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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Solute Redistribution During Aging in a Laser-Based Powder Bed Fusion-Produced Fe-18Ni-9Co-5Mo-Ti Maraging Steel

Solute distribution during the laser-based powder bed fusion of metals process is highly complex because of solidification. This study builds on a previous investigation of how solute heterogeneities across different scales influence phase distribution and aging physical phenomena in a Fe-18Ni-9Co-5Mo-Ti maraging steel (Santana et al. in Addit Manuf 104494, 2024). Previous work using energy-dispersive X-ray spectroscopy revealed heterogeneous Ni and Mo enrichment at intercellular regions. Using X-ray diffraction, 8 ± 3% retained austenite was quantified in as-built samples. Additionally, electron backscatter diffraction analysis exposed the location of retained austenite along cell boundaries. In this work, scanning transmission electron microscopy results revealed the presence of non-enriched retained austenite in the as-built condition. With increased aging temperature, Ni and Mo enrichment in austenite increased, especially at the austenite/martensite boundary. Solute diffusion was simulated in DICTRA Thermo-Calc® software to assess solute redistribution between the matrix and second phases and to comprehend whether elemental diffusion processes are interconnected. Three different scenarios were considered: (1) solute diffusion in the matrix; (2) diffusion with enriched austenite in the intercellular region; (3) diffusion with non-enriched austenite in the intercellular region. Results showed that Ni partitioning controls austenite growth and that boundary regions exhibit higher element enrichment than the core.

42 ENGINEERING↗
DOE OSTI2015

Absolute position measurement in a gas time projection chamber via transverse diffusion of drift charge

Time Projection Chambers (TPCs) with charge readout via micro pattern gaseous detectors can provide detailed measurements of charge density distributions. We here report on measurements of alpha particle tracks, using a TPC where the drift charge is amplified with Gas Electron Multipliers and detected with a pixel ASIC. We find that by measuring the 3-D topology of drift charge and fitting for its transverse diffusion, we obtain the absolute position of tracks in the drift direction. For example, we obtain a precision of 1~cm for 1~cm-long alpha track segments. To our knowledge this is the first demonstration of such a measurement in a gas TPC. This technique has several attractive features: it does not require knowledge of the initial specific ionization, is robust against bias from diffuse charge below detection threshold, and is also robust against high charge densities that saturate the detector response.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2023

Merging of the superbanana plateau and $\sqrt{v}$ transport regimes in nearly quasisymmetric stellarators

We report alpha particle confinement is one of the most demanding issues for stellarators. It now seems clear that it is possible to design optimized stellarators that confine the background plasma at near tokamak radial transport levels. Moreover, adequate collisionless alpha particle confinement is possible in the core of a highly optimized stellarator. Here, the collisional confinement of barely trapped alphas in an optimized stellarator is considered by accounting for the resonance due to the reversal in direction of the drift within a flux surface and investigating the sensitive role of magnetic shear in keeping this resonance close to the passing boundary in some nearly quasisymmetric stellarator configurations. The treatment relies on a narrow collisional boundary layer formulation that combines the responses of both these resonant pitch angle alphas and the remaining barely trapped alphas. A novel merged regime treatment leads to explicit expressions for the energy diffusivity for both superbanana plateau (or resonant plateau) and $\sqrt{v}$ transport in the large aspect ratio limit for a slowing down tail alpha distribution function, where v is the effective pitch angle scattering collision frequency of the trapped alphas off the background ions. Depending on the details of the optimization scheme and the sign of the magnetic shear, modest magnetic shear can be used to reduce superbanana (or resonant) plateau transport to below the $\sqrt{v}$ transport level. In addition, a quasilinear equation retaining spatial diffusion is derived for a general alpha distribution function that allows the radial alpha transport to modify the distribution so it is no longer isotropic in velocity space.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2020

Rechargeable Alkali-Ion Battery Materials: Theory and Computation

Since its development in the 1970s, the rechargeable alkali-ion battery has proven to be a truly transformative technology, providing portable energy storage for devices ranging from small portable electronics to sizable electric vehicles. Here, we present a review of modern theoretical and computational approaches to the study and design of rechargeable alkali-ion battery materials. Additionally, starting from fundamental thermodynamics and kinetics phenomenological equations, we rigorously derive the theoretical relationships for key battery properties, such as voltage, capacity, alkali diffusivity, and other electrochemically relevant computable quantities. We then present an overview of computational techniques for the study of rechargeable alkali-ion battery materials, followed by a critical review of the literature applying these techniques to yield crucial insights into battery operation and performance. Finally, we provide perspectives on outstanding challenges and opportunities in the theory and computation of rechargeable alkali-ion battery materials.

25 ENERGY STORAGE↗
DOE OSTI2025

Removal of Selenium Oxyanions from Aqueous Solutions by Ion Exchange: Equilibrium, Kinetics, and Mechanistic Modeling

Selenium (Se) is an essential micronutrient but toxic at high concentrations, posing challenges for water treatment. This study investigated the removal of selenate (SeO 4 2– ) and selenite (SeO 3 2– ) using the strong-base anion-exchange resin IRA-900, particularly in the presence of competing sulfate (SO 4 2– ). The performance of the commercially available resin IRA-900 was systematically investigated. The batch equilibrium behavior was studied in both single- and binary-component systems, and the kinetic behavior was investigated in single-component systems. Results confirmed a selectivity order of SeO 4 2– > SO 4 2– > SeO 3 2– , indicating preferential SeO 4 2– removal over competing SO 4 2– but lower affinity for SeO 3 2– . The maximum total exchange capacity was determined to be 2.04 mequiv/g. Furthermore, SeO 3 2– uptake was found to be pH-dependent, whereas SeO 4 2– uptake remained stable across a broad pH range. From a modeling perspective, the Law of Mass Action model effectively described equilibrium data, and a transport–reaction modeling framework captured removal kinetics of oxyanions including film and intraparticle diffusion. Finally, X-ray photoelectron spectroscopy confirmed ion exchange between chloride and Se oxyanions as the primary removal mechanism. These findings provide fundamental insights into the removal of Se oxyanions from aqueous solutions by ion exchange.

IRA-900↗
DOE OSTI2014

Parylene-based active micro space radiator with thermal contact switch

Thermal management is crucial for highly functional spacecrafts exposed to large fluctuations of internal heat dissipation and/or thermal boundary conditions. Since thermal radiation is the only means for heat removal, effective control of radiation is required for advanced space missions. In the present study, a MEMS (Micro Electro Mechanical Systems) active radiator using the contact resistance change has been proposed. Unlike previous bulky thermal louvers/shutters, higher fill factor can be accomplished with an array of electrostatically driven micro diaphragms suspended with polymer tethers. With an early prototype developed with parylene MEMS technologies, radiation heat flux enhancement up to 42% has been achieved.

42 ENGINEERING↗
DOE OSTI2015

Optical waveguides in lithium niobate: Recent developments and applications

The state of the art of optical waveguide fabrication in lithium niobate is reviewed, with particular emphasis on new technologies and recent applications. The attention is mainly devoted to recently developed fabrication methods, such as femtosecond laser writing, ion implantation, and smart cut waveguides as well as to the realization of waveguides with tailored functionalities, such as photorefractive or domain engineered structures. More exotic systems, such as reconfigurable and photorefractive soliton waveguides, are also considered. Classical techniques, such as Ti in-diffusion and proton exchange, are cited and briefly reviewed as a reference standpoint to highlight the recent developments. In all cases, the application-oriented point of view is preferred, in order to provide the reader with an up-to date panorama of the vast possibilities offered by lithium niobate to integrated photonics.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2016

Comparison of fluid neutral models for one-dimensional plasma edge modeling with a finite volume solution of the Boltzmann equation

We derive fluid neutral approximations for a simplified 1D edge plasma model, suitable to study the neutral behavior close to the target of a nuclear fusion divertor, and compare its solutions to the solution of the corresponding kinetic Boltzmann equation. The plasma is considered as a fixed background extracted from a detached 2D simulation. We show that the Maxwellian equilibrium distribution is already obtained very close to the target, justifying the use of a fluid approximation. We compare three fluid neutral models: (i) a diffusion model; (ii) a pressure-diffusion model (i.e., a combination of a continuity and momentum equation) assuming equal neutral and ion temperatures; and (iii) the pressure-diffusion model coupled to a neutral energy equation taking into account temperature differences between neutrals and ions. Partial reflection of neutrals reaching the boundaries is included in both the kinetic and fluid models. We propose two methods to obtain an incident neutral flux boundary condition for the fluid models: one based on a diffusion approximation and the other assuming a truncated Chapman-Enskog distribution. The pressure-diffusion model predicts the plasma sources very well. The diffusion boundary condition gives slightly better results overall. Although including an energy equation still improves the results, the assumption of equal ion and neutral temperature already gives a very good approximation.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

X-ray analysis of electron Bernstein wave heating in MST

A pulse height analyzing x-ray tomography system has been developed to detect x-rays from electron Bernstein wave heated electrons in the Madison symmetric torus reversed field pinch (RFP). Cadmium zinc telluride detectors are arranged in a parallel beam array with two orthogonal multi-chord detectors that may be used for tomography. In addition a repositionable 16 channel fan beam camera with a 55° field of view is used to augment data collected with the Hard X-ray array. The chord integrated signals identify target emission from RF heated electrons striking a limiter located 12° toroidally away from the RF injection port. This provides information on heated electron spectrum, transport, and diffusion. RF induced x-ray emission from absorption on harmonic electron cyclotron resonances in low current (<250 kA) RFP discharges has been observed.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2014

Pfirsch–Schlüter neoclassical heavy impurity transport in a rotating plasma

In this paper, we extend previous analytic theories for the neoclassical transport of a trace heavy impurity in a rotating plasma in the Pfirsch-Schl¨uter regime. The complete diffusive and convective components of the ambipolar particle flux are derived. The solution is valid for arbitrary impurity charge and impurity Mach number and for general geometry. Inclusion of finite main ion temperature gradient effects is shown in the small ion Mach number limit. A simple interpolation formula is derived for the case of high impurity charge and circular geometry. While an enhancement of the diffusion coefficient is found for order one impurity Mach number, a reduction due to the rotation-driven poloidal asymmetry in the density occurs for very large Mach number.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Collisional dependence of Alfvén mode saturation in tokamaks

Saturation of Alfvén modes driven unstable by a distribution of high energy particles as a function of collisionality is investigated with a guiding center code, using numerical eigenfunctions produced by linear theory and numerical high energy particle distributions. The most important resonance is found and it is shown that when the resonance domain is bounded, not allowing particles to collisionlessly escape, the saturation amplitude is given by the balance of the resonance mixing time with the time for nearby particles to collisionally diffuse across the resonance width. Finally, saturation amplitudes are in agreement with theoretical predictions as long as the mode amplitude is not so large that it produces stochastic loss from the resonance domain.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2016

Wavelet-based techniques for the gamma-ray sky

Here, we demonstrate how the image analysis technique of wavelet decomposition can be applied to the gamma-ray sky to separate emission on different angular scales. New structures on scales that differ from the scales of the conventional astrophysical foreground and background uncertainties can be robustly extracted, allowing a model-independent characterization with no presumption of exact signal morphology. As a test case, we generate mock gamma-ray data to demonstrate our ability to extract extended signals without assuming a fixed spatial template. For some point source luminosity functions, our technique also allows us to differentiate a diffuse signal in gamma-rays from dark matter annihilation and extended gamma-ray point source populations in a data-driven way.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗
DOE OSTI2015

WE-B-BRD-00: MRI for Radiation Oncology

The use of MRI in radiation therapy is rapidly increasing. Applications vary from the MRI simulator, to the MRI fused with CT, and to the integrated MRI+RT system. Compared with the standard MRI QA, a broader scope of QA features has to be defined in order to maximize the benefits of using MRI in radiation therapy. These QA features include geometric fidelity, image registration, motion management, cross-system alignment, and hardware interference. Advanced MRI techniques require a specific type of QA, as they are being widely used in radiation therapy planning, dose calculations, post-implant dosimetry, and prognoses. A vigorous and adaptive QA program is crucial to defining the responsibility of the entire radiation therapy group and detecting deviations from the performance of high-quality treatment. As a drastic departure from CT simulation, MRI simulation requires changes in the work flow of treatment planning and image guidance. MRI guided radiotherapy platforms are being developed and commercialized to take the advantage of the advance in knowledge, technology and clinical experience. This symposium will from an educational perspective discuss the scope and specific issues related to MRI guided radiotherapy. Learning Objectives: Understand the difference between a standard and a radiotherapy-specific MRI QA program. Understand the effects of MRI artifacts (geometric distortion and motion) on radiotherapy. Understand advanced MRI techniques (ultrashort echo, fast MRI including dynamic MRI and 4DMRI, diffusion, perfusion, and MRS) and related QA. Understand the methods to prepare MRI for treatment planning (electron density assignment, multimodality image registration, segmentation and motion management). Current status of MRI guided treatment platforms. Dr. Jihong Wang has a research grant with Elekta-MRL project. Dr. Ke Sheng receives research grants from Varian Medical systems.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2015

WE-B-BRD-01: MR-LINAC

The use of MRI in radiation therapy is rapidly increasing. Applications vary from the MRI simulator, to the MRI fused with CT, and to the integrated MRI+RT system. Compared with the standard MRI QA, a broader scope of QA features has to be defined in order to maximize the benefits of using MRI in radiation therapy. These QA features include geometric fidelity, image registration, motion management, cross-system alignment, and hardware interference. Advanced MRI techniques require a specific type of QA, as they are being widely used in radiation therapy planning, dose calculations, post-implant dosimetry, and prognoses. A vigorous and adaptive QA program is crucial to defining the responsibility of the entire radiation therapy group and detecting deviations from the performance of high-quality treatment. As a drastic departure from CT simulation, MRI simulation requires changes in the work flow of treatment planning and image guidance. MRI guided radiotherapy platforms are being developed and commercialized to take the advantage of the advance in knowledge, technology and clinical experience. This symposium will from an educational perspective discuss the scope and specific issues related to MRI guided radiotherapy. Learning Objectives: Understand the difference between a standard and a radiotherapy-specific MRI QA program. Understand the effects of MRI artifacts (geometric distortion and motion) on radiotherapy. Understand advanced MRI techniques (ultrashort echo, fast MRI including dynamic MRI and 4DMRI, diffusion, perfusion, and MRS) and related QA. Understand the methods to prepare MRI for treatment planning (electron density assignment, multimodality image registration, segmentation and motion management). Current status of MRI guided treatment platforms. Dr. Jihong Wang has a research grant with Elekta-MRL project. Dr. Ke Sheng receives research grants from Varian Medical systems.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2015

WE-B-BRD-02: MR Simulation for Radiation Therapy

The use of MRI in radiation therapy is rapidly increasing. Applications vary from the MRI simulator, to the MRI fused with CT, and to the integrated MRI+RT system. Compared with the standard MRI QA, a broader scope of QA features has to be defined in order to maximize the benefits of using MRI in radiation therapy. These QA features include geometric fidelity, image registration, motion management, cross-system alignment, and hardware interference. Advanced MRI techniques require a specific type of QA, as they are being widely used in radiation therapy planning, dose calculations, post-implant dosimetry, and prognoses. A vigorous and adaptive QA program is crucial to defining the responsibility of the entire radiation therapy group and detecting deviations from the performance of high-quality treatment. As a drastic departure from CT simulation, MRI simulation requires changes in the work flow of treatment planning and image guidance. MRI guided radiotherapy platforms are being developed and commercialized to take the advantage of the advance in knowledge, technology and clinical experience. This symposium will from an educational perspective discuss the scope and specific issues related to MRI guided radiotherapy. Learning Objectives: Understand the difference between a standard and a radiotherapy-specific MRI QA program. Understand the effects of MRI artifacts (geometric distortion and motion) on radiotherapy. Understand advanced MRI techniques (ultrashort echo, fast MRI including dynamic MRI and 4DMRI, diffusion, perfusion, and MRS) and related QA. Understand the methods to prepare MRI for treatment planning (electron density assignment, multimodality image registration, segmentation and motion management). Current status of MRI guided treatment platforms. Dr. Jihong Wang has a research grant with Elekta-MRL project. Dr. Ke Sheng receives research grants from Varian Medical systems.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2015

WE-B-BRD-03: MR QA/QC for MRgRT

The use of MRI in radiation therapy is rapidly increasing. Applications vary from the MRI simulator, to the MRI fused with CT, and to the integrated MRI+RT system. Compared with the standard MRI QA, a broader scope of QA features has to be defined in order to maximize the benefits of using MRI in radiation therapy. These QA features include geometric fidelity, image registration, motion management, cross-system alignment, and hardware interference. Advanced MRI techniques require a specific type of QA, as they are being widely used in radiation therapy planning, dose calculations, post-implant dosimetry, and prognoses. A vigorous and adaptive QA program is crucial to defining the responsibility of the entire radiation therapy group and detecting deviations from the performance of high-quality treatment. As a drastic departure from CT simulation, MRI simulation requires changes in the work flow of treatment planning and image guidance. MRI guided radiotherapy platforms are being developed and commercialized to take the advantage of the advance in knowledge, technology and clinical experience. This symposium will from an educational perspective discuss the scope and specific issues related to MRI guided radiotherapy. Learning Objectives: Understand the difference between a standard and a radiotherapy-specific MRI QA program. Understand the effects of MRI artifacts (geometric distortion and motion) on radiotherapy. Understand advanced MRI techniques (ultrashort echo, fast MRI including dynamic MRI and 4DMRI, diffusion, perfusion, and MRS) and related QA. Understand the methods to prepare MRI for treatment planning (electron density assignment, multimodality image registration, segmentation and motion management). Current status of MRI guided treatment platforms. Dr. Jihong Wang has a research grant with Elekta-MRL project. Dr. Ke Sheng receives research grants from Varian Medical systems.

60 APPLIED LIFE SCIENCES↗
DOE OSTI2024

Fast-Charging Li 4 Ti 5 O 12 Anode Driven by Light

Lithium-ion batteries with fast charging capabilities are crucial for widespread adoption of electric vehicles, as they will increase acceptance of the technology and reduce range anxiety for drivers. To achieve this, advanced fast charging technologies and alternative methods to enhance the slow electrochemical processes are desperately required. This study applied light-emitting diode (LED) photo-assisted fast charging to Li 4 Ti 5 O 12 (LTO), a large bandgap cubic spinel material, to enhance charging speed through electronic-structure coupling. UV LED-generated light irradiation on to the electrode interface boosted the ion diffusion and lithium cation addition by a factor of 1.3 during electrochemical lithiation, resulting in a 30% decrease in charging time under ambient conditions. Red LED light was not effective in accelerating the reaction as it does not provide sufficient energy. The first-principles calculations support the concept that UV illumination generates charges by overcoming the material’s bandgap and effectively reducing it through the introduction of additional titanium defect states.

25 ENERGY STORAGE↗
DOE OSTI2019

Utilizing Highly Scattered Light for Intelligence through Aerosols

This communication is the final report for the project Utilizing Highly Scattered Light for Intelligence through Aerosols funded by the Laboratory Directed Research and Development (LDRD) program at Sandia National Laboratories and lasting six months in 2019. Aerosols like fog reduce visibility and cause down-time that for critical systems or operations are unacceptable. Information is lost due to the random scattering and absorption of light by tiny particles. Computational diffuse optical imaging methods show promise for interpreting the light transmitted through fog, enabling sensing and imaging to improve situational awareness at depths 10 times greater than current methods. Developing this capability first requires verification and validation of diffusion models of light propagation in fog. For this reason, analytical models were developed and compared to experimental data captured at the Sandia National Laboratory Fog Chamber facility. A methodology was developed to incorporate the propagation of scattered light through the imaging optics to a pixel array. The diffusion approximation to the radiative transfer equation was found to predict light propagation in fog under the appropriate conditions.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗