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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1980

Gas phase hydrogen permeation in alpha titanium and carbon steels

Commercially pure titanium and heats of Armco ingot iron and steels containing from 0.008-1.23 w/oC were annealed or normalized and machined into hollow cylinders. Coefficients of diffusion for alpha-Ti and alpha-Fe were determined by the lag-time technique. Steady state permeation experiments yield first power pressure dependence for alpha-Ti and Sievert's law square root dependence for Armco iron and carbon steels. As in the case of diffusion, permeation data confirm that alpha-titanium is subject to at least partial phase boundary reaction control while the steels are purely diffusion controlled. The permeation rate in steels also decreases as the carbon content increases. As a consequence of Sievert's law, the computed hydrogen solubility decreases as the carbon content increases. This decreases in explained in terms of hydrogen trapping at carbide interfaces. Oxidizing and nitriding the surfaces of alpha-titanium membranes result in a decrease in the permeation rate for such treatment on the gas inlet surfaces but resulted in a slight increase in the rate for such treatment on the gas outlet surfaces. This is explained in terms of a discontinuous TiH2 layer.

Johnson, D. L.↗
NASA NTRS1989

Gas-phase flowrate effect on disintegrating cryogenic liquid-jets

Two phase liquid and gaseous nitrogen flow in a pneumatic two fluid atomizer was investigated. Characteristic dropsize for cryogenic sprays were measured with a scattered light scanning instrument developed at NASA-Lewis. Tests were conducted primarily in the aerodynamic stripping regime of liquid jet atomization. At a sampling distance of bar-x=1.3 cm, the Sauter mean, D(sub 32), and volume median, D(sub v.5), drop diameters were measured and correlated with nitrogen gas flowrate, W(sub n), to give the following expressions: D sub 32 to the -1=210W(sub n) to the -1.33 and D(sub v.5) to the -1=150 W(sub n to the -1.33, where reciprocal diameters and gas flowrate are in cm (-1) and g/sec, respectively. The exponent 1.33 for nitrogrn gas flowrate, W(sub n), is the same as that predicted by atomization theory for liquid-jet breakup in high velocity gasflow. When the spray was sampled at axial distances of bar-x=2.5 and 4.5 cm downstream of the atomizer, the exponent decreased to 1.2 and 0.9, respectively. This was attributed to the loss of small droplets due to their rapid vaporization.

Ingebo, Robert D.↗
NASA NTRS1990

Gas-phase flowrate effect on disintegrating cryogenic liquid-jets

Two phase liquid and gaseous nitrogen flow in a pneumatic two fluid atomizer was investigated. Characteristic dropsize for cryogenic sprays were measured with a scattered light scanning instrument developed at NASA-Lewis. Tests were conducted primarily in the aerodynamic stripping regime of liquid jet atomization. At a sampling distance of bar-x =1.3 cm, the Sauter mean, D(sub 32), and volume median, D(sub v.5), drop diameters were measured and correlated with nitrogen gas flowrate, W(sub n), to give the following expressions: D sub 32 to the -1=210W(sub n) to the -1.33 and D(sub v.5) to the -1=150 W(sub n to the -1.33, where reciprocal diameters and gas flowrate are in cm (-1) and g/sec, respectively. The exponent 1.33 for nitrogen gas flowrate, W(sub n), is the same as that predicted by atomization theory for liquid-jet breakup in high velocity gasflow. When the spray was sampled at axial distances of bar-x=2.5 and 4.5 cm downstream of the atomizer, the exponent decreased to 1.2 and 0.9, respectively. This was attributed to the loss of small droplets due to their rapid vaporization.

Ingebo, Robert D.↗
NASA NTRS1990

Collision-induced gas phase dissociation rates

The Landau-Zener theory of reactive cross sections was applied to diatomic molecules dissociating from a ladder of vibrational states. The result predicts a dissociation rate that is quite well duplicated by an Arrhenius function having a preexponential temperature dependence of about T(sub -1/2), at least for inert collision partners. This relation fits experimental data reasonably well. The theory is then used to calculate the effect of vibrational nonequilibrium on dissociation rate. For Morse oscillators, the results are about the same as given by Hammerling, Kivel, and Teare in their analytic approximation for harmonic oscillators, though at very high temperature a correction for the partition function limit is included. The empirical correction for vibration nonequilibrium proposed by Park, which is a convenient algorithm for CFD calculations, is modified to prevent a drastic underestimation of dissociation rates that occurs with this method when vibrational temperature is much smaller than the kinetic temperature of the gas.

Hansen, C. Frederick↗
NASA NTRS1971

Alkyl substituent effects on gas-phase acidities - The influence of hybridization.

Exploration of the effect on acidity of alkyl groups bonded to trigonal and digonal carbon. Some results on the relative acidities of toluene and p-xylene, and acetylene and substitute acetylenes, as determined by ion cyclotron resonance (icr) spectroscopy, are described. Some limitations of the CNDO/2 calculation method are discussed.

Brauman, J. I.↗
NASA NTRS1972

Solid-gas phase equilibria and thermodynamic properties of cadmium selenide.

Accurate vapor pressures are determined through direct weight loss measurements using the Knudsen effusion technique. The experimental data are evaluated by establishing the mode of vaporization and determining the heat capacity of cadmium selenide at elevated temperatures. Additional information is obtained through a second- and third-law evaluation of data, namely, the heat of formation and the absolute entropy of cadmium selenide. A preferential loss of selenium during the initial heating of CdSe is observed, which leads to a deviation in stoichiometry.

Sigai, A. G.↗
NASA NTRS1973

Gas phase recombination of hydrogen and deuterium atoms

Rate constants for the reaction H + H + M - H2 + M, with M = H2, He, and Ar were measured over the temperature range 77 to 298 K. Hydrogen atoms were produced by thermal dissociation and absolute atom concentrations were measured through use of self-balancing, isothermal catalytic probe detector. The specific rate constants were 8.1 + or - 0.4 x 10 to the minus 33rd power, 7.0 + or - 0.4 x 10 to the minus 33rd power, and 9.2 + or - 0.6 x at 298 K for M = H2, He, and Ar respectively; these values rising to 18.5 + or - 2.2 x 10 to the minus 33rd power, 12.0 + or - 1.5 x 10 to the minus 33rd power, and 27.4 + or - 4.6 x 10 to the minus 33rd power cm to the 6th power/molecules sq/sec at 77 K. for the equivalent deuterium atom process with D2 as the third body, the rate constants are 6.1 + or - 0.3 x 10 to the minus 33rd power cm to the 6th power/molecules sq/sec at 298 K and 15.1 + or - 1.0 x 10 to the minus 33rd power cm to the 6th power/molecules sq/sec at 77 K. These values are compared with previous experimental measurements and with recent theoretical calculations.

Trainor, D. W.↗
NASA NTRS1971

Gas-phase acidities of binary hydrides.

The preferred direction of proton transfer in a reaction between a hydride molecule and a hydride ion was studied in order to determine the relative acidities of some binary hydrides. Sufficient data are presented to make clear the periodic trends in acidities and the underlying trends in other fundamental thermochemical quantities which influence acidity. The bond dissociation energies and electron affinities of the hydrides considered are listed in a table.

Brauman, J. I.↗
NASA NTRS1975

Ultraviolet-gas phase and -photocatalytic synthesis from CO and NH3

Ammonium cyanate is identified as the major product of the photolysis of gaseous NH3-CO mixtures at 206.2 or 184.9 nm. Lesser amounts of urea, biurea, biuret semicarbazide, formamide and cyanide are observed. A series of 18 reactions underlying the formation of photolysis products is presented and discussed. Photocatalytic syntheses of C-14-urea, -formamide, and -formaldehyde are carried out through irradiation of (C-14)O and NH3 in the presence of Vycor, silica gel, or volcanic ash shale surfaces. The possible contributions of the relevant reactions to the abiotic synthesis of organic nitrogen compounds on Mars, the primitive earth, and in interstellar space are examined.

Hubbard, J. S.↗