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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

Optical stark effect in the 2-photon spectrum of NO

A large optical Stark effect has been observed in the two-photon spectrum X(2)Pi yields A(2)Sigma(+)_ in NO. It is explained as a near-resonant process in which the upper state of the two-photon transition is perturbed by interactions with higher-lying electronic states coupled by the laser field. A theoretical analysis is presented along with coupling parameters determined from ab initio wave functions. The synthetic spectrum reproduces the major experimental features.

Huo, W. M.↗

Optical Stark effect in the two-photon spectrum of NO

A large optical Stark effect has been observed in the two-photon spectrum X(2)Pi yields A(2)Sigma(+) - in NO. It is explained as a near-resonant process in which the upper state of the two-photon transition is perturbed by interactions with higher-lying electronic states coupled by the laser field. A theoretical analysis is presented along with coupling parameters determined from ab initio wave functions. The synthetic spectrum reproduces the major experimental features.

Huo, W. M.↗

Analysis of boron carbides' electronic structure

The electronic properties of boron-rich icosahedral clusters were studied as a means of understanding the electronic structure of the icosahedral borides such as boron carbide. A lower bound was estimated on bipolaron formation energies in B12 and B11C icosahedra, and the associated distortions. While the magnitude of the distortion associated with bipolaron formation is similar in both cases, the calculated formation energies differ greatly, formation being much more favorable on B11C icosahedra. The stable positions of a divalent atom relative to an icosahedral borane was also investigated, with the result that a stable energy minimum was found when the atom is at the center of the borane, internal to the B12 cage. If incorporation of dopant atoms into B12 cages in icosahedral boride solids is feasible, novel materials might result. In addition, the normal modes of a B12H12 cluster, of the C2B10 cage in para-carborane, and of a B12 icosahedron of reduced (D sub 3d) symmetry, such as is found in the icosahedral borides, were calculated. The nature of these vibrational modes will be important in determining, for instance, the character of the electron-lattice coupling in the borides, and in analyzing the lattice contribution to the thermal conductivity.

Howard, Iris A.↗

A model of inner cometary ionospheres

A hydrodynamical model to describe the movement of the thermalized charged components in the inner ionosphere of comet Halley is presented. Photoelectrons are included by applying a two-stream-type approach. The numerical scheme describes shock transitions in a natural way. Solutions are obtained for a number of different assumptions concerning electron heating rates but all show that the electron temperature increases sharply where the collisional electron neutral coupling becomes unimportant. This temperature increase is accompanied by an increase in the plasma pressure and in its associated polarization electric field, and causes the plasma flow to go subsonic. In certain cases this transition occurs as an inner shock which may explain the observed ion pile-up in Halley's comet.

Korosmezey, A.↗

Jet-resolved vibronic structure in the higher excited states of N2O - Ultraviolet three-photon absorption spectroscopy from 80,000 to 90,000/cm

Ionization-detected UV multiphoton absorption spectroscopy of the excited states of N2O is presented, showing Rydberg structure within 20,000/cm of the first ionization threshold. Despite evidence for strong Rydberg-continuum coupling in the form of broadened bands and Fano line-shapes, the Rydberg structure persists, with atomic-like quantum defects and vibration structure well-matched with that of the ion. In the most clearly resolved spectrum, corresponding to the 3p(delta)1Pi state, Renner-Teller and Herzberg-Teller coupling of electronic and vibrational angular momentum are revealed. It is suggested that these mixings are properties of the N2O(+)Pi ion core.

Patsilinakou, E.↗

New advancements in charge-coupled device technology - Sub-electron noise and 4096 x 4096 pixel CCDs

This paper reports on two new advancements in CCD technology. The first area of development has produced a special purpose CCD designed for ultra low-signal level imaging and spectroscopy applications that require sub-electron read noise floors. A nondestructive output circuit operating near its 1/f noise regime is clocked in a special manner to read a single pixel multiple times. Off-chip electronics average the multiple values, reducing the random noise by the square-root of the number of samples taken. Noise floors below 0.5 electrons rms are reported. The second development involves the design and performance of a high resolution imager of 4096 x 4096 pixels, the largest CCD manufactured in terms of pixel count. The device utilizes a 7.5-micron pixel fabricated with three-level poly-silicon to achieve high yield.

Janesick, James R.↗

A new numerical code for simulating current-driven instabilities on auroral field lines

A new code is described with open boundary conditions for simulating electrostatic instabilities driven by field-aligned currents in narrow channels whose widths are smaller than the plasma skin depth. The reflection of Alfven waves at regions containing plasma waves coupling the electron and ion motion is found to cause a reduction of the field-aligned current and limits it to a critical value which is marginal for the excitation of electrostatic ion-cyclotron waves at a height of 1-2 R(e). Electron heating due to current-driven plasma turbulence causes the overall plasma density in the system to decrease. The plasma density in the region of upward current is enhanced relative to that in the region of downward current, and the current density in upward-directed current channels can be larger than in downward-directed ones.

Goertz, C. K.↗

Connector Mechanism Has Smaller Stroke

System for connecting electrical and/or fluid lines includes mechanism reducing length of stroke necessary to make or break connections. Feature enables connection and disconnection in confined space, and compensates for misalignment between connectors. Connector in active member moves upward at twice the speed of downward stroke of passive member. Stroke amplified within connector system. Applications include connections between modular electronic units, coupled vehicles, and hydraulic systems.

Milam, M. Bruce↗

A new method for the calculation of photodissociation cross sections

A time-independent quantum mechanical approach to the calculation of photodissociation cross sections is developed. The method is based on the use of a discrete variable representation and the application of absorbing boundary conditions. Both total photodissociation cross sections and partial cross sections (hence product state distributions) are obtained using the same basic technique, but the calculation is particularly efficient when only the former quantity is required. The method is applied to the photodissociation of HCl(+) for which accurate potential energy curves and dipole moment functions are available, to the photodissociation of ClCN which is a direct process, involving a single excited electrosonic state, and to the photodissociation of ICN, which involves several strongly coupled excited electronic states.

Seideman, Tamar↗

A limitation of the generation of magnetic fields

Simple arguments are put forward to show that the currents produced in disks by radiative or other types of drag forces on electrons must give rise to extraordinarily small magnetic fields. The field strengths are consistent with earlier (more complex) treatments of this class of problem, but inconsistent with the claims of recent papers in the literature. The discrepancies involve the treatment of self-induction. Ion-electron inductive coupling limits the generated magnetic field to have an associated ion Larmor radius greater than or of order of the radius of the disk, a result which follows most directly from conservation of canonical ion momentum, p + eA/c. An explicit time-dependent model for the buildup of the field leads to the same conclusion. If internal velocity gradient scales are smaller than the ion Larmor radius, and the plasma is not collision dominated, standard dynamo amplification within the disk is hardly likely to be effective. But to explain the Galactic field, dynamo amplification in a collisional plasma is also likely to be problematic. The difficulties posed by the existence of ordered Galactic-scale magnetic fields are made all the more acute by the simplicity and the scope of the discussed field limitation.

Balbus, Steven A.↗

Studies of Intercellular Communication and Intracellular Metabolic Responses by Bone Cells to Simulated Weightlessness

Spaceflight affects the weight bearing skeletal tissues by reducing the rate of new bone formation. This effect on the long bones of flown rats has been quantitated but the effect at the cellular level and the mechanism(s) involved are not understood. We are applying electron microscopy, coupled with histochemistry and immunocytochemistry to determine the cellular functions most affected by spaceflight. The emphasis for study of these samples from SLS-1, a 9-day mission, is on the histochemical and structural changes of the endosteal and perivascular osteoblasts found in diaphyseal bone of femur and tibia. Work is still in progress but some findings are described: (1) An expected decrease in alkaline phosphatase activity in osteoblasts from flight animals, but an increase in enzyme activity in the stromal stem cells adjacent to the osteoblast. (2) An increase in osteoclastic TRAP activity in the trabecular bone region in response to spaceflight. (3) A large increase in procollagen containing secretory granules in osteoblasts in the recovery group, and a significant decrease in granule numbers in the flight group.

Doty, Stephen B.↗

Brazing of Stainless Steel to Yttria-Stabilized Zirconia Using Gold-Based Brazes for Solid Oxide Fuel Cell Applications

Two gold-base active metal brazes (gold-ABA and gold-ABA-V) were evaluated for oxidation resistance to 850 C, and used to join yttria-stabilized zirconia (YSZ) to a corrosion-resistant ferritic stainless steel for possible use in solid oxide fuel cells. Thermogravimetric analysis and optical microscopy and scanning electron microscopy coupled with energy-dispersive spectroscopy were used to evaluate the braze oxidation behavior, and microstructure and composition of the YSZ/braze/steel joints. Both gold-ABA and gold-ABA-V exhibited nearly linear oxidation kinetics at 850 C, with gold-ABA-V showing faster oxidation than gold-ABA. Both brazes produced metallurgically sound YSZ/steel joints due to chemical interactions of Ti and V with the YSZ and steel substrates.

Singh, M.↗

Implications of Weak Link Effects on Thermal Characteristics of Transition-Edge Sensors

Weak link behavior in transition-edge sensor (TES) microcalorimeters creates the need for a more careful characterization of a device's thermal characteristics through its transition. This is particularly true for small TESs where a small change in the bias current results in large changes in effective transition temperature. To correctly interpret measurements, especially complex impedance, it is crucial to know the temperature-dependent thermal conductance, G(T), and heat capacity, C(T), at each point through the transition. We present data illustrating these effects and discuss how we overcome the challenges that are present in accurately determining G and T from I-V curves. We also show how these weak link effects vary wi.th TES size. Additionally, we use this improVed understanding of G(T) to determine that, for these TES microcalorimeters. Kaptiza boundary resistance dominates the G of devices with absorbers while the electron-phonon coupling also needs to be considered when determining G for devices without absorbers

Bailey, C. N.↗

Enhanced Quasiparticle Lifetime in a Superconductor by Selective Blocking of Recombination Phonons with a Phononic Crystal

When quasiparticles in a BCS (Bardeen-Cooper-Schrieffer) superconductor recombine into Cooper pairs, phonons are emitted within a narrow band of energies above the pairing energy at 2 delta. We show that a phonon band gap restricting the escape of recombination phonons from a superconductor can increase the quasiparticle recombination lifetime by more than an order of magnitude. A phonon band gap can be realized and matched to the recombination energy with a phononic crystal, a periodically patterned dielectric membrane. We discuss in detail the nonequilibrium quasiparticle and phonon distributions that arise in a superconductor due to a phonon band gap and a pair-breaking photon signal. Although intrinsically a nonequilibrium effect, the lifetime enhancement in the small-signal regime is remarkably similar to an estimate from an equilibrium formulation. The equilibrium estimate closely follows exp (Omega (sub bg) divided by k (sub B)T (sub b)), where Omega (sub bg) is the phonon band gap energy bandwidth above 2 and T (sub b) is the phonon bath temperature of the coupled electron-phonon system. We discuss the impact of a phononic band gap on the performance of a superconducting circuit element and propose a microwave resonator to measure the enhancement in the quasiparticle lifetime.

Rostem, K.↗

Quantifying the Energy Budget in the Solar Wind from 13.3 to 100 Solar Radii

A variety of energy sources, ranging from dynamic processes, such as magnetic reconnection and waves, to quasi steady terms, such as plasma pressure, may contribute to the acceleration of the solar wind. We utilize a combination of charged particle and magnetic field observations from the Parker Solar Probe (PSP) to attempt to quantify the steady-state contribution of the proton pressure, the electric potential, and the wave energy to the solar wind proton acceleration observed by PSP between 13.3 and ∼100 solar radii (R☉). The proton pressure provides a natural kinematic driver of the outflow. The ambipolar electric potential acts to couple the electron pressure to the protons, providing another definite proton acceleration term. Fluctuations and waves, while inherently dynamic, can act as an additional effective steady-state pressure term. To analyze the contributions of these terms, we utilize radial binning of single-point PSP measurements, as well as repeated crossings of the same stream at different distances on individual PSP orbits (i.e., fast radial scans). In agreement with previous work, we find that the electric potential contains sufficient energy to fully explain the acceleration of the slower wind streams. On the other hand, we find that the wave pressure plays an increasingly important role in the faster wind streams. The combination of these terms can explain the continuing acceleration of both slow and fast wind streams beyond 13.3 R☉.

J S Halekas↗

Downfolding Complex Materials Problems Onto Model Hamiltonians for Quantum Computers

Simulating the properties of quantum materials is expected to be one of the exciting applications for quantum computers and where we hope to see advantages over classical hardware. The complexity of ab initio Hamiltonians describing the physics of application-relevant materials places them beyond the realm of possibility for solution on near-term hardware with a limited number of qubits. Various Hamiltonian approximations, including Hamiltonian downfolding, offers a possibility towards simulating complex materials on near-term hardware. This is accomplished by approximating the relevant physics of a given material through their representation by simpler model Hamiltonians, such as the Hubbard Hamiltonian or extensions of it. Here we employ a well-defined first-principles methodology for deriving downfolded multi-band extended Hubbard Hamiltonians of materials, capturing strong electronic correlation and electron-phonon coupling, based on the formalism of Wannier functions and the calculation of the screened Coulomb interaction. We demonstrate for a variety of systems that quantum simulation of these downfolded Hamiltonians reproduces key properties, thus establishing downfolding as a promising route to achieve near-term simulation of application-relevant systems on quantum hardware.

Antonios Markos Alvertis↗

Downfolding complex materials problems onto model Hamiltonians for quantum computers

Simulating the properties of quantum materials is expected to be one of the exciting applications for quantum computers and where we hope to see advantages over classical hardware. The complexity of ab initio Hamiltonians describing the physics of application-relevant materials places them beyond the realm of possibility for solution on near-term hardware with a limited number of qubits. Various Hamiltonian approximations, including Hamiltonian downfolding, offers a possibility towards simulating complex materials on near-term hardware. This is accomplished by approximating the relevant physics of a given material through their representation by simpler model Hamiltonians, such as the Hubbard Hamiltonian or extensions of it. Here we employ a well-defined first-principles methodology for deriving downfolded multi-band extended Hubbard Hamiltonians of materials, capturing strong electronic correlation and electron-phonon coupling, based on the formalism of Wannier functions and the calculation of the screened Coulomb interaction. We demonstrate for a variety of systems that quantum simulation of these downfolded Hamiltonians reproduces key properties, thus establishing downfolding as a promising route to achieve near-term simulation of application-relevant systems on quantum hardware.

Antonios M. Alvertis↗

Antenna-Coupled Superconducting Tunnel Junctions with Single-Electron Transistor Readout for Detection of Sub-mm Radiation

Antenna-coupled superconducting tunnel junction detectors have the potential for photon-counting sensitivity at sub-mm wavelengths. The device consists of an antenna structure to couple radiation into a small superconducting volume and cause quasiparticle excitations, and a single-electron transistor to measure currents through tunnel junction contacts to the absorber volume. We will describe optimization of device parameters, and recent results on fabrication techniques for producing devices with high yield for detector arrays. We will also present modeling of expected saturation power levels, antenna coupling, and rf multiplexing schemes.

Stevenson, T. R.↗