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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,423 records · Page 79

Used Fuel Disposition Campaign: Phase I Ring Compression Testing of High-Burnup Cladding

The purpose of ring compression testing is to generate data to support the development of the technical basis for extended storage and transportation of high-burnup fuel. Argonne National Laboratory developed the methodology of using ring compression tests (RCTs) for radial-hydride-treated (RHT) cladding to generate data for the Nuclear Regulatory Commission (NRC) on the behavior of high-burnup Zircaloy-4 (Zry-4) and ZIRLO™ cladding. The RHT/RCT methodology is an established test protocol accepted by NRC for generating data to support the technical basis for licensing storage and transportation casks with high-burnup fuel. In July 2011, Phase I testing for DOE on high-burnup M5 ® cladding was initiated under the ANL FY11 Work Package Transportation; Phase I testing for DOE on high-burnup M5 ® cladding continued into fiscal year 2012 under the ANL FY12 Work Package Engineering Materials Experimental. This report highlights the results of completed Phase I testing of high-burnup M5 ® cladding and the revised three-year test plan, which is included in the Appendix.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Summary of Compression Testing of U-10Mo

The mechanical properties of depleted uranium plus 10 weight percent molybdenum alloy (U-10Mo) have been evaluated by high temperature compression testing. Compression testing was conducted at three strain rates over a temperature range of 400 to 800°C. The results indicate that with increasing test temperature, material flow stress decreases and the material becomes more sensitive to strain rate. In addition, above the eutectoid transformation temperature, the drop in material flow stress is prominent and shows a strain-softening behavior, especially at lower strain rates.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

University of Arizona Compressed Air Energy Storage

Boiled down to its essentials, the grant’s purpose was to develop and demonstrate the viability of compressed air energy storage (CAES) for use in renewable energy development. While everyone agrees that energy storage is the key component to enable widespread adoption of renewable energy sources, the development of a viable scalable technology has been missing. The Department of Energy has focused on expanded battery research and improved forecasting, and the utilities have deployed renewable energy resources only to the extent of satisfying Renewable Portfolio Standards. The lack of dispatchability of solar and wind-based electricity generation has drastically increased the cost of operation with these components. It is now clear that energy storage coupled with accurate solar and wind forecasting make up the only combination that can succeed in dispatchable renewable energy resources. Conventional batteries scale linearly in size, so the price becomes a barrier for large systems. Flow batteries scale sub-linearly and promise to be useful if their performance can be shown to provide sufficient support for solar and wind-base electricity generation resources. Compressed air energy storage provides the most desirable answer in terms of scalability and performance in all areas except efficiency. With the support of the DOE, Tucson Electric Power and Science Foundation Arizona, the Arizona Research Institute for Solar Energy (AzRISE) at the University of Arizona has had the opportunity to investigate CAES as a potential energy storage resource.

25 ENERGY STORAGE↗

Shock compression experiments on Lithium Deuteride single crystals.

S hock compression exper iments in the few hundred GPa (multi - Mabr) regime were performed on Lithium Deuteride (LiD) single crystals . This study utilized the high velocity flyer plate capability of the Sandia Z Machine to perform impact experiments at flyer plate velocities in the range of 17 - 32 km/s. Measurements included pressure, density, and temperature between %7E200 - 600 GPa along the Principal Hugoniot - the locus of end states achievable through compression by large amplitude shock waves - as well as pressure and density of re - shock states up to %7E900 GPa . The experimental measurements are compared with recent density functional theory calculations as well as a new tabular equation of state developed at Los Alamos National Labs.

Knudson, Marcus D.↗

Parallel Tensor Compression for Large-Scale Scientific Data.

As parallel computing trends towards the exascale, scientific data produced by high-fidelity simulations are growing increasingly massive. For instance, a simulation on a three-dimensional spatial grid with 512 points per dimension that tracks 64 variables per grid point for 128 time steps yields 8 TB of data. By viewing the data as a dense five way tensor, we can compute a Tucker decomposition to find inherent low-dimensional multilinear structure, achieving compression ratios of up to 10000 on real-world data sets with negligible loss in accuracy. So that we can operate on such massive data, we present the first-ever distributed memory parallel implementation for the Tucker decomposition, whose key computations correspond to parallel linear algebra operations, albeit with nonstandard data layouts. Our approach specifies a data distribution for tensors that avoids any tensor data redistribution, either locally or in parallel. We provide accompanying analysis of the computation and communication costs of the algorithms. To demonstrate the compression and accuracy of the method, we apply our approach to real-world data sets from combustion science simulations. We also provide detailed performance results, including parallel performance in both weak and strong scaling experiments.

59 BASIC BIOLOGICAL SCIENCES↗

Numerical Simulations of the Kolsky Compression Bar Test

The Kolsky compression bar, or split Hopkinson pressure bar (SHPB), is an ex- perimental apparatus used to obtain the stress-strain response of material specimens at strain rates in the order of 10 2 to 10 4 1/s. Its operation and associated data re- duction are based on principles of one-dimensional wave propagation in rods. Second order effects such as indentation of the bars by the specimen and wave dispersion in the bars, however, can significantly affect aspects of the measured material response. Finite element models of the experimental apparatus were used here to demonstrate these two effects. A procedure proposed by Safa and Gary (2010) to account for bar indentation was also evaluated and shown to improve the estimation of the strain in the bars significantly. The use of pulse shapers was also shown to alleviate the effects of wave dispersion. Combining the two can lead to more reliable results in Kolsky compression bar testing.

Corona, Edmundo↗

Design and Testing of CO 2 Compression Using Supersonic Shock Wave Technology

This report summarizes work performed by Ramgen and subcontractors in pursuit of the design and construction of a 10 MW supersonic CO2 compressor and supporting facility. The compressor will demonstrate application of Ramgen’s supersonic compression technology at an industrial scale using CO2 in a closed-loop. The report includes details of early feasibility studies, CFD validation and comparison to experimental data, static test experimental results, compressor and facility design and analyses, and development of aerodynamic tools. A summary of Ramgen's ISC Engine program activity is also included. This program will demonstrate the adaptation of Ramgen's supersonic compression and advanced vortex combustion technology to result in a highly efficient and cost effective alternative to traditional gas turbine engines. The build out of a 1.5 MW test facility to support the engine and associated subcomponent test program is summarized.

42 ENGINEERING↗

On the Preconditioning of a Newton-Krylov Solver for a High-Order reconstructed Discontinuous Galerkin Discretization of All-Speed Compressible Flow with Phase Change for Application in Laser-Based Additive Manufacturing

This dissertation focuses on the development of a fully-implicit, high-order compressible ow solver with phase change. The work is motivated by laser-induced phase change applications, particularly by the need to develop large-scale multi-physics simulations of the selective laser melting (SLM) process in metal additive manufacturing (3D printing). Simulations of the SLM process require precise tracking of multi-material solid-liquid-gas interfaces, due to laser-induced melting/ solidi cation and evaporation/condensation of metal powder in an ambient gas. These rapid density variations and phase change processes tightly couple the governing equations, requiring a fully compressible framework to robustly capture the rapid density variations of the ambient gas and the melting/evaporation of the metal powder. For non-isothermal phase change, the velocity is gradually suppressed through the mushy region by a variable viscosity and Darcy source term model. The governing equations are discretized up to 4th-order accuracy with our reconstructed Discontinuous Galerkin spatial discretization scheme and up to 5th-order accuracy with L-stable fully implicit time discretization schemes (BDF2 and ESDIRK3-5). The resulting set of non-linear equations is solved using a robust Newton-Krylov method, with the Jacobian-free version of the GMRES solver for linear iterations. Due to the sti nes associated with the acoustic waves and thermal and viscous/material strength e ects, preconditioning the GMRES solver is essential. A robust and scalable approximate block factorization preconditioner was developed, which utilizes the velocity-pressure (vP) and velocity-temperature (vT) Schur complement systems. This multigrid block reduction preconditioning technique converges for high CFL/Fourier numbers and exhibits excellent parallel and algorithmic scalability on classic benchmark problems in uid dynamics (lid-driven cavity ow and natural convection heat transfer) as well as for laser-induced phase change problems in 2D and 3D.

42 ENGINEERING↗

X-Ray Diffraction Measurements on Laser-Compressed Polycrystalline Samples Using a Short-Pulse Laser Generated X-Ray Source

Existing models for most materials do not describe phase transformations and associated lattice dy- namics (kinetics) under extreme conditions of pressure and temperature. Dynamic x-ray diffraction (DXRD) allows material investigations in situ on an atomic scale due to the correlation between solid-state structures and their associated diffraction patterns. In this LDRD project we have devel- oped a nanosecond laser-compression and picosecond-to-nanosecond x-ray diffraction platform for dynamically-compressed material studies. A new target chamber in the Target Bay in building 983 was commissioned for the ns, kJ Z-Beamlet laser (ZBL) and the 0.1 ns, 250 J Z-Petawatt (ZPW) laser systems, which were used to create 8-16 keV plasma x-ray sources from thin metal foils. The 5 ns, 15 J Chaco laser system was converted to a high-energy laser shock driver to load material samples to GPa stresses. Since laser-to-x-ray energy conversion efficiency above 10 keV is low, we employed polycapillary x-ray lenses for a 100-fold fluence increase compared to a conventional pinhole aperture while simultaneously reducing the background significantly. Polycapillary lenses enabled diffraction measurements up to 16 keV with ZBL as well as diffraction experiments with ZPW. This x-ray diffraction platform supports experiments that are complementary to gas guns and the Z facility due to different strain rates. Ultimately, there is now a foundation to evaluate DXRD techniques and detectors in-house before transferring the technology to Z. This page intentionally left blank.

36 MATERIALS SCIENCE↗

1,000+ cycles of a 350 bar prototype cryo-compressed pressure vessel

A type 3 pressure vessel similar to the vessel used in their prototype cryo-compressed vehicle was leased by BMW AG (Munich, Germany) to Lawrence Livermore National Laboratory (Live rmore, CA) in order to conduct multiple cryo-compressed fills at the testing facility, using the Linde 900 bar LH 2 pump.

47 OTHER INSTRUMENTATION↗

Triaxial Compression Results on Core from Borehole U-15n, NNSS, in support of SPE

Triaxial compression tests from core hole U-15n are part of a larger material characterization effort for the Source Physics Experiment (SPE) project. This larger effort encompasses characterizing Climax Stock granite rock from the Nevada National Security Site (NNSS) both before and after each SPE shot. The current test series includes triaxial compression tests on dry and saturated intact granite and fault material at 100, 200, 300, and 400 MPa confining pressure.

58 GEOSCIENCES↗

Progress Summary: 17-Month Compression Set and Load Retention of Thermally Accelerated Aged Siloxane Specimens (Additively Manufactured by the Direct-Ink-Write (DIW) 3D Printing Technique) was Measured

Accelerated aging of polymeric materials is needed to predict their long-term mechanical functionality. Two key metrics used to evaluate their performance are compression set and load retention. A baseline (time = 0) mechanical assessment was done prior to initiating the accelerated aging process to acquire initial thickness and load values for future calculation of compression set and load retention.

36 MATERIALS SCIENCE↗

Compressor-less Hydrogen Refueling Station Using Thermal Compression

The goal of this project was to demonstrate the technical and economic feasibility of using thermal compression to create the hydrogen pressure necessary to operate vehicle hydrogen fueling stations. The concept of utilizing the exergy within liquid hydrogen to build pressure rather than mechanical components such as compressors or cryogenic liquid pumps has several advantages. In theory, the compressor-less hydrogen station will have lower operating and maintenance costs because the compressors found in conventional stations require large amounts of electricity to run and are prone to mechanical breakdowns. The thermal compression station also utilizes some of the energy used to liquefy the hydrogen as work to build pressure, this is energy that in conventional stations is lost as heat to the environment.

08 HYDROGEN↗

Mixed gases in compressed cylinders: some popular misconceptions and explanations

Many industrial applications and scientific investigations require gaseous premixes. These are generally available in compressed gas cylinders from commercial vendors. Despite many decades of working knowledge with compressed premixed gases, various individuals from the production plants have expressed concerns regarding the ability of the gases to remain mixed in storage and delivery. In this brief tutorial, we show the mathematics and physics that underwrite our confidence in the use of premixed gases as we explain the following: The conditions in which separation of gases due to gravity is of practical concern; The conditions for preferential extraction of lighter gases from premixed gas tank; The time length necessary for homogeneous mixing of gases by molecular kinetics.

36 MATERIALS SCIENCE↗

Microstructural Changes to Thermally Sprayed Materials Subjected to Dynamic Compression

Dynamic compression of materials can induce a variety of microstructural changes. As thermally-sprayed materials have highly complex microstructures, the expected pressure at which changes occur cannot be predicted a priori. In addition, typical in-situ measurements such as velocimetry are unable to adequately diagnose microstructural changes such as failure or pore collapse. Quasi-isentropic compression experiments with sample recovery were conducted to examine microstructural changes in thermally sprayed tantalum and tantalum-niobium blends up to 8 GPa pressure. Spall fracture was observed in all tests, and post-shot pore volume decreased relative to the initial state. The blended material exhibited larger spall planes with fracture occurring at interphase boundaries. An estimate of the pressure at which pore collapse is complete was determined to be ~26 GPa for pure tantalum and ~19 GPa for the tantalumniobium blend under these loading conditions.

36 MATERIALS SCIENCE↗

Applying Compression-Based Metrics to Seismic Data in Support of Global Nuclear Explosion Monitoring

The analysis of seismic data for evidence of possible nuclear explosion testing is a critical global security mission that relies heavily on human expertise to identify and mark seismic signals embedded in background noise. To assist analysts in making these determinations, we adapted two compression distance metrics for use with seismic data. First, we demonstrated that the Normalized Compression Distance (NCD) metric can be adapted for use with waveform data and can identify the arrival times of seismic signals. Then we tested an approximation for the NCD called Sliding Information Distance (SLID), which can be computed much faster than NCD. We assessed the accuracy of the SLID output by comparing it to both the Akaike Information Criterion (AIC) and the judgments of expert seismic analysts. Our results indicate that SLID effectively identifies arrival times and provides analysts with useful information that can aid their analysis process.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Data Science and Computation for Rapid and Dynamic Compression Experiment Workflows at Experimental Facilities (Workshop Overview) [Slides]

Motivation for this workshop stems from these items: Compression experiments are important to LANL's core mission. The scientific community is sometimes frustrated at the pace of discovery. Data analytics for other experimental regimes are advancing. Now is the time as facilities are upgraded and coming online. Advances in data analytics and computational resources could push compression experiment discoveries to a new level.

97 MATHEMATICS AND COMPUTING↗

Data Science and Computation for Rapid and Dynamic Compression Experiment Workflows at Experimental Facilities, September 8-11, 2020. Workshop Report

The application of high pressure to materials has enabled discoveries in scientific fields such as planetary science, materials science, and materials synthesis. Recent advances in X-ray user light sources and other facilities, co-location and integration of user facilities with high-pressure drivers, availability of high-performance computing (HPC) platforms, and the development of new data science techniques have created opportunities for, and challenges in, advancing data analytics for rapid and dynamic compression experiments. To address these challenges, harness the emerging technology now available, and expedite scientific discovery, Los Alamos National Laboratory (LANL) hosted a virtual workshop entitled “Data Science and Computation for Rapid and Dynamic Compression Workflows at Experimental Facilities” from September 8 to 11, 2020. The workshop included 95 registered scientists and analytics experts from 15 universities, 9 United States (US) national laboratories, 5 US and European X-ray light sources, neutron sources such as the Los Alamos Neutron Science Center (LANSCE), other big science facilities such as the National Ignition Facility (NIF), and an industry representative. The workshop included 31 invited talks and 4 lightning talks by students and postdocs.

36 MATERIALS SCIENCE↗