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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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All sourcesNASA NTRSDOE OSTI
NASA NTRS2016

B33C-0612: Evaluation of Simulated Biospheric Carbon Dioxide Fluxes and Atmospheric Concentrations Using Global in Situ Observations

Atmospheric mixing ratios of carbon dioxide (CO2) are largely controlled by anthropogenic emission sources and biospheric sources/sinks. Global biospheric fluxes of CO2 are controlled by complex processes facilitating the exchange of carbon between terrestrial ecosystems and the atmosphere. These processes which play a key role in these terrestrial ecosystem-atmosphere carbon exchanges are currently not fully understood, resulting in large uncertainties in the quantification of biospheric CO2 fluxes. Current models with these inherent deficiencies have difficulties simulating the global carbon cycle with high accuracy. We are developing a new modeling platform, GEOS-Chem-CASA by integrating the year-specific NASA-CASA (National Aeronautics and Space Administration - Carnegie Ames Stanford Approach) biosphere model with the GEOS-Chem (Goddard Earth Observation System-Chemistry) chemical transport model to improve the simulation of atmosphere-terrestrial ecosystem carbon exchange. We use NASA-CASA to explicitly represent the exchange of CO2 between terrestrial ecosystem and atmosphere by replacing the baseline GEOS-Chem land net CO2 flux and forest biomass burning CO2 emissions. We will present the estimation and evaluation of these "bottom-up" land CO2 fluxes, simulated atmospheric mixing ratios, and forest disturbance changes over the last decade. In addition, we will present our initial comparison of atmospheric column-mean dry air mole fraction of CO2 predicted by the model and those retrieved from NASA's OCO-2 (Orbiting Carbon Observatory-2) satellite instrument and model-predicted surface CO2 mixing ratios with global in situ observations. This evaluation is the first step necessary for our future work planned to constrain the estimates of biospheric carbon fluxes through "top-down" inverse modeling, which will improve our understanding of the processes controlling atmosphere-terrestrial ecosystem greenhouse gas exchanges, especially over regions which lack in situ observations.

in situ observations↗
NASA NTRS1985

Measurements of concentrations of chlorofluoromethanes (CFMs) carbon dioxide and carbon isotope ratio in stratospheric and tropospheric air by grab-sampling systems

Measurements of concentrations of chlorofluoromethanes (CFMs), carbon dioxide and carbon isotope ratio in stratospheric and tropospheric air by grab-sampling systems are reported. The balloon-borne grab-sampling system has been launched from Sanriku Balloon Center three times since 1981. It consists of: (1) six sampling cylinders, (2) eight motor driven values, (3) control and monitor circuits, and (4) pressurized housing. Particular consideration is paid to the problem of contamination. Strict requirements are placed on the choice of materials and components, construction methods, cleaning techniques, vacuum integrity, and sampling procedures. An aluminum pressurized housing and a 4-m long inlet line are employed to prevent the sampling air from contamination by outgassing of sampling and control devices. The sampling is performed during the descent of the system. Vertical profiles of mixing ratios of CF2Cl2, CFCl3 and CH4 are given. Mixing ratios of CF2Cl2 and CFCl3 in the stratosphere do not show the discernible effect of the increase of those in the ground level background, and decrease with altitude. Decreasing rate of CFCl3 is larger than that of CF2Cl2. CH4 mixing ratio, on the other hand, shows diffusive equilibrium, as the photodissociation cross section of CH4 is small and concentrations of OH radical and 0(sup I D) are low.

Itoh, T.↗
NASA NTRS1993

Solubilities of carbon dioxide and water in rhyolitic melt at 850 C and 750 bars

Concentrations of carbon dioxide and water dissolved in glasses quenched from rhyolitic melts equilibrated with H2O-CO2 fluids at 850 C and 750 bar were measured using IR spectroscopy; concentrations of H2O and CO2 in the quenched fluids were measured manometrically. The mole fraction of CO2 in the quenched fluid ranged from 0.06 to 0.91. Concentrations of CO2 in the coexisting rhyolitic melt increased from 23(+/-6) ppm for the sample equilibrated with the most CO2-poor fluid to 515(+/-16) ppm for that equilibrated with the most CO2-rich fluid. The water content of the melt varied from 0.51(+/-0.06) to 3.34(+/-0.08) wt pct. Our results show that concentrations of molecular CO2 and H2O in the glasses obey Henry's Law; the mole fractions of molecular CO2 and molecular H2O in the quenched melts are proportional to their fugacities in the coexisting vapor. CO2 contents of vapor-saturated melts are not enhanced by addition of water to CO2-rich vapor, contrary to previous reports for silicate melts at higher pressures. The Henrian behavior of CO2 and H2O at low pressure considerably simplifies modeling of the degassing of silicic magmas.

Blank, J. G.↗
NASA NTRS2005

Diagnostics Adapted for Heat-Treating Furnace Environment

Diagnostics developed for the in situ monitoring of rocket combustion environments were adapted for use in heat-treating furnaces. Simultaneous, in situ monitoring of the carbon monoxide, carbon dioxide, methane, water, and hydrogen concentrations in the endothermic gas of a heat-treating furnace were demonstrated under a Space Act Agreement between the NASA Lewis Research Center, the Heat Treating Network, and Akron Steel Treating Company. This endothermic gas, or "endogas," is produced in a catalytic process, where natural gas is "cracked" in the presence of air. Variations in the composition of the natural gas supplied lead to variations in the composition of the endothermic gas. These variations could lead to an unacceptable quality of steel products that are hardened through the carborization process that uses this gas. Conventional methods of monitoring the endogas include measuring the dew point of the gas and the oxygen concentration. From these data, the carbon monoxide content of the gas can be calculated. This carbon monoxide concentration creates the carbon potential needed for carburization. Several weak links are present in this approach. The oxygen monitor deteriorates over time, and the measurement might be inaccurate by 50 percent. Also, the chemistry equations, which are based on several assumptions, such as secondary species concentrations, provide only an approximate estimate of the carbon monoxide concentration. To address these weaknesses, we investigated a new method based on ordinary Raman spectroscopy, in which the carbon monoxide concentration is measured directly and in situ. This method measures the laser light scattered from the molecules. Each species interacts with the light and scatters the light at a different frequency. Spectral monitoring of the scattered light intensity at each molecular frequency of interest provides the species concentrations. One advantage over the conventional method is that several species can be monitored simultaneously. A second advantage is that the measurement is direct; there is no need to make assumptions, to filter the gas, or to calibrate the instrument. An instrument was designed consisting of a laser and a detection system within an enclosure, connected to an optical probe by fibers. For determining carbon monoxide concentration, the probe is mounted on the endothermic gas line, close to the generator. Optical fibers with a length of 150 ft have been used to transmit laser light from the instrument to the probe. There, the light is focused into the gas, and the scattered light is collected and transmitted back to the instrument where it is analyzed with a photomultiplier and lock-in amplifier. Laboratory tests have shown that with the current system the concentration of carbon monoxide, water, nitrogen, oxygen, and hydrogen in the air can be monitored with an accuracy of 1 percent. The concentration of carbon dioxide in the air can be monitored with an accuracy of 0.5 percent, and the concentration of methane with an accuracy of 0.2 percent. This instrument was taken to the Akron Steel Treating Plant, where field tests are in progress to verify the system capabilities. Planned developments are improving the accuracy, monitoring multiple locations, and reducing instrument size and cost.

Source record↗
NASA NTRS1982

Increased atmospheric carbon dioxide and climate feedback mechanisms

As a consequence of fossil fuel burning, the atmospheric concentration of carbon dioxide has increased from 314 ppm in 1958, when detailed measurements of this quantity began, to a present value of 335 ppm; and it is estimated that during the next century, the CO2 concentration will double relative to its assumed preindustrial value of 290 ppm. Since CO2 is an infrared-active gas, increases in its atmospheric concentration would lead to a larger infrared opacity for the atmospheric which, by normal logic, would result in a warmer Earth. A number of modeling endeavors suggest a 2 to 4 C increase in global mean surface temperature with doubling of the CO2 concentration. But such estimates of CO2-induced warming are highly uncertain because of a lack of knowledge of climate feedback mechanisms. Interactive influences upon the solar and infrared opacities of the Earth-atmosphere system can either amplify or damp a climate-forcing mechanism such as increasing CO2. Climate feedback mechanisms discussed include climate sensitivity, cloudiness-radiation feedback, climate change predictions, and interactive atmospheric chemistry.

Cess, R. D.↗
NASA NTRS1977

An experimental and analytical study of acetylene and ethylene oxidation behind shock waves

An experimental and analytical study of the oxidation of acetylene and ethylene behind incident shock waves was carried out over the temperature range 1815-2365 K at reaction pressures between 1.1 and 1.7 atm. The oxidation process was monitored by measuring radiation from carbon dioxide, carbon monoxide, and the reaction O + CO yields CO2 + h nu. The recorded emission profiles were analyzed to obtain concentrations for carbon dioxide, carbon monoxide, and the product of oxygen atom and the carbon monoxide concentrations. On the basis of this data and induction time data reported in the literature, kinetic models for acetylene and ethylene oxidation were assembled.

Jachimowski, C. J.↗
NASA NTRS2009

Single Longitudinal Mode, High Repetition Rate, Q-switched Ho:YLF Laser for Remote Sensing

Ho:YLF/LuLiF lasers have specific applications for remote sensing such as wind-speed measurement and carbon dioxide (CO2) concentration measurement in the atmosphere because the operating wavelength (around 2 m) is located in the eye-safe range and can be tuned to the characteristic lines of CO2 absorption and there is strong backward scattering signal from aerosol (Mie scattering). Experimentally, a diode pumped Ho:Tm:YLF laser has been successfully used as the transmitter of coherent differential absorption lidar for the measurement of with a repetition rate of 5 Hz and pulse energy of 75 mJ [1]. For highly precise CO2 measurements with coherent detection technique, a laser with high repetition rate is required to averaging out the speckle effect [2]. In addition, laser efficiency is critically important for the air/space borne lidar applications, because of the limited power supply. A diode pumped Ho:Tm:YLF laser is difficult to efficiently operate in high repetition rate due to the large heat loading and up-conversion. However, a Tm:fiber laser pumped Ho:YLF laser with low heat loading can be operated at high repetition rates efficiently [3]. No matter whether wind-speed or carbon dioxide (CO2) concentration measurement is the goal, a Ho:YLF/LuLiF laser as the transmitter should operate in a single longitudinal mode. Injection seeding is a valid technique for a Q-switched laser to obtain single longitudinal mode operation. In this paper, we will report the new results for a single longitudinal mode, high repetition rate, Q-switched Ho:YLF laser. In order to avoid spectral hole burning and make injection seeding easier, a four mirror ring cavity is designed for single longitudinal mode, high repetition rate Q-switched Ho:YLF laser. The ramp-fire technique is chosen for injection seeding.

Bai, Yingxin↗
NASA NTRS2011

Application of Commercial Non-Dispersive Infrared Spectroscopy Sensors for Sub-Ambient Carbon Dioxide Detection

Monitoring carbon dioxide (CO2) concentration within a spacecraft or spacesuit is critically important to ensuring the safety of the crew. Carbon dioxide uniquely absorbs light at wavelengths of 3.95 micrometers and 4.26 micrometers. As a result, non-dispersive infrared (NDIR) spectroscopy can be employed as a reliable and inexpensive method for the quantification of CO2 within the atmosphere. A multitude of commercial-off-the-shelf (COTS) NDIR sensors exist for CO2 quantification. The COTS sensors provide reasonable accuracy so long as the measurements are attained under conditions close to the calibration conditions of the sensor (typically 21.1 C and 1 atm). However, as pressure deviates from atmospheric to the pressures associated with a spacecraft (8.0-10.2 PSIA) or spacesuit (4.1-8.0 PSIA), the error in the measurement grows increasingly large. In addition to pressure and temperature dependencies, the infrared transmissivity through a volume of gas also depends on the composition of the gas. As the composition is not known a priori, accurate sub-ambient detection must rely on iterative sensor compensation techniques. This manuscript describes the development of recursive compensation algorithms for sub-ambient detection of CO2 with COTS NDIR sensors. In addition, the basis of the exponential loss in accuracy is developed theoretically considering thermal, Doppler, and Lorentz broadening effects which arise as a result of the temperature, pressure, and composition of the gas mixture under analysis. As a result, this manuscript provides an approach to employing COTS sensors at sub-ambient conditions and may also lend insight into designing future NDIR sensors for aerospace application.

Swickrath, Michael J.↗
NASA NTRS2012

Application of Commercial Non-Dispersive Infrared Spectroscopy Sensors for Sub-Ambient Carbon Dioxide Detection

Monitoring carbon dioxide (CO2) concentration within a spacecraft or spacesuit is critically important to ensuring the safety of the crew. Carbon dioxide uniquely absorbs light at wavelengths of 3.95 micrometers and 4.26 micrometers. As a result, non-dispersive infrared (NDIR) spectroscopy can be employed as a reliable and inexpensive method for the quantification of CO2 within the atmosphere. A multitude of commercial off-the-shelf (COTS) NDIR sensors exist for CO2 quantification. The COTS sensors provide reasonable accuracy as long as the measurements are attained under conditions close to the calibration conditions of the sensor (typically 21.1 C (70.0 F) and 1 atmosphere). However, as pressure deviates from atmospheric to the pressures associated with a spacecraft (8.0{10.2 pounds per square inch absolute (psia)) or spacesuit (4.1{8.0 psia), the error in the measurement grows increasingly large. In addition to pressure and temperature dependencies, the infrared transmissivity through a volume of gas also depends on the composition of the gas. As the composition is not known a priori, accurate sub-ambient detection must rely on iterative sensor compensation techniques. This manuscript describes the development of recursive compensation algorithms for sub-ambient detection of CO2 with COTS NDIR sensors. In addition, the source of the exponential loss in accuracy is developed theoretically. The basis of the loss can be explained through thermal, Doppler, and Lorentz broadening effects that arise as a result of the temperature, pressure, and composition of the gas mixture under analysis. This manuscript provides an approach to employing COTS sensors at sub-ambient conditions and may also lend insight into designing future NDIR sensors for aerospace application.

Swickrath, Michael J.↗
NASA NTRS1979

Venus upper atmosphere neutral gas composition - First observations of the diurnal variations

Measurements of the composition, temperature, and diurnal variations of the major neutral constituents in the thermosphere of Venus are being made with a quadrupole mass spectrometer on the Pioneer Venus Orbiter. Concentrations of carbon dioxide, carbon monoxide, molecular nitrogen, atomic oxygen, and helium are presented, in addition to an empirical model of the data. The concentrations of the heavy gases, carbon dioxide, carbon monoxide, and molecular nitrogen, rapidly decrease from the evening terminator toward the nightside; the concentration of atomic oxygen remains nearly constant and the helium concentration increases, an indication of a nightside bulge. The kinetic temperature inferred from scale heights drops rapidly from 230 K at the terminator to 130 K at a solar zenith angle of 120 deg, and to 112 K at the antisolar point.

Niemann, H. B.↗
NASA NTRS2001

Measuring the Spectral Expression of Carbon Dioxide in the Solar Reflected Spectrum with AVIRIS

Carbon dioxide is a low-concentration, but important, component of the Earth's atmosphere. This gas absorbs electromagnetic radiation (EMR) in several regions of the spectrum. Absorption of energy by carbon dioxide adds heat to the atmosphere. In the world today, the burning of fossil fuels and other anthropogenic processes adds carbon dioxide to the atmosphere. Other natural processes in the Earth's system both add and remove carbon dioxide. Overall, measurements of atmospheric carbon dioxide at selected sites around the globe show an increased carbon dioxide concentration in the atmosphere. A figure shows the measured carbon dioxide from Mauna Loa, Hawaii, from 1958 to 2000. Overall, the concentration has increased from 315 to 365 ppm at this site over this period. (There is also a yearly cycle to the concentration that is timed with and hypothesized to be related to the vegetation growing season in the Northern Hemisphere.) The overall expected effect of this increase of atmospheric carbon dioxide is trapping of heat in the atmosphere and global warming. While this overall relationship between carbon dioxide and global warming seems straightforward, many of the specific details relating to regional and local sources and sinks and gradients of carbon dioxide are not well understood. A remote sensing capability to measure carbon dioxide could provide important inputs for scientific research to better understand the distribution and change in atmospheric carbon dioxide at detailed spatial and temporal levels. In pursuit of this remote sensing of carbon dioxide objective, this paper analyzes the expression of carbon dioxide in the spectral range measured by the Airborne Visible/Infrared Imagery Spectrometer (AVIRIS). Based on these analyses, a spectral-fitting algorithm that uses AVIRIS measured spectra and MODTRAN radiative-transfer code modeled spectra to derive total column carbon dioxide abundance has been developed. This algorithm has been applied to an AVIRIS data set acquired over Pasadena, California, in 1999 and a data set acquired over the Pacific Ocean near Hawaii in 2000 with promising results. This is ongoing research; the current initial analyses, measurements, and results are reported in this paper.

Green, Robert O.↗
NASA NTRS2016

Advanced Supported Liquid Membranes for Carbon Dioxide Control in Cabin Applications

The development of new, robust, life support systems is critical to NASA's continued progress in space exploration. One vital function is maintaining the carbon dioxide (CO2) concentration in the cabin at levels that do not impair the health or performance of the crew. The carbon dioxide removal assembly (CDRA) is the current CO2 control technology on-board the International Space Station (ISS). Although the CDRA has met the needs of the ISS to date, the repeated cycling of the molecular sieve sorbent causes it to break down into small particles that clog filters or generate dust in the cabin. This reduces reliability and increases maintenance requirements. Another approach that has potential advantages over the current system is a membrane that separates CO2 from air. In this approach, cabin air contacts one side of the membrane while other side of the membrane is maintained at low pressure to create a driving force for CO2 transport across the membrane. In this application, the primary power requirement is for the pump that creates the low pressure and then pumps the CO2 to the oxygen recovery system. For such a membrane to be practical, it must have high CO2 permeation rate and excellent selectivity for CO2 over air. Unfortunately, conventional gas separation membranes do not have adequate CO2 permeability and selectivity to meet the needs of this application. However, the required performance could be obtained with a supported liquid membrane (SLM), which consists of a microporous material filled with a liquid that selectively reacts with CO2 over air. In a recently completed Phase II SBIR project, Reaction Systems, Inc. fabricated an SLM that is very close to meeting permeability and selectivity objectives for use in the Portable Life Support System (PLSS). This paper describes work carried out to evaluate its potential for use in the cabin.

Wickham, David T.↗
NASA NTRS1985

Electrochemical CO2 concentration for the Space Station Program

Under the sponsorship of NASA, Electrochemical Carbon Dioxide (CO2) Concentration EDC technology has been developed that removes CO2 continuously or cyclically from low CO2 partial pressure (400 Pa) atmospheres with the performance and operating characteristics required for Space Station applications. The most recent advancement of this technology is the development of an advanced preprototype subsystem, the CS-3A, to remove the metabolic CO2 produced by three persons from the projected Space Station atmosphere. This paper provides an overview of EDC technology, shows how it is ideally suited for Space Station application, and presents technology enhancements that will be demonstrated by the CS-3A subsystem development program.

Lance, N.↗
NASA NTRS2007

Flame Radiation, Structure, and Scalar Properties in Microgravity Laminar Fires

Results from microgravity combustion experiments conducted in the Zero Gravity Research Facility (ZGF) 5.18 second drop facility are reported. The results quantify flame radiation, structure, and scalar properties during the early phase of a microgravity fire. Emission mid-infrared spectroscopy measurements have been completed to quantitatively determine the flame temperature, water and carbon dioxide vapor concentrations, radiative emissive power, and soot concentrations in microgravity laminar methane/air, ethylene/nitrogen/air and ethylene/air jet flames. The measured peak mole fractions for water vapor and carbon dioxide are found to be in agreement with state relationship predictions for hydrocarbon/air combustion. The ethylene/air laminar flame conditions are similar to previously reported results including those from the flight project, Laminar Soot Processes (LSP). Soot concentrations and gas temperatures are in reasonable agreement with similar results available in the literature. However, soot concentrations and flame structure dramatically change in long-duration microgravity laminar diffusion flames as demonstrated in this report.

Feikema, Douglas↗
NASA NTRSDate not supplied

Novel Aprotic Heterocyclic Anion-based Ionic Liquids for Carbon Dioxide Capture

Ionic liquids (ILs), or organic salts with melting points at or below room temperature are an incredibly versatile class of materials with many possible applications for NASA’s exploration needs. In particular, appropriately designed ILs can have a high affinity for absorbing carbon dioxide, making them excellent candidates for use as liquid sorbents in cabin air revitalization systems. Unfortunately, many of these ILs have high viscosity, which is only exacerbated by carbon dioxide uptake. High viscosity limits the rate of carbon dioxide uptake. A new class of IL sorbent containing aprotic heterocyclic anions (AHA) has been shown to offer excellent carbon dioxide uptake without a corresponding increase in viscosity. However, there is a paucity of sorption data for these AHA ILs at low partial pressures of carbon dioxide. This paper reports on the characterization of sorption behavior for AHA ILs previously reported in the literature at low concentrations of carbon dioxide and the synthesis and characterization of new, water miscible AHA ILs. Characterization of the new ILs includes measurement of density, viscosity, thermal stability, carbon dioxide capacity, carbon dioxide absorption kinetics, and water-IL vapor liquid equilibrium. Overall, these news ILs are promising alternatives to many of the commonly used IL sorbents.

Eric Townsend Fox↗
NASA NTRS2010

The Use of Remote Sensing Data for Advancing America's Energy Policy

After briefly reviewing America's Energy Policy laid out by the Obama Administration, we outline how a Global Carbon Observing System designed to monitor Carbon from space can provide the necessary data and tools to equip decision makers with the knowledge necessary to formulate effective energy use and practices policy. To stabilize greenhouse gas emissions in the atmosphere in a manner that it does not interfere with the Earth's climate system (which is one of the goals of United Nations Framework for Convention on Climate Change) requires vastly improved prediction of the atmospheric carbon dioxide (CO2) concentrations. This in torn requires a robust understanding of the carbon exchange mechanisms between atmosphere, land, and oceans and a clear understanding of the sources and sinks (i.e. uptake and storage) of CO2. We discuss how the Carbon Observing System from space aids in better understanding of the connection between the carbon cycle and climate change and provides more accurate predictions of atmospheric CO2 concentration. It also enables implementation of greenhouse gas (GHG) mitigation policies such as cap and trade programs, international climate treaties, as well as formulation of effective energy use policies.

Valinia, Azita↗