Search NASA⌕ Search

SEARCH · Search NASA

Results for “Battery Modeling”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1991

New Secondary Batteries Utilizing Electronically Conductive Polypyrrole Cathode

To gain a better understanding of the dynamic behavior in electronically conducting polypyrroles and to provide guidance toward designs of new secondary batteries based on these polymers, two mathematical models are developed; one for the potentiostatically controlled switching behavior of polypyrrole film, and one for the galvanostatically controlled charge/discharge behavior of lithium/polypyrrole secondary battery cell. The first model is used to predict the profiles of electrolyte concentrations, charge states, and electrochemical potentials within the thin polypyrrole film during switching process as functions of applied potential and position. Thus, the detailed mechanisms of charge transport and electrochemical reaction can be understood. Sensitivity analysis is performed for independent parameters, describing the physical and electrochemical characteristic of polypyrrole film, to verify their influences on the model performance. The values of independent parameters are estimated by comparing model predictions with experimental data obtained from identical conditions. The second model is used to predict the profiles of electrolyte concentrations, charge state, and electrochemical potentials within the battery system during charge and discharge processes as functions of time and position. Energy and power densities are estimated from model predictions and compared with existing battery systems. The independent design criteria on the charge and discharge performance of the cell are provided by studying the effects of design parameters.

Yeu, Taewhan↗
NASA NTRS1973

Study of the zinc-silver oxide battery system

Theoretical and experimental models for the evaluation of current distribution in flooded, porous electrodes are discussed. An approximation for the local current distribution function was derived for conditions of a linear overpotential, a uniform concentration, and a very conductive matrix. By considering the porous electrode to be an analog of chemical catalyst structures, a dimensionless performance parameter was derived from the approximated current distribution function. In this manner the electrode behavior was characterized in terms of an electrochemical Thiele parameter and an effectiveness factor. It was shown that the electrochemical engineering approach makes possible the organizations of theoretical descriptions and of practical experience in the form of dimensionless parameters, such as the electrochemical Thiele parameters, and hence provides useful information for the design of new electrochemical systems.

Nanis, L.↗
NASA NTRS1989

Optimization of the lithium/thionyl chloride battery

A 1-D math model for the lithium/thionyl chloride primary cell is used in conjunction with a parameter estimation technique in order to estimate the electro-kinetic parameters of this electrochemical system. The electro-kinetic parameters include the anodic transfer coefficient and exchange current density of the lithium oxidation, alpha sub a,1 and i sub o,i,ref, the cathodic transfer coefficient and the effective exchange current density of the thionyl chloride reduction, alpha sub c,2 and a sup o i sub o,2,ref, and a morphology parameter, Xi. The parameter estimation is performed on simulated data first in order to gain confidence in the method. Data, reported in the literature, for a high rate discharge of an experimental lithium/thionyl chloride cell is used for an analysis.

White, Ralph E.↗
NASA NTRS1983

Expected cycle life vs. depth of discharge relationships of well-behaved single cells and cell strings

The present investigation is concerned with the factors which might influence the cycle life vs. depth of discharge relationship, taking into account the rate of loss of cell capacity, the amount of excess capacity built into the cells, and the penalty in capacity loss resulting from the use of deep depths of discharge. 'First principles' are used to develop a cell life model for somewhat arbitrary conditions. This model is then used to estimate the cycle life vs. depth of discharge relationships for 'well behaved' cells. The stochastic variations associated with groupings of single cells are then introduced to the battery pack cycle life model. The term 'well behaved' cell is used to describe a single cell which does not suffer any abrupt failure mode during the course of its operation. It gradually loses capacity for any number of the usual reasons at a rate which is the product of the fractional depth of discharge and a factor which is characteristic of the cell under consideration.

Thaller, L. H.↗
NASA NTRSDate not supplied

Material Property Estimation in Thin Battery Components Using Guided Wave Measurement, Experimental Dispersion Curve Extraction and Finite Element Modeling

At NASA, we are investigating nondestructive evaluation (NDE) and structural health monitoring (SHM) techniques to detect precursors of thermal runaway failure in lithium metal based lithium ion batteries (LIB). The approach is centered on computational simulation models to guide inspection and aid in interpretation of results. Since lithium metal LIBs have combinations of solid and fluid-filled porous materials, obtaining accurate material properties is both challenging and critical for successful simulation of battery inspection. To this end, we investigated a multi-verification approach for material characterization of thin battery components. First, a laser Doppler vibrometer (LDV) was used to measure guided wave fields in thin (microns-thick) battery components subject to broadband excitation. The time-space wavefield data was converted to frequency-wave number data to extract guided wave dispersion curves. A data visualization and post processing graphics user interface (GUI) was developed at NASA to aid the data exploration and analysis. Due to the thinness of the samples, low frequency-thickness-product plate wave approximations allowed for the calculation of closed-form solutions for material elastic property estimation. These approximations were then verified by calculating the Lamb wave solutions using the previously obtained material properties. Finally, the estimated elastic material properties were implemented in a COMSOL simulation model, and dispersion curves were extracted from simulation results. The dispersion curves and derived material properties were then compared to the analysis results from the experimental data. These comparisons informed on the accuracy of the measured material properties and helped demonstrate the accuracy of the finite element analysis (FEA) computational models. This assessment will prove vital when we start simulating more complex multi-layer components and poroelastic media. This paper gives a brief background of the problem space, outlines the workflow for data analysis and verification, shows results from the workflow, and gives an overview of future plans for simulation of lithium metal LIB inspection.

Peter Juarez↗
NASA NTRS1997

Behavior of 2-Cell CPV Ni-H2 Battery During Pulse Discharge

A study was carried out to determine the transient voltage behavior of the 2-cell CPV nickel-hydrogen battery with the objective of using the results as a basis for mathematical modeling. The 2-cell CPV battery which is manufactured by Eagle Picher, Inc. for the GOES program yields 18.5 Ah at C/2 rate of discharge at 10 C with a mid-discharge voltage of 2.514 V. The capacity increased with decrease of temperature and a maximum capacity of 22 Ah was obtained at -5 C. The pulse tests consisted of obtaining the voltage profile in the first 20 milliseconds of the one minute pulse discharge at 37 A and pulse discharge was repeated as a function of state- of- charge. The pulse test at 10 C and 20 C provided voltage profiles with the expected decrease in voltage as the pulse was applied. The end of pulse voltage decreased with the state-of-charge. The battery voltage was above 2V at the end of the one-minute pulse at 8 % state-of-charge at 10 C. The voltage profile during the 37 A pulse discharge consists of an initial drop in voltage which was independent of the state of charge. The invariability in the value for the initial drop in voltage with state of charge is a very important observation. The results show that towards the end of discharge the dominant resistance is not ohmic in nature. It could be hypothesized from the nature of the voltage transients that the dominant mechanism towards the end of discharge is proton diffusion. The study also shows that the dominant resistance in the voltage plateau during discharge is activation polarization.

Vaidyanathan, Hari↗
NASA NTRS1998

Behavior of 2-Cell CPV Ni-H2 Battery During Pulse Discharge

A study was carried out to determine the transient voltage behavior of the 2-cell CPV nickel-hydrogen battery with the objective of using the results as a basis for mathematical modeling. The 2-cell CPV battery which is manufactured by Eagle Picher, Inc. for the GOES program yields 18.5 Ah at C/2 rate of discharge at 10 C with a mid-discharge voltage of 2.514 V. The capacity increased with decrease of temperature and a maximum capacity of 22 Ah was obtained at -5 C. The pulse tests consisted of obtaining the voltage profile in the first 20 milliseconds of the one minute pulse discharge at 37 A and pulse discharge was repeated as a function of state-of-charge. The pulse test at 10 C and 20 C provided voltage profiles with the expected decrease in voltage as the pulse was applied. The end of pulse voltage decreased with the state-of-charge. The battery voltage was above 2V at the end of the one-minute pulse at 8 % state-of-charge at 10 C. The voltage profile during the 37 A pulse discharge consists of an initial drop in voltage which was independent of the state of charge. The invariability in the value for the initial drop in voltage with state of charge is a very important observation. The results show that towards the end of discharge the dominant resistance is not ohmic in nature. It could be hypothesized from the nature of the voltage transients that the dominant mechanism towards the end of discharge is proton diffusion. The study also shows that the dominant resistance in the voltage plateau during discharge is activation polarization.

Vaidyanathan, Hari↗
NASA NTRS1997

Behavior of 2 Cell CPV NI-H2 Battery During Pulse Discharge

A study was carried out to determine the transient voltage behavior of the 2-cell CPV nickel-hydrogen battery with the objective of using the results as a basis for mathematical modeling. The 2-cell CPV battery which is manufactured by Eagle Picher, Inc. for the GOES program yields 18.5 Ah at C/2 rate of discharge at 10 C with a mid-discharge voltage of 2.514 V. The capacity increased with decrease of temperature and a maximum capacity of 22 Ah was obtained at - 5 C. The pulse test consisted of obtaining the voltage profile in the first 20 milliseconds of the one minute pulse discharge at 37 A and pulse discharge was repeated as a function of state-of-charge. The pulse test at 10 C and 20 C provided voltage profiles with the expected decrease in voltage as the pulse was applied. The end of pulse voltage decreased with the state-of-charge. The battery voltage was above 2V at the end of the one-minute pulse at 12% state-of-charge at 10 C. The voltage profile during the 37 A pulse discharge consists of an initial drop in voltage which was independent of the state of charge. The invariability in the value for the initial drop in voltage with state of charge is a very important observation and indicates that towards the end of discharge the dominant resistance is not ohmic in nature. It could be hypothesized from the nature of the voltage transients that the dominant mechanism towards the end of discharge is proton diffusion. The study also shows that the dominant resistance in the voltage plateau during discharge is activation polarization.

Gopalakrishna, M. Rao↗
NASA NTRSDate not supplied

Modeling Spacecraft Power Systems Using the SPACE Code

The NASA Glenn Research Center’s Power Architecture and Analysis Branch performs spacecraft electrical power system (EPS) performance analysis using the System Power Analysis for Capability Evaluation (SPACE) model. Accurately predicting EPS performance requires a wide range of inputs, including the spacecraft’s position, attitude, solar array temperature, load demand, and data on the EPS itself. By operating as a combined analysis tool with integrated orbit mechanics, attitude, shadowing, thermal, solar array, battery, and electrical component models, SPACE provides flexibility for the analyst to examine various scenarios without a time-consuming iterative process involving separate analysis tools and groups. SPACE also achieves short run times by tailoring the complexity of the included models, providing enough fidelity to ensure accurate EPS performance predictions without being bogged down by unnecessary detail. These advantages that SPACE has over similar power system models has contributed to its successful use on a variety of human spaceflight programs for over three decades, and makes it applicable across the development cycle from early conceptual design up through on-orbit operations.

Electrical Power System↗
NASA NTRS2004

Research Symposium II

Contents include the following: High power density motors. The training process of the organization development and training office. Modeling and analysis of a regenerative fuel cell propulsion system for a high altitude long endurance. Increasing the thermal stability of aluminum titanate for solid oxide mJEL cell anodes. Microstructural evaluation of forging parameters for superalloy disks. Epoxy adgesives for stator magnet assembly in stirling radioisotope generator. Nickel-Hydrogen and lithium ion space batteries. Statistical and prediction modeling of the Ka band using experimental results from ACTS propagation terminals at 20.185 and 27.505 GHz.

Source record↗
NASA NTRS1988

Nickel cadmium battery performance simulation - A means toward optimum design in satellite applications

It is noted that electrochemically based cell models can advance state-of-the-art battery prediction by allowing variations in the parameters that constitute wear-out and predict end-of-life performance. This modeling method is used as the foundation for the simulation of Ni-Cd battery performance. This simulation tool consists of a comprehensive computer model to be developed which would predict the voltage behavior of a battery under mission conditions.

Clark, K.↗
NASA NTRS1975

NiCd battery reliability for shuttle serviced spacecraft

Data from life-cycle testing of 22-cell NiCd batteries designed for shuttle-service spacecrafts are analyzed, first by averaging battery cycle lives as a function of temperature and depth of discharge, and then by calculating single cell failure and survival probabilities as a function of temperature, depth of discharge, and number of operating cycles. The single cell data are used to calculate battery survival probabilities. A mathematical failure model which is a function of the quantity of charge through the battery and the temperature is characterized, suggesting a predictive capability for accurate estimation of energy storage subsystem life and performance of accelerated tests. The failure mechanism described is apparently independent of most charge-discharge parameters and common to most cell sizes.

Eliason, J.↗
NASA NTRS1983

The 1982 Goddard Space Flight Center Battery Workshop

Various topics concerned with advanced battery technology are addressed including lithium cell and battery safety developments, mathematical modelling, charge control of aerospace power systems, and the application of nickel hydrogen cells/batteries vis-a-vis nickel cadmium cells/batteries.

Halpert, G.↗
NASA NTRS1993

NASA Center update: Jet Propulsion Laboratory

The topics covered are presented in viewgraph form and include the following: flight project support activities for TOPEX and the Mars Observer; and research/development and engineering activities for NiCd model development, secondary lithium battery development, the sodium-NiCl2 moderate temperature battery, Li-SOCl2 batteries for the Centaur launch vehicle, and direct hydrocarbon/methanol fuel cells.

Distefano, Sal↗
NASA NTRS1976

The computer simulation of automobile use patterns for defining battery requirements for electric cars

The modeling process of a complex system, based on the calculation and optimization of the system parameters, is complicated in that some parameters can be expressed only as probability distributions. In the present paper, a Monte Carlo technique was used to determine the daily range requirements of an electric road vehicle in the United States from probability distributions of trip lengths, frequencies, and average annual mileage data. The analysis shows that a daily range of 82 miles meets to 95% of the car-owner requirements at all times with the exception of long vacation trips. Further, it is shown that the requirement of a daily range of 82 miles can be met by a (intermediate-level) battery technology characterized by an energy density of 30 to 50 Watt-hours per pound. Candidate batteries in this class are nickel-zinc, nickel-iron, and iron-air. These results imply that long-term research goals for battery systems should be focused on lower cost and longer service life, rather than on higher energy densities

Schwartz, H.-J.↗
NASA NTRS1991

Modeling of Space Station power system components and their interactions

The authors demonstrate that the functional modeling approach is feasible in modeling large-scale spacecraft power systems such as the Space Station electric power system (EPS). The functional models for the solar array sequential shunt unit and the battery charging/discharging unit are presented. The functional modeling approach has also been applied to simulate other major EPS components. The usefulness of this approach in system-level studies has been demonstrated by incorporating these models into a power system model and simulating the system behavior under various conditions. The simulation results are consistent with those obtained experimentally. With larger time step size and reduced model complexity, the computation time required by the functional modeling approach is short. Functional models are effective in simulation studies of system-level issues, especially for large-scale power systems including many power electronic components.

Tam, Kwa-Sur↗