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At least 145 records · Page 8

Application of Remote Sensing to Assess the Impact of Short Term Climate Variability on Coastal Sedimentation

The purpose of this joint University of Wisconsin (UW) and Louisiana State University (LSU) project has been to relate short term climate variation to response in the coastal zone of Louisiana in an attempt to better understand how the coastal zone is shaped by climate variation. Climate variation in this case largely refers to variation in surface wind conditions that affect wave action and water currents in the coastal zone. The primary region of focus was the Atchafalaya Bay and surrounding bays in the central coastal region of Louisiana. Suspended solids in the water column show response to wind systems both in quantity (through resuspension) and in the pattern of dispersement or transport. Wind systems associated with cold fronts are influenced by short term climate variation. Wind energy was used as the primary signature of climate variation in this study because winds are a significant influence on sediment transport in the micro-tidal Gilf of Mexico coastal zone. Using case studies, the project has been able to investigate the influence of short term climate variation on sediment transport. Wind energy data, collected daily for National Weather Service (NWS) stations at Lake Charles and New Orleans, LA, were used as an indicator of short term climate variation influence on seasonal time scales. A goal was to relate wind energy to coastal impact through sediment transport. This goal was partially accomplished by combining remote sensing and wind energy data. Daily high resolution remote sensing observations are needed to monitor the complex coastal zone environment, where winds, tides, and water level all interact to influence sediment transport. The NASA Earth Observing System (EOS) era brings hope for documenting and revealing response of the complex coastal transport mosaic through regular high spatial resolution observations from the Moderate resolution Imaging Spectrometer (MODIS) instrument. MODIS observations were sampled in this project for information content and should continue to be viewed as a resource for coastal zone monitoring. The project initialized the effort to transfer a suspended sediment concentration (SSC) algorithm to the MODIS platform for case 2 waters. MODIS enables monitoring of turbid coastal zones around the globe. The MODIS SSC algorithm requires refinements in the atmospheric aerosol contribution, sun glint influence, and designation of the sediment inherent optical properties (IOPs); the framework for continued development is in place with a plan to release the algorithm to the MODIS direct broadcast community.

Menzel, W. Paul↗

Model Advancements to Enable Impact Analysis of Climate Change on Streamflow Temperature

With support from the Department of Energy’s Water Power Technologies Office, Pacific Northwest National Laboratory (PNNL) has developed new tools that incorporate cutting-edge climate and hydrological science capabilities to assess the potential long-term impacts of future climate conditions on unregulated streamflow and water temperature within watershed-river-reservoir systems. The objectives of this project were achieved by enhancing key hydrologic and hydrodynamic models and transferring them to a high-performance computing environment to provide a high-spatiotemporal resolution, multi-scale modeling framework. The new modeling framework has the potential to quantify risks related climate change impacts on runoff, unregulated streamflow, and water temperature. Initial development and demonstration of the modeling framework was conducted under historical and future climate conditions in the Columbia River Basin in the Pacific Northwest and the Connecticut River Basin in New England.

13 HYDRO ENERGY↗

Future Intensity‐Duration‐Frequency Curves of Extreme Precipitation in the Midwest United States From Convection‐Permitting Modeling

Abstract During the last four decades, global warming has statistically significant intensified extreme precipitation events in the Midwestern United States (defined here as the region covering Illinois, Indiana, Ohio, and Kentucky), leading to increased risks to human life, property, and infrastructure. To enable climate change adaptation and resilience across various economic and social sectors in this region, updated information about future climate changes, specifically at finer spatial scales, is essential. Leveraging a new 150‐year dynamical downscaling data set at convection‐permitting resolution, this study introduces a framework to construct the projected future intensity‐duration‐frequency (IDF) curves of heavy precipitation, which are prominent tools for infrastructure design and water resources management. This framework generates IDF curves at both sub‐daily and multi‐day duration utilizing hourly in situ observations as well as quantile‐based statistical techniques in bias‐correction and return levels selection. The assumption of non‐stationarity in the distribution parameter fitting process is also implemented in this workflow. Compared to historical IDF curves for 1980–2022, future projected IDF curves for 2058–2100 under Representative Concentration Pathway (RCP) 4.5 and RCP 8.5 scenarios indicate an average intensity increase of approximately 15% and 25%, respectively, across 74 stations, considering both annual and seasonal timescales. Future projections suggest that extreme precipitation events may become more severe across six investigated return periods, with longer return periods showing a greater increase. The frequency of future extreme precipitation events in the Midwest region is also projected to double. Furthermore, current results reveal spatial heterogeneity of future trends across stations owing to the high‐resolution input data set. Plain Language Summary This study investigates the evolving nature of extreme precipitation events in the Midwestern United States under a changing climate. By leveraging a high‐resolution dynamical downscaling data set, we construct projected intensity‐duration‐frequency (IDF) curves for future extreme rainfall events. These curves serve as vital tools for infrastructure planning and water resource management. Our analysis reveals a significant increase in both the intensity and frequency of extreme precipitation events in the region. Future projected IDF curves for the late century indicate an average intensity increase of approximately 15%–25% compared to historical values. Moreover, the frequency of such events is expected to double. Spatial heterogeneity in future trends is observed across different stations within the Midwest, highlighting the importance of high‐resolution modeling in capturing localized climate variability. These findings underscore the urgent need for climate adaptation strategies to mitigate the increasing risks associated with extreme precipitation events in the region. Key Points This study introduces a workflow to construct future intensity‐duration‐frequency (IDF) curves over the Midwest United States using a new convection‐permitting modeling data set The current IDF construction workflow reproduces well the historical observed IDF 30 curves in summer months with median relative errors of 2.4% among 74 stations and 6 investigated durations The projected IDF curves show diverse future trends of extreme precipitation across stations, with intensity increases of approximately 15% and 25% under RCP4.5 and RCP8.5 climate scenarios, respectively, and a doubling of frequency on average

Nguyen, Trung↗

Dynamics of Playa Lakes in the Texas High Plains

The author has identified the following significant results. This project is designed to correlate ERTS-1 satellite imagery signatures with the water balance ecosystem and geology of select playa lake basins in West Texas. The principal work consisted of monitoring the weather instruments, the measurement of water levels and water depths examination of MSS imagery, and measurement of water and mud areas by use of ESIAC (Electronic Satellite Image Analysis Console) at Stanford Research Center, Menlo Park, California. A cost/benefit analysis, comparing the use of ERTS-1 data to more conventionally secured data, revealed that use of ERTS-1 data for such a survey reduces cost from $2.00 to $0.03/square mile.

Reeves, C. C., Jr.↗

Ultrasonic Waves in Water Visualized With Schlieren Imaging

The Acoustic Liquid Manipulation project at the NASA Glenn Research Center at Lewis Field is working with high-intensity ultrasound waves to produce acoustic radiation pressure and acoustic streaming. These effects can be used to propel liquid flows to manipulate floating objects and liquid surfaces. Interest in acoustic liquid manipulation has been shown in acoustically enhanced circuit board electroplating, microelectromechanical systems (MEMS), and microgravity space experiments. The current areas of work on this project include phased-array ultrasonic beam steering, acoustic intensity measurements, and schlieren imaging of the ultrasonic waves.

Juergens, Jeffrey R.↗

Influence of the Yukon River on the Bering Sea

Physical and biological oceanography of the northern Bering Sea including the influence of the Yukon River were studied. Satellite data acquired by the Advanced Very High Resolution Radiometer (AVHRR), the LANDSAT Multispectral Scanner (MSS) and the Thematic Mapper (TM) sensor were used to detect sea surface temperatures and suspended sediments. Shipboard measurements of temperature, salinity and nutrients were acquired through the Inner Shelf Transfer and Recycling (ISHTAR) project and were compared to digitally enhanced and historical satellite images. The satellite data reveal north-flowing, warm water along the Alaskan coast that is highly turbid with complex patterns of surface circulation near the Yukon River delta. To the west near the Soviet Union, cold water, derived from an upwelling, mixes with shelf water and also flows north. The cold and warm water coincide with the Anadyr, Bering Shelf and Alaskan coastal water masses. Generally, warm Alaskan coastal water forms near the coast and extends offshore as the summer progresses. Turbid water discharged by the Yukon River progresses in the same fashion but extends northward across the entrance to Norton Sound, attaining its maximum surface extent in October. The Anadyr water flows northward and around St. Lawrence Island, but its extent is highly variable and depends upon mesoscale pressure fields in the Arctic Ocean and the Bering Sea.

Dean, Kenneson G.↗

RAFT: Reconfigurable Array of High-Efficiency Ducted Turbines for Hydrokinetic Energy Harvesting

Diversifying the energy harvesting portfolio is crucial to achieving the ambitious goal of transitioning to clean energy by 2030. Marine hydrokinetic energy has garnered renewed interest due to its high harvesting potential in the U.S., and the resource's reliability and predictability—remaining relatively constant on a daily basis and available 24/7. However, there are currently few commercial devices capable of harnessing the energy from flowing water. This project aims to bridge that gap by designing and evaluating a novel hydrokinetic turbine concept that can efficiently harvest energy from both rivers and tidal streams. The RAFT (Reconfigurable Array of High-Efficiency Ducted Turbines) concept introduces a duct surrounding the turbine rotor and creates an array of small 5-kW units. The duct serves two primary purposes: (1) it enhances hydrodynamic efficiency by accelerating flow to the rotor, and (2) it functions as a structural component, facilitating the formation of modular arrays that lower costs. This project focuses on demonstrating this concept and validating these benefits through simulations and scaled prototype testing. The project team includes 8 faculty members and over 20 students from 3 universities, organized into three core areas: hydrodynamics, electrical systems, and structural analysis, with additional teams dedicated to system integration, environmental assessment and risk management, and tech-to-market strategy. The team successfully demonstrated the increased hydrodynamic efficiency of a ducted turbine compared to an unducted version using high-fidelity simulations and prototype tests. Moreover, design optimization efforts led to surpassing the SHARKS program's goal of 60% reduction of the levelized cost of energy with a significant margin.

13 HYDRO ENERGY↗

Ensemble-Based Characterization of Historical Storm Types in ERA5 over CONUS

We present Storm-Type Labeled Precipitation, a gridded dataset that classifies ERA5 precipitation over CONUS (20–50° N, 125–66° W) by storm type at 6-hourly resolution. Each grid cell/time step is assigned to one of five classes—mesoscale convective system (MCS), extratropical cyclone (ETC), hurricane (HUR), atmospheric river (AR), or other convective, with an “unidentified” code reserved for cases with no detected type. Two products are provided: (i) a TempestExtremes (TE)–only version, and (ii) a hybrid TRACK–TE version that uses TRACK for ETCs and HURs and TE for MCSs and ARs. Outputs are integer masks aligned to ERA5 precipitation, supporting storm-type attribution of rainfall, event compositing, trend analysis, and model evaluation. Future work will extend detection to high-resolution downscaled Earth system model projections to support evaluations of projected changes in hydrologic hazards that may threaten critical water and energy infrastructures.

Rastogi, Deeksha [ORNL] (ORCID:0000000204624027)↗

The JERS-1 Amazon Multi-Season Mapping Study (JAMMS)

Regional mapping of the Amazon basin using imaging radar is described. Two 60-day periods of radar mapping will be conducted, one in 1995, and one in 1996. One period will view the low-water season, and the other will view during the high-flood season. The main objective of the JAMMS project is to generate a regional map showing inundation throughout the Amazon Basin by comparing the two data sets.

Amazon Radar Mapping Earth Satellite JAMMS flood p↗

High-Resolution Specification of the Land and Ocean Surface for Improving Regional Mesoscale Model Predictions

The exchange of energy and moisture between the Earth's surface and the atmospheric boundary layer plays a critical role in many meteorological processes. High-resolution, accurate representations of surface properties such as sea-surface temperature (SST), soil temperature and moisture content, ground fluxes, and vegetation are necessary to better understand the Earth-atmosphere interactions and improve numerical predictions of sensible weather. The NASA Short-term Prediction Research and Transition (SPoRT) Center has been conducting separate studies to examine the impacts of high-resolution land-surface initialization data from the Goddard Space Flight Center Land Information System (LIS) on subsequent WRF forecasts, as well as the influence of initializing WRF with SST composites derived from the MODIS instrument. This current project addresses the combined impacts of using high-resolution lower boundary data over both land (LIS data) and water (MODIS SSTs) on the subsequent daily WRF forecasts over Florida during May 2004. For this experiment, the WRF model is configured to run on a nested domain with 9- km and 3-kin grid spacing, centered on the Florida peninsula and adjacent coastal waters of the Gulf of Mexico and Atlantic Ocean. A control configuration of WRF is established to take all initial condition data from the NCEP Eta model. Meanwhile, two WRF experimental runs are configured to use high-resolution initialization data from (1) LIS land-surface data only, and (2) a combination of LIS data and high-resolution MODIS SST composites. The experiment involves running 24-hour simulations of the control WRF configuration, the MS-initialized WRF, and the LIS+MODIS-initialized WRF daily for the entire month of May 2004. All atmospheric data for initial and boundary conditions for the Control, LIS, and LIS+MODIS runs come from the NCEP Eta model on a 40-km grid. Verification statistics are generated at land surface observation sites and buoys, and the impacts of the high-resolution lower boundary data on the development and evolution of mesoscale circulations such as sea and land breezes are examined, This paper will present the results of these WRF modeling experiments using LIS and MODIS lower boundary datasets over the Florida peninsula during May 2004.

Case, Jonathan L.↗

The SeaFlux Turbulent Flux Dataset Version 1.0 Documentation

Under the auspices of the World Climate Research Programme (WCRP) Global Energy and Water cycle EXperiment (GEWEX) Data and Assessment Panel (GDAP), the SeaFlux Project was created to investigate producing a high-resolution satellite-based dataset of surface turbulent fluxes over the global oceans. The most current release of the SeaFlux product is Version 1.0; this represents the initial release of turbulent surface heat fluxes, associated near-surface variables including a diurnally varying sea surface temperature.

Clayson, Carol Anne↗

INSTRUMENTATION FOR IN-CORE REAL-TIME MECHANICAL TESTING OF STRUCTURAL MATERIALS (INCREASE) PROJECT

Idaho National Laboratory (INL), in collaboration with the Electric Power Research Institute (EPRI), Nuclear Regulatory Commission, French Atomic and Alternative Energies Commission (CEA), Joint Research Centre, Nuclear Research and Consultancy Group, and Research Center Rez, is the operating agent of the In-Core Real-Time Mechanical Testing of Structural Materials (INCREASE) joint experimental program (JEEP) project that operates within the Nuclear Energy Agency (NEA)’s Framework for Irradiation Experiments (FIDES-II) program. The first objective of the INCREASE project is to design a shared capsule that can house a variety of in-core mechanical testing instrumentation for enabling smart irradiation experiments. The second objective is to collect in core stress relaxation data pertaining to high priority stainless steel (SS) materials under light water reactor conditions with target temperature of 340°C +/-20°C and a minimum neutron damage of 2 displacement per atom (dpa). The INCREASE project will be demonstrated in the Massachusetts Institute of Technology Nuclear Research Reactor (MITR).

36 MATERIALS SCIENCE↗

Robust In-Situ Strain Measurements to Monitor CO 2 Storage

The goal of this project was to develop and demonstrate robust instrumentation to monitor the in-situ strain tensor in order to improve the reliability and security of CO 2 storage in geologic formations. We met the original goals of the project and the major overarching accomplishment is the advancement of strain tensor monitoring from an intriguing concept to a commercially available technology with a solid foundation of novel instruments supported by theoretical analyses and validation experiments. The main accomplishments of the project are summarized below. We designed, built and evaluated nine new optical fiber strainmeters and tiltmeters using Michelson interferometers to measure deformation with ultra-high resolution at both shallow and deep point locations in the subsurface. These are the robust strainmeters that motivated the title of the project. We designed, built and evaluated a novel method of measuring distributed strain in optical fibers with nanostrain resolution, and cm-scale location, and sampling into the seismic band. The new method is called Coherence-length-gated Microwave Photonics Interfereometry (CMPI). CMPI technology has advantages over existing commercial DAS and DSS methods. We developed and demonstrated capabilities to deploy instruments in the field and used them to measure strain caused by ambient signals like barometric pressure and tides, as well as induced signals like surface loading and pore pressure changes from pumping tests. We deployed a working strainmeter at 1,700 ft depth, slightly above an active reservoir. This is to our knowledge the greatest depth a strainmeter has been deployed and the techniques we used can readily be extended to greater depths. Optical fiber borehole tensor strainmeter techology was advanced from a TRL 4 at the start, to a TRL of 7 at the conclusion of the project. The project included advances in simulations and theoretical analyses. We developed and demonstrated a computational workflow that uses machine learning to reduce the computational requirements and make it practical to use Bayesian inversion to solve large numerical poroelastic analyses needed to interpret strain tensor field data. We evaluated the strain tensor fields and time series that would be caused by leaks of CO 2 or other fluids from reservoirs. These simulations demonstrated that signals from leaks could be measured with instruments developed for the project, opening a potentially new method for ensuring storage security. We showed that strains in caprock can be used to estimate pressure in a reservoir. This avoids the need to drill monitoring wells into the reservoir, and it expands the capabilities of monitoring in the caprock. The project includes a derivation and application of a novel analytical solution to the strains in the vicinity of a pressurized poroelastic inclusion. This solution explains field data measured during injeciton tests at the North Avant Field, and it will simplify future interpretation of strain tensor data. The project included a broad range of experiments, and of the most significant is the characterization of the strain tensor at an array three strainmeters during six injection tests at the North Avant Field, Oklahoma. This demonstrated repeatability of the strain signal measured by the new instruments developed for the project, and it showed similarities between the strain signal at shallow depths and pressure in the underlying reservoir. We also demonstrated that useful strain data can be measured at reservoir depths. This confirms that strain tensor data can be measured throughout the caprock over a reservoir. The project demonstrated the feasibility of using the strain tensor and distributed strain measured in caprock during a variety of different well tests where the pumping rate was constant, sinusoidal and positive, or a periodic square wave with zero net rate. This further strengthens the validity of using strain data to characterize reservoirs and aquifers. We also demonstrated that strain caused be fluctuations of air pressure and water pressure in the vadose zone can be measured and interpreted, suggesting that high resolution distributed strain measurements hold promise for monitoring the vadose zone. The project partially supported nine graduate students in the Environmental Engineering, Hydrogeology, Electrical Engineering programs at Clemson University. The research was described in nine journal papers, 23 talks and conference abstracts. Additional journal papers are in preparation. A new company called Tensora was started to provide strainmeter technology for commercial applications.

01 COAL, LIGNITE, AND PEAT↗

The Global Water Monitor: Lake, Wetland, and River Reach Monitoring for Resource Management and Hazard Observation

The Global Water Monitor is a monitoring program offering surface water-related products for lakes, reservoirs, river reaches, and wetlands, https://blueice.gsfc.nasa.gov/gwm. These products are derived from multiple satellite-based altimetry and multispectral imaging platforms. The primary measurements are water level, slope, and extent, derived from a series of NASA and other agency instruments (Sentinel-3,-6, ICESat-2, SWOT, MODIS). The system serves stakeholders, the US Department of Agriculture Foreign Agricultural Service and the US Geological Survey, as well as various international, national, state, and intelligence agencies, engineers, ecologists, and hydrological researchers. Considering the sensitivity of ground-based data and the remote accessibility of many basins, the satellites offer global coverage, accuracy, and continuity of measurements. Observation of storage fluctuations in lakes and reservoirs provides users with knowledge of short and long-term drought conditions that can affect both water and energy resources. Emphasis is on changing climatic conditions, water sharing between nations, and regional stability. Measurements across a wetland complex can assist with efforts to assess hydrological dynamics with a focus on conservation efforts that aid both natural ecology and the sharing of precious water resources – the latter potentially being required in a basin across the municipal, crop irrigation, aquaculture, livestock, and power station spectrum. Observations of river reaches assists in the collection of basic hydraulic information, particularly in gauge-poor regions, for modelling efforts and the estimation of discharge, and at high-latitudes satellite-based river observations serve projects that warn of spring melts and flood hazards. We look at how recent improvements in instrument technology and mission operations are assisting with acquiring true global coverage and cross-validation efforts, and how stakeholders interact with the project in terms of setting requirements, product format, and accessibility methods. Examples show the application of the products across a range of programs, and in addition to meeting operational requirements, how the multi-decadal surface water levels are creating a high-quality timeline of Earth Data Records.

Lakes↗

Reducing Data Center Peak Cooling Demand and Energy Costs with Underground Thermal Energy Storage (UTES)

By recent estimates, data center energy demands are projected to consume between 6.7% and 12% of U.S. annual electricity generation by the year 2028, driven primarily by expanded demands from cloud services, big data analytics, and Artificial Intelligence (AI) (Shehabi et al., 2024). As much as 40% of data center total energy consumption are loads associated with the site infrastructure cooling systems, and these are often highly water consumptive (Aljbour et al., 2024). For energy system planners, this presents significant challenges to meeting and managing the anticipated loads, and especially the peak loads of projected data center deployments. Geothermal technologies offer two unique solutions to these challenges: 1) by serving loads through the deployment of new conventional and/or next-generation geothermal power technologies such as EGS and 2) through an often-overlooked opportunity to reduce data center peak cooling loads. The latter is the focus of this paper which explores Cold Underground Thermal Energy Storage ("Cold UTES") as an emerging industrial-scale geothermal cooling solution. This cooling solution is energy efficient, non-water-consumptive, and utilizes long duration energy storage (LDES) on both diurnal and seasonal time scales. Cold UTES has the potential to also function as a virtual power plant (VPP). The US Department of Energy's Geothermal Technologies Office is supporting R&D to understand the grid and system-wide value, costs, and impacts of deploying this emergent cooling solution at scale.

AI↗

Adsorption of Water on JSC-1A Lunar Simulant Samples

Remote sensing probes sent to the moon in the 1990s indicated that water may exist in areas such as the bottoms of deep, permanently shadowed craters at the lunar poles, buried under regolith. Water is of paramount importance for any lunar exploration and colonization project which would require self-sustainable systems. Therefore, investigating the interaction of water with lunar regolith is pertinent to future exploration. The lunar environment can be approximated in ultra-high vacuum systems such as those used in thermal desorption spectroscopy (TDS). Questions about water dissociation, surface wetting, degree of crystallization, details of water-ice transitions, and cluster formation kinetics can be addressed by TDS. Lunar regolith specimens collected during the Apollo missions are still available though precious, so testing with simulant is required before applying to use lunar regolith samples. Hence, we used for these studies JSC-1a, mostly an aluminosilicate glass and basaltic material containing substantial amounts of plagioclase, some olivine and traces of other minerals. Objectives of this project include: 1) Manufacturing samples using as little raw material as possible, allowing the use of surface chemistry and kinetics tools to determine the feasibility of parallel studies on regolith, and 2) Characterizing the adsorption kinetics of water on the regolith simulant. This has implications for the probability of finding water on the moon and, if present, for recovery techniques. For condensed water films, complex TDS data were obtained containing multiple features, which are related to subtle rearrangements of the water adlayer. Results from JSC-1a TDS studies indicate: 1) Water dissociation on JSC-1a at low exposures, with features detected at temperatures as high as 450 K and 2) The formation of 3D water clusters and a rather porous condensed water film. It appears plausible that the sub- m sized particles act as nucleation centers.

Goering, John↗

Decline in Seasonal Snow during a Projected 20-Year Dry Spell

Snowpack loss in midlatitude mountains is ubiquitously projected by Earth system models, though the magnitudes, persistence, and time horizons of decline vary. Using daily downscaled hydroclimate and snow projections, we examine changes in snow seasonality across the U.S. Pacific Southwest region during a simulated severe 20-year dry spell in the 21st century (2051–2070) developed as part of the 4th California Climate Change Assessment to provide a “stress test” for water resources. Across California’s mountains, substantial declines (30–100% loss) in median peak annual snow water equivalent accompany changes in snow seasonality throughout the region compared to the historic period. We find that 80% of historic seasonal snowpacks transition to ephemeral conditions. Subsetting empirical-statistical wildfire projections for California by snow seasonality transition regions indicates a two-to-four-fold increase in the area burned, consistent with recent observations of high elevation wildfires following extended drought conditions. By analyzing six of the major California snow-fed river systems, we demonstrate snowpack reductions and seasonality transitions result in concomitant declines in annual runoff (47–58% of historical values). The negative impacts to statewide water supply reliability by the projected dry spell will likely be magnified by changes in snowpack seasonality and increased wildfire activity.

54 ENVIRONMENTAL SCIENCES↗

Research tool development for catalyst, catalyst/ionomer, and ionomer characterization above 100°C (CRADA Final Report)

There is a need to develop experimental tools that address the catalyst and ionomer interface under high-temperature proton-exchange-membrane (HT-PEM) operating conditions (dry, >100°C). These conditions mean traditional water-based measurements for membrane and ionomer properties are insufficient; new ex-situ techniques are required to address and characterize expected novel materials. In this project we develop a microelectrode cell for high temperature kinetics and gas transport properties and ex-situ ionomer thin-film characterization under these conditions. We use baseline Nafion and phosphoric-acid imbibed membranes as prototype materials for measuring the membrane/acid/ionomer systems with Pt microelectrodes and demonstrate feasibility of the tools.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗