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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1992

Origin and evolution of planetary atmospheres

This report concerns several research tasks related to the origin and evolution of planetary atmospheres and the large-scale distribution of volatile elements in the Solar System. These tasks and their present status are as follows: (1) we have conducted an analysis of the volatility and condensation behavior of compounds of iron, aluminum, and phosphorus in the atmosphere of Venus in response to publish interpretations of the Soviet Venera probe XRF experiment data, to investigate the chemistry of volcanic gases, injection of volatiles by cometary and asteroidal impactors, and reactions in the troposphere; (2) we have completed and are now writing up our research on condensation-accretion modeling of the terrestrial planets; (3) we have laid the groundwork for a detailed study of the effects of water transport in the solar nebula on the bulk composition, oxidation state, and volatile content of preplanetary solids; (4) we have completed an extensive laboratory study of cryovolcanic materials in the outer solar system; (5) we have begun to study the impact erosion and shock alteration of the atmosphere of Mars resulting from cometary and asteroidal bombardment; and (6) we have developed a new Monte Carlo model of the cometary and asteroidal bombardment flux on the terrestrial planets, including all relevant chemical and physical processes associated with atmospheric entry and impact, to assess both the hazards posed by this bombardment to life on Earth and the degree of cross-correlation between the various phenomena (NO(x) production, explosive yield, crater production, iridium signature, etc.) that characterize this bombardment. The purpose of these investigations has been to contribute to the developing understanding of both the dynamics of long-term planetary atmosphere evolution and the short-term stability of planetary surface environments.

Lewis, John S.↗
NASA NTRS1984

Planetary geomorphology field studies: Iceland and Antarctica

Field studies of terrestrial landforms and the processes that shape them provide new directions to the study of planetary features. These studies, conducted in Iceland and in Antarctica, investigated physical and chemical weathering mechanisms and rates, eolitan processes, mudflow phenomena, drainage development, and catastrophic fluvial and volcanic phenomena. Continuing investigations in Iceland fall in three main catagories: (1) catastrophic floods of the Jokulsa a Fjollum, (2) lahars associated with explosive volcanic eruptions of Askja caldera, and (3) rates of eolian abrasion in cold, volcanic deserts. The ice-free valleys of Antarctica, in particular those in South Victoria Land, have much is common with the surface of Mars. In addition to providing independent support for the application of the Iceland findings to consideration of the martian erosional system, the Antarctic observations also provide analogies to other martian phenomena. For example, a family of sand dunes in Victoria Valley are stabilized by the incorporation of snow as beds.

Malin, M. C.↗
NASA NTRS1980

Thermal history, chemical composition and relationship of comets to the origin of life

The role of thermal processes in determining the chemical composition of comets is considered, and implications of possible cometary constituents for the origin and evolution of life on earth are discussed. It is shown that the inclusion of short-lived Al-26 from a nearby supernova explosion into cometary nuclei could lead to comets with surfaces cool enough to retain H2O and interiors warm enough for thermal processing to occur, with the production of complex organic molecules such as amino acids and nucleic acid bases. It is thus suggested that comets may have played a part in seeding the primitive earth with biological polymers capable of self-replication or of evolving towards that capability, and may even be responsible for the subsequent introduction of organic material capable of infecting already existing cells.

Irvine, W. M.↗
NASA NTRS1950

On the theory of the propagation of detonation in gaseous systems

The existing theory of detonation is critically examined. It is shown that the considerations with which the steady value of the velocity of detonation is chosen are not convincing. In connection with the problem of the process of the chemical reaction in a detonation wave, the objections raised against the conceptions of Le Chatelier and Vieille of the 19th century with regard to the ignition of the gas by the shock wave are refuted. On the basis of this concept, it is possible to give a rigorous foundation for the existing method of computing the detonation velocity. The distributions of the temperature, the pressure, and the velocity in the detonation wave front as the chemical reaction proceeds, are considered. On the assumption of the absence of losses, the pure compression of the gas in the shock wave at the start of the chemical reaction develops a temperature that is near the temperature of combustion of the given mixture at constant pressure.

THEORIES - DETONATION WAVES↗
NASA NTRS1981

Measurements of nitric oxide after a nuclear burst

Measurements of ozone and nitric oxide in a nuclear cloud 7 days after the explosion are reported. No measurable increase above ambient density of either ozone or nitric oxide was found. Results from a chemistry model of the cloud do not agree with the measurement unless 'nonstandard' assumptions are made with regard to the operating chemical processes. A number of possible explanations of the results are discussed.

Mcghan, M.↗
NASA NTRS2006

Intelligent Chemical Sensor Systems for In-space Safety Applications

Future in-space and lunar operations will require significantly improved monitoring and Integrated System Health Management (ISHM) throughout the mission. In particular, the monitoring of chemical species is an important component of an overall monitoring system for space vehicles and operations. For example, in leak monitoring of propulsion systems during launch, inspace, and on lunar surfaces, detection of low concentrations of hydrogen and other fuels is important to avoid explosive conditions that could harm personnel and damage the vehicle. Dependable vehicle operation also depends on the timely and accurate measurement of these leaks. Thus, the development of a sensor array to determine the concentration of fuels such as hydrogen, hydrocarbons, or hydrazine as well as oxygen is necessary. Work has been on-going to develop an integrated smart leak detection system based on miniaturized sensors to detect hydrogen, hydrocarbons, or hydrazine, and oxygen. The approach is to implement Microelectromechanical Systems (MEMS) based sensors incorporated with signal conditioning electronics, power, data storage, and telemetry enabling intelligent systems. The final sensor system will be self-contained with a surface area comparable to a postage stamp. This paper discusses the development of this "Lick and Stick" leak detection system and it s application to In-Space Transportation and other Exploration applications.

Hunter, G. W.↗
NASA NTRS1999

Simulation of Unsteady Hypersonic Combustion Around Projectiles in an Expansion Tube

The temporal evolution of combustion flowfields established by the interaction between wedge-shaped bodies and explosive hydrogen-oxygen-nitrogen mixtures accelerated to hypersonic speeds in an expansion tube is investigated. The analysis is carried out using a fully implicit, time-accurate, computational fluid dynamics code that we developed recently for solving the Navier-Stokes equations for a chemically reacting gas mixture. The numerical results are compared with experimental data from the Stanford University expansion tube for two different gas mixtures at Mach numbers of 4.2 and 5.2. The experimental work showed that flow unstart occurred for the Mach 4.2 cases. These results are reproduced by our numerical simulations and, more significantly, the causes for unstart are explained. For the Mach 5.2 mixtures, the experiments and numerical simulations both produced stable combustion. However, the computations indicate that in one case the experimental data were obtained during the transient phase of the flow; that is, before steady state had been attained.

Yungster, S.↗
NASA NTRS1982

Magma vesiculation and pyroclastic volcanism on Venus

Theoretical consideration of the magma vesiculation process under observed and inferred venusian surface conditions suggests that vesicles should form in basaltic melts, especially if CO2 is the primary magmatic volatile. However, the high surface atmospheric pressure (about 90 bars) and density on Venus retard bubble coalescence and disruption sufficiently to make explosive volcanism unlikely. The products of explosive volcanism (fire fountains, convecting eruption clouds, pyroclastic flows, and topography-mantling deposits of ash, spatter, and scoria) should be rare on Venus, and effusive eruptions should dominate. The volume fraction of vesicles in basaltic rocks on Venus are predicted to be less than in chemically similar rocks on earth. Detection of pyroclastic landforms or eruption products on Venus would indicate either abnormally high volatile contents of Venus magmas (2.5-4 wt%) or different environmental conditions (e.g., lower atmospheric pressure) in previous geologic history.

Garvin, J. B.↗
NASA NTRS1972

Design, testing, fabrication and launch support of a liquid chemical barium release payload (utilizing the liquid fluorine-barium salt/hydrazine system)

A payload was designed which included a cryogenic oxidizer tank, a fuel tank, and burner section. Release of 30 lb of chemicals was planned to occur in 2 seconds at the optimum oxidizer to fuel ratio. The chemicals consisted of 17 lb of liquid fluorine oxidizer and 13 lb of hydrazine-barium salt fuel mixture. The fuel mixture was 17% barium chloride, 16% barium nitrate, and 67% hydrazine, and contained 2.6 lb of available barium. Two significant problem areas were resolved during the program: explosive valve development and burner operation. The release payload was flight tested, from Wallops Island, Virginia. The release took place at an altitude of approximately 260 km. The release produced a luminous cloud which expanded very rapidly, disappearing to the human eye in about 20 seconds. Barium ion concentration slowly increased over a wide area of sky until measurements were discontinued at sunrise (about 30 minutes).

Stokes, C. S.↗
NASA NTRS1991

Ionizable-Substance Detector

Device that includes all conventional components of fuel cell and electrolyzer continuously monitors concentration of ionizable substance in stream of fluid without significantly disrupting flow or chemical composition. Among substances monitored are hydrogen, sodium, fluorine, chlorine, oxygen, and bromine. Useful in early detection of fluctuations, malfunctions, or hazards. Particularly useful for detecting hydrogen in stream of water in closed system containing oxygen, wherein concentration of hydrogen must not exceed given maximum, lest hydrogen react explosively with oxygen. Also used to monitor exhaust stream to comply with environmental-protection requirements.

Mcelroy, William↗
NASA NTRS2003

Explosion Welding for Hermetic Containerization

A container designed for storing samples of hazardous material features a double wall, part of which is sacrificed during an explosion-welding process in which the container is sealed and transferred to a clean environment. The major advantage of this container sealing process is that once the samples have been sealed inside, the outer wall of what remains of the container is a clean surface that has not come into contact with the environment from which the samples were taken. Thus, there is no need to devise a decontamination process capable of mitigating all hazards that might be posed by unanticipated radioactive, chemical, and/or biological contamination of the outside of the container. The container sealing method was originally intended to be used to return samples from Mars to Earth, but it could also be used to store samples of hazardous materials, without the need to decontaminate its outer surface. The process stages are shown. In its initial double-wall form, the volume between the walls is isolated from the environment; in other words, the outer wall (which is later sacrificed) initially serves to protect the inner container from contamination. The sample is placed inside the container through an opening at one end, then the container is placed into a transfer dock/lid. The surfaces that will be welded together under the explosive have been coated with a soft metallic sacrificial layer. During the explosion, the sacrificial layer is ejected, and the container walls are welded together, creating a strong metallic seal. The inner container is released during the same event and enters the clean environment.

Dolgin, Benjamin↗
NASA NTRS1995

Models of Fallback

The impact of a typical Shoemaker-Levy 9 fragment produced three light peaks as seen from Earth. The first peak is related to the entry of the fragment into the jovian atmosphere. The second peak occurs when the exploding fireball rises above Jupiter's limb into direct view from Earth. The third peak, much the brightest, occurs when the ejecta plume falls back on the atmosphere. Here we present a simple, highly idealized model of a ballistic plume, which we then use to fit the observed light curve of the R impact as recorded at Mauna Kea and Mt.Palomar. The nominal R fragment has diameter 500 m and mass 3x10(sup)13 g, with energy release of 5x10(sup)26 ergs. The largest events were about three times more energetic. These sizes agree with those deduced by Ashaug and Benz from the dynamics of tidal disruption. Chemical products of the reentry shock included the sulfur compounds S2, CS, and CS2. These were emplaced very high in the atmosphere (ca. 100 microbars). The yield of the reduced compounds CS and CS2, coupled with the apparent absence of the oxidized compounds SO and SO2, indicate that the explosions occurred above the jovian water clouds.

Zahnle, Kevin↗
NASA NTRS2004

A Million-Second Chandra View of Cassiopeia A

We introduce a million-second observation of the supernova remnant Cassiopeia A with the Chandra X-ray Observatory. The bipolar structure of the Si-rich ejecta (NE jet and SW counterpart) is clearly evident in the new images, and their chemical similarity is confirmed by their spectra. These are most likely due to jets of ejecta as opposed to cavities in the circumstellar medium, since we can reject simple models for the latter. The properties of these jets and the Fe-rich ejecta will provide clues to the explosion of Cas A.

Hwang, Una↗
NASA NTRS1973

Chemical reactivity of hydrogen, nitrogen, and oxygen atoms at temperatures below 100 k

The synthesis of unusual compounds by techniques employing cryogenic cooling to retard their very extreme reactivity was investigated. Examples of such species that were studied are diimide (N2H2), cyclobutadiene (C4H4), cyclopropanone (C3H4O), oxirene (C2H2O), and many others. Special purpose cryogenically cooled inlet arrangements were designed such that the analyses incurred no warm-up of the cold, and frequently explosively unstable, compounds. Controlled energy electron impact techniques were used to measure critical potentials and to develop the molecular energetics and thermodynamics of these molecules and to gain some insight into their kinetic characteristics as well. Three and four carbon strained ring molecules were studied. Several reactions of oxygen and hydrogen atoms with simple molecules of H, N, C, and O in hard quench configurations were studied. And the quench stabilization of BH3 was explored as a model system in cryochemistry.

Mcgee, H. A., Jr.↗
NASA NTRS1995

Helmet-Mounted Display Of Clouds Of Harmful Gases

Proposed helmet-mounted opto-electronic instrument provides real-time stereoscopic views of clouds of otherwise invisible toxic, explosive, and/or corrosive gas. Display semitransparent: images of clouds superimposed on scene ordinarily visible to wearer. Images give indications on sizes and concentrations of gas clouds and their locations in relation to other objects in scene. Instruments serve as safety devices for astronauts, emergency response crews, fire fighters, people cleaning up chemical spills, or anyone working near invisible hazardous gases. Similar instruments used as sensors in automated emergency response systems that activate safety equipment and emergency procedures. Both helmet-mounted and automated-sensor versions used at industrial sites, chemical plants, or anywhere dangerous and invisible or difficult-to-see gases present. In addition to helmet-mounted and automated-sensor versions, there could be hand-held version. In some industrial applications, desirable to mount instruments and use them similarly to parking-lot surveillance cameras.

Diner, Daniel B.↗
NASA NTRS1983

A comparison of volcanic eruption processes on earth, moon, Mars, Io and Venus

The physical, chemical, and atmospheric characteristics of the silicate planets and satellites are surveyed in terms of their effects on the volcanic evolution of the surfaces of these bodies. The equations relating the parameters affecting magma ascent through the crust and eruption are analyzed, and three major types of eruption are characterized: effusive, steady explosive, and unsteady explosive. This analytical framework is then used to predict the nature of volcanic activity on each of the planets and satellites, and the predictions are compared with actual observations. Outstanding problems are discussed, with emphasis on the need for a general model of planetary interior dynamics applicable to bodies with varying degrees of interior viscosity, mantle activity, and lithospheric plate tectonics.

Wilson, L.↗
NASA NTRS1990

Explosive nucleosynthesis in SN 1987A. II - Composition, radioactivities, and the neutron star mass

The 20 solar mass model of Nomoto and Hashimoto (1988) is utilized with a 6 solar mass. He core is used to perform explosive nucleosynthesis calculations. The employed explosion energy of 10 to the 51st ergs lies within the uncertainty range inferred from the bolometric light curve. The nucleosynthesis processes and their burning products are discussed in detail. The results are compared with abundances from IR observations of SN 1987A and the average nucleosynthesis expected for Type II supernovae in Galactic chemical evolution. The abundances of long-lived radioactive nuclei and their importance for the late light curve and gamma-ray observations are predicted. The position of the mass cut between the neutron star and the ejecta is deduced from the total amount of ejected Ni-56. This requires a neutron star with a baryonic mass of 1.6 + or - 0.045 solar mass, which corresponds to a gravitational mass of 1.43 + or - 0.05 solar mass after subtracting the binding energy of a nonrotating neutron star.

Thielemann, Friedrich-Karl↗
NASA NTRS1988

The theory of gamma-ray emergence in supernova 1987A

It was anticipated that the decay of Co-56 to Fe-56 in SN1987A would give rise to detectable gamma-ray emission at 847 and 1238 keV with a peak flux of 0.001 photon/sq cm/s about one year after the explosion. Both these lines were detected in August, with a strength within a factor of two of 0.001 photon/sq cm/s, but about six months earlier than predicted. It is shown here that the early emergence of gamma-rays can be accounted for in a 'mixed' model in which an approximately isotropic process destroys chemical segregation with respect to radial mass coordinate and velocity.

Pinto, Philip A.↗