Search NASA⌕ Search

SEARCH · Search NASA

Results for “CLEAVAGE”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Minimum wafer thickness by rotated ingot ID wafering

The efficient utilization of materials is critical to certain device applications such as silicon for photovoltaics or diodes and gallium-gadolinium-garnet for memories. A variety of slicing techniques has been investigated to minimize wafer thickness and wafer kerf. This paper presents the results of analyses of ID wafering of rotated ingots based on predicted fracture behavior of the wafer as a result of forces during wafering and the properties of the device material. The analytical model indicated that the minimum wafer thickness is controlled by the depth of surface damage and the applied cantilever force. Both of these factors should be minimized. For silicon, a minimum thickness was found to be approximately 200 x 10 - 6th m for conventional sizes of rotated ingot wafering. Fractures through the thickness of the wafer rather than through the center supporting column were found to limit the minimum wafer thickness. The model suggested that the use of a vacuum chuck on the wafer surface to enhance cleavage fracture of the center supporting core and, with silicon, by using 111-line-type ingots could have potential for reducing minimum wafer thickness.

Chen, C. P.↗
NASA NTRS1984

Rapidly solidified NiAl and FeAl

Melt spinning was used to produce rapidly solidified ribbons of the B2 intermetallics NiAl and FeAl. Both Fe-40Al and Fe-45Al possessed some bend ductility in the as spun condition. The bend ductility of Fe-40Al, Fe-45Al, and equiatomic NiAl increased with subsequent heat treatment. Heat treatment at approximately 0.85 T (sub m) resulted in significant grain growth in equiatomic FeAl and in all the NiAl compositions. Low bend ductility in both FeAl and NiAl generally coincided with intergranular failure, while increased bend ductility was characterized by increasing amounts of transgranular cleavage fracture.

Gaydosh, D. J.↗
NASA NTRS1985

Ceramic wear in indentation and sliding contact

The various wear mechanisms involved with single-crystal ceramic materials in indentation and in sliding contacts. Experiments simulating interfacial events have been conducted with hemispherical, conical and pyramidal indenters (riders). With spherical riders, under either abrasive or adhesive conditions, two types of fracture pits have been observed. First, spherical-shaped fracture pits and wear particles are found as a result of either indenting or sliding. These are shown to be due to a spherical-shaped fracture along the circular or spherical stress trajectories. Second, polyhedral fracture pits and debris, produced by anisotropic fracture, and also found both during indenting and sliding. These are primarily controlled by surface and subsurface cracking along cleavage planes. Several quantitative results have also been obtained from this work. For example, using a pyramidal diamond, crack length of Mn-Zn ferrite in the indentation process grows linearly with increasing normal load. Moreover, the critical load to fracture both in indentation and sliding is essentially isotropic and is found to be directly proportional to the indenter radius.

Miyoshi, K.↗
NASA NTRS1985

Decomposition of ethylene on small Pd particles

New results have been obtained which contribute to the understanding of hydrocarbon reactions on the surface of highly dispersed metal systems. Small particle of Pd were grown by electron beam evaporation on cleavage planes of high purity natural mica under ultrahigh vacuum conditions. Samples were subsequently characterized by transmission electron microscopy. Average particle sizes ranged from about 1 to 10 nm diameter. The chemisoption and decomposition of C2H4 on the Pd particles was studied using Auger electron spectroscopy and flash thermal desorption. It is shown that (a) C2H4 decomposes on Pd particles at room temperature, (b) specific surface sites are causing decomposition, and (c) the proportion of such active sites is significantly greater for the smaller metal particles. This enhanced reactivity may be due to an increase in the density of step, corner, and edge sites with a decrease in particle size.

Durrer, W. G.↗
NASA NTRS1986

Crack Growth in Single-Crystal Silicon

Report describes experiments on crack growth in single-crystal silicon at room temperature in air. Crack growth in (111) cleavage plane of wafers, 50 by 100 by 0.76 mm in dimension, cut from Czochralski singlecrystal silicon studied by double-torsion load-relaxation method and by acoustic-emission measurements. Scanning electron microscopy and X-ray topography also employed. Results aid in design and fabrication of silicon photovoltaic and microelectronic devices.

Chen, C. P.↗
NASA NTRS1986

Transpression as the main deformational event in an Archaean greenstone belt, northeastern Minnesota

Deformed and metamorphosed sedimentary and volcanic rocks of the Vermilion district constitute an Archean greenstone belt trending east-west between higher grade rocks of the Vermilion Granitic Complex to the north and the Giants Range batholith to the south. Metamorphic grade is low throughout, being lowest in the center of the belt (chlorite zone of the greenschist facies). All the measured strain, a cleavage or schistosity, and a mineral lineation in this belt are attributed to the main phase of deformation D sub 2 that followed an earlier nappe-forming event D sub 1, which left little evidence of penetrative fabric. Previous work assumed that the D sub 2 deformation resulted from north-south compression across the district. It is now believed that a significant component of this deformation resulted from dextral shear across the whole region. Thus the Vermilion fault, a late-state largely strike-slip structure that bounds the Vermilion district to the north, may simply be the latest, most brittle expression of a shear regime that was much more widespread in space and time. Features that are indicative of shear include ductile shear zones with sigmoidal foliation patterns, highly schistose zones with the development of shear bands, feldspar clasts or pyrite cubes with asymmetric pressure shadows, and the fact that the asymmetry of the F sub 2 folds is predominantly Z for at least 15 km south of the Vermilion fault.

Hudleston, P. J.↗
NASA NTRS1986

Preliminary structural model for the southwestern part of the Michipicoten greenstone belt, Ontario

The southwestern part of the Michipicoten Greenstone Belt includes a 100 sq km fume kill extending northeastwards from the twon of Wawa, Ontario. Except for a strip along the Magpie River that is covered by Pleistocene gravels, outcrop in the fume kill averages about 30-50%. Within this area are all the major lithologic belts characteristic of the southwestern fourth of the Michipicoten Greenstone Belt. All of the area mapped to date lies within Chabenel Township, recently mapped at 4" = 1 mile. Following a brief reconnaissance in 1983, mapping at a scale of 1" = 400' was begun within and adjacent to the fume kill in 1984. Two objectives are sought (1) determinaion of the geometry and sequence of folding, faulting, cleavage development, and intrusion; and (2) defining and tracing lithologic packages, and evaluating the nature of the contacts between these packages. Results for objective (1) are discussed in a companion abstract; this abstract will present tentative results for objective.

Mcgill, G. E.↗
NASA NTRS1986

Tensile behavior of Fe-40Al alloys with B and Zr additions

Both Fe-40Al and Fe-40Al-0.1Zr with and without B were produced by the hot extrusion of powdered metal. Tensile properties were determined from room temperature to 1100 K in air. All of the materials possessed some ductility at room temperature, and addition of B caused an increase in ductility and a change in fracture mode from intergranular to transgranular cleavage. At high temperatures, failure was caused primarily by the formation of grain boundary cavities in all of the alloys. The effect of Zr addition was unclear because of the complexity of the various microstructures. Comparison of air and vacuum testing at high temperatures revealed that an apparent oxidation assisted mechanism reduced high temperature ductility in these alloys, especially at 900 K.

Gaydosh, D. J.↗
NASA NTRS1986

Gated photochemical hole burning in photoadducts of polyacenes

A photoadduct of anthracene and tetracene (A-T) in a polymer matrix at 1.5 K generates an absorption spectrum which exhibits two-color, photon-gated photochemical hole burning (PHB) when irradiated with narrowband exciting light into the 0-0 band of the S1-S0 absorption. The efficiency of this PHB process is found to be enhanced by simultaneous irradiation near the maximum of the Tn-T1 absorption of A-T; hole widths of less than 0.07/cm have been observed for this photochemical cleavage of A-T.

Iannone, Mark↗
NASA NTRS1986

Further observations of SCC in alpha-beta brass Considerations regarding the appearance of crack arrest markings during SCC

A series of constant displacement and constant extension rate stress corrosion cracking (SCC) tests was performed on an alpha-beta brass alloy in 1 N Na2SO4 solutions. The chosen mechanical and electrochemical conditions resulted in predominantly transgranular, cleavage-like failure at high (about 8 to 50 microns/s) average crack propagation rates. Crack arrest markings were observed on selected transgranular facets, which almost exclusively bordered regions of ductile overload failure. It is proposed that the observed crack velocities and the specific nature of the arrest mark appearance are most consistent with a cracking mechanism involving adsorption or some other interaction with a damaging environmental species.

Hintz, M. B.↗
NASA NTRS1986

Kinetics of the hydrolysis of guanosine 5'-phospho-2-methylimidazolide

The hydrolysis kinetics of guanosine 5'-phospho-2-methylimidazolide (2-MeImpG) in aqueous buffered solutions of various pH's was studied at 75 and 37 C, using spectrophotometric and HPLC techniques. The hydrolysis was found to be very slow even at low pH. At 75 C and pH at or below l.0, two kinetic processes were observed: the more rapid one was attributed to the hydrolysis of the phosphoimidazolide P-N bond; the second, much slower one, was attributed to the cleavage of the glycosidic bond. It is noted that the P-N hydrolysis in phosphoimidazolides is very slow compared to other phosphoramidates, and that this might be one of the reasons why the phosphoimidazolides showed an extraordinary ability to form long oligomers under template-directed conditions.

Kanavarioti, Anastassia↗
NASA NTRS1988

Applications of elastic-viscoplastic constitutive models in dynamic analyses of crack run-arrest events

Applications of nonlinear techniques to the first series of six HSST wide-plate crack-arrest tests that were performed are described. The experiments include crack initiations at low temperatures and relatively long (20 cm) cleavage propagation phases which are terminated by arrest in high temperature regions. Crack arrest are then followed by ductile tearing events. Consequently, the crack front regions are exposed to wide ranges of strain rates and temperatures.

Bass, B. R.↗
NASA NTRS1988

Structure of Southwestern Michipicoten Greenstone Belt, Ontario: Evidence for Archean accretion

The results of detailed mapping of a well exposed (by a large fume kill) Archean Michipicoten greenstone belt of Ontario is discussed. Numerous structural features are described including soft sediment deformation, thrust faults, isoclinal folds, and sill intrusion, which apparently formed prior to the earliest flattening cleavage. It was inferred that all of these events may have taken place before the rocks were completely lithified, and the question was raised as to whether early soft sediment and tectonic deformation were coeval. If so, the overall picture would permit (but not compel) recognition of a convergent oceanic environment such as an accretionary wedge or forearc basin.

Mcgill, George E.↗
NASA NTRS1987

The microstructure and tensile properties of extruded melt-spun ribbons of iron-rich B2 FeAl

The microstructure of extruded rods of iron-rich FeAl(B2-structure), as characterized by TEM, SEM, optical microscopy and x-ray diffractometry, consisted of elongated grains with a 111-line fibre texture containing a high dislocation density. Numerous oxide particles were found, mostly in lines which reflected the matrix flow during extrusion. In addition, some large inclusions were present. Tensile testing of annealed, relatively dislocation-free specimens as a function of increasing temperature found increasing ductility up to 900K, above which a ductility drop occurred accompanied by a change in fracture mode, from transgranular cleavage to intergranular fracture. The yield strength, which was independent of temperature up to 800K (at about 500MPa), also decreased rapidly as diffusion became more important. The predominant slip vector changed from 111-line to 100-line around 700K.

Baker, I.↗
NASA NTRS1988

Microdeformation in Vredefort rocks; evidence for shock metamorphism

Planar microdeformations in quartz from basement or collar rocks of the Vredefort Dome have been cited for years as the main microtextural evidence for shock metamorphism in this structure. In addition, Schreyer describes feldspar recrystallization in rocks from the center of the Dome as the result of transformation of diaplectic glass, and Lilly reported the sighting of mosaicism in quartz. These textural observations are widely believed to indicate either an impact or an internally produced shock origin for the Vredefort Dome. Two types of (mostly sub) planar microdeformations are displayed in quartz grains from Vredefort rocks: (1) fluid inclusion trails, and (2) straight optical discontinuities that sometimes resemble lamellae. Both types occur as single features or as single or multiple sets in quartz grains. Besides qualitative descriptions of cleavage and recrystallization in feldspar and kinkbands in mica, no further microtextural evidence for shock metamorphism at Vredefort has been reported to date. Some 150 thin sections of Vredefort basement rocks were re-examined for potential shock and other deformation effects in all rock-forming minerals. This included petrographic study of two drill cores from the immediate vicinity of the center of the Dome. Observations recorded throughout the granitic core are given along with conclusions.

Reimold, W. U.↗
NASA NTRS1988

The effect of hydrogen on the deformation and fracture of PWA 1480

The effect of internal hydrogen on mechanical properties and fracture behavior is studied in the single-crystal nickel-base superalloy PWA 1480. In particular, plane strain fracture toughness and tensile tests have been performed in hydrogen-free samples and hydrogen-gas phase-charged samples in two different sample orientations. The mechanical properties, as well as the fracture process, were found to be very dependent on orientation. Hydrogen did not affect the yield strength but reduced the uniform tensile elongation more than 75 percent. However, hydrogen reduced the tensile reduction-in-area and the fracture toughness by only 10 percent. Cleavage of the eutectic gamma-prime, as well as the role of hydrogen trapping, will be discussed. These results will be analyzed in terms of the effects that orientation, microstructure, and hydrogen have on the fracture process.

Walston, W. S.↗
NASA NTRS1990

Determination of the thermal stability of perfluoroalkylethers

The thermal decomposition temperatures of several commercial and custom synthesized perfluoroalkylether fluids were determined with a computerized tensimeter. In general, the decomposition temperatures of the commercial fluids were all similar and significantly higher than those for custom synthesized fluids. Correlation of the decomposition temperatures with the molecular structures of the primary components of the commercial fluids revealed that the stability of the fluids is not affected by intrinsic factors such as carbon chain length, branching, or cumulated difluoroformal groups. Instead, correlation with extrinsic factors revealed that the stability may be limited by the presence of small quantities of thermally unstable material and/or chlorine-containing material arising from the use of chlorine-containing solvents during synthesis. Finally, correlation of decomposition temperatures with molecular weights for Demnum and Krytox fluids supports a chain cleavage reaction mechanism for Demnum fluids and an unzipping reaction mechanism for Krytox fluids.

Helmick, Larry S.↗
NASA NTRS1990

The effect of hydrogen and microstructure on the deformation and fracture behavior of a single crystal nickel-base superalloy

A study was conducted on the effects of internal hydrogen and microstructure on the deformation and fracture of a single crystal nickel-base superalloy. In particular, room temperature plane strain fracture toughness and tensile tests were performed on hydrogen-free and hydrogen charged samples of PWA 1480. The role of microstructure was incorporated by varying the levels of porosity and eutectic gamma/gamma prime through hot isostatic pressing and heat treatment. The room temperature behavior of PWA 1480 was unusual because precipitate shearing was not the primary deformation mechanism at all strains. At strains over 1 percent, dislocations were trapped in the gamma matrix and an attempt was made to relate this behavior to compositional differences between PWA 1480 and other superalloys. Another unique feature of the tensile behavior was cleavage of the eutectic gamma/gamma prime, which is believed to initiate the failure process. Fracture occurred on (111) planes and is likely a result of shear localization along these planes. Elimination of the eutectic gamma/gamma prime greatly improved the tensile ductility, but pososity had no effect on tensile properties. Large quantities of hydrogen (1.74 at. percent) were gas-phase charged into the material, but surprisingly this was not a function of the amount of porosity or eutectic gamma/gamma prime present. Desorption experiments suggest that the vast majority of hydrogen is at reversible lattice trapping sites. This large, uniform concentration of hydrogen dramatically reduced the tensile strain to failure, but only slightly affected the reduction in area. Available hydrogen embrittlement models were examined in light of these results and it was found that the hydrogen enhanced localized plasticity model can explain much of the tensile behavior. K(IC) fracture toughness tests were conducted, but it was necessary to also perform J(IC) tests to provide valid data.

Walston, William S.↗