO 4 – from Representative Nuclear Waste Streams with Layered Potassium Metal Sulfide Materials

Many efforts have focused on the sequestration and immobilization of 99Tc because the radionuclide is highly mobile in oxidizing environments and presents serious health risks due to its radiotoxicity and long half-life (t1/2 = 213 000 a). One of the more common methods for Tc removal from solution and immobilization in solids is based on reducing Tc from highly soluble Tc(VII) to sparingly soluble Tc(IV). In order to remove solution Tc through this reduction process, the Tc-sequestering solid must contain a reducing agent and, ideally, the Tc-sequestering material would function in a large range of chemical environments. For long-term stability, the reduced Tc would preferentially be incorporated into the resulting mineral structure instead of simply being sorbed onto the mineral surface. Here, we report results obtained from batch sorption experiments performed in anoxic and oxic conditions with two sulfide-containing potassium metal sulfide (KMS) materials, known as KMS-2 and KMS-2-SS. In deionized water in anoxic conditions after 15 d of contact, KMS-2 is capable of removing ~45% of Tc and KMS-2-SS is capable of removing ~90% of Tc. The improved performance of KMS-2-SS compared to KMS-2 in deionized water in anoxic conditions appears to be linked both to a higher pH resulting from the batch sorption experiments performed with KMS-2-SS and a higher overall purity of KMS-2-SS. Both materials perform even better in highly caustic (pH~13.5), high ionic strength (8.0 M) simulated Hanford low-activity waste solutions, removing more than 90% Tc after 15 d of contact in anoxic conditions. Post-reaction solids analysis indicate that Tc(VII) is reduced to Tc(IV) and that Tc(IV) is bonded to S atoms in the resulting KMS-2 structure in a Tc2S7 form. In contrast to previous ion exchange experiments with other KMS materials, the batch sorption experiments examining Tc removal cause the initially crystalline KMS materials to lose much of their initial long-range order.

Environmental Molecular Sciences Laboratory↗