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Results for “CROSS COUPLING”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2026

Data for "Photoinduced Chemomimetic Biocatalysis for Enantioselective Intermolecular Radical Conjugate Addition"

Exploiting nature’s catalysts for non-natural transformations that are inaccessible to chemocatalysis is highly desirable but challenging. On the one hand, the widespread nicotinamide-dependent oxidoreductases have not been utilized for single-electron-transfer-induced bimolecular cross-couplings; on the other, the addition of catalytic asymmetric radical conjugate to terminal alkenes remains a challenge owing to strong racemic background reaction and unselective termination of prochiral radical species. Here we report a chemomimetic biocatalysitic approach for construction of alpha-carbonyl stereocentres via an unnatural intermolecular conjugate addition of N-(acyloxy)phthalimides-derived radicals with acceptor-substituted terminal alkenes, by combination of visible-light excitation and nicotinamide-dependent ketoreductases (KREDs). Based on protein crystal structure, we engineered KREDs via a semi-rational mutagenesis strategy to improve reaction outcomes with a small and high-quality variants library. Mechanistic investigations combining wet experiments, crystallographic studies and computational simulations demonstrate that the repurposed biocatalyst can suppress racemic background reaction and unselected side reactions, yielding enantioselectivity that is challenging to achieve by chemocatalysis.

Catalysis↗
DOE OSTI2025

Towards Cluster State Generation with Spatial Modes

We leverage spatial modes to generate multipartite entangled states in a cross-coupled SU(1,1) interferometer with intensity-difference squeezing of 4.2 dB. Theoretical analysis shows that the generated state can be converted to a cluster state.

Leger, Zacharie [ORNL] (ORCID:0000000179044775)↗
NASA NTRS1968

Multichip packaging with thermal insulation

Thermal insulation technique permits low and high power electronic chips to operate in the same package without thermal cross-coupling. An alumina glass shield thermally isolates the low power chip from the high power chip while Kovar substrate acts as a heat sink to remove heat from the high power chip.

Mc Inturff, R. G.↗
NASA NTRS1971

A study of human performance in a rotating environment

Consideration is given to the lack of sufficient data relative to the response of man to the attendant oculovestibular stimulations induced by multi-directional movement of an individual within the rotating environment to provide the required design criteria. This was done to determine the overall impact of artificial gravity simulations on potential design configurations and crew operational procedures. Gross locomotion and fine motor performance were evaluated. Results indicate that crew orientation, rotational rates, vehicle design configurations, and operational procedures may be used to reduce the severity of the adverse effects of the Coriolis and cross-coupled angular accelerations acting on masses moving within a rotating environment. Results further indicate that crew selection, motivation, and short-term exposures to the rotating environment may be important considerations for future crew indoctrination and training programs.

Green, J. A.↗
NASA NTRS1974

Fail-safe bidirectional valve driver

Cross-coupled diodes are added to commonly used bidirectional valve driver circuit to protect circuit and power supply. Circuit may be used in systems requiring fail-safe bidirectional valve operation, particularly in chemical- and petroleum-processing control systems and computer-controlled hydraulic or pneumatic systems.

Fujimoto, H.↗
NASA NTRS1972

Considerations for stability and control of V/STOL aircraft: A review of AGARD report 577

Revisions which have been made to previous V/STOL handling qualities requirments based on criteria are discussed. A discussion of the pilot's desire for a particular characteristic is given. In addition, data and reference material are provided to back up the proposed criteria to permit the user to understand the limitations of the data on which the criteria are based. A review is included of several controversial areas including pitch control sensitivity, static longitudinal stability, roll control power, roll-yaw cross coupling, and vertical flight path control.

Anderson, S. B.↗
NASA NTRS1972

A comparison of CMG steering laws for High Energy Astronomy Observatories (HEAOs)

A comparison of six selected control moment gyro steering laws for use on the HEAO spacecraft is reported. Basic equations are developed to project the momentum and torque of four skewed, single gimbal CMGs into vehicle coordinates. In response to the spacecraft attitude error signal, six algorithms are derived for controlling the CMG gimbal movements. HEAO performance data are obtained using each steering law and compared on the basis of such factors as accuracy, complexity, singularities, gyro hang-up and failure adaption. Moreover, each law is simulated with and without a magnetic momentum management system. The performance of any steering law is enhanced by the magnetic system. Without magnetics, the gimbal angles get large and there are significant differences in steering law performances due to cross coupling and nonlinearities. The performance of the pseudo inverse law is recommended for HEAO.

Davis, B. G.↗
NASA NTRS1972

Semicircular canals as a primary etiological factor in motion sickness.

Data are presented which support the view that the semicircular canals of humans can act as the essential factor for the production of motion sickness and the evocation of symptoms characteristic of this malady in the absence of 'motion.' Quantitative grading of acute symptoms demonstrated that motion sickness can be evoked by stimuli which are adequately provocative and unique for the canals. These results are compared with those of two provocative rotational tests that introduce Coriolis (cross-coupled angular acceleration) forces or generate a rotating linear acceleration vector. Wide interindividual differences but only slight intraindividual differences among the six provocative test conditions are revealed, indicating that individuals usually possess an overall susceptibility to motion which is relatively independent of its type. The fact that typical symptoms of motion sickness were also produced by bithermal irrigation of several subjects who represented a wide range of susceptibility adds to the evidence that semicircular canals can act as the primary etiological factor in this malady.

Miller, E. F., II↗
NASA NTRS1975

Low-loss, circularly-polarized dichroic plate

Dichroic plate has orthogonally-disposed, loaded dipole apertures with their orientations arranged so as to cancel cross-coupling effects which would otherwise result in power loss to circularly polarized signal.

Woo, R. T.↗
NASA NTRS1973

Concepts for a theoretical and experimental study of lifting rotor random loads and vibrations (the effects of some rotor feedback systems on rotor-body dynamics), Phase 7-A

The effects of three gyroless rotor feedback systems: (1) coning feedback, (2) proportional tilting feedback, and (3) a combination of these on the rotor-body dynamics of hingeless rotorcraft are studied with a simplified analytical model in the advance ratio range from 0 to .8. Combinations of feedback phase angles and control phase angles are selected to minimize control cross coupling and control sensitivity changes between low and high speed flight. For the feedback systems thus selected the effects of feedback gain and control actuator time lag on the stability both with fixed hub and in free flight is studied, whereby the rotorcraft is free in pitch, roll and vertical motion but otherwise restrained. For the free flight is studied, whereby the rotorcraft is free in pitch, roll and vertical motion but otherwise restrained. For the free flight conditions the effects of a horizontal tail are also determined in itself and in combination with the rotor feedback systems.

Hohenemser, K. H.↗
NASA NTRS1973

Dynamic stability testing of aircraft - Needs versus capabilities

Highlights of a recent survey of the future needs for dynamic stability information for such aerospace vehicles as the Space Shuttle and advanced high-performance military aircraft, indicating the importance of obtaining this information for high-angle-of-attack high-Reynolds-number conditions. A review of the wind-tunnel capabilities in North America for measuring dynamic stability derivatives reveals an almost total lack of such capabilities for Mach numbers above 0.1 at angles of attack higher than 25 deg. In addition, capabilities to obtain certain new cross-coupling derivatives and information on effects of the coning motion are almost completely lacking. Recommendations are made regarding equipment that should be constructed to remedy this situation.

Orlik-Rueckemann, K. J.↗
NASA NTRS1973

A novel triaxial vibration test technique

The present work examines the circumstances under which simultaneous multiaxial vibration testing may be desirable, the testing techniques and equipment required to make it feasible, and the type of results that may be obtained together with some practical limitations to the techniques. Two schemes for performing vibration testing simultaneously or sequentially along three mutually perpendicular axes are considered and the most promising, involving a 'floating' technique, is presented in some detail. Practical problems associated with jig design and system resonances, cross-coupling between the various degrees of freedom, secondary loads on shaker elements, and system drift, are considered and workable solutions proposed. A simple simulation of multiaxial testing of a 1.1-pound inertia-simulated model of an Apollo command module is presented.

Wignot, J. E.↗
NASA NTRS1974

Reaction control system plume flow field interaction effects on the Space Shuttle orbiter

This paper presents an analysis of data obtained from wind tunnel tests of the aerodynamic interference induced by the reaction control system jets on Space Shuttle orbiter configurations. The test data was obtained using cold gas simulation techniques with nozzles scaled to match jet exit momentum ratio as the primary parameter at Mach numbers from 2.5 to 10. Significant induced effects have been found that degrade the performance of the pitch and roll reaction controls and that induce cross-coupling effects for yaw reaction control. Analysis of the induced data shows good correlation with jet exit momentum ratio.

Rausch, J. R.↗
NASA NTRS1975

Polarization tracking of a partially coherent signal using a double loop

We consider the problem of simultaneously estimating the phase and polarization angles of a linearly polarized electromagnetic wave. The solution of this problem has applications to space communications and ionospheric probing. The nonlinear stochastic characteristics of a cross-coupled double-loop implementation for the tracker are evaluated using the multidimensional Fokker-Planck equation. The exact stationary probability density is found for a special case of equal signal-to-noise ratio (SNR) in the two loops. The stationary probability density is obtained for a general class of double loops when the two loop bandwidths differ greatly.

Ohlson, J. E.↗
NASA NTRS1975

Space shuttle orbiter reaction control system jet interaction study

The space shuttle orbiter has forward mounted and rear mounted Reaction Control Systems (RCS) which are used for orbital maneuvering and also provide control during entry and abort maneuvers in the atmosphere. The effects of interaction between the RCS jets and the flow over the vehicle in the atmosphere are studied. Test data obtained in the NASA Langley Research Center 31 inch continuous flow hypersonic tunnel at a nominal Mach number of 10.3 is analyzed. The data were obtained with a 0.01 scale force model with aft mounted RCS nozzles mounted on the sting off of the force model balance. The plume simulations were accomplished primarily using air in a cold gas simulation through scaled nozzles, however, various cold gas mixtures of Helium and Argon were also tested. The effect of number of nozzles was tested as were limited tests of combined controls. The data show that RCS nozzle exit momentum ratio is the primary correlating parameter for effects where the plume impinges on an adjacent surface and mass flow ratio is the parameter where the plume interaction is primarily with the external stream. An analytic model of aft mounted RCS units was developed in which the total reaction control moments are the sum of thrust, impingement, interaction, and cross-coupling terms.

Rausch, J. R.↗