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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,405 records · Page 78

Examination of cutouts from Nb3Sn coated cavity inner surfaces

The potential for higher operating temperature and higher gradient have motivated SRF cavity researchers to pursue Nb3Sn as an alternative to Nb for nearly fifty years. Far and away the most common embodiment has been a few micron-thick Nb3Sn layer on the cavity interior surface obtained by vapor diffusion coating, with one or another set of parameters. While many cavities have been made and RF tested, reports of dissecting a cavity in detail to examine the coating and relate it to RF measurements are rare. We coated a BCP-treated single cell cavity in a typical process of tin/tin chloride activation at 500 C followed by tin vapor deposition at 1200 C. After RF-testing, we cut and examined sections from several locations to learn composition, thickness topography of the interior surface. The effect of process variables, such as surface preparation, process temperature and duration, and vapor chemistry needs to be explored.

Eremeev, Grigory↗

Arctic Ice Nucleation Sampling during MOSAiC (INPMOSAIC2) Field Campaign Report

The accelerated rate of warming in the Arctic is of great concern due to potential impacts that include release of greenhouse gases from permafrost, melting glacial ice contributing to sea level rise, and declining sea ice cover exposing the darker ocean surface. These processes induce positive feedbacks and contribute to further warming that affects climate globally. Clouds play a crucial role in regulating the energy reaching the sea ice and snow surfaces, but the magnitude of their effects on surface temperature is not well constrained in the Arctic. Aerosols are an important contributor by serving as seeds for cloud particle formation, but even less is known about their overall impact and origin. In particular, aerosols that serve as ice nucleating particles (INPs) are vastly understudied, especially above the central Arctic Ocean. However, INPs likely play a significant role in arctic mixed-phase cloud (AMPC) microphysics and the resulting impacts of such clouds on the surface energy budget over the sea ice.

54 ENVIRONMENTAL SCIENCES↗

Effective radiative forcing in the aerosol–climate model CAM5.3-MARC-ARG

We quantify the effective radiative forcing (ERF) of anthropogenic aerosols modelled by the aerosol–climate model CAM5.3-MARC-ARG. CAM5.3-MARC-ARG is a new configuration of the Community Atmosphere Model version 5.3 (CAM5.3) in which the default aerosol module has been replaced by the two-Moment, Multi-Modal, Mixing-state-resolving Aerosol model for Research of Climate (MARC). CAM5.3-MARC-ARG uses the ARG aerosol-activation scheme, consistent with the default configuration of CAM5.3. We compute differences between simulations using year-1850 aerosol emissions and simulations using year-2000 aerosol emissions in order to assess the radiative effects of anthropogenic aerosols. We compare the aerosol lifetimes, aerosol column burdens, cloud properties, and radiative effects produced by CAM5.3-MARC-ARG with those produced by the default configuration of CAM5.3, which uses the modal aerosol module with three log-normal modes (MAM3), and a configuration using the modal aerosol module with seven log-normal modes (MAM7). Compared with MAM3 and MAM7, we find that MARC produces stronger cooling via the direct radiative effect, the shortwave cloud radiative effect, and the surface albedo radiative effect; similarly, MARC produces stronger warming via the longwave cloud radiative effect. Overall, MARC produces a global mean net ERF of - 1.79 ± 0.03 W m -2 , which is stronger than the global mean net ERF of - 1.57 ± 0.04 W m -2 produced by MAM3 and - 1.53 ± 0.04 W m -2 produced by MAM7. The regional distribution of ERF also differs between MARC and MAM3, largely due to differences in the regional distribution of the shortwave cloud radiative effect. We conclude that the specific representation of aerosols in global climate models, including aerosol mixing state, has important implications for climate modelling.

54 ENVIRONMENTAL SCIENCES↗

Indirect sensing of atmospheric temperature and water vapor using microwaves.

A prototype of the Nimbus E microwave spectrometer was flown in an airplane over various atmospheric and surface conditions. Effects of clouds and the terrestrial surface on the data are discussed. Using a multiple-regression statistical method of inverting the equation of radiative transfer, estimates of temperature and integrated contents of water vapor and liquid water in the atmosphere below the aircraft were made from the microwave data obtained at high altitude. These estimates are compared with direct measurements made by other experiments on board the aircraft, in both clear atmospheres and in the presence of clouds.

Rosenkranz, P. W.↗

The search for the cause of the low albedo of the moon

Experimentation concerning lunar weathering and its effect on the albedo of the surface cover consisted of: (1) determination of the surface chemical composition of lunar soil and ground-up rock samples by Auger electron spectroscopy, (2) measurement of the optical albedo of these samples, and (3) proton or alpha-particle irradiation of terrestrial rock chips and rock powders and of ground-up lunar rock samples in order to determine the optical and surface chemical effect of simulated solar wind.

Gold, T.↗

Morphological growth of sputtered MoS2 films

Sputtered MoS2 films from 300 A to 20,000 A thick were deposited on metal and glass surfaces. The substrate effects such as surface temperature, finish, pretreatment, and chemistry as they affect the film formation characteristics were investigated by optical, electron transmission, electron diffraction, and scanning electron microscopy. Substrate temperature and surface chemistry were found to be the prime variables as to the formation of a crystalline or amorphous film. The friction characteristics are strictly influenced by the type of film formed. Surface chemistry and surface pretreatment account for compound formation and corresponding grain growth, which directly affect the adhesion characteristics, resulting in poor adherence. Scratches, impurities, inhomogeneities, etc., are favorable nucleation sites for the growth of isolated and complex nodules within the film.

Spalvins, T.↗

Report of the panel on dynamics and aeroelasticity

Model scaling for flutter analysis is reviewed. Characteristics of the Langley Transonic Dynamics Tunnel (TDT) are described and several features are recommended for inclusion in the National Transonic Facility. Problem areas suggested for the NTF include: Reynolds number effects on control surface unsteady aerodynamics; effects of Reynolds number on buffet onset and loads; transonic unsteady aerodynamics; and Reynolds number effects on flutter characteristics of wing planforms and airfoils.

Houbolt, J.↗

Measurements of heat transfer distribution over the surfaces of highly loaded turbine nozzle guide vanes

The results of an experimental study of aerodynamic (surface velocity) and heat transfer distributions over the surfaces of two different, highly loaded, low-solidity contemporary turbine vane designs are presented. The aerodynamic configurations of the two vanes were carefully selected to emphasize fundamental differences in the character of the solution surface pressure distributions and the consequent effect on surface heat transfer distributions. The experimental measurements were made in moderate-temperature, three-vane cascades under steady-state conditions. The principal independent parameters (Mach number, Reynolds number, turbulence intensity, and wall-to-gas temperature ratio) were varied over ranges consistent with actual engine operation, and the heat matrix was structured to provide an assessment of the independent influence of each parameter. These measurements are intended to serve as verification data for a parallel analytical code development effort. The results of this parallel effort are briefly reviewed, and the principal conclusions to date are summarized.

Nealy, D. A.↗

NDE of PWA 1480 single crystal turbine blade material

Cantilever bending fatigue specimens were examined by fluorescent liquid penetrant and radioactive gas penetrant (Krypton) non-destructive evaluation (NDE) methods and tested. Specimens with cast, ground, or polished surface were evaluated to study the effect of surface condition on NDE and fatigue crack initiation. Fractographic and metallurgical analyses were performed to determine the nature of crack precursors. Preliminary results show that fatigue strength was lower for specimens with cast surfaces than for specimens with machined surfaces. The liquid penetrant and gas penetrant techniques both provided indications of a large population of defects on the cast surfaces. On ground or polished specimen surfaces, the gas penetrant appeared to estimate the actual number of voids more accurately than the liquid penetrant.

Klima, Stanley J.↗

NDE of PWA 1480 single crystal turbine blade material

Cantilever bending fatigue specimens were examined by fluorescent liquid penetrant and radioactive gas penetrant (Krypton) Nondestructive Evaluation (NDE) methods and tested. Specimens with cast, ground, or polished surfaces were evaluated to study the effect of surface condition on NDE and fatigue crack initiation. Fractographic and metallurgical analyses were performed to determine the nature of crack precursors. Preliminary results show that fatigue strength was lower for specimens with cast surfaces than for specimens with machined surfaces. The liquid penetrant and gas penetrant techniques both provided indications of a large population of defects on the cast surfaces. On ground or polished specimen surfaces, the gas penetrant appeared to estimate the actual number of voids more accurately than the liquid penetrant.

Klima, Stanley J.↗

A Wind Tunnel Experiment for Trailing Edge Circulation Control on a 6 Percent 2-D Airfoil up to Transonic Mach Numbers

A wind tunnel test was conducted on a six percent thick slightly cambered elliptical circulation control airfoil with both upper and lower surface blowing. Parametric evaluations of jet slot heights and Coanda surface shapes were conducted at mass flow coefficients (C(sub mu)) from 0.0 to 0.12. The test data was acquired in the NASA Langley Transonic Dynamics Tunnel at Mach numbers of 0.8 and 0.3 at Reynolds numbers per foot of 1.05 x 10(exp 6) and 2.43 x 10(exp 5) respectively. For the transonic condition, (Mach = 0.8 at alpha = +3 deg), it was generally found that the smaller slot and larger Coanda surface were more effective overall than other slot/Coanda surface combinations. Generally it was found at Mach = 0.3 at alpha = 6 deg that the smaller slot and smaller Coanda surface were more effective overall than other slot/Coanda surface combinations.

Alexander, Michael G.↗

Numerical Modeling of Flow Distribution in Micro-Fluidics Systems

This paper describes an application of a general purpose computer program, GFSSP (Generalized Fluid System Simulation Program) for calculating flow distribution in a network of micro-channels. GFSSP employs a finite volume formulation of mass and momentum conservation equations in a network consisting of nodes and branches. Mass conservation equation is solved for pressures at the nodes while the momentum conservation equation is solved at the branches to calculate flowrate. The system of equations describing the fluid network is solved by a numerical method that is a combination of the Newton-Raphson and successive substitution methods. The numerical results have been compared with test data and detailed CFD (computational Fluid Dynamics) calculations. The agreement between test data and predictions is satisfactory. The discrepancies between the predictions and test data can be attributed to the frictional correlation which does not include the effect of surface tension or electro-kinetic effect.

Majumdar, Alok↗

Surface Hardness Testing of Mobile Launcher 1 (ML-1) Vehicle Support Posts (VSP) Following Artemis I Launch Exposure

Following the successful launch of Artemis I on November 16th, 2022 (Fig 1), a surface hardness assessment was performed on the eight primary VSPs (Figs. 2, 3) located on the Zero Deck of the ML. This assessment was performed as part of an instrument investigation for strain gauges installed on VSP interior surfaces that had a “strange reaction”. This report does not address the VSP strain gauge investigation, but rather VSP structural integrity for future service (Artemis II, III, …). Surface hardness measurements were taken to assess the strength of the ASTM A148 steel castings to confirm thermal exposure from launch had not reannealed the VSPs. However unlikely, it is possible high temperature may have heated and tempered (reannealed) the VSPs, resulting in a change of built-in stresses. This loss in built-in stress may explain the change in off-set measured by the strain gauges. Initial hardness measurements were made at two interior surfaces of VSPs near the strain gauges and the corresponding exterior surfaces (engine hole-facing). Field hardness measurements on the exterior, engine hole surface-facing surfaces for all eight VSPs ranged from 175 to 226 HB/P, well below the minimum hardness of 302 Brinell (HB). Opposing interior surface hardness measurements near strain gauges ranged from 264 to 358 HB/P. In all cases for flight VSPs, a drop in interior-to-exterior hardness ranging from 70 to 132 HB/P was measured. Surface hardness measurements were then made on the two spare VSPs not exposed to launch temperatures for baseline comparison. These two spare VSPs had a drop in Brinell hardness from interior to exterior surfaces ranging from 3 to 17 HB/P. The large interior-to-exterior delta hardness for eight flight VSPs but not for the two spare VSPs suggests launch exposure temperatures softened the exterior surfaces, raising two questions: 1) Are the VSPs compromised for future use, and 2) How deep is the exterior surface softening effect? To address concerns of low surface hardness values at non-critical exterior surfaces, additional field surface hardness measurements were taken at high-stress locations on VSP3: Both door jams, back radius, and internal left and right radius near the base. These values came in well above the required minimum hardness (317 to 365 HB/P). For a more representative pre-launch versus post-launch surface hardness comparison, VSP Acceptance Data Packages (ADPs) were reviewed, and hardness measurements were made at the same eight original locations on VSP3 where hardness measurements were made at the foundry. To determine the degree of softening, 1/8” of material was machined away at three exterior surfaces of engine hole-facing side (Fig. 4). A significant increase in surface hardness was measured ranging from 50 to 86 HB/P. Values at these three locations were still slightly below the required minimum hardness, so an additional 1/8” material was machined away, and hardness values were retaken. At the ¼” depth, hardness values increased to 321 to 324 HB/P. These values fall above the required minimum, concluding surface hardness testing. Rationale for VSP continued use was reached with no restrictions during a Chief Engineering Review based on hardness values exceeding minimum at critical locations and subsurface locations for VSP #3.

Artemis I↗

Unusual materials effects observed on the thermal control surfaces experiment (S0069)

A number of unusual effects were observed on the Thermal Control Surface Experiment (TCSE) test samples, front cover, and structural components. These include induced UV fluorescence, the migration and degradation of KRS-5 materials, atomic oxygen effects, contamination, texturing, discoloration, and meteoroid/debris impact. LDEF (Long Duration Exposure Facility) mission induced fluorescence was observed on several TCSE samples. Similar fluorescence was observed on LDEF leading edge materials from Experiment A0114.

Zwiener, James M.↗

Embedding PbS Quantum Dots (QDs) in Pb-Halide Perovskite Matrices: QD Surface Chemistry and Antisolvent Effects on QD Dispersion and Confinement Properties

Hybrid materials of metal chalcogenide colloidal quantum dots (QDs) embedded in metal halide perovskites (MHPs) have led to composites with synergistic properties. Here, we investigate how QD size, surface chemistry, and MHP film formation methods affect the resulting optoelectronic properties of QD/MHP “dot-in-matrix” systems. We monitor the QD absorption and photoluminescence throughout synthesis, ligand exchange, and transfer into the MHP ink, and we characterize the final QD/MHP films via electron microscopy and transient absorption. In addition, we are the first to globally map how PbS QDs are distributed on the micrometer scale within these dot-in-matrix systems, using three-dimensional (3D) tomography time-of-flight secondary ion mass spectrometry. The surface chemistry imparted during synthesis directly affects the optical properties of the dot-in-matrix composites. Pb-halide passivation leads to QD/MHP dot-in-matrix samples with optical properties that are well-described by a theoretical model, based on a Type I finite-barrier heterostructure between the PbS QD and the MHP matrix. Samples without Pb-halide passivation show complicated size-dependent behavior, indicating a transition from a Type I heterostructure between the PbS QD wells and MHP barriers for small-sized QDs to PbS QDs that are electronically decoupled from the MHP matrix for larger QDs. Furthermore, the choice in perovskite antisolvent crystallization method leads to a difference in the spatial QD distribution within the perovskite matrix, differences in carrier lifetime, and photoluminescence shifts of up to 180 meV for PbS in methylammonium lead iodide. This work establishes an understanding of such emerging synergistic systems relevant for technologies such as photovoltaics, infrared emitters and detectors, and other unexplored technological applications.

92 SC - Basic Energy Sciences (BES) (SC-22)↗

A self-adjusting platinum surface for acetone hydrogenation

We show that platinum displays a self-adjusting surface that is active for the hydrogenation of acetone over a wide range of reaction conditions. Reaction kinetics measurements under steady-state and transient conditions at temperatures near 350 K, electronic structure calculations employing density-functional theory, and microkinetic modeling were employed to study this behavior over supported platinum catalysts. The importance of surface coverage effects was highlighted by evaluating the transient response of isopropanol formation following either removal of the reactant ketone from the feed, or its substitution with a similarly structured species. The extent to which adsorbed intermediates that lead to the formation of isopropanol were removed from the catalytic surface was observed to be higher following ketone substitution in comparison to its removal, indicating that surface species leading to isopropanol become more strongly adsorbed on the surface as the coverage decreases during the desorption experiment. This phenomenon occurs as a result of adsorbate–adsorbate repulsive interactions on the catalyst surface which adjust with respect to the reaction conditions. Reaction kinetics parameters obtained experimentally were in agreement with those predicted by microkinetic modeling when the binding energies, activation energies, and entropies of adsorbed species and transition states were expressed as a function of surface coverage of the most abundant surface intermediate (MASI, C 3 H 6 OH*). It is important that these effects of surface coverage be incorporated dynamically in the microkinetic model (e.g., using the Bragg–Williams approximation) to describe the experimental data over a wide range of acetone partial pressures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗