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At least 1,423 records · Page 79

Multiphysics Simulation of the Thermal Response of a Nanofibrous Target in a High-Intensity Beam

Nanofibrous structures are of high interest to the fields of engineering and materials science, and investigation of their properties as well as discovery of novel applications for them both constitute lively areas of research. A very promising application of nanofiber mats lies in the field of accelerator technology: beam targets made from nanofiber mats offer a solution to the problem of advancing the "intensity frontier"–-the limit on the beam intensities that can be realized in fixed target experiments and neutrino production facilities. However, testing has shown that the survivability of these nanofiber targets depends strongly on their manufacturing parameters, such as the packing density of fibers. In this work, we will use multiphysics simulations to perform a thermal study on how nanofiber targets react to high intensity beams, so that the dependency of the targets’ lifetime on their construction parameters can be better understood.

43 PARTICLE ACCELERATORS↗

DOE SBIR 2014 Topic 2.C – Phase I Final Report

Freshwater is a vital resource for human survival as well as a key component of a wide range of industrial and agricultural needs. However, only 0.65% of the world’s water resources are available as freshwater, and the demand on the world’s water reserves continues to increase, with the demand beginning to outpace the supply in many areas. A water-energy nexus is being reached that requires low –cost and –energy solutions for various degrees of treated water. In a 2012 survey, 88% of Americans were concerned about potential water shortages and approximately two-thirds of the world’s population will be suffering a water shortage over the next few years. Seawater and other saline water materials make up around 98% of the available water, representing an almost unlimited supply of water. The energy, cost and maintenance to remove salts and other unwanted compounds is a barrier to widespread implementation of salt-to-freshwater facilities. These facilities most commonly use reverse osmosis (RO) systems. Due to the high required pressures and moving parts these facilities consume much grid energy and require constant maintenance leading to high capital and operational costs. RO also generates highly concentrated brine that is costly to safely return to the ocean. Capacitive desalination (or capacitive deionization [CDI]) has no moving parts (aside from a low pressure pump and valves), operates at low pressure and does not generate brine that is hazardous to marine life. Not only can the capacitive charge/discharge be cycled almost indefinitely but the system uses low energy and capacitive discharge electrical current can be co-generated back to the system. However, CDI has not seen widespread use for large- or small- scale desalination because electrode efficiency limits the extraction rate below what is useful for most applications. Mainstream Engineering Corporation (MEC) has demonstrated an innovative new electrode structure for the high efficiency desalination of brackish water by capacitive deionization. Electrode manufacturing (nanomanufacturing) is a highly scalable and low-cost electrochemical self-assembly method using a templated process that Mainstream has pioneered and leveraged for several energy technologies over the last decade. The primary accomplishment for Phase I is the fabrication and demonstration of CDI electrode structures are: • Demonstrating the linear scalability of templated approach to the fabrication scaling the electrode structure. • Demonstrated the ability to tune the fabrication of the electrode structures to produce electrodes with a highly controllable aligned nanopore diameter and nanopore depth. • Demonstrated the efficient removal of a sodium chloride salt from brackish water with a 60 times improvement in mg-salt removed/g-carbon compared to a commercial system under the same conditions. • Demonstrated good reproducibility and stability of the electrode structure under realistic CDI operating conditions. • Demonstrated charge efficiency as high as 93% with an expected system level energy requirement of 0.7 to 1.5 kWh/m3 of water; significantly lower than the 2.9 to 3.7 kWh/m3 observed for RO systems Based on the performance characteristics of the electrodes, Mainstream was able to propose a modular and scalable capacitive deionization design that can be adapted to a wide range of conditions providing energy efficient desalination of brackish water.

36 MATERIALS SCIENCE↗

RILEM TC ISR Summer 2015 Activity Report

With aging infrastructures, instances of Alkali Silica Reaction (ASR) and Delayed Ettringite Formation (DEF), broadly covered under the term Internal Swelling Reaction (ISR), are increasingly being detected. They have been observed in bridges, dams, and most recently in nuclear power plants. Concrete swelling may result in bridge partial failure, dams with structural cracks and misaligned turbine shafts, and locked slice gates. For nuclear reactors micro-cracks may cause increased gas permeability which will jeopardize the containment integrity and may decrease the residual structural resistance under accidental loading. This TC, which limits its activity to structures with known expansive concrete, seeks to address two complementary but fundamental questions: a) What is the kinetics of the reaction and b) How would it affect the integrity of the structure (serviceability and strength) and thus establish a science based prognostic to the structure owner.

42 ENGINEERING↗

In-Situ Printing of Conductive Polylactic Acid (cPLA) Strain Sensors Embedded into Additively Manufactured Parts using Fused Deposition Modeling

Additive Manufacturing (AM) technology has been around for decades, but until recently, machines have been expensive, relatively large, and not available to most institutions. Increased technological advances in 3D printing and awareness throughout industry, universities, and even hobbyists has increased demand to substitute AM parts in place of traditionally manufactured (subtractive) designs; however, there is a large variability of part quality and mechanical behavior due to the inherent printing process, which must be understood before AM parts are used for load bearing and structural design.

42 ENGINEERING↗

WEC Farm Functions: Defining the Behaviors of the Farm

Capabilities and functions are hierarchical structures (i.e. taxonomies) that are used in a systems engineering framework to identify complimentary requirements for the system: what the system must do to achieve what it must be. In the case of capabilities, the taxonomy embodies the list of characteristics that are desired, from the perspective of the stakeholders, for the system to be successful. In terms of the functions, the hierarchy represents the solution agnostic (i.e. independent of specific design embodiments) elements that are needed to meet the stakeholder requirements. This paper will focus on the development of the functions. The functions define the fundamental elements of the solution that must be provided in order to achieve the mission and deliver the capabilities. They identify the behaviors the farm must possess, i.e. the farm must be able to generate and deliver electricity from wave power. High-level functions are independent of the technology or design used to implement the function. However, detailed functions may begin to border on specific design choices. Hence a strong effort has been made to maintain functions that are design agnostic.

13 HYDRO ENERGY↗

CarbonSAFE Phase I: Integrated CCS Pre-Feasibility – Northwest Gulf of Mexico (Final Research Performance Progress Report)

Offshore storage achieves two major objectives for the US commercial large scale CCS deployment: 1. Adding large capacity to serve local regional, and potentially broader objectives 2. Lowering risk by providing storage with one public owner, away from population, with no conflict with water resources and reduced concern about induced seismicity. A high-concentration CO 2 source was identified as the top candidate for the project and going forward with the CarbonSAFE Phase II proposal. The top-rated source is the NET Power facility in Houston (La Porte), Texas. A manuscript based on analysis of results from the two-stage survey conducted in eight selected Texas counties was submitted to the International Journal of Greenhouse Gas Control on August 21, 2018. A primary confining interval (seal) is associated with MFS9 (biochronozone Amphistegina B) which can reach a thickness of up to 250 m. However, the Amphistegina B confining interval thins considerably in the onshore direction. Consequently, the most suitable portion of the Miocene section for future CO 2 sequestration in the study area is considered to be the offshore area where Amphistegina B is thickest. Based on three models for capacity assessment, the study proposes a base case for the High Island 10-L Field in which 9 wells operated for 12 years each completed into 4 zones will emplace a total of 150MMT of CO 2 with wells placed in the water leg where all the plume will slowly migrate into the structural trap is feasible in terms of geology and engineering. The 10-L Field was assessed in more detail than other examined oil and gas fields in the study area in order to look at some specifics about how initial future CCS projects might be accomplished in the favorable GoM of the US region and expand the sites to a larger set to experiment with matching all the possible sources to sinks. The 10-L site is large enough to accept CO 2 from multiple sinks; the expanded sinks are estimated to be large enough to accept all the CO 2 from the region plus some from outside the region. A number of uncertainties were identified. The largest and most consequential uncertainty is the cost of offshore pipelines in the study setting, which impacts the conditions where CO 2 transport would be by ship versus the cases where pipeline would be preferred. Ships are preferred for small volumes and short durations; pipelines for larger volumes and long duration. Additional work is needed to advance the maturity of multiple sinks available, to continue outreach to industries and the public, and to develop realistic source opportunities. The study demonstrates that industrial source clusters connected to a transport hub delivering CO 2 to a nearby storage complex is the most cost-effective and improved way to de-carbonize industrial activities, particularly, in an expected low-carbon and increasing carbon price environmental. The feasibility of the new business models should be based on the best use of the existing infrastructure and strategically build on new supporting infrastructure to drive down the costs of large-scale CCS deployment. Assessing the pre-feasibility of the commercial implementation of a CCS cluster and hub in the GoM energy ecosystem, our study links these elements successfully through an optimized combination (minimum cost) of CO 2 sources on land with offshore storage. Offshore storage achieves two major objectives for the US commercial large scale CCS deployment: 1. Adding large capacity to serve local regional, and potentially broader objectives 2. Lowering risk by providing storage with one public owner, away from population, with no conflict with water resources and reduced concern about induced seismicity.

54 ENVIRONMENTAL SCIENCES↗

Extending PETSc's Composable Hierarchical Solvers (Final Technical Report)

This report documents research activities conducted at CU Boulder as part of Extending PETSc’s Composable Hierarchical Solvers, which has been part of a collaboration with Argonne National Laboratory (separate award). Our work has focused on performance-portable end-to-end GPU solvers demonstrated via exemplary applications in nonlinear fluid and structural mechanics. We describe advances in algorithmic composition and analysis in the context of these applications, but the implementations are fully documented and decoupled, and in use by other projects. We believe the vertical integration achieved through collaboration with ECP’s CEED and the PSAAP center at CU was necessary to take risks with data structures and algorithms.

42 ENGINEERING↗

Precursor Analysis Report: SQL Slammer Worm Infection of Davis-Besse Nuclear Power Plant 2003

The SQL Slammer Worm Infection of Davis-Besse Nuclear Power Plant 2003 Precursor Analysis Report leverages publicly available information about Davis-Besse’s 2003 cyber attack and catalogs anomalous observables for each technique employed in the attack. This analysis is based upon the methodology of the Cybersecurity for the Operational Technology Environment (CyOTE) program. On 25 January 2003, the SQL Slammer worm infected more than 90% of vulnerable hosts and crashed the internet in 10 to 15 minutes, making it one of the fastest spreading worms in history. SQL Slammer is a fileless, memory-resident worm that remotely exploits a stack-based buffer overflow vulnerability on local hosts to intensively scan and rapidly self-propagate across the internet. The worm infected approximately 300,000 unpatched hosts running Microsoft Structured Query Language (SQL) Server 2000 or Microsoft Desktop Engine (MSDE) 2000 with SQL Server Resolution Service. The SQL Slammer worm indirectly infected FirstEnergy’s Davis-Besse nuclear power plant by first infecting a consultant’s company network server and then propagating through an external misconfigured connection into Davis-Besse’s site network. The infection caused major network congestion, slow performance, data overloads, and the inability of local hosts to communicate with each other, which eventually caused a loss of availability and a loss of view when the Safety Parameter Display System (SPDS) and Plant Process Computer (PPC) crashed. At the time of the infection, the plant was already offline, the digital monitoring systems had redundant analog backups, and the plant control and safety functions were not affected, so there were no concerns of a safety breach. However, this incident resulted in many lessons learned and spawned important discussions about cybersecurity’s role in nuclear safety and electric power reliability regulation, policy, and guidance. Researchers and analysts identified 10 unique techniques utilized during the attack with a total of 640 observables using MITRE ATT&CK® for Industrial Control Systems. The CyOTE program assesses observables accompanying techniques used prior to the triggering event to identify opportunities to detect malicious activity. If observables accompanying the attack techniques are perceived and investigated prior to the triggering event, earlier comprehension of malicious activity can take place. Eight of the identified techniques used during Davis-Besse cyber attack were precursors to the triggering event. Analysis identified 596 observables associated with these precursor techniques, 428 of which were assessed to have an increased likelihood of being perceived in the 331 days preceding the triggering event. The response and comprehension time could have been reduced if the observables had been identified earlier. The information gathered in this report contributes to a library of observables tied to a repository of artifacts, data sources, and technique detection references for practitioners and developers to support the comprehension of indicators of attack. Asset owners and operators can use these products if they experience similar observables or to prepare for comparable scenarios.

45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL DEF↗

Advances in Atomic Layer Deposition (ALD) Nanolaminate Synthesis of Thermoelectric Films in Porous Templates for Improved Seebeck Coefficient

Thermoelectrics is a green renewable energy technology which can significantly contribute to power generation due to its potential in generating electricity out of waste heat. The main challenge for the development of thermoelectrics is its low conversion efficiency. One key strategy to improve conversion efficiency is reducing the thermal conductivity of thermoelectric materials. In this paper, the state-of-the-art progresses made in improving thermoelectric materials are reviewed and discussed, focusing on phononic engineering via applying porous templates and ALD deposited nanolaminates structure. The effect of nanolaminates structure and porous templates on Seebeck coefficient, electrical conductivity and thermal conductivity, and hence in figure of merit zT of different types of materials system, including PnCs, lead chalcogenide-based nanostructured films on planar and porous templates, ZnO-based superlattice, and hybrid organic-inorganic superlattices, will be reviewed and discussed.

36 MATERIALS SCIENCE↗

Observational Signatures of Planets in Protoplanetary Disks: Temperature Structures in Spiral Arms

High-resolution imaging of protoplanetary disks has unveiled a rich diversity of spiral structure, some of which may arise from disk-planet interaction. Using 3D hydrodynamics with β cooling to a vertically stratified background, as well as radiative-transfer modeling, we investigate the temperature rise in planet-driven spirals. In rapidly cooling disks, the temperature rise is dominated by a contribution from stellar irradiation, 0.3%–3% inside the planet radius but always < 0.5% outside. When cooling time equals or exceeds dynamical time, however, this is overwhelmed by hydrodynamic PdV work, which introduces a ~10%–20% perturbation within a factor of ~2 from the planet’s orbital radius. We devise an empirical fit of the spiral amplitude Δ(T)=(M{sub p}/M{sub th}){sup c}(f{sub PdV}e{sup -t{sub a}{sub r}{sub m}/t{sub c}}+f{sub rad}) to take into account both effects. Where cooling is slow, we find also that temperature perturbations from buoyancy spirals—a strictly 3D, nonisothermal phenomenon—become nearly as strong as those from Lindblad spirals, which are amenable to 2D and isothermal studies. Our findings may help explain observed thermal features in disks like TW Hydrae and CQ Tauri, and underscore that 3D effects have a qualitatively important effect on disk structure.

42 ENGINEERING↗

Electro-dynamic machine, system and method

One embodiment is a unique Vernier machine comprising a rotor and a stator. The rotor comprises a back portion and a plurality of permanent magnets. The stator comprises a plurality of ferromagnetic arm structures, a plurality of ferromagnetic pole structures extending from each of the ferromagnetic arm structures in a direction toward the permanent magnets, and a plurality of conductive windings disposed about respective ones of the plurality of ferromagnetic arm structures. The ferromagnetic pole structures are structured to collect magnetic flux from the permanent magnets. The ferromagnetic pole structures of each of said ferromagnetic arm structures are spaced apart from one another according to a non-uniform pattern such that the ferromagnetic pole structures of a given ferromagnetic arm structure have substantially the same angular position relative to the permanent magnets radially opposite from the ferromagnetic pole structures of the given ferromagnetic arm structure.

42 ENGINEERING↗

Facile clay exfoliation using polymer silicone surfactants

The present invention is directed to processes for preparing a silicone surfactant intercalated clay and a polymer-clay nanocomposite. The processes use silicone surfactants having a molecular weight in the range of 10,000 to 100,000 Dalton to achieve fully exfoliating clay structures. Using these macromolecular silicone surfactants, along with the engineered control of the processing pH and drying stress conditions, this invention provides simple and low-cost methods of making a fully-exfoliated polymer-clay nanocomposite.

Yang, Arthur Jin-Ming↗

Flexible linkages for thermal management at cryogenic temperatures

Cryogenic system design often presents the competing requirements of thermal coupling between components while de-coupling them structurally. Good thermal coupling is necessary for adequate thermal management during cryogenic operation of the system and to reduce the cooldown time from the ambient to cryogenic temperature. Structural de-coupling is essential to reduce thermal stresses during cooldown, mitigate the trasmission of vibration and loads to sensitive and/or fragile components, and compensate for integration misalignments. Flexible thermal links (FTLs) are an essential component of cryogenic systems that provides a balance between thermal coupling and structural isolation.

42 ENGINEERING↗

Biofuels as Heavy Fuel Oil Substitutes in the Maritime Sector: Findings and Potential Pathways

The United States Department of Energy has commissioned four national laboratories to evaluate the feasibility of biofuels in the maritime sector. This effort is briefly described including the overall project goals, structure and aims. The large two-stroke crosshead engines used to power large merchant vessels were of particular interest since they can burn lower combustion quality fuels relative to four-stroke engines. This characteristic allows for consideration of pyrolysis oils and hydrothermal liquefaction (HTL) oils which are feedstock agnostic and, in the raw state, are more economical compared to distillate drop-in fuels. Pyrolysis and HTL oils are collectively known as bio-intermediates since they require additional processing for use in distillate fuel systems. The key limiting feature is that these bio-intermediate fuels will cause asphaltene precipitation when blended with heavy fuel oils (HFOs) such as very low sulfur fuel oil (VLSFO) unless they are upgraded to remove water and oxygenates. Economics are the key driver at this point in time, and preliminary techno-economic analyses (TEAs) indicate that bio-intermediates have potentially lower cost relative to other biofuels such as biodiesel and renewable diesel. Additionally, life cycle analyses (LCAs) of feedstocks and pathways show the life cycle carbon reduction benefit relative to heavy fuel oils. In addition to TEA and LCA results, we also present on the technical feasibility of these fuels. These studies have focused on the properties of biofuel blends with VLSFO that are critical to the fuel systems of maritime vessels fueled with HFOs. These properties include the compatibility with fuel system metals, viscosity, and blend stability. Aging studies with blends of VLSFO with biodiesel, HTL, and pyrolysis oils are also presented. Future efforts being planned to conduct additional biofuel testing, including the use of biofuels as pilot fuels in zero carbon shipping options fueled with ammonia and methanol, ship-based demonstrations, and bioresource competition studies.

Kass, Michael↗

Void swelling of conventional and composition engineered HT9 alloys after high-dose self-ion irradiation

Ferritic/martensitic (F/M) steels are being considered as potential structural materials for next generation nuclear reactors, and variants of the alloy HT9 are some of the most promising candidates. In this study, two conventional and two composition engineered HT9 alloys were irradiated using 3.5 MeV Fe 2+ up to 600 peak displacement-per-atom (dpa) at 450 °C. Void swelling and microstructure evolution were characterized for each alloy and compared. The two conventional HT9 alloys (INL and ACO3) showed similar void swelling behavior due to their similar elemental composition and processing conditions. The INL HT9 exhibited a maximum of 2.4% swelling and the ACO3 HT9 showed a maximum of 2.8% swelling at 342 and 393 average local dpa, respectively. On the other hand, the two-composition engineered HT9 alloys with varying N contents (10 ppm for low N and 440 ppm for high N) showed disparate swelling behavior. The low N HT9 exhibited a maximum of 4.6% swelling, while the high N HT9 showed a maximum of 0.7% swelling at 342 average local dpa. Changes in the N content also affected Ni/Si rich G-phase formation. The low N HT9 showed a larger size and lower density of G-phase precipitates compared with the high N HT9 after 600 peak dpa irradiation. This study compares the void swelling behavior of the ion irradiated four current HT9 alloys to extremely high doses, with the void swelling data from neutron irradiated HT9 alloys. Furthermore, the comparison lends critical insights into how well these current alloys can withstand high neutron fluxes in future reactors, especially since the low N and high N HT9 alloys have never been exposed to such high doses before.

36 MATERIALS SCIENCE↗

Nanoscale strain wave generation by a piezoelectric grating from polar vortices

Nanostructures formed by spontaneously broken symmetry have provided new ways to manipulate quantum states. Specifically, topological structures with periodic spatial ordering, such as polar vortices and skyrmions, can be ideal hosts for creating engineered responses in both spatial and frequency domains. So far, however, only a few examples of such hierarchical engineering have been reported in the literature. Here we demonstrate that the spatially modulated piezoelectric response of a polar vortex structure can create strain waves with a characteristic nanoscale wavefront. Using time-resolved pump–probe resonant X-ray scattering and diffraction measurements, coupled with dynamical phase-field simulations, we show that the piezoelectric modulation of the spontaneously formed polar vortex crystal functions as an acoustic diffraction grating. This system converts incoming laterally uniform strain waves into outgoing waves with a characteristic sub-terahertz frequency, driven by an intrinsic excitation of the polar vortex crystal. Moreover, our phase-field simulations suggest that the dynamic mechanical displacements exhibiting vortex textures are generated from both space- and time-varying piezoelectric responses. Our findings illustrate a new method for generating nanoscale strain waves with unique spatial textures by tuning the hierarchical order of polar topologies to engineer new collective modes, allowing for a wide range of control through the topological lattice.

ferroelectrics↗

Understanding low temperature oxidation activity of nanoarray-based monolithic catalysts: from performance observation to structural and chemical insights

Monolithic catalysts have been widely used in automotive, chemical, and energy relevant industries. Nano-array based monolithic catalysts have been developed, demonstrating high catalyst utilization efficiency and good thermal/mechanical robustness. Compared with the conventional wash-coat based monolithic catalysts, they have shown advances in precise and optimum microstructure control and feasibility in correlating materials structure with properties. Recently, the nano-array based monolithic catalysts have been studied for low temperature oxidation of automotive engine exhaust and exhibited interesting and promising catalytic activities. Here, this review focuses on discussing the key catalyst structural parameters that affect the catalytic performance from the following aspects, (1) geometric shape and crystal planes, (2) guest atom doping and defects, (3) array size and size-assisted active species loading, and (4) the synergy effect of metal oxide in composite nano-arrays. Prior to the discussion, an overview of the current status of synthesis and development of the nano-array based monolithic catalysts is introduced. The performance of these materials in low temperature simulated engine exhaust oxidation is also demonstrated. Finally, we hope this review will elucidate the science and chemistry behind the good oxidation performance of the nanoarray- based monolithic catalysts, and serve as a timely and useful research guide for rational design and further improvement of the nano-array based monolithic catalysts for automobile emission control.

36 MATERIALS SCIENCE↗

Investigation of 3D printed lightweight hybrid composites via theoretical modeling and machine learning

Hybrid composites combine two or more different fillers to achieve multifunctional or advanced material properties, such as lightweight and enhanced mechanical properties. The properties of the composites significantly depend on their microstructures, which can be tailored via advanced 3D printing processes. Understanding the process-structure-property relationships is critical to enable the design and engineering of novel hybrid composites for applications in aerospace, automotive, and protective coatings. Here, for this work, we develop 3D printable and lightweight hybrid composites and leverage the conventional design of experiments, a theoretical hybrid model, and an image-driven machine learning (ML) method to investigate their mechanical behaviors. The hybrid composites are formulated with elastomer matrix, microfillers, and thin-shell particles, enabling a significant degree of design freedom of microstructures with densities and mechanical properties varying up to 70% and 91%, respectively. Our statistical analysis indicates that the 3D printing path direction and the microfibers fraction are dominating process parameters with contribution percentages of 45.3% and 57.7% on the specific stiffness and strength, respectively. A hybrid mechanics model is developed based on a simple Weibull distribution function and classical single-filler models to effectively capture the variations in mechanical properties, however, it overestimates the values due to its statistical constraints and idealization of experimental uncertainty. The image-driven ML model leverages the microscale images directly without losing the structural details, shows more accurate predictions with experimental data, and has 48.6% lower root mean square error than the theoretical model.

3D printing↗