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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8

Revealing the role of redox reaction selectivity and mass transfer in current–voltage predictions for ensembles of photocatalysts

Photocatalysts are conceptually simple reaction units where nanoscale semiconductors integrated with catalysts drive a pair of redox reactions on illumination. However, the proximity of reaction sites performing cathodic and anodic reactions poses dire challenges to realize large light-to-fuel conversion efficiencies. In this study, a powerful, yet straightforward, equivalent-circuit detail-balance modeling framework is developed and applied to evaluate the performance of photocatalytic systems featuring multiple light absorbers. Specifically, low bandgap iridium-doped strontium titanate is modeled as a Z-scheme photocatalyst to achieve desirable hydrogen evolution and iron-based redox shuttle oxidation reactions. Our model has unique capabilities to simulate competing redox reactions and address mass-transfer limitations. In a significant departure from state-of-the-art circuit models, our study develops tools to perform load-line analyses by incorporating a net electrochemical load curve that includes both desired and competing redox reactions. Consequently, reaction selectivity is predicted from equivalent circuit models for photocatalytic and photoelectrochemical systems. Our investigation into ensembles comprised of multiple, semi-transparent light absorbers reveals their potential to outperform a single, optically thick light absorber, particularly when operated under mass-transfer-limited conditions. However, this outcome hinges on minimizing mass-transfer rates of select redox species to prevent undesired reactions of hydrogen oxidation and/or redox shuttle reduction. Our findings demonstrate that reaction selectivity can be achieved by tuning asymmetry in redox species mass-transfer even with perfectly symmetric electrocatalytic charge-transfer coefficients. The influences of various kinetic, mass-transfer, and thermodynamic parameters are explored to offer crucial insights for synthesis of the next-generation of photocatalysts and selective coatings, and reactor designs.

25 ENERGY STORAGE↗

Remote Sensing of Dissolved Organic Carbon (DOC) Stocks, Fluxes and Transformations Along the Land-Ocean Aquatic Continuum: Advances, Challenges, and Opportunities

From stream headwaters to the deep ocean, dissolved organic carbon (DOC) is ubiquitous across the world’s aquatic systems, where it fulfills important biogeochemical and ecological functions. Importantly, DOC is a dynamic component of the carbon cycle and represents a global reservoir (mass of carbon) equivalent in size to the atmospheric CO 2 pool. The mobilization, transport, and transformations of DOC along the land-ocean aquatic continuum biogeochemically connect terrestrial landscapes, freshwater and marine ecosystems, and the atmosphere. As a result, DOC budgets are vulnerable to climate- and human-driven changes. Having the ability to quantify DOC stocks, fluxes, and transformations consistently and accurately in aquatic systems is therefore critical to our understanding of DOC’s functions in the environment and of their susceptibility to change. In recent years, optical techniques and synoptic earth observations have opened new doors to achieve this objective on a global scale. In this review, we explore how in situ measurements, earth observations, and the models they inform have facilitated the large-scale quantification of DOC stocks, fluxes, and transformations along the land-ocean aquatic continuum and how they have helped shape our current understanding of the global DOC cycle. The review also explores the limitations and challenges we still face today, and discusses how upcoming and future sensors are expected to provide new insights into our understanding of the global DOC cycle.

Dissolved organic carbon↗

GEER Status Update

History: The Glenn Extreme Environments Rig (GEER) first became operational in the early part of 2015. Since that time GEER has completed a number of scientific tests and has undergone improvements in the chemical delivery system and analytics following a year of operations experience. Recent Updates: In June 2016, the GEER process system was rebuilt to provide a more robust system, higher accuracy and new capabilities. New insulation was installed on the exterior of the pressure vessel and gas lines. The newly revamped GEER plumbing system can provide extremely precise custom gas mixtures using any gas desired by the investigator in any combination. GEER can heat the resulting mixture up to 500 deg C and 1500 psia. The 304 stainless steel vessel walls were polished to reduce corrosion rate and reduce unwanted chemical reactions. The process lines were replaced with high purity Sulfinert coated tubing. The GEER team added the ability to individually boost specialty gases to GEER thus allowing operators to make very precise changes to the gas chemistry inside of GEER during a test while at high temperature and pressure. High accuracy mass flow meters were added to further improve gas mixing accuracy and precision. An in-line, integrated Inficon MicroGC Fusion was added for real time gas analysis along with a high purity gas sampling system, providing fully automated, real time analysis of the gas chemistry inside of GEER in minutes. This complements a co-located mass spectrometer and both are used for regular monitoring of the vessel chemistry. All internal vessel components were replaced with polished 304SS equivalents. Hot vent down capability was increased. Finally, an automated liquid injection system was added and is rated for max vessel operating conditions of (1500 psia, 500 C). Recent Results and Publications: In May 2016, GEER completed a test that exposed high temperature electronics to Venus surface conditions for 21.5 days. This demonstrated the potential for operating robotic spacecraft in the Venus environment without the need for thermal or environmental protection. Results from this test were published in December 2016 and received national media attention. In April 2017 GEER implemented an 80 day test at Venus surface conditions to simulate chemical weathering of expected Venus minerals. This test supported a ROSES award to a team led by Prof. Ralph Harvey of Case Western Reserve University. The test concluded in July 2017 and nearly doubled previous operation record of 42 days at Venus surface conditions. Preliminary results of these and previous experiments were presented at the recent Venus Modeling Workshop. In June 2017, NASA TM2017-219437 "Chemical and Microstructural Changes in Metallic and Ceramic Materials Exposed to Venusian Surface Conditions" was published. This report provides an extensive and valuable resource detailing the behavior of a variety of engineering materials at Venus surface conditions. Community Involvement: An external science advisory panel has been formed.

Kremic, Tibor↗

Propellant Slosh Analysis for the Solar Dynamics Observatory

The Solar Dynamics Observatory (SDO) mission, part of the Living With a Star program, is a geosynchronous satellite with tight pointing requirements. Due to a large amount of liquid propellant, a detailed slosh analysis is required to ensure the tight pointing budget can be satisfied. Much of the high fidelity slosh analysis and simulation has been performed via computational fluid dynamics. Even though this method of simulation is very accurate, it requires significant computational effort and specialized knowledge, limiting the ability of the SDO project to access fluid dynamics simulations at will. Furthermore, it is very difficult to incorporate most of these models into simulations of the overall spacecraft and its environment. Ultimately, the effects of the propellant slosh on the attitude stability and pointing performance of the entire spacecraft are of great interest to attitude control engineers. Equivalent mechanical models, such as models that approximate the fluid slosh effects by analogy to the movements of a point-mass pendulum, are important tools in simulating propellant slosh dynamics as part of the entire attitude determination and control system. This paper describes some of the current methods used to analyze and model slosh. It focuses on equivalent mechanical models and their incorporation into control-based analysis tools such as Simulink. The SDO mission is used as the case study for this work.

Mason, Paul A. C.↗

PG 0308 + 096 and PG 1026 + 002 - Two new short period binary stars resulting from common-envelope evolution

Ultraviolet spectroscopy, optical spectroscopy, and spectrophotometry have been used to study the excess UV stars PG 0308 + 096 and PG 1026 + 002. Both objects are short-period binary systems, each containing a DA white dwarf star and a dM star. Orbital periods of approximately 0.284 day for PG 0308 + 096, and aproximately 0.597 day for PG 1026, have been found by spectroscopic analysis of the H-alpha emission line. Ly-alpha and Balmer line profile fitting were used to estimate the mass of white dwarf stars; mass estimates for the dM stars are based on their spectral types. The orbital inclinations are derived from these masses, the periods, and amplitudes of the H-alpha radial velocity curves. The equivalent width of the H-alpha emission line, in each binary system, varies with the orbital phase in such a manner as to imply that it arises, in large part at least, from the hemisphere of the M star that faces the white dwarf star.

Saffer, Rex A.↗

A user's guide to the SUDAN computer program for determining the vibration modes of structural systems

The use of the SUDAN computer program for analyzing structural systems for their natural modes and frequencies of vibration is described. SUDAN is intended for structures which can be represented as an equivalent system of beam, spring, and rigid-body substructures. User-written constraint equations are used to analytically join the mass and stiffness matrices of the substructures to form the mass and stiffness matrices of the complete structure from which all the frequencies and modes of the system are determined. The SUDAN program can treat the case in which both the mass and stiffness matrices of the coupled system may be singular simultaneously. A general description of the FORTRAN IV program is given, the computer hardware and software specifications are indicated, and the input required by the program is described.

Kvaternik, R. G.↗

Z Camelopardalis - Outburst P Cygni profiles and quiescent continuum

The first orbital study of the C IV P Cygni profile in the dwarf nova Z Cam, a system of intermediate inclination. A modulation of the absorption equivalent width is apparent, with phases suggesting an effect from the mass-transfer stream. Over the outburst cycle, the strength of the P Cygni absorption and emission components is greater after outburst than during the standstill configuration, while the terminal velocities and central absorption wavelengths are similar. The continuum flux distributions during the decline from outburst and during quiescence are discussed.

Szkody, P.↗

Liquid Oxygen/Liquid Methane Test Summary of the RS-18 Lunar Ascent Engine at Simulated Altitude Conditions at NASA White Sands Test Facility

Tests were conducted with the RS18 rocket engine using liquid oxygen (LO2) and liquid methane (LCH4) propellants under simulated altitude conditions at NASA Johnson Space Center White Sands Test Facility (WSTF). This project is part of NASA s Propulsion and Cryogenics Advanced Development (PCAD) project. "Green" propellants, such as LO2/LCH4, offer savings in both performance and safety over equivalently sized hypergolic propellant systems in spacecraft applications such as ascent engines or service module engines. Altitude simulation was achieved using the WSTF Large Altitude Simulation System, which provided altitude conditions equivalent up to approx.120,000 ft (approx.37 km). For specific impulse calculations, engine thrust and propellant mass flow rates were measured. Propellant flow rate was measured using a coriolis-style mass-flow meter and compared with a serial turbine-style flow meter. Results showed a significant performance measurement difference during ignition startup. LO2 flow ranged from 5.9-9.5 lbm/sec (2.7-4.3 kg/sec), and LCH4 flow varied from 3.0-4.4 lbm/sec (1.4-2.0 kg/sec) during the RS-18 hot-fire test series. Thrust was measured using three load cells in parallel. Ignition was demonstrated using a gaseous oxygen/methane spark torch igniter. Data was obtained at multiple chamber pressures, and calculations were performed for specific impulse, C* combustion efficiency, and thrust vector alignment. Test objectives for the RS-18 project are 1) conduct a shakedown of the test stand for LO2/methane lunar ascent engines, 2) obtain vacuum ignition data for the torch and pyrotechnic igniters, and 3) obtain nozzle kinetics data to anchor two-dimensional kinetics codes.

Melcher, John C., IV↗

Liquid Oxygen/Liquid Methane Test Results of the RS-18 Lunar Ascent Engine at Simulated Altitude Conditions at NASA White Sands Test Facility

Tests were conducted with the RS-18 rocket engine using liquid oxygen (LO2) and liquid methane (LCH4) propellants under simulated altitude conditions at NASA Johnson Space Center White Sands Test Facility (WSTF). This project is part of NASA's Propulsion and Cryogenics Advanced Development (PCAD) project. "Green" propellants, such as LO2/LCH4, offer savings in both performance and safety over equivalently sized hypergolic propulsion systems in spacecraft applications such as ascent engines or service module engines. Altitude simulation was achieved using the WSTF Large Altitude Simulation System, which provided altitude conditions equivalent up to ~122,000 ft (~37 km). For specific impulse calculations, engine thrust and propellant mass flow rates were measured. LO2 flow ranged from 5.9 - 9.5 lbm/sec (2.7 - 4.3 kg/sec), and LCH4 flow varied from 3.0 - 4.4 lbm/sec (1.4 - 2.0 kg/sec) during the RS-18 hot-fire test series. Propellant flow rate was measured using a coriolis mass-flow meter and compared with a serial turbine-style flow meter. Results showed a significant performance measurement difference during ignition startup due to two-phase flow effects. Subsequent cold-flow testing demonstrated that the propellant manifolds must be adequately flushed in order for the coriolis flow meters to give accurate data. The coriolis flow meters were later shown to provide accurate steady-state data, but the turbine flow meter data should be used in transient phases of operation. Thrust was measured using three load cells in parallel, which also provides the capability to calculate thrust vector alignment. Ignition was demonstrated using a gaseous oxygen/methane spark torch igniter. Test objectives for the RS-18 project are 1) conduct a shakedown of the test stand for LO2/methane lunar ascent engines, 2) obtain vacuum ignition data for the torch and pyrotechnic igniters, and 3) obtain nozzle kinetics data to anchor two-dimensional kinetics codes. All of these objectives were met with the RS-18 data and additional testing data from subsequent LO2/methane test programs in 2009 which included the first simulated-altitude pyrotechnic ignition demonstration of LO2/methane.

Melcher, John C., IV↗

Evolutionary Design of Controlled Structures

Basic physical concepts of structural delay and transmissibility are provided for simple rod and beam structures. Investigations show the sensitivity of these concepts to differing controlled-structures variables, and to rational system modeling effects. An evolutionary controls/structures design method is developed. The basis of the method is an accurate model formulation for dynamic compensator optimization and Genetic Algorithm based updating of sensor/actuator placement and structural attributes. One and three dimensional examples from the literature are used to validate the method. Frequency domain interpretation of these controlled structure systems provide physical insight as to how the objective is optimized and consequently what is important in the objective. Several disturbance rejection type controls-structures systems are optimized for a stellar interferometer spacecraft application. The interferometric designs include closed loop tracking optics. Designs are generated for differing structural aspect ratios, differing disturbance attributes, and differing sensor selections. Physical limitations in achieving performance are given in terms of average system transfer function gains and system phase loss. A spacecraft-like optical interferometry system is investigated experimentally over several different optimized controlled structures configurations. Configurations represent common and not-so-common approaches to mitigating pathlength errors induced by disturbances of two different spectra. Results show that an optimized controlled structure for low frequency broadband disturbances achieves modest performance gains over a mass equivalent regular structure, while an optimized structure for high frequency narrow band disturbances is four times better in terms of root-mean-square pathlength. These results are predictable given the nature of the physical system and the optimization design variables. Fundamental limits on controlled performance are discussed based on the measured and fit average system transfer function gains and system phase loss.

Masters, Brett P.↗

Exploring Changes in Quasar Spectral Energy Distributions across C IV Parameter Space

We examine the UV/X-ray properties of 1378 quasars in order to link empirical correlations to theoretical models of the physical mechanisms dominating quasars as a function of mass and accretion rate. The clarity of these correlations is improved when (1) using C IV broad emission line equivalent width (EQW) and blueshift (relative to systemic) values calculated from high signal-to-noise ratio reconstructions of optical/UV spectra and (2) removing quasars expected to be absorbed based on their UV/X-ray spectral slopes. In addition to using the traditional C IV parameter space measures of C IV EQW and blueshift, we define a "C IV ∥ distance" along a best-fit polynomial curve that incorporates information from both C IV parameters. We find that the C IV ∥ distance is linearly correlated with both the optical-to-X-ray slope, α ox , and broad-line He II EQW, which are known spectral energy distribution indicators, but does not require X-ray or high spectral resolution UV observations to compute. The C IV ∥ distance may be a better indicator of the mass-weighted accretion rate, parameterized by L/L Edd , than the C iv EQW or blueshift alone, as those relationships are known to break down at the extrema. Conversely, there is only a weak correlation with the X-ray energy index (Γ), an alternate L/L Edd indicator. We find no X-ray or optical trends in the direction perpendicular to the C IV distance that could be used to reveal differences in accretion disk, wind, or corona structure that could be widening the C IV EQW–blueshift distribution. A different parameter (such as metallicity) not traced by these data must come into play.

79 ASTRONOMY AND ASTROPHYSICS↗

Pterodactyl: Thermal Protection System for Integrated Control Design of a Mechanically Deployed Entry Vehicle

The need for precision landing of high mass payloads on Mars and the return of sensitive samples from other planetary bodies to specific locations on Earth is driving the development of an innovative NASA technology referred to as the Deployable Entry Vehicle (DEV). A DEV has the potential to deliver an equivalent science payload with a stowed diameter 3 to 4 times smaller than a traditional rigid capsule configuration. However, the DEV design does not easily lend itself to traditional methods of directional control. The NASA Space Technology Mission Directorate (STMD)’s Pterodactyl project is currently investigating the effectiveness of three different Guidance and Control (G&C) systems – actuated flaps, Center of Gravity (CG) or mass movement, and Reaction Control System (RCS) – for use with a DEV using the Adaptable, Deployable, Entry, and Placement Technology (ADEPT) design. This paper details the Thermal Protection System (TPS) design and associated mass estimation efforts for each of the G&C systems. TPS is needed for the nose cap of the DEV and the flaps of the actuated flap control system. The development of a TPS selection, sizing, and mass estimation method designed to deal with the varying requirements for the G&C options throughout the trajectory is presented. The paper discusses the methods used to i) obtain heating environments throughout the trajectory with respect to the chosen control system and resulting geometry; ii) determine a suitable TPS material; iii) produce TPS thickness estimations; and, iv) determine the final TPS mass estimation based on TPS thickness, vehicle control system, vehicle structure, and vehicle payload.

Hays, Zane B.↗

Propulsion Physics Using the Chameleon Density Model

To grow as a space faring race, future spaceflight systems will require a new theory of propulsion. Specifically one that does not require mass ejection without limiting the high thrust necessary to accelerate within or beyond our solar system and return within a normal work period or lifetime. The Chameleon Density Model (CDM) is one such model that could provide new paths in propulsion toward this end. The CDM is based on Chameleon Cosmology a dark matter theory; introduced by Khrouy and Weltman in 2004. Chameleon as it is hidden within known physics, where the Chameleon field represents a scalar field within and about an object; even in the vacuum. The CDM relates to density changes in the Chameleon field, where the density changes are related to matter accelerations within and about an object. These density changes in turn change how an object couples to its environment. Whereby, thrust is achieved by causing a differential in the environmental coupling about an object. As a demonstration to show that the CDM fits within known propulsion physics, this paper uses the model to estimate the thrust from a solid rocket motor. Under the CDM, a solid rocket constitutes a two body system, i.e., the changing density of the rocket and the changing density in the nozzle arising from the accelerated mass. Whereby, the interactions between these systems cause a differential coupling to the local gravity environment of the earth. It is shown that the resulting differential in coupling produces a calculated value for the thrust near equivalent to the conventional thrust model used in Sutton and Ross, Rocket Propulsion Elements. Even though imbedded in the equations are the Universe energy scale factor, the reduced Planck mass and the Planck length, which relates the large Universe scale to the subatomic scale.

Robertson, Glen A.↗

Small to Full Height Scale Comparisons of Cesium Ion Exchange Performance with Crystalline Silicotitanate

The U.S. Department of Energy’s (DOE) Hanford Site houses 56 million gallons of high-level radioactive waste generated from plutonium production from 1944 to 1988. The supernatant waste, currently stored in underground tanks, is intended to be vitrified following filtration and 137 Cs removal at the Hanford Waste Treatment and Immobilization Plant (WTP) Low-Activity Waste (LAW) Vitrification Facility. The WTP Pretreatment Facility will not be operational for several years. The Tank Side Cesium Removal (TSCR) system is a technology demonstration that will remove cesium from tank waste supernate to support directly feeding LAW to the vitrification facility. The 137 Cs removal is important to meet the WTP LAW contract specification and ultimately for creating a contact-handled waste form. The waste acceptance criteria (WAC) limit for the WTP LAW Facility is <3.18E-5 Ci 137 Cs per mole Na. The TSCR system is skid mounted and employs two key technologies: dead end filtration for solids removal and ion exchange (IX) for cesium removal. Filtration is necessary to protect the functionality of the IX columns. The IX process utilizes sodium form crystalline silicotitanate (CST) IX media produced by UOP Honeywell, LLC (Des Plaines, IL) under the product name IONSIV R9140-B, 18 x 50 mesh, in a lead-lag-polish column configuration. Each column contains a CST bed height of 92 inches and a volume of approximately 157 gallons of CST IX media. The full-scale TSCR operation will run at a residence time of 1.9 bed volumes (BV)/h, which results in a superficial velocity of 7.3 cm/min and a flowrate of ~5 gal/min. Column testing at small (2.5% of the full bed height), medium (12% of the full bed height), and full-height scales has been previously conducted to evaluate process variables and scale up performance of Cs exchange onto the CST. Cesium load performances from various sieve cuts at the small scale indicated that a 30-mesh sieve cut be tested to determine if it better reflects the 12% and full-height column performances at the small scale. Two process flowrates were tested in the small-column configuration with <30-mesh CST and simulant solutions. These tests were compared to full-height column tests at the same residence times to assess CST particle size effect on column scaling. Table S.1 summarizes the observed column performance determined for the two flowrates juxtaposed to the previous work with 5.6 M Na simulant at higher scales (used as benchmarks). The WAC breakthroughs between the small and full-height tests at 1.3 BV/h differed by ~59 BVs. The WAC breakthroughs for small, medium, and full-height tests at 1.8 BV/h were consistent at 240 BVs. The 50% Cs breakthroughs were nominally equivalent for all column tests. The common transition zones and onsets of Cs breakthrough at the 1.8 BV/h tests indicated that the Cs mass transfers were equivalent and thus the <30-mesh CST Cs load performance at the small scale successfully modeled that of the full-height system. It is recommended that the <30-mesh CST be used in subsequent 10-mL CST bed tests.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Development of Pericyclic Gearbox for Roving Application

Many aerospace mechanisms require high gear reduction ratios to reduce the high output speed of a motor to much lower speeds for precision rotation. Conventionally this actuation is performed with multiple gear stages, typically including a harmonic gearbox, and is required to be lightweight for spaceflight. One application of multiple gear stages is in rover wheel actuators intended for use on the Moon and Mars. These actuators require low total mass, high reliability, and precision actuation due to their remote operation. The pericyclic gearbox has the capability in a single stage to provide high reduction ratios equivalent to multiple conventional stages. Some benefits of utilizing pericyclic gear technology over multiple conventional stages are a compact form, fewer total parts, no reliance on flexible members (such as in harmonic drives), and lower total system mass. The goal of this work was to modify and build on existing modeling tools to determine the feasibility of utilizing the pericyclic gearbox for such an application. Critical aspects to consider were gear tooth loads, gear mesh efficiency, bearing loads, bearing efficiency, and total system mass. Developed tools were then used to examine a single stage pericyclic gearbox's trends in mass and efficiency for a Mars 2020 rover wheel actuator mechanism design case which was then compared to multistage gearbox designs.

Krantz, Timothy↗

Alternate approaches to vibration and shock analysis using NASTRAN

A method that derives an approximate equivalent static load to a base excitation shock analysis is described. The transient analysis in the current level of NASTRAN, level 16, does not directly provide for either input acceleration forcing functions or enforced boundary displacement. In the suggested alternate analysis format, equivalent force input functions are applied to the constrained locations by using the artifice of placing a large mass, with respect to the total system mass, at the desired acceleration input points. This shortcut static analysis approach is presented to approximate the expensive and time consuming dynamics analysis approach to the base excitation shock analysis.

Denver, R. E.↗

Numerical and boundary condition effects on the prediction of detonation engine behavior using detailed numerical simulations

High-fidelity numerical simulations of an experimental rotating detonation engine with discrete fuel/air injection were conducted. A series of configurations with different feed-plenum pressures but with constant equivalence ratio were studied. Detailed chemical kinetics for the hydrogen/air system is used. A resolution study for the full rotating detonation engine (RDE) system simulation is also conducted. Two kinds of boundary conditions, a total pressure boundary and a constant mass flow rate boundary, are used to assess the effects of the inlet boundary. As mass flow rate is increased, the total pressure boundary causes more error in the axial pressure distribution while the constant mass flow rate gives a better solution for all cases ran. The simulations confirm experimental findings, and reproduce qualitative as well as some of the quantitative trends. These results demonstrate that a) fuel-air mixing is highly non-uniform within the detonation chamber, leading to variations in local equivalence ratio, b) the fuel and oxidizer injectors experience significant backflow as the detonation wave passes over, but recover at different rates which further augments the inefficiencies in mixing, and c) parasitic combustion in the mixing region makes the detonation wave weak by extending the reaction zone across the wave.

33 ADVANCED PROPULSION SYSTEMS↗