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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

Structural insights into transcriptional regulation by the helicase RECQL5

Abstract Transcription poses a major challenge for genome stability. The RECQL5 helicase helps safeguard genome integrity and is the only member of the human RecQ helicase family that directly binds to RNA polymerase II (Pol II) and affects its progression. While RECQL5 mitigates transcription stress in cells, the molecular mechanism underlying this phenomenon is unclear. Here, we use cryo-electron microscopy to determine the structures of stalled human Pol II elongation complexes (ECs) bound to RECQL5. Our structures reveal the molecular interactions stabilizing RECQL5 binding to the Pol II EC and highlight its role as a transcriptional roadblock. Additionally, we find that, in its nucleotide-free state, RECQL5 twists the downstream DNA in the EC and, upon nucleotide binding, undergoes a conformational change that allosterically induces Pol II toward a post-translocation state. We propose that this mechanism may help restart Pol II elongation and, therefore, contribute to reducing transcription stress.

Biochemistry & Molecular Biology↗
DOE OSTI2024

Advances in Miscanthus × Giganteus Planting Techniques May Increase Carbon Uptake in the Establishment Year

Agricultural lands hold significant potential for CO 2 sequestration, particularly when utilizing biomass crops and agricultural residues. Among these, Miscanthus × giganteus (mxg) stands out due to its high productivity and carbon sequestration capabilities. Recognizing the importance of such biomass crops, the Intergovernmental Panel on Climate Change (IPCC) has identified Bioenergy with Carbon Capture and Storage (BECCS) as a crucial strategy for achieving net-zero CO 2 emissions by 2050. This study examines the carbon uptake potential of mxg during its establishment year at the Sustainable Advanced Bioeconomy Research (SABR) farm in Iowa, USA, where mxg was planted at a density exceeding previous studies. Using eddy covariance (EC) measurements, we quantified the net ecosystem carbon exchange (NEE), and derived gross primary productivity (GPP), and ecosystem respiration (R eco ). Our findings reveal that SABR's mxg exhibited a significant carbon uptake of –621 g C m –2 , a threefold increase compared to a similar EC site in the “corn-belt” (University of Illinois Energy Research Farm; UIEF), which was established with lower planting density and pre-commercial planting equipment. Favorable growing conditions and advanced planting technologies at SABR likely contributed to this high carbon uptake. Comparisons with other global EC studies indicated a strong correlation between higher planting densities and greater carbon uptake. These results suggest that increasing mxg planting density can enhance carbon uptake, but further studies are necessary to evaluate the impacts under varying environmental conditions and management practices. Additionally, economic analyses are essential to determine the viability of higher planting densities. Our study underscores the potential of optimized mxg management practices to contribute significantly to CO 2 uptake and supports the development of BECCS as a viable climate change mitigation strategy.

09 BIOMASS FUELS↗
DOE OSTI2024

Capacity Fade of Graphite/NMC811: Influence of Particle Morphology, Electrolyte, and Charge Voltage

LiNi 0.8 Mn 0.1 Co 0.1 O 2 (NMC811) is an important Li-ion battery cathode material; however, there is a tradeoff between delivered capacity and capacity retention. As the charge potential increases the capacity rises but at the expense of capacity retention. The decrease in capacity retention has been ascribed to several factors including particle cracking, surface reconstruction, transition metal dissolution, and electrolyte reactivity. The present study compares 4.1 and 4.3 V charging limits in commercially relevant graphite/NMC811 pouch cells for single crystal (SC) and polycrystalline (PC) NMC811 with ethylene carbonate (EC)-containing or EC-free electrolytes. The electrochemistry is rationalized through analysis of electrochemical impedance spectroscopy, positive electrode X-ray photoelectron spectroscopy, soft X-ray absorption spectroscopy, X-ray diffraction, and negative electrode mapping by X-ray fluorescence. Graphite/SC-NMC811 cells show high-capacity retention at 4.1 V but exhibit degradation at 4.3 V charging potentials. The EC-free electrolyte cells led to higher capacity fade, especially when charged to 4.3 V. Cathode dissolution and deposition on the negative electrode from PC-NMC811 cells was higher than for samples from SC-NMC811 cells. This study reveals the impact of material type, charge voltage, and electrolyte composition on the reactions at the positive electrode, their influence on the negative electrode, and evolution with cycle number.

36 MATERIALS SCIENCE↗
DOE OSTI2024

In Situ Liquid Electron Microscope Cells Strongly Attenuate Electrochemical Behavior

In situ electrochemical Scanning Transmission Electron Microscopy (ec-S/TEM) probes the dynamics of electrochemical processes in real time and at high spatial resolution. This method utilizes microfabricated electrochemical cells, with enclosed dimensions of 800 μm wide, 800 μm long, and 1–2 μm tall, with electron-transparent silicon nitride windows. Working, counter, and reference electrodes in the configuration studied are deposited Pt with a planar surface area of about 1 μm 2 and a height of 50 nm. The cell confines the electrolyte within a 1 μm tall channel, and the microfabricated electrodes have a non-standard geometry, are coplanar, and are not front-facing. As such, standard assumptions of electrochemical experiments do not apply. COMSOL modeling was used to compare and contrast differences in electrochemical behavior between conventional experimental setups and the in situ ec-S/TEM cells. Cell height strongly affected voltammogram measurements: peak magnitudes and shifts correlate directly to cell height. Reactant concentration above the electrode quickly decreases during deposition, leading to a planar diffusion-dominated regime. The concentration gradient prioritizes particle growth along the thin edges of the electrode and not on the planar part of the electrode. Experiments done in the ec-S/TEM ex situ of a TEM verify the model’s accuracy.

Wittman, Reed M. [Oak Ridge National Laboratory (O↗
DOE OSTI2024

Laboratory time series moisture manipulative experiment from sediment across the contiguous US: time series aerobic respiration and geochemistry (v2)

This dataset supports a broader study examining the effects of wetting and drying on hyporheic zone respiration across the contiguous United States (CONUS). The dataset provides data generated from a laboratory moisture manipulation experiment. The contents include time series aerobic respiration and moisture; dissolved oxygen; sediment geochemistry data; and field metadata (including qualitative information on instream and river corridor characteristics). Samples were collected as part of the WHONDRS CONUS-Scale Model-Sample Study (CM). This study was designed following ICON (integrated, coordinated, open, and networked) principles to facilitate a model-experiment (ModEx) iteration approach, leveraging crowdsourced sampling across the CONUS. The data package associated with the CM study is available at https://data.ess-dive.lbl.gov/view/doi:10.15485/1923689. CM sampling began in April 2022 and ended in October 2023. This study uses subsamples from a subset of CM samples collected between June 2022 and June 2023. The original field samples were labeled as CM_###. Subsequent subsamples for this study were labeled as EC_###. The labels from the field samples and the EC subsamples can be mapped directly based on the digits following the prefix and underscore (i.e., EC_001 is a subsample from CM_001). See the critical details section below for more details on sample naming. This data package was originally published in August 2024. It was updated in February 2026 (v2; new and modified files). See the change history section in the readme for more details. For details on how to navigate this data package, see this infographic from the River Corridor SFA https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA/About. This dataset is comprised of one folder of raw Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) data and one main data folder containing (1) file-level metadata; (2) data dictionary; (3) field metadata; (4) readme; (5) field protocol; and a (6) a subfolder with sediment sample data from the incubation experiment. The sample data subfolder contains (1) dissolved organic carbon (DOC, measured as non-purgeable organic carbon, NPOC); (2) total nitrogen (TN); (3) adenosine triphosphate (ATP); (4) percent carbon and nitrogen; (5) effect size; (6) iron (II); (7) gravimetric moisture; (8) respiration rates and raw dissolved oxygen values; (9) specific conductance; (10) pH; (11) temperature; (12) a summary containing median values of each data type for each treatment (wet and dry); (13) methods codes; (14) FTICR-MS methods; and (15) a subfolder of 9.4 Tesla FTICR-MS data. This folder contains three subfolders, one containing the sediment .xml data files, one containing the sediment CoreMS output files, the other containing instructions and scripts for processing the files in CoreMS (https://github.com/EMSL-Computing/CoreMS). All files are .csv, .pdf, .R, .ref, or .xml.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2024

Electron cloud simulations in the Fermilab booster

As part of Fermilab's Proton Improvement Plan-II (PIP-II),the Fermilab Booster synchrotron will operate at a higherintensity, increasing from 4.5 x 10^12 to 6.7 x 10^12 protons per pulse (ppp). A potential challenge for achievinghigh intensity performance arises from rapid transverse instabilities induced by electron cloud (EC). This researchpresents EC simulations using PyECLOUD, which is anadvanced computational tool that incorporates measurements of the secondary electron yield (SEY) from theBooster's combined function magnet material. By systematically varying beam parameters in PyECLOUD, such asbunch structure, SEY, bunch length, and intensity, it becomes possible to forecast the impact of EC effects on thebeam stability of the PIP-II era Booster.

43 PARTICLE ACCELERATORS↗
DOE OSTI2024

Electron Cloud Simulations in the Fermilab Booster

As part of Fermilab's Proton Improvement Plan-II (PIP-II), the Fermilab Booster synchrotron will operate at a higher intensity, increasing from 4.5×1012 to 6.7×1012 protons per pulse [ppp]. A potential challenge for achieving high-intensity performance arises from rapid transverse instabilities induced by electron cloud (EC). This research presents EC simulations using PyECLOUD, which is an advanced computational tool that incorporates measurements of the secondary electron yield (SEY) from the Booster's combined function magnet material. By systematically varying beam parameters in PyECLOUD, such as bunch structure, bunch length, and intensity, the EC effects on beam stability and overall performance of Booster can be predicted.

43 PARTICLE ACCELERATORS↗
DOE OSTI2024

The Role of Deep Convection and Large-scale Circulation in Driving Model Spread in Low Cloud Feedback and Equilibrium Climate Sensitivity

This project aims to advance the understanding of the processes that drive the large uncertainties in climate change projections, use observations to constrain model physics and reduce the inter-model spread in equilibrium climate sensitivity (ECS). There are three major goals: 1) Characterize the representation of the physical pathways that link deep convection, large-scale circulation and low cloud feedback in CMIP6 model simulations and determine the relative contribution of each pathway to the CMIP6 model spread in low cloud feedback and ECS; 2) Use process-oriented diagnostics and multiple observations to evaluate CMIP6 model performance in capturing the observed cloud-circulation relation and deep convection characteristics including convective transition statistics and the bulk properties of mesoscale convective systems (MCSs). Error decomposition in CMIP6 models will be performed. 3) Conduct E3SM short-range hindcasts following the DOE Cloud-Associated Parameterizations Testbed (CAPT) protocol to pinpoint specific model parameters/processes that are crucial to the representation of deep convection, circulation, clouds and the pathways that connect them. We will modify convective parameters in E3SM and analyze the perturbed physics experiments (PPEs) to isolate model parameters that are critical to the uncertainty of ECS.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

In-situ/operando study of Cu-based nanocatalysts for CO 2 electroreduction using electrochemical liquid cell TEM

The structure of a nanocatalyst during electrocatalytic reactions often deviates from its pristine structure due to intrinsic properties, or physical and chemical adsorption at the catalytic surfaces. Taking Cu-based catalysts for CO 2 electroreduction reactions (CO 2 RR) as an example, they often experience segregation, leaching, and alloying during reactions. With the recent breakthrough development of high-resolution polymer electrochemical liquid cells, in-situ electrochemical liquid cell transmission electron microscopy (EC-TEM) alongside other advanced microscopy techniques, has become a powerful platform for revealing electrocatalysts restructuring at the atomic level. Considering the complex reactions involving electrified solid-liquid interfaces and catalyst structural evolution with intermediates, systematic studies with multimodal approaches are crucial. In this article, we demonstrate a research protocol for the study of electrocatalysts structural evolution during reactions using the in-situ EC-TEM platform. Using Cu and CuAg nanowire catalysts for CO 2 RR as model systems, we describe the experimental procedures and findings. We highlight the platform’s crucial role in elucidating atomic-scale pathways of nanocatalyst restructuring and identifying catalytic active sites, as well as avoiding potential artifacts to ensure unbiased conclusions. Using the multimodal characterization toolbox, we provide the opportunity to correlate the structure of a working catalyst with its performance. Finally, we discuss advancements as well as the remaining gap in elucidating the structural-performance relationship of working catalysts. We expect this article will assist in establishing guidelines for future investigations of complex electrochemical reactions, such as CO 2 RR and other catalytic processes, using the in-situ EC-TEM platform.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1972

Electronic characteristics of 'real' CdS surfaces.

Photovoltage spectroscopy (including photovoltage inversion and photovoltage quenching) was used to determine the electronic characteristics of real (basal and prismatic) surfaces of CdS. In room atmosphere, surface states with the following positions were found in the cadmium surfaces: Ec - Et equal to 0.05, 0.4, and 0.8 eV, and Ev - Et equal to 0.83 eV. The same surface states were present in the sulfur surfaces, with the exception of those at Ec - Et equal to 0.4 eV. In the prismatic and unetched basal surfaces, states at Ec - Et equal to 1.1 eV were found in addition to all of those found on the cadmium surfaces.

Lagowski, J.↗
NASA NTRS1980

Cogeneration Technology Alternatives Study (CTAS). Volume 6: Computer data. Part 1: Coal-fired nocogeneration process boiler, section A

Various advanced energy conversion systems (ECS) are compared with each other and with current technology systems for their savings in fuel energy, costs, and emissions in individual plants and on a national level. About fifty industrial processes from the largest energy consuming sectors were used as a basis for matching a similar number of energy conversion systems that are considered as candidates which can be made available by the 1985 to 2000 time period. The sectors considered included food, textiles, lumber, paper, chemicals, petroleum, glass, and primary metals. The energy conversion systems included steam and gas turbines, diesels, thermionics, stirling, closed cycle and steam injected gas turbines, and fuel cells. Fuels considered were coal, both coal and petroleum based residual and distillate liquid fuels, and low Btu gas obtained through the on-site gasification of coal. Computer generated reports of the fuel consumption and savings, capital costs, economics and emissions of the cogeneration energy conversion systems (ECS's) heat and power matched to the individual industrial processes are presented for coal fired process boilers. National fuel and emissions savings are also reported for each ECS assuming it alone is implemented.

Knightly, W. F.↗
NASA NTRS1982

Perfect fluids in the Einstein-Cartan theory

It is pointed out that whereas most of the discussion of the Einstein-Cartan (EC) theory involves the relationship between gravitation and elementary particles, it is possible that the theory, if correct, may be important in certain extreme astrophysical and cosmological problems. The latter would include something like the collapse of a spinning star or an early universe with spin. A set of equations that describe a macroscopic perfect fluid in the EC theory is derived and examined. The equations are derived starting from the fundamental variational principle for a perfect fluid in general relativity. A brief review of the study by Ray (1972) is included, and the results for the EC theory are presented.

Ray, J. R.↗
NASA NTRS1985

Executive control systems in the engineering design environment

An executive control system (ECS) is a software structure for unifying various applications codes into a comprehensive system. It provides a library of applications, a uniform access method through a cental user interface, and a data management facility. A survey of twenty-four executive control systems designed to unify various CAD/CAE applications for use in diverse engineering design environments within government and industry was conducted. The goals of this research were to establish system requirements to survey state-of-the-art architectural design approaches, and to provide an overview of the historical evolution of these systems. Foundations for design are presented and include environmental settings, system requirements, major architectural components, and a system classification scheme based on knowledge of the supported engineering domain(s). An overview of the design approaches used in developing the major architectural components of an ECS is presented with examples taken from the surveyed systems. Attention is drawn to four major areas of ECS development: interdisciplinary usage; standardization; knowledge utilization; and computer science technology transfer.

Hurst, P. W.↗
NASA NTRS1986

The electron-cyclotron maser instability as the source of solar type V continuum

In this paper, it is proposed that the electron-cyclotron (EC) maser instability can be the source of solar type V bursts. The propagation of electrons up an open field line is examined, and it is shown that the resultant distribution can be subject to the bump-in-tail (BIT) or the EC maser instabilities, or both. The characteristics of the emission from the BIT and EC maser instabilities when they are driven by such distributions are compared. It is proposed that type V bursts are produced by the coalescence of the upper hybrid waves produced by the maser instability, while type IIIs are produced by the BIT instability.

Winglee, R. M.↗
NASA NTRS1987

Radar cross section of an open-ended circular waveguide Calculation of second-order diffraction terms

The radar cross section of an open-ended, semi-infinite circular waveguide is calculated by the geometrical theory of diffraction and the equivalent-current (EC) method. Both single- and double-diffraction terms are included. It is found that the double-diffraction term is stronger than the single-diffraction term for the horizontal polarization at wide-angle incidence. Its inclusion is necessary in order to check with experimental data and the asymptotic expansion of the exact Wiener-Hopf solution. The EC method is used for the single diffraction. On the other hand the double-diffraction term is obtained by using the EC method for axial incidence and geometrical theory of diffraction for wide-angle incidence. These two solutions are matched with a proper matching function. This technique is computationally more efficient than the matching technique of integration over the equivalent currents.

Lee, C. S.↗
NASA NTRS1992

EOSDIS/DADS requirements

A brief summary of the Earth Observing System Data and Information System (EOSDIS) Core System (ECS) Data Archive and Distribution System (DADS) requirements is given. Among the requirements are the following: the ECS relationship to EOSDIS Version-O; phased implementation of ECS; and data ingest, archive, and distribution daily data volumes anticipated at each of the 7 Distributed Active Archive Centers (DAAC's).

Berbert, John↗
NASA NTRS1991

EOS ground data and operations support

The Earth Observing System (EOS) is planned as a space-based measurement system, earth-science research program, and data and information system (EOSDIS). It will consist of several observatories with multiple earth sensing instruments to provide investigators with a thorough, long-term view of the earth's environment. Providing the data handling and flight operations support for EOS will be the EOSDIS Core System (ECS). The ECS will command and control the observatories consisting of core service platforms and science instruments, and it will transport, process, and store the EOS data, provide access to the data for years, and support researchers. EOS and EOSDIS are briefly described to provide a context for a description of the ECS.

Smith, Gene↗
NASA NTRS1992

Electrochemical CO2 and O2 separation for crew and plant environments

The study describes a closed ecosystem concept that includes electrochemical CO2 and O2 separators and a moisture condenser/separator for maintaining CO2, O2, and humidity levels in the crew and plant habitats at their respective optimal conditions. The key processes of this concept are aqueous electrolyte-based electrochemical CO2 and O2 separations. The principles and cell characteristics of these electrochemical gas separation processes are described. Also presented are descriptions of test hardware and the test results of the Electrochemical CO2 Separator (ECS) and the Electrochemical O2 Separator (EOS), and the combination of the ECS and the EOS. The test results proved that the ECS and EOS processes for the combined concept are viable.

Lee, M. G.↗