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At least 145 records · Page 8

Investigation of Oxygen-Induced Quenching of Phosphorescence in Photoexcited Aromatic Molecules by Positron Annihilation Spectroscopy

Platinum OctaEthyl Porphyrin (Pt.OEP) is an efficient phosphor under ultraviolet excitation. The phosphorescent triplet state P(T(Sup 1)) is readily quenched by the oxygen O2 molecules. This phenomenon is being utilized as the basis for global air pressure measurements in aerodynamic facilities at various laboratories. The exact mechanism by which O2 molecules quench the P(T(Sup 1) approaches P(S(Sub O)) transitions is still unknown. The diamagnetic singlet states P(S(Sub n)), which feed P(T(Sub 1)) states via intersystem crossings, would presumably not be affected by O2. It must be only the magnetic P(T(Sub 1)) states, which can interact with the paramagnetic O2 molecules, that are affected. However, our positron lifetime and Doppler broadening studies suggest the formation of O2P(S(Sub n)), complexes which can also eventually reduce the population of the P(T(Sub 1)) states (i.e., quench phosphorescence). This reduction is possible because higher triplet states in (Pt.OEP) are admixed with the P(S(Sub 1)), states via spin orbit interactions. The experimental procedures and the results of various measurements are presented in this paper.

Singh, Jag J.↗

Formation and Migration of Trans-Neptunian Objects

We consider that trans-Neptunian objects (TNOs) with diameter d greater than 100 kilometers moving now in not very eccentric orbits could be formed directly by the compression of large rarefied dust condensations (with a greater than 30 AU), but not by the accretion of smaller solid planetesimals. Probably, some planetesimals with d approximately 100- 1000 kilometers in the feeding zone of the giant planets and even large main-belt asteroids also could be formed directly by such compression. Some smaller objects (TNOs, planetesimals, asteroids) could be debris of larger objects, and other such objects could be formed directly by compression of condensations. A small portion of planetesimals from the feeding zone of the giant planets that entered into the trans-Neptunian region could left in eccentrical orbits beyond Neptune and became so called "scattered objects". Our computer runs in which gravitational interactions of bodies were taken into account with the use of the spheres method, showed that the embryos of Uranus and Neptune could increase their semimajor axes from less than 10 AU to their present values, moving permanently in orbits with small eccentricities, due to gravitational interactions with the migrating planetesimals. Later on, Thommes et al. considered a similar model using direct numerical integration. The total amount of water delivered to the Earth during the formation of the giant, planets was about the mass of water in the Earth oceans. The end of such bombardment could be caused mainly by the planetesimals that became scattered objects. For the present mass of the trans-Neptunian belt, the collisional lifetime of 1-kilometer TNO is about the age of the Solar system, but only a small portion (less than 1%) of 100-km TNOs could be destroyed during this age. The probability of destruction of a typical TNO (with 30 less than a,less than 50 AU) by scattered objects can be of the same order of magnitude as that by typical TNOs. TNOs could be even more often destroyed during planet formation than during last 4 Gyr. The analysis of the results of the orbital evolution of Jupiter-crossing objects (JCOs) and TNOs showed that, in principle, the trans-Neptunian belt can provide up to 100% of Earth-crossing objects, but, of course, some of them came from the main asteroid belt. Most of the collisions of former JCOs with the Earth were from orbits with aphelia inside Jupiter's orbit and belonged to a small portion of objects which moved in such orbits for a long time. About 1 of 300 JCOs collided with the Sun. The ratio of the total mass of icy planetesimals that migrated from the feeding zone of the giant planets and collided with the planet to the mass of this planet was greater (by a factor of 3 in our runs) for Mars than that for Earth and Venus.

Ipatov, S. I.↗

A Presentation of Spectacular Visualizations. Visions of Our Planet's Atmosphere, Land and Oceans: ETheater Presentation

The NASA/NOAA/AMS Earth Science Electronic Theater presents Earth science observations and visualizations in a historical perspective. Fly in from outer space to Florida and the KSC Visitor's Center. Go back to the early weather satellite images from the 1960s see them contrasted with the latest International global satellite weather movies including killer hurricanes & tornadic thunderstorms. See the latest spectacular images from NASA and NOAA remote sensing missions like GOES, NOAA, TRMM, SeaWiFS, Landsat7, & new Terra which will be visualized with state-of-the art tools. Shown in High Definition TV resolution (2048 x 768 pixels) are visualizations of hurricanes Lenny, Floyd, Georges, Mitch, Fran and Linda. See visualizations featured on covers of magazines like Newsweek, TIME, National Geographic, Popular Science and on National & International Network TV. New Digital Earth visualization tools allow us to roam & zoom through massive global images including a Landsat tour of the US, with drill-downs into major cities using 1 m resolution spy-satellite technology from the Space Imaging IKONOS satellite. Spectacular new visualizations of the global atmosphere & oceans are shown. See massive dust storms sweeping across Africa. See ocean vortices and currents that bring up the nutrients to feed tiny plankton and draw the fish, giant whales and fisherman. See how the ocean blooms in response to these currents and El Nino/La Nina climate changes. The demonstration is interactively driven by a SGI Octane Graphics Supercomputer with dual CPUs, 5 Gigabytes of RAM and Terabyte disk using two projectors across the super sized Universe Theater panoramic screen.

Hasler, Fritz↗

Visions of Our Planet's Atmosphere, Land and Oceans Electronic-Theater 2001

The NASA/NOAA/AMS Electronic Theater presents Earth science observations and visualizations in a historical perspective. Fly in from outer space to Fredericton New Brunswick. Drop in on the Kennedy Space Center and Park City Utah, site of the 2002 Olympics using 1 m IKONOS "Spy Satellite" data. Go back to the early weather satellite images from the 1960s and see them contrasted with the latest US and International global satellite weather movies including hurricanes & tornadoes. See the latest spectacular images from NASA/NOAA and Canadian remote sensing missions like Terra GOES, TRMM, SeaWiFS, Landsat 7, and Radarsat that are visualized & explained. See how High Definition Television (HDTV) is revolutionizing the way we communicate science in cooperation with the American Museum of Natural History in NYC. See dust storms in Africa and smoke plumes from fires in Mexico. See visualizations featured on Newsweek, TIME, National Geographic, Popular Science covers & National & International Network TV. New visualization tools allow us to roam & zoom through massive global images eg Landsat tours of the US, Africa, & New Zealand showing desert and mountain geology as well as seasonal changes in vegetation. See animations of the polar ice packs and the motion of gigantic Antarctic Icebergs from SeaWinds data. Spectacular new visualizations of the global atmosphere & oceans are shown. See massive dust storms sweeping across Africa. See vortexes and currents in the global oceans that bring up the nutrients to feed tiny plankton and draw the fish, whales and fisherman. See the how the ocean blooms in response to these currents and El Nino/La Nina climate changes. The demonstration is interactively driven by a SGI Onyx II Graphics Supercomputer with four CPUs, 8 Gigabytes of RAM and Terabyte of disk. With multiple projectors on a giant screen. See the city lights, fishing fleets, gas flares and bio-mass burning of the Earth at night observed by the "night-vision" DMSP military satellite.

Hasler, A. F.↗

Electronic-Theater 2001: Visions of Our Planet's Atmosphere, Land and Oceans

The NASA/NOAA/AMS Electronic Theater presents Earth science observations and visualizations in a historical perspective. Fly in from outer space to Wisconsin, Madison and the Monona Terrace Center. Drop in on the Kennedy Space Center and Park City Utah, site of the 2002 Olympics using I m IKONOS "Spy Satellite" data. Go back to the early weather satellite images from the 1960s pioneered by UW. Scientists and see them contrasted with the latest US and International global satellite weather movies including hurricanes & tornadoes. See the latest spectacular images from NASA/NOAA remote sensing missions like Terra GOES, TRMM, SeaWiFS, Landsat 7 that are visualized & explained. See how High Definition Television (HDTV) is revolutionizing the way we communicate science in cooperation with the American Museum of Natural History in NYC. See dust storms in Africa and smoke plumes from fires in Mexico. See visualizations featured on Newsweek, TIME, National Geographic, Popular Science covers & National & International Network TV. New visualization tools allow us to roam & zoom through massive global images eg Landsat tours of the US, Africa, & New Zealand showing desert and mountain geology as well as seasonal changes in vegetation. See animations of the polar ice packs and the motion of gigantic Antarctic Icebergs from SeaWinds data. Spectacular new visualizations of the global atmosphere & oceans are shown. See massive dust storms sweeping across Africa. See vortices and currents in the global oceans that bring up the nutrients to feed tiny plankton and draw the fish, whales and fisherman. See the how the ocean blooms in response to these currents and El Nina/La Nina climate changes. The demonstration is interactively driven by a SGI Onyx 11 Graphics Supercomputer with four CPUs, 8 Gigabytes of RAM and Terabyte of disk. With five projectors on a giant IMAX sized 18 x 72 ft screen. See the city lights, fishing fleets, gas flares and bio-mass burning of the Earth at night observed by the "nightvision" DMSP military satellite.

Hasler, Authur↗

Interactions among convection, magnetic fields and p-mode oscillations in the sun

Two papers on different aspects of the excitation and damping of solar oscillations were accepted for publication in the Astrophysical Journal. The first paper evaluates the rate at which turbulent convection feeds energy into individual p-modes. It is shown that stochastic excitation by turbulent convection provides a satisfactory fit to the product of the mode energies and linewidths. A somewhat surprising conclusion is that entropy fluctuations are about an order of magnitude more significant than are fluctuations of the Reynolds stress in exciting p-modes. However, entropy fluctuations cannot excite f-modes. This may account for the relatively low energies of the f-modes compared to those of the p-modes. The second paper explores the role of scattering of acoustic modes by turbulent velocity fluctuations. Scattering of a mode is concentrated near the top of its acoustic cavity. Because the turbulence has low Mach number, scattering couples modes having similar frequencies. Its net effects are to increase the linewidths of all modes and to transfer energy from p-modes to f-modes. Scattering is likely to be the dominant source for the linewidths of p-modes. In particular, it may account for the unexpectedly large linewidths measured for low frequency modes. Copies of preprints of the two papers referred to above are attached. The remainder of the report is devoted to a description of unpublished results.

Goldreich, Peter↗

PBI nanofiber mat-reinforced anion exchange membranes with covalently linked interfaces for use in water electrolysers

Anion exchange membranes (AEM) are key components in anion exchange membrane water electrolysers. Recently developed materials are less susceptible to the alkaline degradation of the polymer backbone and quaternary ammonium groups. A remaining challenge is the mechanical stability in contact with hot water and dimensional stability when the temperature of the feed solution changes. One solution is to reinforce membranes with a porous support. Since support materials like PEEK or PTFE have a different swelling behavior than the matrix and no strong interactions with the matrix, voids can form, and gas crossover increases. In this work, we approach this issue by pore filling polybenzimidazole nanofiber mats with the bromomethylated precursor of mTPN, an ultra-stable AEM material. During drying, a covalent interaction between support (PBI amine groups) and matrix (-CH 2 Br) is established. After quaternization, the optimized PBI/mTPN-50.120 composite membrane still shows a high conductivity of 62 mS cm –1 , but 37% reduced length swelling in comparison to the non-reinforced membrane. Tensile strength and Young's modulus increase 17% and 56% to 49 MPa and 680 MPa, respectively. In an electrolyser, a stable voltage of 1.98V at 0.25 A cm –2 was achieved, and no change in membrane resistance was observed over the test time of 200 h (50°C, 1 M KOH, catalysts based on Ni/Fe and Mo).

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Metal Hydride Compressor for High-Pressure (875 bar) Hydrogen Delivery

Metal hydride hydrogen compression utilizes a reversible heat-driven interaction of a hydride-forming metal alloy with hydrogen gas. This paper reports on the development of a laboratory scale two-stage Metal Hydride Compressor (MHC) system with a feed pressure of 150 bar delivering high purity H2 gas at outlet pressures up to 875 bar. Stage 1 and stage 2 AB 2 metal hydrides are identified based on experimental characterization of the pressure-composition-temperature (PCT) behavior of candidate materials. The selected metal hydrides are each combined with expanded natural graphite, increasing the thermal conductivity of the composites by an order of magnitude. These composites are integrated in two compressor beds with internal heat exchangers that alternate between hydrogenation and dehydrogenation cycles by thermally cycling between 20 °C and 150 °C. The prototype compressor achieved compression of hydrogen from 150 bar to 700 bar with an average flow rate of 33.6 g/hr.

08 HYDROGEN↗

Integrating microbial communities into algal biotechnology: a pathway to enhanced commercialization

Microalgae are increasingly recognized for their potential in wastewater treatment and the sustainable production of feedstock for fuel, feed, food, and other bioproducts. Like conventional agricultural systems, algal cultivation involves complex microbial communities. However, despite their pivotal role in cultivation outcomes, especially at the commodity-scale, the critical interactions between microalgae and their microbiomes are often overlooked. Here we synthesize current knowledge on the taxonomic diversity, ecological roles, and biotechnological potential of algal microbiomes, with a focus on their interactions with algal hosts through nutrient exchange, growth modulation, pathogen defense, and environmental conditioning. We also examine how environmental factors such as nutrient availability, salinity, and temperature influence these interactions. Advances in microbiome engineering, including synthetic biology and ecological approaches, offer opportunities to enhance beneficial algal-microbiome interactions, thereby improving growth, resilience, and yield. These advancements could lead to more sustainable and economically viable microalgae cultivation, with far-reaching implications for environmental management and biotechnological innovation. By addressing key economic and environmental barriers, microbiome engineering holds transformative potential to revolutionize large-scale algae cultivation and provide sustainable solutions to global challenges.

Microbiology↗

Water resources planning for rivers draining into Mobile Bay

The application of remote sensing, automatic data processing, modeling and other aerospace related technologies to hydrological engineering and water resource management are discussed for the entire river drainage system which feeds the Mobile Bay estuary. The adaptation and implementation of existing mathematical modeling methods are investigated for the purpose of describing the behavior of Mobile Bay. Of particular importance are the interactions that system variables such as river flow rate, wind direction and speed, and tidal state have on the water movement and quality within the bay system.

April, G. C.↗

An expert system to analyze high frequency dependent data for the space shuttle main engine turbopumps

The prototype expert system ADDAMX identifies selected sinusoid frequencies from spectral data graphs as speed frequencies and harmonics from each turbopump, frequency feed through from one turbopump to another, frequencies generated by turbopump bearings, pseudo 3N for the phase 2 high pressure fuel turbopump, and electrical noise. ADDAMX does the analysis in an interactive or batch mode and the results can be displayed on the screen or hardcopy.

Garcia, Raul C., Jr.↗

Analysis of airframe/engine interactions in integrated flight and propulsion control

An analysis framework for the assessment of dynamic cross-coupling between airframe and engine systems from the perspective of integrated flight/propulsion control is presented. This analysis involves to determining the significance of the interactions with respect to deterioration in stability robustness and performance, as well as critical frequency ranges where problems may occur due to these interactions. The analysis illustrated here investigates both the airframe's effects on the engine control loops and the engine's effects on the airframe control loops in two case studies. The second case study involves a multi-input/multi-output analysis of the airframe. Sensitivity studies are performed on critical interactions to examine the degradations in the system's stability robustness and performance. Magnitudes of the interactions required to cause instabilities, as well as the frequencies at which the instabilities occur are recorded. Finally, the analysis framework is expanded to include control laws which contain cross-feeds between the airframe and engine systems.

Schierman, John D.↗

Visions of Our Planet's Atmosphere, Land and Oceans: Electronic-Theater 2000

The NASA/NOAA/AMS Earth Science Electronic Theater presents Earth science observations and visualizations in a historical perspective. Fly in from outer space to the Delaware Bay and Philadelphia area. Go back to the early weather satellite images from the 1960s see them contrasted with the latest International global satellite weather movies including killer tropical cyclones & tornadic thunderstorms. See the latest spectacular images from NASA, NOAA & UMETSAT remote sensing missions like GOES, Meteosat, NOAA, TRMM, SeaWiFS, Landsat7, & new Terra which will be visualized with state-of-the art tools. Shown in High Definition TV resolution (2048 x 768 pixels) are visualizations of hurricanes Lenny, Floyd, Georges, Mitch, Fran and Linda. see visualizations featured on covers of magazines like Newsweek, TIME, National Geographic, Popular Science and on National & International Network TV. New Digital Earth visualization tools allow us to roam & zoom through massive global images including Landsat tours of the US, and Africa with drill downs of major global cities using 1 m resolution commercialized spy-satellite technology from the Space Imaging IKONOS satellite. Spectacular new visualizations of the global atmosphere & oceans are shown. See massive dust storms sweeping across Africa. see ocean vortexes and currents that bring up the nutrients to feed tiny plankton and draw the fish, giant whales and fisherman. See the how the ocean blooms in response to these currents and El Nino/La Nina climate changes. The demonstration is interactively driven by a SGI Octane Graphics Supercomputer with dual CPUs, 5 Gigabytes of RAM and Terabyte disk using two projectors across a super sized panoramic screen.

Hasler, A. F.↗

Visions of Our Planet's Atmosphere, Land & Oceans - ETheater Presentation

The NASA/NOAA/AMS Earth Science Electronic Theater presents Earth science observations and visualizations in a historical perspective. Fly in from outer space to Florida and the KSC Visitor's Center. Go back to the early weather satellite images from the 1960s see them contrasted with the latest International global satellite weather movies including killer hurricanes & tornadic thunderstorms. See the latest spectacular images from NASA and NOAA remote sensing missions like GOES, NOAA, TRMM, SeaWiFS, Landsat7, & new Terra which will be visualized with state-of-the art tools. Shown in High Definition TV resolution (2048 x 768 pixels) are visualizations of hurricanes Lenny, Floyd, Georges, Mitch, Fran and Linda. See visualizations featured on covers of ma'gazines like Newsweek, TIME, National Geographic, Popular Science and on National & International Network TV. New Digital Earth visualization tools allow us to roam & zoom through massive global images including a Landsat tour of the US, with drill-downs into major cities using 1 m resolution spy-satellite technology from the Space Imaging IKONOS satellite. Spectacular new visualizations of the global atmosphere & oceans are shown. See massive dust storms sweeping across Africa. See ocean vortexes and currents that bring up the nutrients to feed tiny plankton and draw the fish, giant whales and fisherman. See the how the ocean blooms in response to these currents and El Nino/La Nina climate changes. The demonstration is interactively driven by a SGI Octane Graphics Supercomputer with dual CPUS, 5 Gigabytes of RAM and Terabyte disk using two projectors across the super sized Universe Theater panoramic screen.

Hasler, F.↗

A Presentation of Spectracular Visualizations

The NASA/NOAA/AMS Earth Science Electronic Theater presents Earth science observations and visualizations in a historical perspective. Fly in from outer space to Florida and the KSC Visitor's Center. Go back to the early weather satellite images from the 1960s see them contrasted with the latest International global satellite weather movies including killer hurricanes & tornadic thunderstorms. See the latest spectacular images from NASA and NOAA remote sensing missions like GOES, NOAA, TRMM, SeaWiFS, Landsat7, & new Terra which will be visualized with state-of-the art tools. Shown in High Definition TV resolution (2048 x 768 pixels) are visualizations of hurricanes Lenny, Floyd, Georges, Mitch, Fran and Linda. See visualizations featured on covers of magazines like Newsweek, TIME, National Geographic, Popular Science and on National & International Network TV. New Digital Earth visualization tools allow us to roam & zoom through massive global images including a Landsat tour of the US, with drill-downs into major cities using I m resolution spy-satellite technology from the Space Imaging IKONOS satellite. Spectacular new visualizations of the global atmosphere & oceans are shown. See massive dust storms sweeping across Africa. See ocean vortexes and currents that bring up the nutrients to feed tiny plankton and draw the fish, giant whales and fisherman. See the how the ocean blooms in response to these currents and El Nino/La Nina climate changes. The demonstration is interactively driven by a SGI Octane Graphics Supercomputer with dual CPUs, 5 Gigabytes of RAM and Terabyte disk using two projectors across the super sized Universe Theater panoramic screen.

Hasler, Fritz↗

A Presentation of Spectacular Visualizations

The NASA/NOAA/AMS Earth Science Electronic Theater presents Earth science observations and visualizations in a historical perspective. Fly in from outer space to Florida and the KSC Visitor's Center. Go back to the early weather satellite images from the 1960s see them contrasted with the latest International global satellite weather movies including killer hurricanes and tornadic thunderstorms. See the latest spectacular images from NASA and the National Oceanic and Atmospheric Administration (NOAA) remote sensing missions like the Geostationary Operational Environmental Satellites (GOES), NOAA, Tropical Rainfall Measuring Mission (TRMM), SeaWiFS, Landsat7, and new Terra which will be visualized with state-of-the art tools. Shown in High Definition TV resolution (2048 x 768 pixels) are visualizations of hurricanes Lenny, Floyd, Georges, Mitch, Fran, and Linda. See visualizations featured on covers of magazines like Newsweek, TIME, National Geographic, Popular Science, and on National and International Network TV. New Digital Earth visualization tools allow us to roam and zoom through massive global images including a Landsat tour of the US, with drill-downs into major cities using one meter resolution spy-satellite technology from the Space Imaging IKONOS satellite. Spectacular new visualizations of the global atmosphere and oceans are shown. See massive dust storms sweeping across Africa. See ocean vortexes and currents that bring up the nutrients to feed tiny plankton and draw the fish, giant whales and fisherman. See the how the ocean blooms in response to these currents and El Nino/La Nina climate changes. The demonstration is interactively driven by a SGI Octane Graphics Supercomputer with dual CPUs, 5 Gigabytes of RAM and Terabyte disk using two projectors across the super sized Universe Theater panoramic screen.

Hasler, Fritz↗

NASA/NOAA/AMS Earth Science Electronic Theatre

The NASA/NOAA/AMS Earth Science Electronic Theater presents Earth science observations and visualizations in a historical perspective. Fly in from outer space to Florida and the KSC Visitor's Center. Go back to the early weather satellite images from the 1960s see them contrasted with the latest International global satellite weather movies including killer hurricanes & tornadic thunderstorms. See the latest spectacular images from NASA and NOAA remote sensing missions like GOES, NOAA, TRMM, SeaWiFS, Landsat 7, & new Terra which will be visualized with state-of-the art tools. Shown in High Definition TV resolution (2048 x 768 pixels) are visualizations of hurricanes Lenny, Floyd, Georges, Mitch, Fran and Linda. See visualizations featured on covers of magazines like Newsweek, TIME, National Geographic, Popular Science and on National & International Network TV. New Digital Earth visualization tools allow us to roam & zoom through massive global images including a Landsat tour of the US, with drill-downs into major cities using 1 m resolution spy-satellite technology from the Space Imaging IKONOS satellite, Spectacular new visualizations of the global atmosphere & oceans are shown. See massive dust storms sweeping across Africa. See ocean vortexes and currents that bring up the nutrients to feed tiny plankton and draw the fish, giant whales and fisherman. See the how the ocean blooms in response to these currents and El Nino/La Nina climate changes. The demonstration is interactively driven by a SGI Octane Graphics Supercomputer with dual CPUs, 5 Gigabytes of RAM and Terabyte disk using two projectors across the super sized Universe Theater panoramic screen.

Hasler, Fritz↗

Brief Update on Advancements by Commercial Vendors/Options for Feeding and Pumping Biomass Slurries for Hydrothermal Liquefaction

In 2011, Pacific Northwest National Laboratory (PNNL), working as a partner in the National Advanced Biofuels Consortium, issued a report assessing the viable industrial feed system and pump options for a 2000 dry metric tons per day production-scale hydrothermal liquefaction (HTL) plant (Berglin et al. 2012). This report was issued as PNNL-21981, Review and Assessment of Commercial Vendors/Options for Feeding and Pumping Biomass Slurries for Hydrothermal Liquefaction, and will be referred to as “Pump Survey” for reference. It had the following scope: • Identify relevant applications and industries operating at comparable scales • Interact with commercial vendors and pursue integration between vendors • Take advantage of commercial off-the-shelf (COTS) technology • Supply and support vendor needs for biomass feedstock rheology characterization • Provide vendors with process requirements to support selection of conceptual design for feedstock handing and pump system • Obtain cost data to the extent possible from equipment vendors to support the technical economic analysis (TEA) • Identify issues associated scale-up. The current document represents an update to the prior report in order to: 1. Identify advancements in vendor-reported technologies 2. List reports of new experience or trials with biomass pumping applications 3. Determine if technology/application gaps identified in the prior report have been filled 4. Capture ideas on future research.

09 BIOMASS FUELS↗