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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

TPSAS-NF1676L-16824-DND

The Atmospheric Science Data Center (ASDC) at NASA Langley Research Center is responsible for the ingest, archive, and distribution of NASA Earth Science data in the areas of radiation budget, clouds, aerosols, and tropospheric chemistry. Currently, the ASDC supports more than 44 projects and has over 1,700 archived data sets, which increase daily. The ASDC?s implementation mission with iRODS is to establish a consolidated, shared services capability that will provide higher quality, more cost effective and efficient services, and greater access to our current science community users and future diverse customers.

Tiffany Mathews↗

Recent Advances in High Altitude Pseudosatellites (HAPS) and Potential Roles in Future Earth Observing Systems

In August 2001 the NASA Environmental Research Aircraft and Sensor Technology (ERAST) Program flew the Helios aircraft to an altitude of nearly 100,000ft, demonstrating a new type of remote sensing platform. Nearly 20 years later the earth science community has unmet observational requirements to loiter over regions of interest for days or weeks as well as to follow airmasses to study chemistry and dynamics in concert with spaceborne observations. Recent advances in materials science and engineering have enabled improved battery power density, solar panel efficiency, and light yet strong structural materials required to effectively operate high-altitude (50-70k ft altitude) Pseudo-Satellites (HAPS) for 30+ days. The rapid commercialization of small unmanned aircraft has also contributed to the maturation of HAPS by making avionics, GPS, and other sub-systems smaller and less expensive. HAPS payloads provide high-resolution data that complement geostationary and polar orbiting satellites, while also enabling in-situ sampling of atmospheric chemistry and dynamics. Recent commercial interest in HAPS for 4G/5G and WIFI has funded development of a new generation of aircraft available to the science community. Here I report on a project under the NASA Airborne Science Program to test and demonstrate earth observations from a prototype aircraft being developed under a NASA Small Business Innovative Research Phase II. This aircraft will demonstrate the ability for a solar electric aircraft to deliver a 2u cubesat-based passive optical imaging satellite to 70,000ft for 30 or more days. Discussion will include the anticipated maturation timeline for HAPS, development and operational challenges, and examples of mission concepts that might contribute to future earth observing systems.

Helios aircraft↗

In-situ exploration of Venus on a global scale : direct measurements of origins and evolution, meterology, dynamics, and chemistry by a long-duration aerial science station

Drifting in the strong winds of Venus under benign Earth-like temperature and pressure conditions, an instrumented balloon-borne science station presents a viable means to explore, in-situ, the Venusian atmosphere on a global scale. Flying over the ground at speeds exceeding 240 km/hour while floating in the Venusian skies near 55 km altitude for several weeks, such an aerostat can conduct a 'world tour' of our neighboring planet, as it circumnavigates the globe multiple times during its flight from equatorial to polar latitudes. Onboard science sensors can repeatedly and directly sample gas compositions, atmospheric pressures and temperatures and cloud particle properties, giving unprecedented insight into the chemical processes occurring within the sulfuric clouds. Additionally, interferometric tracking via Earth-based radio observatories can yield positions and windspeeds to better than 10 cm/sec over one-hour periods, providing important information for understanding the planet's meridional circulation and enigmatic zonal super-rotation, as well as local dynamics associated with meteorological processes. As well, hundreds of GCMS spectra collected during the flight can provide measurements of noble gas compositions and their isotopes with unprecedented accuracy, thereby enabling fundamental new insights into Venus's origin and evolution.

Venus↗

STS-107 Mission after the Mission: Recovery of Data from the Debris of Columbia

STS-107 was a 16-day, dedicated research mission that included over 80 experiments, spanning many disciplines including biology, physics, chemistry, and earth sciences, including many student experiments. The mission was considered a resounding success until February 1, 2003, when tragedy struck the Columbia and her crew as she re-entered the atmosphere over Texas. During the mission, approximately one third of the overall data was obtained but much more was stored in the flight hardware systems. This paper documents a new set of STS-107 experiment objectives, a "mission after the mission," in which several experiment teams attempted, and, in many cases succeeded, to recover data from their flight hardware, now debris. A description of the data recovery efforts is included for these five experiment facilities: Combustion Module-2, Critical Viscosity of Xenon-2, Commercial Instrumentation Technology Associates Biomedical Experiments-2, Biological Research in Canisters-14, and Commercial Protein Crystal Growth.

Over, A. P.↗

ATMOS: Long term atmospheric measurements for mission to planet Earth

A long-term, space-based measurement program, together with continued balloon and aircraft-borne investigations, is essential to monitor the predicted effects in the atmosphere, to determine to what extent the concentration measurements agree with current models of stratospheric chemistry, and to determine the condition of the ozone layer. The Atmospheric Trace Molecule Spectroscopy (ATMOS) Experiment is currently making comprehensive, global measurements of Earth's atmosphere as part of the Atmospheric Laboratory for Applications and Science (ATLAS) program on the Space Shuttle. Part of NASA's Mission to Planet Earth, ATLAS is a continuing series of missions to study Earth and the Sun and provide a more fundamental understanding of the solar influences on Earth's atmosphere. The ATMOS program, instruments, and science results are presented.

Source record↗

Global-to-local air quality forecasts using the NASA GEOS Composition Forecast System

Since 2019, the NASA Global Earth Observing System (GEOS) model has been used to generate global, near-real-time estimates and daily five-day forecasts of atmospheric composition at a horizontal resolution of 0.25 degrees (~25 km) from the surface up to the lower mesosphere. This composition forecast system (“GEOS-CF”) combines the GEOS weather forecasting model with the state-of-the-science GEOS-Chem chemistry module to deliver detailed analysis of a wide range of air pollutants, including the policy-relevant species such as ozone, carbon monoxide, nitrogen oxides, sulfur dioxide and fine particulate matter (PM2.5). Because GEOS-CF includes atmospheric levels up through the stratosphere, this system has been leveraged to support the Tropospheric Emissions: Monitoring of Pollution (TEMPO) satellite mission and provide stratospheric intrusion alerts to ground-based monitoring stations. We will present recent advances to GEOS-CF which target increased computational efficiency and accuracy. These include the incorporation of simplified chemistry mechanisms to accelerate model forecasts, use of model-observation data fusion techniques to provide highly localized forecasts, and assimilation of satellite observations to produce more accurate model analyses. We further discuss our attempts to make these tools publicly available on platforms outside the NASA domain, such as Google Earth Engine and Amazon Web Services with the goal to facilitate the integration of state-of-the-science air quality information onto platforms used by stakeholders, air quality managers, and the public.

Emma Knowland↗

A Panchromatic Imaging Fourier Transform Spectrometer for the NASA Geostationary Coastal and Air Pollution Events Mission

This paper summarizes the design and development of the Panchromatic Imaging Fourier Transform Spectrometer (PanFTS) for the NASA Geostationary Coastal and Air Pollution Events (GEO-CAPE) Mission. The PanFTS instrument will advance the understanding of the global climate and atmospheric chemistry by measuring spectrally resolved outgoing thermal and reflected solar radiation. With continuous spectral coverage from the near-ultraviolet through the thermal infrared, this instrument is designed to measure pollutants, greenhouse gases, and aerosols as called for by the U.S. National Research Council Decadal Survey; Earth Science and Applications from Space: National Imperatives for the Next Decade and Beyond1. The PanFTS instrument is a hybrid instrument based on spectrometers like the Tropospheric Emissions Spectrometer (TES) that measures thermal emission, and those like the Orbiting Carbon Observatory (OCO), and the Ozone Monitoring Instrument (OMI) that measure scattered solar radiation. Simultaneous measurements over the broad spectral range from IR to UV is accomplished by a two sided interferometer with separate optical trains and detectors for the ultraviolet-visible and infrared spectral domains. This allows each side of the instrument to be independently optimized for its respective spectral domain. The overall interferometer design is compact because the two sides share a single high precision cryogenic optical path difference mechanism (OPDM) and metrology laser as well as a number of other instrument systems including the line-of-sight pointing mirror, the data management system, thermal control system, electrical system, and the mechanical structure. The PanFTS breadboard instrument has been tested in the laboratory and demonstrated the basic functionality for simultaneous measurements in the visible and infrared. It is set to begin operations in the field at the California Laboratory for Atmospheric Remote Sensing (CLARS) observatory on Mt. Wilson measuring the atmospheric chemistry across the Los Angeles basin. Development has begun on a flight size PanFTS engineering model (EM) that addresses all critical scaling issues and demonstrates operation over the full spectral range of the flight instrument which will show the PanFTS instrument design is mature.

Imaging spectrometer(↗

Data and scripts associated with "Coupled primary production and respiration in a large river contrasts with smaller rivers and streams."

This data package is associated with the publication "Coupled primary production and respiration in a large river contrasts with smaller rivers and streams." in review at Limnology and Oceanography (Roley et al. 2023). This study focuses on understanding ecosystem metabolism for the Hanford Reach of the Columbia River in Washington state, a free-flowing stretch with a substantial discharge. Large rivers have been overlooked compared to small and medium rivers due to the challenges associated with measurements. Our study presents novel ways to address these challenges and highlights that metabolism patterns in large rivers differ from those observed in small-medium rivers and requires the application of knowledge and tools beyond those implemented for smaller rivers.This data package includes the data and R scripts for the analyses described in Roley et al. 2023. It includes dissolved oxygen and temperature data from a dissolved oxygen HOBO sensor, light data collected from the National Solar Radiation Database (https://nsrdb.nrel.gov/) and hydrologic variables estimated from the MASS-1 model (Niehus et al.; 2014). It also includes metabolism estimates (gross primary production, ecosystem respiration, and net ecosystem production) estimated via streamMetabolizer (Appling et al.; 2018). All analyses in the paper can be replicated with these data and scripts.The data package is comprised of one main data folder. The folder includes (1) file-level metadata (flmd); (2) a data dictionary (dd) for each data file; (3) data files; and (4) R scripts for metabolism estimates and data analysis. All files are .R, .csv, or .pdf.

54 ENVIRONMENTAL SCIENCES↗

A network of soil moisture, soil temperature, air temperature, net radiation, ground heat flux and ground water for Chicago, Illinois

This dataset contains environmental monitoring data collected using solar-powered Multi-Function Research (MFR) Long Range Wide Area (LoRaWAN)-enabled nodes at 11 sites in Chicago, Illinois, as part of the DOE Urban Integrated Field Lab CROCUS project. The MFR node system consists of an Input/Output Digital Input Module (IB8) interface box (ICT International) providing wired connections for environmental sensors and an MFR-Node-L data logger that manages power, data processing, and LoRaWAN communication. The wireless data are ingested via Sage network (https://sagecontinuum.org/) nodes that contain LoRaWAN antennae. Measurements were collected from 11 MFR nodes deployed across Chicago State University (CSU), Northeastern Illinois University (NEIU), Northwestern University (NU), University of Illinois Chicago (UIC), West Woodlawn "Blacks in Green" (BIG), and Indian Boundary Prairies (IBP). Each MFR node supports a consistent suite of sensors measuring atmospheric, soil, and hydrological variables. Atmospheric measurements include 2m air temperature (°C), 2m vapor pressure deficit (kPa), and 2m shortwave/longwave radiation (incoming and outgoing, W/m²) measured using ATH-VPD and Apogee SN500 sensors. Soil measurements include volumetric water content (VWC, %) and temperature (°C) at four depths (15, 30, 45, and 60 cm below surface) using Meter Teros54 sensors, and heat flux (W/m²) at 10 cm depth using Huske HFP01-05 sensors. At selected locations, Meter Hydros21 sensors measure groundwater depth (mm), specific conductivity (dS/m), and temperature (°C). The dataset includes timestamps, site identifiers with location names, device IDs, Global Positioning System (GPS) coordinates, variable names with units, measurement depths, values, sensor names, and Sage node identifiers. All timestamps are in local Chicago time (CDT/CST). Quality control flags are provided using a 6-bit binary system indicating physical range violations, step spikes, 24-hour flat-line conditions, 6-hour jitter, 7-day ultra-low variance, and persistent high offset. Data is provided in CSV and CF-compliant NetCDF formats. This dataset is part of a larger collection of CROCUS environmental monitoring data, including linked datasets from Air Quality Transmitter (AQT) sensors, Weather Transmitter (WXT) sensors, and Sap Flow Meter (SFM1x) sensors.

Chicago↗

Future Orbiting and In-Situ Exploration of Venus: Mount Etna as Terrestrial Analog

The exploration of Venus will soon experience a new golden era thanks to the recently selected NASA Deep Atmosphere of Venus Investigation of Noble gases, Chemistry and Imaging (DAVINCI) mission, NASA Venus Emissivity, Radio Science, InSAR, Topography & Spectroscopy (VERITAS) mission, and ESA EnVision mission. The DAVINCI mission will focus on the analysis of the the atmospheric vertical structure and composition of Earth’s twin planet and on the geologic structure of a tesserae terrain. The VERITAS mission will investigate the geologic features of its surface as well as geodynamic characteristics of the subsurface, providing high-resolution emissivity data, a global radar map at an approximate resolution of 30 meters/pixel, and estimation of the gravity anomaly of the shallow crust of the planet. The ESA EnVision mission will be complementary to the two NASA missions, providing high resolution 0.8-2.5 micron emissivity data, Synthetic Aperture Radar (SAR) data, and Subsurface Radar Sounder (SRS) data. Beyond those, the proposed Roscosmos-NASA Venera-D mission will also be equipped with an orbiter that will investigate the atmospheric composition and circulation, as well as a lander that will analize the in-situ chemical composition and the surface-atmosphere interactions.

P. D’Incecco↗

NIAC Phase 1 Final Study Report on Titan Aerial Daughtercraft

Saturns giant moon Titan has become one of the most fascinating bodies in the Solar System. Even though it is a billion miles from Earth, data from the Cassini mission reveals that Titan has a very diverse, Earth-like surface, with mountains, fluvial channels, lakes, evaporite basins, plains, dunes, and seas [Lopes 2010] (Figure 1). But unlike Earth, Titans surface likely is composed of organic chemistry products derived from complex atmospheric photochemistry [Lorenz 2008]. In addition, Titan has an active meteorological system with observed storms and precipitation-induced surface darkening suggesting a hydrocarbon cycle analogous to Earths water cycle [Turtle 2011].Titan is the richest laboratory in the solar system for studying prebiotic chemistry, which makes studying its chemistry from the surface and in the atmosphere one of the most important objectives in planetary science [Decadal 2011]. The diversity of surface features on Titan related to organic solids and liquids makes long-range mobility with surface access important [Decadal 2011]. This has not been possible to date, because mission concepts have had either no mobility (landers), no surface access (balloons and airplanes), or low maturity, high risk, and/or high development costs for this environment (e,g. large, self-sufficient, long-duration helicopters). Enabling in situ mobility could revolutionize Titan exploration, similarly to the way rovers revolutionized Mars exploration. Recent progress on several fronts has suggested that small-scale rotorcraft deployed as daughtercraft from a lander or balloon mothercraft may be an effective, affordable approach to expanding Titan surface access. This includes rapid progress on autonomous navigation capabilities of such aircraft for terrestrial applications and on miniaturization, driven by the consumer mobile electronics market, of high performance of sensors, processors, and other avionics components needed for such aircraft. Chemical analysis, for example with a mass spectrometer, will be important to any Titan surface mission. Anticipating that it may be more practical to host chemical analysis instruments on a mothership than a daughtercraft, we defined system and mission concepts that deploy a small rotorcraft, termed a Titan Aerial Daughtercraft (TAD), from a lander or balloon to perform high-resolution imaging and mapping, potentially land to acquire microscopic images or other in situ measurements, and acquire samples to return to analytical instruments on the mothership. In principle, the ability to recharge batteries in TAD from a radioisotope or other long-lived power source on the mothership could enable multiple sorties. For a lander-based mission, a variety of landing sites is conceivable, including near lake margins, in dry lake beds, or in regions of plains, dunes, or putative cryovolanic or impact melt features. Such missions may require landing with greater precision than in previous missions (Huygens) and mission studies; this could also enhance the ability of TAD to reach interesting terrain from the landing site. Precision descent may also benefit balloon missions, with or without a daughtercraft, by increasing the probability that the balloon will drift over desired terrain early in its mission. Given these potential benefits, the overall concept studied here includes brief consideration of precision descent for landing or balloon deployment, followed by one or more sorties by a rotorcraft deployed from the mothership, with the ability to return to the mothership.

Saturn↗

The Aura Mission, Science and Validation

The EOS-Aura Mission is designed to answer three basic questions concerning the Earth's atmosphere: 1) Is stratospheric ozone recovering as predicted, 2) what are the processes that control air quality, and 3) how is changes in atmospheric chemistry effecting climate? Aura's four instruments work synergistically and are dedicated to answering these questions. Aura's instruments observe from the ultraviolet to the microwave region and view in the nadir and limb. This capability allows measurements of all the critical source, radical, and reservoir gases in the stratosphere to be observed globally on a daily basis. Aura will also continue the TOMS global ozone trend record. Observations in the troposphere will be conducted with the best spatial resolution and coverage ever achieved from space. Key pollutants, including aerosols, gases, and their precursors are the primary targets for Aura. High vertical resolution measurements will be made in the vicinity of the tropopause to better define the interactions of the UT/LS and particularly determine the amount downward transport of ozone and upward transport.of water vapor where both contribute to climate forcing. Aura will also measure aerosols in the stratosphere and troposphere where they play a role in ozone chemistry, air quality and climate. Aura data will be used by several environmental agencies for their decision support systems. Aura post launch validation program includes an augmented ground based measurement program which include the operational networks which measure atmospheric composition. Validation will be conducted under a range of geophysical conditions and throughout most of Aura s observing range. Balloon campaigns will conducted from a variety of latitudes and numerous aircraft missions are planned to cover an altitude range from the middle troposphere to the lower stratosphere and include in-situ and remote sensors. Long duration Un-inhabited aircraft are also being considered as part of the validation program. Substantial collaboration is planned with other chemistry satellite missions such as Envisat, SciSat, and Odin in order to make efficient use of resources and to provide continuity among these missions.

Hilsenrath, Ernest↗

Development of a Grid-Independent Geos-Chem Chemical Transport Model (v9-02) as an Atmospheric Chemistry Module for Earth System Models

The GEOS-Chem global chemical transport model (CTM), used by a large atmospheric chemistry research community, has been re-engineered to also serve as an atmospheric chemistry module for Earth system models (ESMs). This was done using an Earth System Modeling Framework (ESMF) interface that operates independently of the GEOSChem scientific code, permitting the exact same GEOSChem code to be used as an ESM module or as a standalone CTM. In this manner, the continual stream of updates contributed by the CTM user community is automatically passed on to the ESM module, which remains state of science and referenced to the latest version of the standard GEOS-Chem CTM. A major step in this re-engineering was to make GEOS-Chem grid independent, i.e., capable of using any geophysical grid specified at run time. GEOS-Chem data sockets were also created for communication between modules and with external ESM code. The grid-independent, ESMF-compatible GEOS-Chem is now the standard version of the GEOS-Chem CTM. It has been implemented as an atmospheric chemistry module into the NASA GEOS- 5 ESM. The coupled GEOS-5-GEOS-Chem system was tested for scalability and performance with a tropospheric oxidant-aerosol simulation (120 coupled species, 66 transported tracers) using 48-240 cores and message-passing interface (MPI) distributed-memory parallelization. Numerical experiments demonstrate that the GEOS-Chem chemistry module scales efficiently for the number of cores tested, with no degradation as the number of cores increases. Although inclusion of atmospheric chemistry in ESMs is computationally expensive, the excellent scalability of the chemistry module means that the relative cost goes down with increasing number of cores in a massively parallel environment.

CTM↗

Emphasizing Spectrum Management for Sustainable Development Research and Applications in Disaster Management

NASA's spaceborne Earth and Heliospheric Observatories and airborne sensors provide a plethora of measurements. These measurements are used in science research to understand the climatology of our home planet and the solar fluxes and cycle of the only star in our solar system 'Sun' which is critical driver for the retention of life on Earth. Specifically, these measurements help us to understand the water and energy cycle, the carbon cycle, weather and climate, atmospheric chemistry, solar variability, and solid Earth and interior to feed into sophisticated mathematical models to analyze and predict the Earth's behavior as an integrated system. The main thrust of this research is on improving the prediction capability in the areas of weather, long term climate and solid Earth processes, and further help the humanity and future generations in terms of societal benefits in managing natural disasters, sustainability issues and many more. This work is further linked with our contributions in the Global Earth Observing System of Systems (GEOSS) Specifically, the data and knowledge resulting from the Earth observing systems and analytical models of the Earth can be made available for assimilation into decision support systems to serve society for disaster management. Through partnerships with national and international agencies and organizations, NASA's Science Mission Directorate's, Applied Sciences Program contributes to benchmarking practical uses of observations and predictions from Earth science remote sensing systems research. The objective is to establish innovative solutions using Earth observations and science information to provide decision support that can be adapted in applications of national and international priority. We along with the international community will continue this critical field of investigation by using our existing and future sensors from space, airborne and insitue environment. In our quest to expanding our knowledge, there will be a need for deploying additional sensors to obtain high spatial, temporal and spectral resolution measurements. These sensors operate in multiple spectral band ranging from UV, visible, infrared, microwave and radio frequency ranges. Of a particular concern is the microwave frequency bands which play a key role in land, ocean, moisture sensing. This is because of a growing commercial demand in the area of high speed broadband communication all over the world, the electronic manufacturers are looking into high frequency microwave spectral bands. This may present a risk to the remote sensing sensors because of additional sources of noise that can impair the highly sensitive passive remote sensing instruments.

Ambrose, Stephen↗

The Stratospheric Aerosol and Gas Experiment IV

Atmospheric composition continues to be a key Earth science focus for international space agencies and research organizations. The target constituent varies depending upon the topic area of interest such as monitoring the ozone layer and the efficacy of the Montreal Protocol, assessing the influence of volcanic eruptions and large wildfires on the atmosphere, improving our knowledge of transport processes, or evaluating the impacts of greenhouse gases on climate. Additionally, there is a growing need for measurement continuity of many trace gases both from an inability to properly assess long-term trends without it as well as the reliance of reanalyses and chemistry climate models on observational input. To this end, proper continuity requires continuous and overlapping multi-instrument data records of which spaceborne measurements are a critical component. However, most current satellite systems are well beyond their expected lifetimes, and so we look toward the future to develop the Stratospheric Aerosol and Gas Experiment (SAGE) IV as a future mission concept. Enabled by the NASA Earth Science Technology Office’s (ESTO) Instrument Incubator Program, the SAGE IV Pathfinder project has developed and validated a prototype demonstration that paves the way for a future SAGE IV spaceflight mission. Utilizing solar occultation imaging, SAGE IV will be capable of measuring key species in the stratosphere and upper troposphere with the same quality as previous SAGE instruments but with greatly improved pointing knowledge and extensibility to new science targets. Furthermore, current technological advancements allow SAGE IV to fit within a CubeSat framework and make use of commercial hardware, significantly reducing the size and cost when compared with traditional missions and enabling sustainability of future measurements.

Robert Damadeo↗

The Stratospheric Aerosol and Gas Experiment (SAGE) IV

Atmospheric composition continues to be a key Earth science focus for international space agencies and research organizations. The target constituent varies depending upon the topic area of interest such as monitoring the ozone layer and the efficacy of the Montreal Protocol, assessing the influence of volcanic eruptions and large wildfires on the atmosphere, improving our knowledge of transport processes, or evaluating the impacts of greenhouse gases on climate. Additionally, there is a growing need for measurement continuity of many trace gases both from an inability to properly assess long-term trends without it as well as the reliance of reanalyses and chemistry climate models on observational input. To this end, proper continuity requires continuous and overlapping multi-instrument data records of which spaceborne measurements are a critical component. However, most current satellite systems are well beyond their expected lifetimes, and so we look toward the future to develop the Stratospheric Aerosol and Gas Experiment (SAGE) IV as a future mission concept. Enabled by the NASA Earth Science Technology Office’s (ESTO) Instrument Incubator Program, the SAGE IV Pathfinder project developed and validated a prototype demonstration that paves the way for a future SAGE IV spaceflight mission. Utilizing solar occultation imaging, SAGE IV will be capable of measuring key species in the stratosphere and upper troposphere with the same quality as previous SAGE instruments but with greatly improved pointing knowledge and extensibility to new science targets. The precision and stability of a well-designed occultation instrument can act as a calibration reference standard for other spaceborne instruments, ensuring proper continuity of the desired science targets. Furthermore, current technological advancements allow SAGE IV to fit within a CubeSat framework and make use of commercial hardware, significantly reducing the size and cost when compared with traditional missions and enabling sustainability of future measurements.

Robert Damadeo↗

Global Impacts of Marine Methanethiol Emissions and Chemistry in the Atmosphere

Oceanic emissions of dimethyl sulfide (DMS) have long been known to influence aerosol particle composition, cloud condensation nuclei (CCN) concentration, and Earth’s radiative budget. However, the impact of oceanic emissions of methanethiol (MeSH), a sulfur compound produced by the same oceanic precursor as DMS, has been relatively less explored. The gas-phase oxidation of MeSH has a higher effective yield of SO 2 and a shorter oxidative lifetime compared to DMS, highlighting the relevance of this pathway for the modeled representation of particle formation, growth, and CCN abundance in the marine atmosphere. Here, we use the global chemical transport model GEOS-Chem to explore possible scenarios representative of specific environmental conditions and MeSH emission schemes based on previous experimental studies. We further implement and test previously reported chemical mechanisms for MeSH oxidation, along with additional improvements, highlighting key uncertainties and sensitivities for regional and global sulfur budgets. We place our results in the context of recent modeling updates to DMS chemistry and cloud processing, which further impact SO 2 production in the marine atmosphere in parallel with MeSH oxidation. Within the overall marine sulfur budget, our findings highlight that MeSH plays a significant role in SO 2 production in the marine atmosphere, contributing to regional surface layer concentration increases of up to 40–60%. These results point to the importance of MeSH for efforts aimed at improving the modeled representation of sulfur spatiotemporal patterns relevant to air quality predictions and climate impact assessments.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

PreSens Dissolved Oxygen and Temperature Data, Old Woman Creek National Estuarine Research Reserve, Huron, OH, 2022-07-06 to 2023-12-15

This dataset contains collected dissolved oxygen (DO) and temperature measurements of the air, surface water, and underlying soil of a wetland at Old Woman Creek Estuarine Research Reserve in Huron, OH. Dissolved oxygen and temperature measurements were made in the first few centimeters of wetland sediment to assess how oxygen profiles changed over time with hydrological events. Measurements taken outside of the sediment were taken as comparison. Measurements were taken by hand with a PreSens Fibox 4 transmitter, paired with an oxygen dipping probe and temperature sensor, at each field outing. Measurements were taken approximately every 2 weeks around 10 AM EST. The PreSens_DO_Temp_Datafile.csv contains the recorded measurements, and the PreSens_InstallationMethods.csv describes the deployment of the sensor.

54 ENVIRONMENTAL SCIENCES↗