Search NASA⌕ Search

SEARCH · Search NASA

Results for “Experimental matrix”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1989

A simple laminate theory using the orthotropic viscoplasticity theory based on overstress. I - In-plane stress-strain relationships for metal matrix composites

A macromechanics analysis is presented for the in-plane, anisotropic time-dependent behavior of metal matrix laminates. The small deformation, orthotropic viscoplasticity theory based on overstress represents lamina behavior in a modified simple laminate theory. Material functions and constants can be identified in principle from experiments with laminae. Orthotropic invariants can be repositories for tension-compression asymmetry and for linear elasticity in one direction while the other directions behave in a viscoplastic manner. Computer programs are generated and tested for either unidirectional or symmetric laminates under in-plane loading. Correlations with the experimental results on metal matrix composites are presented.

Krempl, Erhard↗
DOE OSTI2025

Relationship between microporous structure and light gas transport through glassy polymeric membranes revealed by molecular simulations

Microporous glassy polymers are attractive materials for gas separation membranes, due to their high permeability and tailorable selectivity, provided physical aging can be delayed. The archetypal microporous glassy polymer, PTMSP, can be blended with a hyper-crosslinked isatin–triptycene porous polymer network (PPN) to delay physical aging. However, while PPN is effective at reducing physical aging, it also affects the permeability of light gases through PTMSP. Molecular dynamics simulations were used here to shed fundamental light on the mechanisms responsible for these effects. Atomistic models are developed that satisfactorily reproduce experimental observations such as matrix density and cavity size distributions for neat PTMSP as well as for PTMSP–PPN blends. Analysis of the simulation results suggests that physical aging is delayed because the PPN inclusions slow down PTMSP relaxation while reducing the connectivity between free volume pockets. To understand how PPN inclusions affect light gas permeability, the atomistic models developed are used to probe CO 2 and CH 4 diffusion and sorption. These simulations are conducted for PTMSP matrices exhibiting varying density, towards reproducing experimental permeability data. Interrogating the simulation trajectories, it is discovered that while CH 4 travels preferentially through the free volume cavities, CO 2 preferentially interacts with the available surfaces, especially in the presence of PPN. These differences help interpret experimental observations. The transport of C 2 H 6 and H 2 S through PTMSP matrices was also investigated. These gases, and in particular H 2 S, were found to absorb within PTMSP, yielding very low diffusion coefficients. The ability to predict differences in diffusion pathways for various natural gas components unveils the possibility of engineering membranes to control permeability and selectivity towards large-scale applications.

Bao Le, Tran Thi [Univ. of Oklahoma, Norman, OK (U↗
NASA NTRS1983

Transverse thermal expansion of carbon fiber/epoxy matrix composites

Thermal expansion coefficients and moduli of elasticity have been determined experimentally for a series of epoxy-matrix composites reinforced with carbon and Kevlar fibers. It is found that in the transverse direction the difference between the properties of the fiber and the matrix is not as pronounced as in the longitudinal direction, where the composite properties are fiber-dominated. Therefore, the pattern of fiber packing tends to affect transverse composite properties. The transverse properties of the composites tested are examined from the standpoint of the concept of homogeneity defined as the variation of packing (or lack thereof) throughout a sample.

Helmer, J. F.↗
NASA NTRS2000

Boiling on Microconfigured Composite Surfaces Enhanced

Boiling heat transfer is one of the key technologies for the two-phase active thermal-control system used on space platforms, as well as for the dynamic power systems aboard the International Space Station. Because it is an effective heat transfer mode, boiling is integral to many space applications, such as heat exchangers and other cooling devices. Nucleate boiling near the critical heat flux (CHF) can transport very large thermal loads with a much smaller device and much lower pumping power than for single-phase heat exchangers. However, boiling performance sharply deteriorates in a reduced-gravity environment, and operation in the CHF regime is somewhat perilous because of the risk of burnout to the device surface. New materials called microconfigured metal-graphite composites can enhance boiling. The photomicrograph shows the microconfiguration (x3000) of the copper-graphite (Cu-Gr) surface as viewed by scanning electronic microscope. The graphite fiber tips appear as plateaus with rugged surfaces embedded in the copper matrix. It has been experimentally demonstrated that this type of material manifests excellent boiling heat transfer performance characteristics and an increased CHF. Nonisothermal surfaces were less sensitive to variations of wall superheat in the CHF regime. Because of the great difference in conductivity between the copper base and the graphite fiber, the composite surfaces have a nonisothermal surface characteristic and, therefore, will have a much larger "safe" operating region in the CHF regime. In addition, the thermocapillary forces induced by the temperature differences between the fiber tips and the metal matrix play an important role in bubble detachment, and may not be adversely affected in a reduced-gravity environment. All these factors indicate that microconfigured composites may improve the reliability and economy (dominant factors in all space applications) of various thermal components found on spacecraft during future missions.

Chao, David F.↗
NASA NTRS1971

Basic characteristics of high-frequency Stark-effect modulation of CO2 lasers.

The molecular Stark effect and its application to the modulation of infrared laser radiation have been investigated both theoretically and experimentally. Using a density matrix approach, a quantum mechanical description of the effect of a time-varying electric field on the absorption coefficient and refractive index of a molecular gas near an absorption line has been formulated. For modulation applications a quantity known as the ?modulation depth' is of prime importance. Theoretical expressions for the frequency dependence of the modulation depth show that the response to the frequency of a time-varying Stark field is separated into a nondispersive and a dispersive region, depending on whether the modulating frequency is less than or greater than the homogeneous absorption linewidth. Experimental results showing nondispersive modulation at frequencies to 30 MHz are presented. In addition it is shown that the response of modulation depth to Stark field amplitude is separated into linear and nonlinear regions, the field at which nonlinearities begin being determined by the absorption spectrum of the molecule being used.

Claspy, P. C.↗
DOE OSTI2024

Matrix-based Omnidirectional Pressure Integratio

This software enables the calculation of the pressure field based on experimental velocity measurements utilizing the matrix-based omnidirectional pressure integration algorithm developed by Dr. John Charonko and Dr. Fernando Zigunov, which is several orders of magnitude faster than the current state of the art.

Zigunov, Fernando↗
NASA NTRS1972

Matrix transformations for spacecraft attitude determination

A common problem for experimental space physicists is the determination of the attitude matrix T which transforms vectors between representations in X and X' coordinate systems according to (vector V sub X) = (T sub XX')(vector V sub X'). A straightforward, simple, and efficient solution for the transformation matrix is a double-cross transformation. It is calculated from any two directions A and B, which are vectors normalized to unit length and are known in both X and X' coordinates. The B direction need be known only well enough to define the plane in which vectors A and B lie. The problem of the intersection of two cones as applicable to attitude solutions is also discussed.

Cauffman, D. P.↗
NASA NTRS1973

Effects of thermal loading on fiber-reinforced composites with constituents of differing thermal expansivities.

Estimates of the magnitudes of elastic stresses and elastoplastic stresses and strains were made for tungsten fiber-reinforced 80Ni + 20Cr matrix composites. Heating or cooling between 80 and 2000 F was assumed. The calculated elastic stresses exceeded representative or estimated strengths of constituents. For composites with less than 0.65 volume fraction of fiber, plastic flow was considered possible, and elastoplastic solutions indicated that stresses would be reduced but with the concomitant occurrence of sufficiently large strain ranges, particularly in the matrix, to pose a possible thermal fatigue problem. Limited experimental studies on tungsten fiber-copper matrix composites heated and cooled a number of times between 80 and 1600 F in a conventional furnace and then heated from 80 to 1652 F in a hot-stage microscope resulted in matrix microfracture for a 70 volume fraction fiber composite and substantial matrix strain for a 40 volue fraction fiber composite.

Hoffman, C. A.↗
DOE OSTI2023

Pauli transfer matrix direct reconstruction: channel characterization without full process tomography

Abstract We present a tomographic protocol for the characterization of multiqubit quantum channels. We discuss a specific class of input states, for which the set of Pauli measurements at the output of the channel directly relates to its Pauli transfer matrix components. We compare our results to those of standard quantum process tomography, showing an exponential reduction in the number of different experimental configurations required by a single matrix element extraction, while keeping the same number of shots. This paves the way for more efficient experimental implementations, whenever a selective knowledge of the Pauli transfer matrix is needed. We provide several examples and simulations.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2023

Engineering chirality at wafer scale with ordered carbon nanotube architectures

Creating artificial matter with controllable chirality in a simple and scalable manner brings new opportunities to diverse areas. Here we show two such methods based on controlled vacuum filtration - twist stacking and mechanical rotation - for fabricating wafer-scale chiral architectures of ordered carbon nanotubes (CNTs) with tunable and large circular dichroism (CD). By controlling the stacking angle and handedness in the twist-stacking approach, we maximize the CD response and achieve a high deep-ultraviolet ellipticity of 40 ± 1 mdeg nm -1 . Our theoretical simulations using the transfer matrix method reproduce the experimentally observed CD spectra and further predict that an optimized film of twist-stacked CNTs can exhibit an ellipticity as high as 150 mdeg nm -1 , corresponding to a g factor of 0.22. Furthermore, the mechanical rotation method not only accelerates the fabrication of twisted structures but also produces both chiralities simultaneously in a single sample, in a single run, and in a controllable manner. The created wafer-scale objects represent an alternative type of synthetic chiral matter consisting of ordered quantum wires whose macroscopic properties are governed by nanoscopic electronic signatures and can be used to explore chiral phenomena and develop chiral photonic and optoelectronic devices.

36 MATERIALS SCIENCE↗
DOE OSTI2021

Full-dimensional quantum stereodynamics of the non-adiabatic quenching of OH(A2Σ+) by H2

Abstract The Born–Oppenheimer approximation, assuming separable nuclear and electronic motion, is widely adopted for characterizing chemical reactions in a single electronic state. However, the breakdown of the Born–Oppenheimer approximation is omnipresent in chemistry, and a detailed understanding of the non-adiabatic dynamics is still incomplete. Here we investigate the non-adiabatic quenching of electronically excited OH(A 2 Σ + ) molecules by H 2 molecules using full-dimensional quantum dynamics calculations for zero total nuclear angular momentum using a high-quality diabatic-potential-energy matrix. Good agreement with experimental observations is found for the OH(X 2 Π) ro-vibrational distribution, and the non-adiabatic dynamics are shown to be controlled by stereodynamics, namely the relative orientation of the two reactants. The uncovering of a major (in)elastic channel, neglected in a previous analysis but confirmed by a recent experiment, resolves a long-standing experiment–theory disagreement concerning the branching ratio of the two electronic quenching channels.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Block-Type Antiferromagnetism in Single Chain Quasi-One-Dimensional K 3 ⁢Fe 2 ⁢Se 4

One-dimensional (1D) structures provide a unique platform to study the correlated quantum interactions and phase transitions such as unconventional magnetism and superconducting states. Here, we report that iron chalcogenide K 3 ⁢Fe 2 ⁢Se 4 exhibits an unusual block-type canted antiferromagnetic (AFM) order with a clear single chain quasi-1D structure, which is structurally different from the two-leg ladder BaFe 2 ⁢Se 3 , through both experimental measurements and density matrix renormalization group (DMRG) calculations. The narrow bandgap semiconductor K 3 ⁢Fe 2 ⁢Se 4 has a quasi-1D edge-shared FeSe4 tetrahedra chain structure and orders antiferromagnetically below 110 K. The magnetic moments couple antiferromagnetically along the quasi-1D chain direction of the 𝑏 axis and form an up-down-down-up (↑−↓−↓−↑)–like spin structure with a commensurate propagation vector 𝒌=⁢(0,0,0), where block-type spin ↑−↑ or ↓−↓ coupling are between the longer Fe-Fe bonds of the quasi-1D chain. DMRG results show that block antiferromagnetic state is stable in K 3 ⁢Fe 2 ⁢Se 4 and reveal that the block-ordered arrangement of Fe 2.5+ ions spins arise from the competition between ferromagnetic and AFM interaction in the presence of strong electronic correlation. Our research results not only report the discovery of a clear block-type canted antiferromagnetic structure in a real quasi-1D chain material but also provide a theoretical approach to understand the block-type antiferromagnetism in quasi-1D iron chalcogenides.

antiferromagnetism↗
DOE OSTI2026

Signatures of QCD conductivities in heavy-ion collisions

Dissipative processes are pivotal for understanding the hydrodynamic evolution of hot and dense quantum chromodynamics (QCD) matter created in relativistic nuclear collisions. The interplay of multiple conserved charges—net baryon, strangeness, and electric charge—is of particular interest. Here, we simulate the longitudinal hydrodynamic evolution with the three diffusion currents in a hydrodynamic model with a lattice-QCD-based equation of state, NEOS -4 D , and estimate rapidity distributions including diffusive corrections to the phase-space distribution in the presence of multiple charges, which ensure charge conservation at particlization. We determine the response of particle yields at midrapidity to changes in the diagonal and off-diagonal conductivities. Inversely, we find that most components of the conductivity matrix can be constrained experimentally using identified particle multiplicities at different collision energies.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2024

Posterior Covariance Matrix Approximations

Here, the Davis equation of state (EOS) is commonly used to model thermodynamic relationships for high explosive (HE) reactants. Typically, the parameters in the EOS are calibrated, with uncertainty, using a Bayesian framework and Markov Chain Monte Carlo (MCMC) methods. However, MCMC methods are computationally expensive, especially for complex models with many parameters. This paper provides a comparison between MCMC and less computationally expensive Variational methods (Variational Bayesian and Hessian Variational Bayesian) for computing the posterior distribution and approximating the posterior covariance matrix based on heterogeneous experimental data. All three methods recover similar posterior distributions and posterior covariance matrices. This study demonstrates that for this EOS parameter calibration application, the assumptions made in the two Variational methods significantly reduce the computational cost but do not substantially change the results compared to MCMC.

97 MATHEMATICS AND COMPUTING↗
DOE OSTI2025

Pion and Kaon decays from lattice QCD and |Vud|, |Vus|

We review lattice calculations of the form factors for Kaon semileptonic decays and the leptonic decay constants of Kaons and Pions. We discuss the determinations of the CKM matrix elements $|V_{ud}|$ and $|V_{us}|$ using the form factors and experimental results. We use the CKM matrix elements to test first-row unitarity of the CKM matrix.

Simone, J. N. [Fermilab] (ORCID:0000000185153337)↗
NASA NTRS1988

A computational study of the TiO2 molecule

A computational investigation of the ground 1A1 and lowest energy B2 states of the titanium dioxide molecule has been carried out. The treatment utilized SCF calculations in an extended basis followed by a CI treatment for each geometry. The ground state geometry agrees well with experiment, while the agreement between the computed vibrational frequency nu1 and the experimental value for a matrix isolated TiO2 is less satisfactory. Population analysis for the ground state indicates less than one excess electron on each oxygen atom. The first excited state has a linear geometry and the singlet and triplet are essentially degenerate.

Ramana, M. V.↗