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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,423 records · Page 79
All sourcesNASA NTRSDOE OSTI
DOE OSTI2016

Confronting the “Indian summer monsoon response to black carbon aerosol” with the uncertainty in its radiative forcing and beyond

While black carbon aerosols (BC) are believed to modulate the Indian monsoons, the radiative forcing estimate of BC suffers from large uncertainties globally. In this paper, we analyze a suite of idealized experiments forced with a range of BC concentrations that span a large swath of the latest estimates of its global radiative forcing. Within those bounds of uncertainty, summer precipitation over the Indian region increases nearly linearly with the increase in BC burden. The linearity holds even as the BC concentration is increased to levels resembling those hypothesized in nuclear winter scenarios, despite large surface cooling over India and adjoining regions. The enhanced monsoonal circulation is associated with a linear increase in the large-scale meridional tropospheric temperature gradient. The precipitable water over the region also increases linearly with an increase in BC burden, due to increased moisture transport from the Arabian sea to the land areas. The wide range of Indian monsoon response elicited in these experiments emphasizes the need to reduce the uncertainty in BC estimates to accurately quantify their role in modulating the Indian monsoons. Finally, the increase in monsoonal circulation in response to large BC concentrations contrasts earlier findings that the Indian summer monsoon may break down following a nuclear war.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2019

Flexible Thermoelectric Devices of Ultrahigh Power Factor by Scalable Printing and Interface Engineering

Printing is a versatile method to transform semiconducting nanoparticle inks into functional and flexible devices. In particular, thermoelectric nanoparticles are attractive building blocks to fabricate flexible devices for energy harvesting and cooling applications. However, the performance of printed devices are plagued by poor interfacial connections between nanoparticles and resulting low carrier mobility. While many rigid bulk materials have shown a thermoelectric figure of merit ZT greater than unity, it is an exacting challenge to develop flexible materials with ZT near unity. Here, a scalable screen-printing method to fabricate high-performance and flexible thermoelectric devices is reported. A tellurium-based nanosolder approach is employed to bridge the interfaces between the BiSbTe particles during the postprinting sintering process. The printed BiSbTe flexible films demonstrate an ultrahigh room-temperature power factor of 3 mW m -1 K -2 and ZT about 1, significantly higher than the best reported values for flexible films. A fully printed thermoelectric generator produces a high power density of 18.8 mW cm -2 achievable with a small temperature gradient of 80 °C. This screen-printing method, which directly transforms thermoelectric nanoparticles into high-performance and flexible devices, presents a significant leap to make thermoelectrics a commercially viable technology for a broad range of energy harvesting and cooling applications.

36 MATERIALS SCIENCE↗
DOE OSTI2018

Laser Rewritable Dichroics through Reconfigurable Organic Charge-Transfer Liquid Crystals

Charge-transfer materials based on the self-assembly of aromatic donor–acceptor complexes enable a modular organic-synthetic approach to develop and fine-tune electronic and optical properties, and thus these material systems stand to impact a wide range of technologies. Through laser-induction of temperature gradients, in this paper, user-defined patterning of strongly dichroic and piezoelectric organic thin films composed of donor–acceptor columnar liquid crystals is shown. Finally, fine, reversible control over isotropic versus anisotropic regions in thin films is demonstrated, enabling noncontact writing/rewriting of micropolarizers, bar codes, and charge-transfer based devices.

36 MATERIALS SCIENCE↗
DOE OSTI2025

In-device Battery Failure Analysis

Lithium-ion batteries are indispensable power sources for a wide range of modern electronic devices. However, battery lifespan remains a critical limitation, directly affecting the sustainability and user experience. Conventional battery failure analysis in controlled lab settings may not capture the complex interactions and environmental factors encountered in real-world, in-device operating conditions. Here, this study analyzes the failure of commercial wireless earbud batteries as a model system within their intended usage context. Through multiscale and multimodal characterizations, the degradations from the material level to the device level are correlated, elucidating a failure pattern that is closely tied to the specific device configuration and operating conditions. The findings indicate that the ultimate failure mode is determined by the interplay of battery materials, cell structural design, and the in-device microenvironment, such as temperature gradients and their fluctuations. This holistic, in-device perspective on environmental influences provides critical insights for battery integration design, enhancing the reliability of modern electronics.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Stable Metallic Enrichment in Conductive Filaments in TaO x –Based Resistive Switches Arising from Competing Diffusive Fluxes

Oxide–based resistive–switching devices hold promise for solid–state memory technology. Information encoding is accomplished by electrically switching the device between two nonvolatile states with low and high resistance states (LRS/HRS). It is generally accepted that the change between these states is due to the motion of oxygen vacancies forming a continuous (LRS) or gapped (HRS) filament between the electrodes. Direct assessments of filaments are rare due to their small size and the difficulty of locating the filament. Electron microscopy experiments reveal the filament structure and chemistry in TaO 2.0 ± 0.2 –based 150 × 150 nm 2 devices with cross–sectional geometry after forming with power dissipation lower than 1 mW. The filaments appear to be roughly hourglass–shaped with a diameter of less than 10 nm and are composed of Ta–rich and O–poor mostly amorphous material with local compositions as Ta–rich as TaO 0.4 . The as–formed HRS has a gap up to 10 nm wide located next to the anode and composed of nearly stoichiometric TaO 2.5 . The tantalum and oxygen distribution is consistent with filaments formed by the motion of both Ta and O driven by temperature gradients (Soret effect) and an electric field. As a result, this interpretation points towards a new compact model of resistive–switching devices.

36 MATERIALS SCIENCE↗
DOE OSTI2020

Progress with the 5D full-F continuum gyrokinetic code COGENT

COGENT is an Eulerian gyrokinetic code being developed for edge plasma modelling. The code is distinguished by the use of a high-order finite-volume (conservative) discretization combined with mapped multi-block grid technology. Our recent work is focused on the development of a 5D full-F COGENT version.Anumerical algorithm utilizing locally a field-aligned multi-block coordinate system is implemented to facilitate simulations of highly anisotropic microturbulence in the presence of a strong magnetic shear. In this approach, the toroidal direction is divided into blocks such that,within each block, the cells are field-aligned and a non-matching (non-conformal) grid interface is allowed at the block boundaries. In this paper we report on details of the numerical implementation and present preliminary results of verification studies performed for the case of the ion temperature gradient (ITG) instability in a sheared toroidal annulus geometry.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2022

Modelling of electrostatic ion-scale turbulence in divertor tokamaks with the gyrokinetic code $\mathrm{COGENT}$

Here, continuum gyrokinetic simulations of electrostatic ion scale turbulence are presented for the case of a diverted (single-null) tokamak geometry. The simulation model, implemented in the finite-volume code COGENT, solves the long-wavelength limit of the full-F gyrokinetic equation for ion species coupled to a vorticity equation for electrostatic potential variations, where a fluid model is used for an electron response. The model describes the ion scale ion temperature gradient (ITG) and resistive drift modes as well as neoclassical ion physics effects. Different turbulence regimes are observed depending on the plasma profiles, and the roles of a self-consistent background electric field and an X-point geometry are explored. In particular, increasing the pedestal density gradient and the corresponding radial electric field is demonstrated to suppress the ITG turbulence, whereas the same edge plasma background can still be destabilized by the resistive modes when the plasma resistivity is increased. The effects of X-point geometry are assessed by comparing cross-separatrix simulations with counterpart calculations performed for a toroidal annulus geometry. For the simulation parameters considered, similar global behaviour is observed in both cases, whereas strong local suppression of turbulence fluctuations is demonstrated near the X-point for the case of a single-null geometry.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2023

A convection-permitting dynamically downscaled dataset over the Midwestern United States

Climate change is expected to have far-reaching effects at both the global and regional scale, but local effects are difficult to determine from coarse-resolution climate studies. Dynamical downscaling can provide insight into future climate projections on local scales. Here, we present a new dynamically downscaled dataset for Indiana and the surrounding regions. Output from the Community Earth System Model (CESM) version 1 is downscaled using the Weather Research and Forecasting model (WRF). Simulations are run with a 24-hr reinitialization strategy and a 12-hr spin-up window. WRF output is bias corrected to the National Centers for Environmental Protection/National Center for Atmospheric Research 40-year Reanalysis project (NCEP) using a modified quantile mapping method. Bias-corrected 2-m air temperature and accumulated precipitation are the initial focus, with additional variables planned for future releases. Regional climate change signals agree well with larger global studies, and local fine-scaled features are visible in the resulting dataset, such as urban heat islands, frontal passages, and orographic temperature gradients. This high-resolution climate dataset could be used for down-stream applications focused on impacts across the domain, such as urban planning, energy usage, water resources, agriculture and public health.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Evaluation of energy balance closure adjustment methods by independent evapotranspiration estimates from lysimeters and hydrological simulations

Here, we report non-closure of the surface energy balance is a frequently observed phenomenon of hydrometeorological field measurements, when using the eddy-covariance method, which can be ascribed to an underestimation of the turbulent fluxes. Several approaches have been proposed in order to adjust the measured fluxes for this apparent systematic error. However, there are uncertainties about partitioning of the energy balance residual between the sensible and latent heat flux and whether such a correction should be applied on 30-minute data or longer time scales. The data for this study originate from two grassland sites in southern Germany, where measurements from weighable lysimeters are available as reference. The adjusted evapotranspiration rates are also compared with joint energy and water balance simulations using a physically-based distributed hydrological model. We evaluate two adjustment methods: the first one preserves the Bowen ratio and the correction factor is determined on a daily basis. The second one attributes a smaller portion of the residual energy to the latent heat flux than to the sensible heat flux for closing the energy balance for every 30-minute flux integration interval. Both methods lead to an improved agreement of the eddy-covariance based fluxes with the independent lysimeter estimates and the physically-based model simulations. The first method results in a better comparability of evapotranspiration rates, and the second method leads to a smaller overall bias. These results are similar between both sites despite considerable differences in terrain complexity and grassland management. Moreover, we found that a daily adjustment factor leads to less scatter than a complete partitioning of the residual for every half-hour time interval. Lastly, the vertical temperature gradient in the surface layer and friction velocity were identified as important predictors for a potential future parameterization of the energy balance residual.

58 GEOSCIENCES↗
DOE OSTI2015

Modeling the effects of dust-radiative forcing on the movement of Hurricane Helene (2006)

This study is the first to relate Saharan dust and tropical cyclone (TC) movement over the eastern and central Atlantic Ocean (ECAO) using observations and modeling. An eastward position forecast bias for TCs over ECAO has been noticed and is potentially related to the neglect of dust-radiative forcing in numerical models. Using 11-year observations we found that aerosol optical depth and TC westward speed over ECAO are correlated (0.62) with a confidence level of 99%. The Weather Research and Forecasting dust model was used to quantitatively study the impact of the dust-radiative forcing on Helene’s (2006) track forecasts with 3 different microphysics schemes. The dust-radiative forcing increases the temperature in the warm Saharan Air Layer, thus increases the temperature gradient and modifies wind speed and/or direction along the southern flank of the dust plume, improving Helene’s track. Including dust-radiative forcing reduces the error in 7-day position forecasts by 27% (~205km).

58 GEOSCIENCES↗
DOE OSTI2019

Understanding the vertical structure of potential vorticity in tropical depressions

Here, potential vorticity (PV) has been used to understand the intensification and motion of a variety of tropical vortices. In this work, atmospheric reanalyses and idealized models are used to understand how the vertical structures of moist convective heating and adiabatic advection jointly shape the vertical structures of PV in tropical depressions. Observationally based estimates reveal a top-heavy PV structure in tropical depressions, contrasting with bottom-heavy structures of absolute vorticity and diabatic PV generation. These distinct vertical structures are reproduced in an axisymmetric model which employs the weak temperature gradient approximation for conceptual simplicity and is forced by stratiform and deep convective heating. When provided in isolation, the stratiform and deep convective heatings produce PV maxima at 500 hPa and near the surface, respectively. When these two heatings are applied simultaneously, interactions between the stratiform and deep convective modes enhance the adiabatic advective tendencies produced by the transverse circulation, making the PV distribution more top-heavy. In the lower and middle troposphere, radial advection also greatly reduces the radius of the PV structure relative to that of the imposed heating, consistent with structures in observed tropical depressions; the implications of these differences in radial structures for using the flux form of the relevant conservation equations (e.g. for PV substance or absolute vorticity) are discussed.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Future of Rice Crop Under Enriched CO2 Environment

Rice (Oryza sativa L.) is the second largest cereal crop produced globally, with a worldwide production of about 720 million metric tons in recent years and contributing toward for 20% of the global calorie intake. The growing condition of rice is extreme such as high vs. low temperature and high vs. low level of CO2 concentration [CO2]. Given CO2 is a key substrate for photosynthesis, the atmospheric concentration of CO2 dominantly influences the growth and yield of rice crop. The main component of rice is the kernel (~90%) which is starch, and the composition and behavior of starch are greatly impacted by environmental drivers including temperature, CO2, and water. Therefore, it is important to understand the variation in production and yield of rice under the elevated [CO2]. Here, we discussed the impacts of elevated [CO2] on the quality and quantity of rice production under current and future climatic conditions. We have discussed the response of rice crops under elevated [CO2] and its interaction with several other biophysical drivers including air temperature, ozone concentration, soil water content, and genotype in various experimental approaches, viz., free-air CO2 enrichment (FACE), open top chambers (OTC), growth chambers, and temperature gradient tunnels. Overall, elevated [CO2] stimulated photosynthesis and production of rice on a short-term, but the long-term effects of elevated [CO2] on the quality and quantity of rice production is yet to be resolved and need some attention with respect to various environmental constraints.

Dari, Biswanath↗
DOE OSTI2018

South Asian monsoon precipitation in CMIP5: a link between inter-model spread and the representations of tropical convection

CMIP5 models exhibit a mean dry bias and a large inter-model spread in simulating Indian monsoon precipitation but the origins of the bias and spread have not been well understood. Using moisture and energy budget analysis that exploits the weak temperature gradients in the tropics, we show that they are linked to the convection simulated over the equatorial Indian Ocean. About half of the 21 models analyzed operate at the steep gradient of the non-linear relationship between the normalized precipitable water and normalized precipitation, where small differences in the former are amplified as large differences in precipitation. These models preferentially produce higher precipitation over the equatorial Indian Ocean, and contribute disproportionately to the inter-model spread and multi-model mean dry bias in monsoon precipitation. Conversely, models on the flat side of the relationship are in better agreement with each other and with observations. Under the RCP8.5 forcing scenario, models on the steep part of the relationship project stronger response to warming and dominate the inter-model spread in the projection. This study identified the normalized precipitable water as a key metric for understanding the behavior of model simulated equatorial and Indian monsoon precipitation.

Hagos, Samson (ORCID:0000000175919933)↗
DOE OSTI2021

Anthropogenic influences on the African easterly jet–African easterly wave system

The African easterly jet (AEJ) and African easterly waves (AEWs) can have both local and far-reaching impacts on weather. It is therefore crucial to understand how the AEJ and AEWs will respond to future climate change. In this study, we examine anthropogenic influences on the AEJ–AEW system using the Weather Research and Forecasting (WRF) model configured as a tropical channel model (TCM). Hindcast simulations for the years 2001–2010 were performed using the WRF TCM, and ten additional years of simulations were performed using the pseudo-global warming method with the initial and boundary conditions of the model modified as if it were the late twenty-first century. A comparison of the simulations from the two climate scenarios indicates robust changes to both the AEJ and AEWs. For the AEJ, the jet is weaker and shifted northwards and upwards in the future climate, in association with an increase in precipitation over the Sahel and a strengthening of the meridional temperature gradient. For the AEWs, there is an increase in the number and strength of the waves in the future climate, in association with an increase in the baroclinic and barotropic energy conversions. Here, the barotropic energy conversion in particular has a larger contribution in the future climate, which manifests in the southern AEW track experiencing greater future strengthening than the northern track.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2018

Coupled Processes Modeling in Rock Salt and Crushed Salt Including Halite Solubility Constraints: Application to Disposal of Heat-Generating Nuclear Waste

This work presents numerical modeling of coupled thermal, hydraulic and mechanical processes in rock salt and crushed salt considering halite solubility constraints. The TOUGH-FLAC simulator is used, with a recently enhanced Equation-Of-State module that includes the thermodynamic properties of aqueous fluids of variable salinity. Laboratory and field scale tests performed on rock salt and crushed salt under temperature gradients are modeled first to evaluate the capabilities of the simulator to reproduce important features, such as porosity changes induced by halite dissolution/precipitation, and brine and heat migration. Since the results are quite satisfactory, the simulator is used to predict the long-term response of a generic salt repository for heat-generating nuclear waste. To evaluate the impacts of halite solubility on the predictions, two simulations that respectively consider or neglect solubility constraints are performed. In the scenario studied, the results are not significantly affected by dissolution/precipitation, and only some differences are observed due to changes in porosity, but the dominating processes remain the same. Finally, with the new provisions, TOUGH-FLAC is more complete in terms of processes occurring around a heat-releasing nuclear waste package and can therefore provide more accurate predictions of the long-term performance of a nuclear waste repository in salt formations.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗
DOE OSTI2019

Effect of Naturally Deposited Film on the Sub-rapid Solidification of Medium Manganese Steel by Using Droplet Solidification Technique

In this study, the effect of naturally deposited film on the interfacial heat transfer during the sub-rapid solidification of medium manganese steel was studied by means of a droplet solidification technique. The heat transfer rates were calculated by the Inverse Heat Conduction Program (IHCP), through computing the responding temperatures’ gradient inside the cooling mold. The results showed that the contact angle between the mold and solidified droplet becomes lower (from 117.539 to 82.217 deg) with the repeat of the dropping tests, which means the wettability improves after the deposition of the natural film. Meanwhile the liquid time (the time from the start of ejection to the initiation of solidification) decreases from 1.76 to 1.28 seconds during the tests, suggesting that the steel keeps in the liquid state shorter. Therefore, the initiation of solidification is advanced, such that there would be less time for matching the scale of the shell and the mold. Consequently, the maximum heat flux increases from 2.90 to 6.35 MW/m{sup 2} with the deposition of the natural film, as the wettability is getting better leading to the reduction of the interfacial thermal resistance. However, the final maximum heat flux was decreasing to 4.98 MW/m{sup 2} due to the increased thickness of the film and corresponding interfacial thermal resistance. Moreover, it was found that the secondary dendrite arm spacing decreased from 10.84 to 5.01 μm at first, and then it increased to 8.11 μm with the variations of heat flux and cooling rate.

36 MATERIALS SCIENCE↗
DOE OSTI2019

Experimental and Mathematical Simulation Study on the Granulation of a Modified Basic Oxygen Furnace Steel Slag

Basic oxygen furnace (BOF) steel slag is a major waste of the steelmaking industry. Utilization of BOF slag contributes to the sustainability of the steel industry by alleviating its environmental impact. Vitrification during cooling is an effective method to promote the cementitious activity of slags with the aim to apply slags in high value-added applications. In the present study, an Al{sub 2}O{sub 3}- and SiO{sub 2}-modified BOF slag was water granulated at a pilot scale. The amorphous and mineral fractions were measured quantitatively. The critical cooling rate to vitrify the modified slag was calculated through the Time-Temperature-Transformation diagrams constructed using in situ confocal scanning laser microscopy. To provide an insight into the crystallization behavior during the granulation process, a mathematical model was developed. The model was validated by comparing the amorphous fraction obtained from experiments with that from simulation. Temperature profiles of the slag particles with varied sizes were calculated with the aid of COMSOL Multiphysics software. The effect of particle size on the vitrified fraction was discussed in detail and the temperature gradient from surface to center of the particle was identified. The results provide novel fundamental understanding of the vitrification process regarding to the slag valorization, which will help the industrial implementation of granulation for pollution remediation and other engineered environmental systems such as chemical industry and pharmaceutical industry.

36 MATERIALS SCIENCE↗
DOE OSTI2024

The Influence of Residual Stress on Fatigue Crack Growth Rates in Stainless Steel Processed by Different Additive Manufacturing Methods

The properties and microstructure of Type 304L stainless steel produced by two additive manufacturing (AM) methods—directed energy deposition (DED) and powder bed fusion (PBF)—are evaluated and compared. Localized heating and steep temperature gradients of AM processes lead to significant residual stress and distinctive microstructures, which may be process-specific and influence mechanical behavior. Test data show that materials produced by DED and PDF have small differences in tensile strengths but clear differences in residual stress and microstructural features. Measured fatigue crack growth rates (FCGRs) for cracks propagating parallel to and perpendicular to the build directions differ between the two AM materials. To separate the influences of residual stress and microstructure, K-control test procedures with decreasing and constant stress intensity factor ranges are used to measure FCGRs in the near-threshold regime (crack growth rates ≤ 1 × 10 −8 m/cycle). Residual stress is quantified by the residual stress intensity factor, K res , measured by the online crack compliance method. Correcting the FCGR data for differences in K res brings results for specimens of the two AM materials into agreement with each other and with results for wrought specimens, when the latter are corrected for crack closure. Differences in microstructure and tensile strength have an insignificant influence on FCGRs in these tests.

additive manufacturing↗