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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,423 records · Page 79
All sourcesNASA NTRSDOE OSTI
NASA NTRS1976

Adsorption of oxygen on W/100/ - Adsorption kinetics and structure

The adsorption of oxygen on W(100) single-crystal surfaces is studied by Auger electron spectroscopy (AES), flash desorption, low-energy electron diffraction (LEED), and retarding-field work-function measurements. The AES results reveal stepwise changes in the sticking coefficients in the coverage range 0 to 1 and activated adsorption at higher coverages. Upon room-temperature adsorption, a series of complex LEED patterns is observed. In layers adsorbed at 1050 K and cooled to room temperature, the p(2 x 1) structure is the first ordered structure observed. This structure shows a reversible order-disorder transition between 700 and 1000 K and is characterized by a work function which is lower than that of the clean surface. Heating room-temperature adsorbates changes their structure irreversibly. At temperatures below 750 K, some new structures are observed.

Bauer, E.↗
DOE OSTI2017

Small influence of magnetic ordering on lattice dynamics in TaFe 1.25 Te 3

Raman scattering spectra of zigzag spin chain TaFe 1.25 Te 3 single crystal are presented in a temperature range from 80 to 300 K. Nine Raman active modes of A g and B g symmetry are clearly observed and assigned by probing different scattering channels, which is confirmed by lattice dynamics calculations. Temperature dependence of the Raman modes linewidth is mainly governed by the lattice anharmonicity. The only deviation from the conventional behavior is observed for A g symmetry modes in a vicinity of the magnetic phase transition at T N ≈ 200 K. This implies that the electron-phonon interaction weakly changes with temperature and magnetic ordering, whereas small changes in the spectra near the critical temperature can be ascribed to spin fluctuations.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
NASA NTRS2002

Characterization of Polar Mesospheric Clouds Using Infrared Measurements from HALOE

Measurements from the Halogen Occultation Experiment (HALOE) revealed the infrared signature of polar mesospheric clouds (PMCs), for the first time, HALOE PMC observations at eight wavelengths (2.45 - 10 microns) show remarkable agreement with model PMC spectra based on ice particle extinction, and thus provide the first confirmation that water ice is the primary component of PMCs. Because PMCs respond to changes in temperature and water vapor, they are considered an indicator of global climate change. We propose to further the understanding of PMCs using a decade of infrared measurements form HALOE. This effort will characterize PMC spectral properties, extinction profiles, and size distributions. Using this information, HALOE measurements will be used to make simultaneous retrievals of H2O3, and temperature, in the presence of PMCs. The simultaneous retrievals of particle properties, H2O3, and temperature will be used with HALOE NO data to provide a significant step forward in the knowledge of PMC characteristics and formation conditions. We will challenge fundamental theories of PMC formation, and investigate changes in PMC properties and related conditions over the length of the HALOE measurement record. HALOE has been operating without flaw since it was launched on October 11, 1991. Consequently, ten southern and ten northern PMC seasons have been observed thus far, providing a wealth of data for the study of PMC and related parameters.

Hervig, Mark E.↗
NASA NTRS2002

Characterization of Polar Mesospheric Clouds Using Infrared Measurements From HALOE

Measurements from the Halogen Occultation Experiment (HALOE) revealed the infrared signature of polar mesospheric clouds (PMCs), for the first time, HALOE PMC observations at eight wavelengths (2.45 - 10 microns) show remarkable agreement with model PMC spectra based on ice particle extinction, and thus provide the first confirmation that water ice is the primary component of PMCs. Because PMCs respond to changes in temperature and water vapor, they are considered an indicator of global climate change. We propose to further the understanding of PMCs using a decade of infrared measurements form HALOE. This effort will characterize PMC spectral properties, extinction profiles, and size distributions. Using this information, HALOE measurements will be used to make simultaneous retrievals of H2O, O3, and temperature, in the presence of PMCs. The simultaneous retrievals of particle properties, H2O, O3, and temperature will be used with HALOE NO data to provide a significant step forward in the knowledge of PMC characteristics and formation conditions. We will challenge fundamental theories of PMC formation, and investigate changes in PMC properties and related conditions over the length of the HALOE measurement record. HALOE has been operating without flaw since it was launched on October 11, 1991. Consequently, ten southern and ten northern PMC seasons have been observed thus far, providing a wealth of data for the study of PMCs and related parameters.

Hervig, Mark E.↗
DOE OSTI2024

Climate change-resilient snowpack estimation in the Western United States

Abstract In the 21st century, warmer temperatures and changing atmospheric circulation will likely produce unprecedented changes in Western United States snowfall 1–3 , with impacts on the timing, amount, and spatial patterns of snowpack 4–7 . The ~900 snow pillow stations are indispensable to water resource management by measuring snow-water equivalent (SWE) 8,9 in strategic but fixed locations 10,11 . However, this network may not be impacted by climate change in the same way as the surrounding area 12 and thus fail to accurately represent unmeasured locations; climate change thereby threatens our ability to measure the effects of climate change on snow. In this work, we show that maintaining the current peak SWE estimation skill is nonetheless possible. We find that explicitly including spatial correlations—either from gridded observations or learned by the model—improves skill at predicting distributed snowpack from sparse observations by 184%. Existing artificial intelligence methods can be useful tools to harness the many available sources of snowpack information to estimate snowpack in a nonstationary climate.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2017

Gas reservoir and a method to supply gas to plasma tubes

A reservoir for storing and supplying a portion of a reservoir gas into a gas-filled tube is presented. The reservoir includes a first vessel having a thermally conductive surface, a meshed vessel having a lid, and placed inside the first vessel to form a cavity between the meshed vessel and the first vessel, at least one tray placed inside the meshed vessel to divide an inner space of the meshed vessel into a plurality of compartments, a sorbent material placed inside the plurality of compartments in the meshed vessel, a temperature control device positioned such that a first portion of the temperature control device is in physical contact with at least a portion of the thermally conductive surface, and a change in the temperature of the temperature control device changes the temperature of the sorbent material, wherein the reservoir gas is retained by the sorbent material at the storage temperature.

36 MATERIALS SCIENCE↗
NASA NTRS1974

Solar wind model predictions for the sources of streams observed at 1 AU - Coronal enhancements or coronal holes

The present paper discusses attempts which have been made to locate the solar sources of the solar wind streams observed at or near 1 AU. Solar-wind data collected by the Mariner 2, Mariner 5, and IMP-1 spacecraft are considered. It is concluded that the type of solar feature considered as the source of solar-wind velocity enhancements depends upon the solar-wind model used. All single-fluid models predict the source to have a significantly higher temperature and lower density than the surrounding region, while the two-fluid model predicts a change in temperature that is much smaller than the predicted change in density.

Jones, D. E.↗
DOE OSTI2020

Wellbore injectivity response to step-rate CO 2 injection: Coupled thermo-poro-elastic analysis in a vertically heterogeneous formation

Safe and permanent carbon geological storages require an elaborate analysis of geomechanical stability. Subsurface injection of CO 2 changes the local temperature and pore pressure and, further, alters the stress due to thermo-poro-elastic responses. A permanent CO 2 storage testing was conducted in the water leg of Cranfield reservoir in Mississippi, USA, where hosted CO 2 enhanced-oil recovery activities. During CO 2 injection, the injection rate was ramped up twice but the bottom-hole pressure did not increase with the imposed injection rates as expected. This unexpected field observation suggests the possibility of an open-mode fracture development at the injector. However, the injector response and potential fracture development have not been rigorously interpreted with detailed near-wellbore temperature and pore pressure change upon the CO 2 injection. In this study, we performed history matching of CO 2 injection using coupled thermo-poro-elastic reservoir simulation to examine the possibility of fracturing. We built a reservoir model including vertical heterogeneity in both petrophysical and geomechanical properties estimated from well-logging analysis and laboratory experiments. The simulation results show that CO 2 injection changes stresses and support the hypothesis of development of an open-mode fracture at the injector during the Cranfield test. The near-injector region exhibits a large temperature reduction up to 55 °C with ensuing effective horizontal stress reduction up to 9.1 MPa. However, a caprock integrity issue is unlikely because of the horizontal stress contrast within layers and low hydraulic communication with the injection zone. This work indicates that the injectant temperature should be considered in the design of high-rate CO 2 injector.

58 GEOSCIENCES↗
NASA NTRS2001

Correlation Studies of Sea Ice Concentration with Surface Temperature and Meltponding

The spatial and temporal variability of sea ice concentrations derived from passive microwave data is studied in conjunction with co-registered high resolution infrared and visible satellite data. Cloud free infrared and visible data provide surface temperature and large scale surface characteristics, respectively, that can be used to better understand regional and seasonal fluctuations in ice concentrations. Results from correlation analysis of ice concentration versus surface temperature data show the intuitively expected negative relationship but the strength in the relationship is unexpectedly very strong. In the Antarctic, the correlation is consistently very high spatially when yearly anomalies are used, and not so high in some areas when seasonal anomalies are used, especially during spring and summer. In the monthly anomalies, the correlation is also good, especially in dynamically active regions. The expanse in the anomalies in surface temperature are shown to go way beyond the sea ice regions into the open ocean and continental areas, suggesting strong atmospheric forcing. Weak correlations are normally found in highly consolidated areas, where large changes in temperature do not cause large changes in ice concentration on a short term, and in open ocean polynya areas, where the change in ice concentration may be cause by melt from the underside of the ice. In the Arctic, strong correlations between surface temperature and ice concentration are evident for all seasons except during the summer. In the summer, factors such as meltponding, surface wetness, and ice breakup, as detected by high resolution visible data, contributes to larger uncertainties in the determination of ice concentration and the lack of good correlation of the variables.

Comiso, J. C.↗
DOE OSTI2019

Lipid Rafts: Buffers of Cell Membrane Physical Properties

Lateral organization of lipids in the cell membrane appears to be an ancient feature of the cell, given the existence of lipid rafts in both eukaryotic and prokaryotic cells. Currently seen as platforms for protein partitioning, we posit that lipid rafts are capable of playing another role: stabilizing membrane physical properties over varying temperatures and other environmental conditions. Membrane composition defines the mechanical and viscous properties of the bilayer. The composition also varies strongly with temperature, with systematic changes in the partitioning of high and low melting temperature membrane components. In this way, rafts function as buffers of membrane physical properties, progressively counteracting environmental changes via compositional changes; i.e., more high melting lipids partition to the fluid phase with increasing temperature, increasing the bending modulus and viscosity, as thermal effects decrease these same properties. To provide an example of this phenomenon, we have performed neutron scattering experiments and atomistic molecular dynamics simulations on a phase separated model membrane. The results demonstrate a buffering effect in both the lateral diffusion coefficient and the bending modulus of the fluid phase upon changing temperature. Furthermore, this demonstration highlights the potentially advantageous stabilizing effect of complex lipid compositions in response to temperature and potentially other membrane destabilizing environmental conditions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2022

Steady state thermo-mechanics and material property definition framework for analyzing DCLL blanket in the fusion nuclear science facility

In this work, a thermo-mechanics model that relies on creating the material property definition framework (MPDF) and multiphysics coupling of the heat transfer and the solid mechanics modules is developed to determine the structural integrity of the recently designed dual cooled lead lithium (DCLL) inboard blanket (IB) for the Fusion Nuclear Science Facility under steady state loads. The MPDF is called to supply fusion relevant neutron irradiation and temperature induced changes in material properties during multiphysics finite element runs, and PbLi temperature profiles are used to approximate Magnetohydrodynamics effect and the nuclear volumetric heating on the PbLi. Neutron irradiation and temperature induced reduction of the yield and ultimate strengths of F82H steel at the first wall (FW) are quantified for one year. A blanket in an assembly with gaps between blanket sectors and another blanket in an assembly with no gaps between blanket sectors, both exposed to radiation damage that lasted for one year are analyzed. Analysis using the elastic ITER structural design criteria for in-vessel components (ITER SDC-IC) design rules and a linear isotropic-hardening-type elastoplastic material model are used where most appropriate. The IB blanket with gaps between blanket sectors will withstand the steady state combined thermal and coolant loads for one year operational period but will fail if no gaps are allowed between blanket sectors. It is recommended that a gap of about 7.62 mm should be provided between IB blanket sectors during assembly which would close up during service, stop neutron streaming, reduce stresses and reduce bending of the FW into the scrape-off layer.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2026

Thermal Regulation of CO 2 Activation Pathways via Interfacial Water Restructuring Enables Ampere-Level, Near-Unity CO Electrosynthesis

Electrochemical reduction of CO 2 to CO is a key step in carbon utilization technologies, yet maintaining high CO selectivity under elevated temperatures relevant to industrial membrane-electrode-assembly (MEA) electrolyzers remains challenging due to the competing hydrogen evolution reaction (HER). Additionally, the temperature dependence of CO selectivity on Cu-based catalysts has remained largely unexplored. Here, we demonstrate that incorporating atomic In or Sn into Cu fundamentally reshapes the selectivity of Cu catalysts at elevated temperatures. Dilute alloy catalysts, In 1 Cu and Sn 1 Cu, achieve >95% FE of CO over a broad current-density window (0.1−1.1 A cm −2 ) at 60 °C in MEA electrolyzers, far exceeding their performance at ambient temperature. In situ attenuated total reflection surface-enhanced infrared absorption spectroscopy suggests that elevating temperature depletes interfacial water activity, which favors a shift in CO 2 activation from a proton-coupled *COOH pathway toward an electron-driven *COO − -associated pathway, while also suppressing HER and CO hydrogenation. In contrast, benchmark CO-selective catalysts such as Ag exhibit minimal temperature-induced changes in CO production at 20−60 °C. These findings identify temperature as an unavoidable yet previously underutilized operating parameter in MEA electrolyzers for high-rate, selective CO production on Cubased catalysts.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1977

Effects of heat treating PM Rene' 95 slightly below the gamma' solvus

An investigation was performed on as-hot-isostatically-pressed (As-HIP) Rene' 95 to obtain additional information on the variation of the amount of gamma prime with solutioning temperatures near the gamma prime solvus temperature and the resulting effects on tensile and stress rupture strength of As-HIP Rene' 95. The amount of gamma prime phase was found to increase at a rate of about 0.5% per degree Celsius as the temperature decreased from the solvus temperature to about 50 C below the gamma prime solvus temperature. The change in the amount of gamma prime phase with decreasing solutioning temperature was observed to be primarily associated with decreasing solubilities of Al+Ti+Nb and increasing solubility of Cr in the gamma phase.

Dreshfield, R. L.↗
NASA NTRS1983

Temperature dependence of mechanical and thermal expansion properties of T300/5208 graphite/epoxy

The 116-394 K temperature range elastic constants, ultimate strengths and thermal expansion behavior of T300/5208 graphite/epoxy laminates of various different lay-up types have been determined. It is noted that most properties exhibit nearly linear temperature dependencies, although the transverse modulus and axial thermal expansion vary nonlinearly with temperature, and change in value by an order of magnitude over the present temperature range.

Hyer, M. W.↗
NASA NTRS2003

Measuring Temperature Reading

There are two requirements for taking a measurement of something. The first is a tool for taking a measurement. The second is scale for making sense of the numbers of the measurement. For example, a ruler is often used to measure short lengths. It is the tool for measurement. On the ruler are one or more number scales with equally spaced numbers. These numbers can be compared with numbers from any other ruler that is accurately set to the same scale. Measuring length is far simpler than measuring temperature. While there is evidence of tools for measuring length at various times in human history, tools and scales for measuring temperature do not appear until more recent human history. Early thermometers, called thermoscopes, first appear in the 1500's. They were crude instruments that were not at all accurate. Most did not even have a number scale associated with them. This made them useless for most practical purposes. Gabriel Fahrenheit created the first accurate thermometer in 1714, and the Fahrenheit temperature scale followed it in 1724. The thermometer s accuracy was based on its use of mercury, a silver colored substance that remains liquid over a wide range of temperatures but expands or contracts in a standard, predictable way with changes in temperature. To set the scale, Fahrenheit created the coldest temperature that he could. He mixed equal parts of ice, water, and salt, and then used this as the zero point, 0 degrees, of his scale. He intended to make 30 degrees the freezing point of water and 90 degrees the temperature of the human body, but he had to later revise these temperatures to be 32 degrees and 96 degrees. In the final version of the scale, the temperature of the human body became 98.6 degrees. 19th century thermoscope

Source record↗
NASA NTRS2020

Impact of Bias in the Marine Air Temperature Observation Set on Atmospheric Reanalyses

Marine air temperature observations are collected by volunteer observing ships carrying automatic meteorological sensor packages. Close proximity of the package mount to a dark colored ship's deck is known to introduce a warm bias on sunny afternoons in summer under low wind conditions. This observation set is used as an influential constraint in the MERRA-2 reanalysis, as well as several other reanalyses, in the poorly sampled surface marine boundary layer. Here we explore the consequences of bias in the marine air temperature observation set during the 36 year period 1980-2015. Marine air temperature observations have mainly been collected along major shipping routes, with the densest coverage in the North Atlantic and North Pacific. In the first part of this presentation we review the historical observation coverage and compare air temperature and contemporaneous SST measurements to identify systematic differences. The comparison suggests the presence of diurnal bias in the air temperature observations peaking in subtropics and midlatitudes latitudes in mid-afternoon local time. In the second part we explore the impact of the marine air temperature observations on MERRA-2 through analysis of the terms in the temperature forecast tendency equation, the equation which describes the contributions to changes in temperature during each analysis cycle. Examination of the temperature forecast tendency equation allows us to separate systematic errors due to such processes and radiation, mixing, and advection and allows us to identify the major source of systematic forecast tendencies. The results show that the marine air temperature measurements introduce an error that can reach 0.4K/dy which also peaks in local afternoon at subtropical latitudes. This bias varies with season and has gradually reduced from the beginning of the MERRA-2 reanalysis in 1980. In the final part we conduct numerical experiments with a version of the MERRA-2 analysis system, comparing experiments when the marine air temperature observations are included or withheld from the analysis system.

Akella, Santharam↗
DOE OSTI2020

Thermal Image Processing for Feature Extraction from Encapsulated Phase Change Materials

Encapsulated inorganic particles with high melting points (>300 °C) are desired as high-temperature Phase Change Materials (PCMs) for next-generation Latent Heat Thermal Energy Storage (LHTES) systems. One of the many challenges during the development of PCMs is to achieve a high throughput that in turn depends on accurately modeling the relation between process parameters and geometric & thermal properties of the PCMs particle. During the production of the PCMs, a high-speed infrared camera is used to acquire images of the encapsulated material under controlled illumination conditions. This research article focuses on the development of image processing techniques for both geometric and thermal feature extraction during the development of the PCMs. A user-friendly GUI has been designed in MATLAB and preliminary experimental results have demonstrated that the method is fast, accurate and reliable for a high throughput production. The extracted features will be used to develop Machine Learning (ML) models to predict the geometric and thermal properties of the PCM based on the process parameter settings. The ML model will accelerate the search for the optimized process settings to boost the throughput of the production.

25 ENERGY STORAGE↗
DOE OSTI2018

Microstrip patch antenna for simultaneous strain and temperature sensing

A patch antenna, consisting of a radiation patch, a dielectric substrate, and a ground plane, resonates at distinct fundamental frequencies that depend on the substrate dielectric constant and the dimensions of the radiation patch. Since these parameters change with the applied strain and temperature, this study investigates simultaneous strain and temperature sensing using a single antenna that has two fundamental resonant frequencies. The theoretical relationship between the antenna resonant frequency shifts, the temperature, and the applied strain was first established to guide the selection of the dielectric substrate, based on which an antenna sensor with a rectangular radiation patch was designed and fabricated. A tensile test specimen instrumented with the antenna sensor was subjected to thermo-mechanical tests. Experiment results validated the theoretical predictions that the normalized antenna resonant frequency shifts are linearly proportional to the applied strain and temperature changes. As a result, an inverse method was developed to determine the strain and temperature changes from the normalized antenna resonant frequency shifts, yielding measurement uncertainty of 0.4 °C and 17.22 μϵ for temperature and strain measurement, respectively.

01 COAL, LIGNITE, AND PEAT↗