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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

Terrestrial radiative cooling: Using the cold universe as a renewable and sustainable energy source

Photonic materials designed at wavelength scales have enabled a range of emerging energy technologies, from solid-state lighting to efficient photovoltaics that have transformed global energy landscapes. Daytime passive radiative cooling materials shed heat from the ground to the cold universe by taking advantage of the terrestrial thermal radiation that is as large as the renewable solar energy. Newly developed photonic materials permit subambient cooling under direct sunshine, and their applications are expanding rapidly enabled by scalable manufacturing. We review here the recent advancement of daytime subambient radiative cooling materials, which allow energy-efficient cooling and are paving the way toward technologies that harvest the coldness from the universe as a new renewable energy source.

Science & Technology - Other Topics↗

Expanding the Knock/Emissions/Misfire Limits for the Realization of Ultra-Low Emissions, High Efficiency Heavy Duty Natural Gas Engines

The Vehicle Technologies Office funds early-stage, high-risk research to develop technology upon which industry can implement innovative transportation energy technologies that increase efficiency, decrease cost, and expand use of domestic energy sources, such as natural gas (NG). To improve the viability of medium and heavy-duty vehicles the natural gas engine efficiency must be closer to that of diesel. This work addresses fundamental limitations to achieve diesel-like efficiencies in heavy duty on-road natural gas engines. The primary goal of this research is to achieve diesel-like efficiencies in heavy duty on-road NG engines, focusing on the Cummins 15 liter engine platform (baseline diesel efficiency of 44% at peak torque). That goal has been achieved, though more work is needed to facilitate practical implementation of the developed technologies.

03 NATURAL GAS↗

Integrated Process for Direct Air Capture of CO 2 and Electrochemical Conversion to Ethanol

This Cooperative Research and Development Agreement (CRADA) between UT-Battelle, LLC and Reactwell, L.L.C. aimed to facilitate the development of an energy-efficient and cost-effective technology that captures carbon dioxide (CO 2 ) from ambient air and converts it electrochemically to ethanol. Direct air capture (DAC) of CO 2 offers the prospect of permanently lowering the atmospheric CO 2 concentration, providing economic and energy-efficient technologies can be developed and deployed at a large scale. DAC has the potential for high-capacity atmospheric CO 2 capture, the flexibility of placement anywhere on earth, and the generation of high-purity CO 2 streams. The most significant technical challenge with DAC is the very low atmospheric concentration of CO 2 , thereby requiring sorbents that bind CO 2 quickly, strongly, and selectively against other components in the air. Integrating DAC with CO 2 conversion into useful chemicals, fuels, or materials can provide an economically feasible solution for mitigating climate change. As long as the carbon contained in these products is taken from the atmosphere and no additional carbon emissions result from their production, processing, and transportation, they can be considered carbon-neutral products. This CRADA facilitated the development of a new net-zero emission technology that closes the carbon cycle by combining DAC with the catalytic electrochemical conversion of CO 2 into ethanol.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Porous Covalent Organic Polymers for Efficient Fluorocarbon‐Based Adsorption Cooling

Abstract Adsorption‐based cooling is an energy‐efficient renewable‐energy technology that can be driven using low‐grade industrial waste heat and/or solar heat. Here, we report the first exploration of fluorocarbon adsorption using porous covalent organic polymers (COPs) for this cooling application. High fluorocarbon R134a equilibrium capacities and unique overall linear‐shaped isotherms are revealed for the materials, namely COP‐2 and COP‐3. The key role of mesoporous defects on this unusual adsorption behavior was demonstrated by molecular simulations based on atomistic defect‐containing models built for both porous COPs. Analysis of simulated R134a adsorption isotherms for various defect‐containing atomistic models of the COPs shows a direct correlation between higher fluorocarbon adsorption capacities and increasing pore volumes induced by defects. Combined with their high porosities, excellent reversibility, fast kinetics, and large operating window, these defect‐containing porous COPs are promising for adsorption‐based cooling applications.

Zheng, Jian↗

Air‐Stable High‐Voltage Li‐Ion Organic Cathode Enabled by Localized High‐Concentration Electrolyte

While lithium‐ion batteries have revolutionized the field of energy storage, their reliance on critical minerals such as cobalt and nickel raises significant concerns over resource availability and supply chain uncertainty. In this study, we revisit dithiin‐fused dilithium naphthazarin (5,8‐dihydroxy‐1,4‐naphthoquinone) (DNP‐Li) as a high‐voltage Li‐ion organic cathode and evaluate its performance in conjunction with localized high‐concentration electrolyte (LHCE). DNP‐Li exhibits remarkable air and thermal stability, a high operating potential of 3.55 V vs. Li + /Li, and a specific capacity of 232 mAh g −1 , positioning it as one of the most promising candidates among Li‐ion organic cathodes. Furthermore, the electrochemical behavior of DNP‐Li is strongly influenced by the electrolyte composition, giving distinct two‐plateau or four‐plateau voltage profiles accompanied by reversible or irreversible phase transitions in carbonate‐based or LHCE electrolyte formulations, respectively. The reduced solubility of DNP‐Li‐based redox intermediates in LHCE enhances cycling stability, achieving a capacity retention of 85% after 50 cycles at 0.1C and 75% after 160 cycles at 0.5C, demonstrating a significant improvement compared to the carbonate‐based electrolyte. This work highlights the critical role of solute–electrolyte interactions in modulating the electrochemical performance of multielectron small‐molecule organic cathodes, offering new pathways for advancing sustainable and high‐efficiency energy storage technologies.

Lakraychi, Alae Eddine [Department of Electrical a↗

NiFe Nanoparticle Nest Supported on Graphene as Electrocatalyst for Highly Efficient Oxygen Evolution Reaction

Abstract Designing cost‐efffective electrocatalysts for the oxygen evolution reaction (OER) holds significant importance in the progression of clean energy generation and efficient energy storage technologies, such as water splitting and rechargeable metal–air batteries. In this work, an OER electrocatalyst is developed using Ni and Fe precursors in combination with different proportions of graphene oxide. The catalyst synthesis involved a rapid reduction process, facilitated by adding sodium borohydride, which successfully formed NiFe nanoparticle nests on graphene support (NiFe NNG). The incorporation of graphene support enhances the catalytic activity, electron transferability, and electrical conductivity of the NiFe‐based catalyst. The NiFe NNG catalyst exhibits outstanding performance, characterized by a low overpotential of 292.3 mV and a Tafel slope of 48 mV dec −1 , achieved at a current density of 10 mA cm − 2 . Moreover, the catalyst exhibits remarkable stability over extended durations. The OER performance of NiFe NNG is on par with that of commercial IrO 2 in alkaline media. Such superb OER catalytic performance can be attributed to the synergistic effect between the NiFe nanoparticle nests and graphene, which arises from their large surface area and outstanding intrinsic catalytic activity. The excellent electrochemical properties of NiFe NNG hold great promise for further applications in energy storage and conversion devices.

Chemistry↗

Falling-film heat exchangers used in desalination systems: A review

With growing demand for fresh water, there has been an increasing interest in energy-efficient desalination technologies. Falling-film-based, multi-effect distillation (MED) systems have been extensively deployed world-wide. The performance of such systems heavily depends on the efficiency of the evaporation process. Here, research on falling-film heat exchangers used in desalination systems, especially MED systems, is critically reviewed to assess the state of the technology. The review includes falling-film evaporation mechanisms, system operation, and scaling issues. Finally, opportunities for further application and areas where more research is needed are identified.

42 ENGINEERING↗

Toward durable stacks: glass-ceramic sealants for intermediate-temperature protonic ceramic electrochemical systems

Protonic ceramic electrochemical cells (PCECs) are emerging as promising technologies for efficient energy conversion and hydrogen production because they operate at intermediate temperatures with improved efficiency and durability compared with conventional solid oxide electrochemical cells. However, the long-term reliability and commercialization of PCEC stacks remain strongly limited by the performance of sealants, which are required to maintain gas tightness, electrical insulation, and mechanical integrity under harsh thermal and chemical environments. Among various sealing approaches, glass-ceramic sealants are considered the most practical and scalable due to their excellent wettability, chemical tunability, and strong interfacial adhesion. This review provides a comprehensive overview of recent advances in glass-ceramic sealants for intermediate-temperature protonic ceramic electrochemical systems. The fundamental design principles of sealant compositions are first discussed, followed by recent developments in deposition methods, sintering strategies, surface treatments, and degradation monitoring techniques. Particular attention is given to the unique challenges associated with PCEC operating conditions, including hydrothermal degradation, interfacial reactions with barium-containing electrolytes, and thermal mismatch. Finally, future opportunities involving sustainable materials, multiscale modeling, additive manufacturing, and artificial intelligence-assisted sealant optimization are highlighted.

glass–ceramic sealants↗

Seamless Wireless Communication Platform for Internet of Things Applications

The rapid growth of the Internet of Things (IoT) devices resulted in the proliferation of wireless technologies to cater to their increasing data rate requirements and support multiple applications. However, such ever-increasing wireless technologies present numerous challenges such as incompatible wireless standards, increased energy consumption, and insecure communication. The traditional gateways proposed in the literature suffers from limitations such as computational complexity, resource requirements, increased cost, and device size. We vision an era of seamless wireless communication to alleviate the aforementioned challenges in IoT applications. through three inter-dependent functionalities namely detection and identification of wireless technologies, energy-efficient transmit power control, and secure end-to-end communication. To prove the concept, a new gateway is proposed to achieve these three functionalities with only physical layer measurements so that the different communication protocols in the higher layers can be avoided. Novel schemes are conceptualized for resource-limited seamless IoT applications. Moreover, the conceptual seamless IoT platform is validated through software-based computer simulation and software-defined radio-based testbed implementation. Finally, the preliminary analysis demonstrates that the proposed platform has great potential in advancing seamless IoT applications.

97 MATHEMATICS AND COMPUTING↗

Polarity effects on wake–up behavior of Al 0.94 B 0.06 N ferroelectrics

Wurtzite ferroelectric materials are promising candidates for energy-efficient memory technologies, particularly for applications requiring high operating temperatures. Asymmetric wake-up behaviors, in which the polarization reversal depends both on polarity and cycle number for the first few dozen cycles, must be better understood for reliable device operation. Here, the detailed analysis of the asymmetric wake-up behavior of thin film Al 0.94 B 0.06 N was performed combining time-resolved switching measurements with Rayleigh analysis, piezoelectric measurements, and etching experiments of progressively switched samples. Furthermore, the analysis shows that the gradual opening of the polarization hysteresis loops associated with wake-up is driven by a gradual increase in the domain-wall density and/or domain-wall mobility with electric field cycle to the polarity opposite to the growth polarity. The insights of this discovery will help to guide interface and polarity design in the eventual deployment of reliable devices based on these materials.

36 MATERIALS SCIENCE↗

Zero-CO Residential Natural Gas Furnace

Residential natural gas furnaces are widely used in the US homes. Manufacturers dedicate significant design and testing resources to meet requirements of design standards. One area of these standards is controlling flue gas carbon monoxide (CO) emissions. To more effectively reduce CO emissions at the flue, we developed a novel catalyst-assisted approach that integrated a low Pt/Rh loading acidic gas reduction (AGR) catalyst with three-way catalyst (TWC) or diesel oxidation catalyst (DOC) components. Compact catalysts were fabricated and assembled into tubular components, which can be seamlessly incorporated into the primary heat exchanger of a representative commercially available condensing furnace. The retrofitted furnace was demonstrated and tested following ANSI/ASHRAE Standard 103-2017. Experimental results showed that both AGR/TWC and AGR/DOC configurations achieved near-zero CO emissions under steady-state and cold-start conditions, compared with up to 500 ppm at a cold start and 17 ppm in a steady state in the OEM furnace. The catalyst-assisted furnaces also exhibited an annual fuel utilization efficiency improvement of more than 1.5% relative to the baseline unit, with a manageable pressure drop of 2.0−2.5 in. of water column. These results demonstrate that the catalyst-assisted approach can effectively eliminate CO emissions and improve energy efficiency. The technology has broad applicability for residential and commercial gas-fired heating systems.

Gao, Zhiming [ORNL] (ORCID:0000000271397995)↗

BTO Market Success Report 2015–2020

This report highlights 28 BTO-supported, technology-oriented research and development (R&D) projects that resulted in the launch of a commercial product, focusing on identifying new technologies or commercialization updates between 2015 and 2020, where the product remained on the market as of March 2021. The report also includes a listing of the full 45 commercial products supported by BTO as well as a listing of 101 lighting components that benefited from BTO support and were commercialized and integrated into finished lighting products during the same timeframe.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Fort Erie On-Demand Transit Case Study

Rural and smaller-sized communities in North America face unique mobility challenges due to their low population density, lower public transit spending per capita compared to major cities, and a high reliance on private vehicles. In recent years, communities such as Fort Erie, Ontario have restructured or advanced their public transit systems using on-demand services. Fort Erie is a relatively sparsely populated region of 32,901 residents, spread across a land area of 166 square kilometers (64 square miles), for an average population density of 193 residents per square kilometer (500 per square mile). In October 2021, the town implemented a mobility-on-demand system integrated with smartphone software to replace its fixed-route community bus system, which consisted of four buses with three routes, each with a roughly one-hour, one way loop. The new service utilizes a fleet of six minivans, two of which are retrofitted with wheelchair-accessible ramps. The system may require that a passenger requesting a standard van walk up to 400 meters (a quarter mile) to their pickup location to optimize vehicle routing while providing origin-to-destination service. The on-demand system proved effective in providing service, eclipsing pre-pandemic ridership by 40%, decreasing greenhouse gas emissions per ride by 63%, and decreasing the cost per ride to the town by 29%. This report documents both the previous system and the new system in terms of routes, ridership, costs, fuel, and other notable system parameters. This work is part of an ongoing series of case studies on providing small communities with on-demand, right-sized vehicle service coupled with a smartphone application.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Understanding Emerging Building Technologies in Federal Performance Contracting Markets

Every year, federal technology evaluation programs test and assess the performance of building technologies that are being considered for wider deployment in federal facilities. Despite these investments in technology validation, many of the technologies evaluated by federal programs struggle to achieve broad penetration into the federal performance contracting market. This report contains the results of a market-research survey conducted by the National Renewable Energy Laboratory to understand barriers to the wider adoption of validated building technologies in the federal performance contracting market and how this information can be used to increase their deployment. The initial phase of this research focuses on the energy service company community and the barriers they perceive to wider adoption of these evaluated technologies. The report ends with an examination of recommendations for how the U.S. Department of Energy's Federal Energy Management Program can assist agencies in deploying emerging building technologies through energy savings performance contracts.

25 ENERGY STORAGE↗

Scaling Deep Energy Retrofits for Residential Walls - Energy, Cost, and Economic Assessment of Five Wall Systems

Providing strong economic and performance value is a primary challenge of convincing homeowners to implement deep energy retrofits to their wall systems. This study combines energy modeling and technoeconomic assessment of six experimental residential retrofit wall systems to typical existing homes in cold climates to evaluate their energy performance and cost effectiveness. Deep energy retrofits can significantly improve the energy performance of a home’s thermal envelope, help manage indoor environmental pollutants, increase homeowner comfort, increase building value, and register significant energy and cost savings in the process. We are evaluating exterior wall retrofit components and construction practices to measure and recommend steps to improve financial performance for manufacturers, installers and consumers. This study leverages a literature review, inputs from an advisory group made up of thermal enclosure experts, and simulations to identify state-of-the-art technologies for energy efficient wall systems that are suitable for cold and very cold climate zones. This paper will present results from energy modeling of six experimental wall systems compared to one baseline, that inform cost and energy performance of the subject wall systems.

Ganguli, Sumitrra↗

Fort Erie Case Study - Transition from Fixed-Route to On-Demand Transit

Rural and smaller-sized communities in North America face unique mobility challenges due to their low population density, lower public transit spending per capita compared to major cities, and a high reliance on private vehicles. In recent years, communities such as Fort Erie, Ontario, have restructured or advanced their public transit systems using on-demand services. Fort Erie is a relatively sparsely populated region of 32,901 residents, spread across a land area of 166 square kilometers (64 square miles), for an average population density of 193 residents per square kilometer (500 per square mile). In October 2021, the town implemented a mobility-on-demand system integrated with smartphone software to replace its fixed-route community bus system, which consisted of four buses with three routes, each with a roughly 1-hour, one-way loop. The new service utilizes a fleet of six minivans, two of which are retrofitted with wheelchair-accessible ramps. The system may require that a passenger requesting a standard van walk up to 400 meters (a quarter mile) to their pickup location to optimize vehicle routing while providing origin-to-destination service. The on-demand system proved effective in providing service, eclipsing pre-pandemic ridership by 40%, decreasing greenhouse gas emissions per ride by 63%, and decreasing the cost to the town per ride by 29%. This report documents both the previous system and the new system in terms of routes, ridership, costs, fuel, and other notable system parameters. This work is part of an ongoing series of case studies on providing small communities with on-demand, right-sized vehicle service coupled with a smartphone application.

ADVANCED PROPULSION SYSTEMS,ENERGY PLANNING, POLIC↗

Advancing Energy Justice in Alaska

NREL works with remote and rural communities across Alaska and the world to develop energy and building technologies that enhance culture, strengthen economies, and improve resilience in a changing environment. Alaska and Arctic communities not only face one of the harshest climates on earth; they also pay some of the highest energy and housing costs in the nation. NREL's Alaska Campus collaborates with communities and tribes to develop affordable, culturally appropriate homes and buildings that combine traditional knowledge and twenty-first century technology. Demonstration homes deployed all over Alaska prove out new technologies in energy efficiency, foundations, indoor air quality, and clean energy. Local workforce development is incorporated into every project: new homes are built by local workers, often including the home's future occupant. With the Arctic warming twice as fast as the rest of the planet, coastal erosion and thawing permafrost are wreaking havoc on roads, buildings, and infrastructure across Alaska. With an inclusive approach to R&D, NREL is helping communities adapt to a changing environment and advancing energy justice in the world's extremes.

Alaska housing prototypes↗