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NASA NTRS1984

Petrologic constraints on the origin of the Moon: Evidence from Apollo 14

The Fra Mauro breccias at Apollo 14 contain distinctive suites of mare basalts and highland crustal rocks that contrast significantly with equivalent rocks from other Apollo sites. These contrasts imply lateral heterogeneity of the lunar crust and mantle on a regional scale. This heterogeneity may date back to the earliest stages of lunar accretion and differentiation. Current theories requiring a Moon-wide crust of Ferroan Anorthosite are based largely on samples from Apollo 16, where all but a few samples represent the FAN suite. However, at the nearside sites, FAN is either scarce (A-15) or virtually absent (A-12, A-14, A-17). It is suggested that the compositional variations could be accounted for by the acceleration of a large mass of material (e.g., 0.1 to 0.2 moon masses) late in the crystallization history of the magma ocean. Besides adding fresh, primordial material, this would remelt a large pocket of crust and mantle, thereby allowing a second distillation to occur in the resulting magma sea.

Shervais, J. W.↗
NASA NTRS2001

Constraining the Mean Crustal Thickness on Mercury

The topography of Mercury is poorly known, with only limited radar and stereo coverage available. However, radar profiles reveal topographic contrasts of several kilometers over wavelengths of approximately 1000 km. The bulk of Mercury's geologic activity took place within the first 1 Ga of the planet's history), and it is therefore likely that these topographic features derive from this period. On Earth, long wavelength topographic features are supported either convectively, or through some combination of isostasy and flexure. Photographic images show no evidence for plume-like features, nor for plate tectonics; I therefore assume that neither convective support nor Pratt isostasy are operating. The composition and structure of the crust of Mercury are almost unknown. The reflectance spectrum of the surface of Mercury is similar to that of the lunar highlands, which are predominantly plagioclase. Anderson et al. used the observed center-of-mass center-of-figure offset together with an assumption of Airy isostasy to infer a crustal thickness of 100-300 km. Based on tidal despinning arguments, the early elastic thickness (T(sub e)) of the (unfractured) lithosphere was approximately equal to or less than 100 km. Thrust faults with lengths of up to 500 km and ages of about 4 Ga B.P. are known to exist on Mercury. Assuming a semicircular slip distribution and a typical thrust fault angle of 10 degrees, the likely vertical depth to the base of these faults is about 45 km. More sophisticated modelling gives similar or slightly smaller answers. The depth to the base of faulting and the elastic layer are usually similar on Earth, and both are thought to be thermally controlled. Assuming that the characteristic temperature is about 750 K, the observed fault depth implies that the heat flux at 4 Ga B.P. is unlikely to be less than 20 mW m(exp -2) for a linear temperature gradient. For an elastic thickness of 45 km, topography at 1000 km wavelength is likely to be about 60% compensated. There are thus likely to be considerable lateral variations in crustal thickness. Additional information is contained in the original extended abstract.

Nimmo, F.↗
NASA NTRS2012

Predicting the Sources and Formation Mechanisms of Evolved Lunar Crust by Linking K/Ca Ratios of Lunar Granites to Analogous Terrestrial Igneous Rocks

Although silicic rocks (i.e. granites and rhyolites) comprise a minor component of the sampled portion of the lunar crust, recent remote sensing studies [e.g., 1-4] indicate that several un-sampled regions of the Moon have significantly higher concentrations of silicic material (also high in [K], [U], and [Th]) than sampled regions. Within these areas are morphological features that are best explained by the existence of chemically evolved volcanic rocks. Observations of silicic domes [e.g., 1-5] suggest that sizable networks of silicic melt were present during crust formation. Isotopic data indicate that silicic melts were generated over a prolonged timespan from 4.3 to 3.9 Ga [e.g., 6-8]. The protracted age range and broad distribution of silicic rocks on the Moon indicate that their petrogenesis was an important mechanism for secondary crust formation. Understanding the origin and evolution of such silicic magmas is critical to determining the composition of the lunar crustal highlands and will help to distinguish between opposing ideas for the Moon's bulk composition and differentiation. The two main hypotheses for generating silicic melts on Earth are fractional crystallization or partial melting. On the Moon silicic melts are thought to have been generated during extreme fractional crystallization involving end-stage silicate liquid immiscibility (SLI) [e.g. 9, 10]. However, SLI cannot account for the production of significant volumes of silicic melt and its wide distribution, as reported by the remote global surveys [1, 2, 3]. In addition, experimental and natural products of SLI show that U and Th, which are abundant in the lunar granites and seen in the remote sensing data of the domes, are preferentially partitioned into the depolymerized ferrobasaltic magma and not the silicic portion [11, 12]. If SLI is not the mechanism that generated silicic magmas on the Moon then alternative processes such as fractional crystallization (only crystal-liquid separation) or partial melting should be considered as viable possibilities to be tested.

Mills, R. D.↗
NASA NTRS1993

Volatility in the lunar crust: Trace element analyses of lunar minerals by PIXE proton microprobe

In situ determination of mineral compositions using microbeam techniques can characterize magma compositions through mineral-melt partitioning, and be used to investigate fine-grained or rare phases which cannot be extracted for analysis. Abundances of Fe, Mn, Sr, Ga, Zr, Y, Nb, Zn, Cu, Ni, Se, and Sb were determined for various mineral phases in a small number of lunar highlands rocks using the PIXE proton microprobe. Sr/Ga ratios of plagioclase and Mn/Zn ratios of mafic silicates show that the ferroan anorthosites and Mg-suite cumulates are depleted in volatile lithophile elements to about the same degree compared with chondrites and the Earth. This links the entire lunar crust to common processes or source compositions. In contrast, secondary sulfides in Descartes breccia clasts are enriched in chalcophile elements such as Cu, Zn, Ni, Se, and Sb, and represent a potential resource in the lunar highlands.

Norman, M. D.↗
NASA NTRS1993

Can weak crust explain the correlation of geoid and topography on Venus?

The effect on geoid and topography of low viscosity crust overlying a steady-state convecting mantle is estimated under the assumption that the shear between crust and mantle does not alter the mantle flow. The weak crustal layer can change the sign of the geoid to topography ratio (admittance). The positive long wavelength admittance for Venus is consistent with a weak crust overlying a mantle with a viscosity that increases strongly with depth. The accepted interpretation of the strong positive correlation of geoid and topography on Venus, is that the convecting mantle of Venus has a constant viscosity with depth. Topography results from vertical normal stresses caused by mantle convection and highlands occur where mantle upwells. For topography to be supported by normal stress, the time scale for crustal flow must be long compared to the time scale for changes in the pattern of mantle flow. Because the high surface temperature of Venus may cause the crust to have a low viscosity, this assumption may be false. Topography should then be dominated by shear coupling between the crust and mantle. In the absence of a crustal layer, convection in a constant viscosity layer gives rise to a geoid anomaly that correlates positively with surface topography. When the viscosity in the layer increases with depth by several orders of magnitude, the surface topography and geoid anomaly become anti-correlated.

Buck, W. Roger↗
NASA NTRS1997

Selection of the Mars Pathfinder Landing Site

The Mars Pathfinder spacecraft will land on a depositional fan near the mouth of the catastrophic outflow channel, Ares Vallis (19.5 deg N, 32.8 deg W). This site offers the prospect of analyzing a variety of rock types from the ancient cratered highlands, intermediate-age ridged plains, and reworked channel deposits. Analyses of these rocks by Pathfinder instruments will enable first-order scientific questions to be addressed, such as differentiation of the crust, the development of weathering products, and the nature of the early environment, as well as their subsequent evolution on Mars. Constraints imposed by: (1) spacecraft and rover designs (which are robust), (2) entry, descent, and landing, (3) scientific potential at various sites, and (4) safety were important considerations in site selection. Engineering constraints require a 70 km by 200 km smooth, flat (low slopes) area located between 10 deg and 20 deg N that is below 0 km elevation, with average radar reflectivity, little dust, and moderate rock abundance. Three regions on Mars are between 10 deg and 20 deg N and below 0 km elevation: Chryse, Amazonis, and Isidis-Elysitun. Science considerations favor sites at the mouths of outflow channels (grab bag sites offer an assay of rock types on Mars), highland sites (early crustal differentiation and climate), and sites covered with dark (unoxidized) material. Sites are considered safe if they are clearly below 0 km elevation, appear acceptably free of hazards in high-resolution (less than 50 m/pixel) Viking orbiter images and have acceptable reflectivity and roughness at radar wavelengths, thermal inertia, rock abundance, red to violet ratio, and albedo. Recent 3.5-cm wavelength radar observations were used to verify elevation, reflectivity, and roughness within the landing ellipses. Three sites meet all of these criteria: Ares Vallis, Tritonis Lacus, and Isidis. Although Isidis appears to be safer than Tritonis and Ares, the greater scientific potential at Ares Vallis resulted in its selection. Comparisons of the Grand Coulee (channel) and the depositional Ephrata Fan of the Channeled Scabland in eastern Washington, with Ar-es Vallis and its depositional fan also suggest the Ares Vallis landing site is safe and scientifically interesting.

Golombek, M. P.↗
NASA NTRS2012

The Violent Early Solar System, as Told by Lunar Sample Geochronology

One of the legacies of the samples collected by the Apollo and Luna missions is the link forged between radiometric ages of rocks and relative ages according to stratigraphic relationships and impact crater size-frequency distributions. Our current understanding of the history of the inner solar system is based on the relative chronology of individual planets, tied to the absolute geochronology of the Moon via these important samples. Sample ages have enabled us to infer that impact-melt breccias from Apollo 14 and 15 record the formation of the Imbrium Basin, those from the highland massifs at Apollo 17 record the age of Serenitatis, those from the KREEP-poor Apollo 16 site record the age of Nectaris, and materials from Luna 24 record the age of Crisium. Ejecta from smaller and younger craters Copernicus and Tycho were sampled at Apollo 12 and 17, respectively, and local craters such as Cone at Apollo 14, and North Ray and South Ray at Apollo 16 were also sampled and ages determined for those events. Much of what we understand about the lunar impact flux is based on these ages. Samples from these nearside locations reveal a preponderance of impact-disturbed or recrystallized ages between 3.75 and 3.95 billion years. Argon and lead loss (and correlated disturbances in the Rb-Sr system) have been attributed to metamorphism of the lunar crust by an enormous number of impacts in a brief pulse of time, called the Lunar Cataclysm or Late Heavy Bombardment. Subsequent high-precision geochronometric analyses of Apollo samples and lunar highlands meteorites show a wider range of ages, but very few older than 4 Ga. The paucity of ancient impact melt rocks has been interpreted to mean that either that most impact basins formed at this time, or that ejecta from the large, near-side, young basins dominates the Apollo samples.

Cohen, Barbara A.↗
NASA NTRS2013

The Violent Early Solar System, as Told by Sample Geochronology

One of the legacies of the samples collected by the Apollo and Luna missions is the link forged between radiometric ages of rocks and relative ages according to stratigraphic relationships and impact crater size-frequency distributions. Our current understanding of the history of the inner solar system is based on the relative chronology of individual planets, tied to the absolute geochronology of the Moon via these important samples. Sample ages have enabled us to infer that impact-melt breccias from Apollo 14 and 15 record the formation of the Imbrium Basin, those from the highland massifs at Apollo 17 record the age of Serenitatis, those from the KREEP-poor Apollo 16 site record the age of Nectaris, and materials from Luna 24 record the age of Crisium. Ejecta from smaller and younger craters Copernicus and Tycho were sampled at Apollo 12 and 17, respectively, and local craters such as Cone at Apollo 14, and North Ray and South Ray at Apollo 16 were also sampled and ages determined for those events. Much of what we understand about the lunar impact flux is based on these ages. Samples from these nearside locations reveal a preponderance of impact-disturbed or recrystallized ages between 3.75 and 3.95 billion years. Argon and lead loss (and correlated disturbances in the Rb-Sr system) have been attributed to metamorphism of the lunar crust by an enormous number of impacts in a brief pulse of time, called the Lunar Cataclysm or Late Heavy Bombardment. Subsequent high-precision geochronometric analyses of Apollo samples and lunar highlands meteorites show a wider range of ages, but very few older than 4 Ga. The paucity of ancient impact melt rocks has been interpreted to mean that either that most impact basins formed at this time, or that ejecta from the large, near-side, young basins dominates the Apollo samples.

Cohen, Barbara↗
NASA NTRS1993

Assimilation of solids during ascent of magmas from the Bartoy Field of the Baikal Region, Siberia

Most investigators ascribe mare basalt magma genesis to partial melting at depths of approximately 130 to greater than 400 km within the cumulate pile deposited from a lunar magma ocean. Mare basalts share with mid-ocean ridge basalts the characteristic of relative depletion in LREE and other incompatible trace elements that arises from melting within 'used' mantle, from which crust-forming elements have already been separated. Some mare basalt types do not show the classical, La-Nd depleted mare basalt REE distributions; however, some types are isotopically heterogeneous. These differences have been ascribed to assimilation, mainly AFC-style, of KREEPy highland material overlying the source region. Might such assimilation occur during magma ascent through the KREEPy material? To gain information from a terrestrial setting on possible assimilation during ascent, we have studied a suite of Quaternary nepheline-hawalites and nepheline-mugearites from the Bartoy cinder cone complex of the Baikal Rift, Siberia. The Bartoy magmas originated from greater than 80 km deep, and erupted through thick Archean crust. We find evidence for assimilation of approximately 31 wt. percent xenocrysts of garnet, aluminous clinopyroxene, kaersutite, and olivine, all presumably from the basalt source region, but no appreciable assimilation of overlying crust, consistent with isotopic constraints. Magmatic superheat made available by rapid ascent and decomposition accounts adequately for the energy of assimilation; no accompanying fractional crystallization is required or evident.

Haas, Johnson R.↗
NASA NTRS1982

Distribution and provenance of lunar highland rock types at North Ray Crater, Apollo 16

In connection with its selenographic setting in the central lunar highlands, the Apollo 16 landing site in the Descartes area is highly important as a prime sampling area for rocks which formed as part of the primordial crust and as a key location for the analysis of the deformation and transport of crustal material by impact processes. The present investigation is concerned with the North Ray crater, which is located on the N-S running boundary between the smooth Cayley plains to the west and the Descartes mountains to the east. Attention is given to aspects of selenography and location of samples, the ejecta distribution of post-Cayley impact craters, sample classification, the frequency distribution of rock types in the North Ray Crater ejecta, an interpretation of compositional and age data, a model of the target stratigraphy and excavation of North Ray Crater, and implications for the emplacement and provenance of North Ray target rocks.

Stoeffler, D.↗
NASA NTRS1999

Petrological Explanations for the Magnetic Anomalies Detected on Mars

The discovery of crustal magnetization in some locations on Mars, particularly the southern highlands, has major implications for the early evolution of Mars. The east-west-trending linear features in the southern highlands with alternating polarity may be the result of an early seafloor spreading process similar to that seen on Earth today. The larger magnetization of the martian crust compared to the Earth can be attributed to its higher Fe content and the proposed minerals associated with this magnetization are multidomain hematite and pyrrhotite. In this study, we discuss the petrological evolution of basalts on Earth and Mars and suggest processes that may enhance crystallization of magnetic minerals in the martian rocks, thereby accounting for their intense magnetic properties.

Weitz, C. M.↗
NASA NTRS2004

Crustal structure of Mars from gravity and topography

Mars Orbiter Laser Altimeter (MOLA) topography and gravity models from 5 years of Mars Global Surveyor (MGS) spacecraft tracking provide a window into the structure of the Martian crust and upper mantle. We apply a finite-amplitude terrain correction assuming uniform crustal density and additional corrections for the anomalous densities of the polar caps, the major volcanos, and the hydrostatic flattening of the core. A nonlinear inversion for Moho relief yields a crustal thickness model that obeys a plausible power law and resolves features as small as 300 km wavelength. On the basis of petrological and geophysical constraints, we invoke a mantle density contrast of 600 kg m-3; with this assumption, the Isidis and Hellas gravity anomalies constrain the global mean crustal thickness to be >45 km. The crust is characterized by a degree 1 structure that is several times larger than any higher degree harmonic component, representing the geophysical manifestation of the planet's hemispheric dichotomy. It corresponds to a distinction between modal crustal thicknesses of 32 km and 58 km in the northern and southern hemispheres, respectively. The Tharsis rise and Hellas annulus represent the strongest components in the degree 2 crustal thickness structure. A uniform highland crustal thickness suggests a single mechanism for its formation, with subsequent modification by the Hellas impact, erosion, and the volcanic construction of Tharsis. The largest surviving lowland impact, Utopia, post-dated formation of the crustal dichotomy. Its crustal structure is preserved, making it unlikely that the northern crust was subsequently thinned by internal processes.

Neumann, G. A.↗
NASA NTRS1978

Luna 24 - Lateral heterogeneity in the lunar crust

Results of petrological investigations of Luna 24 soil samples are compared with data from Apollo and other Luna missions in order to determine the large scale composition of the lunar surface and crust. Modal analysis of the 90 to 150 micron soil fraction and electron microprobe analysis of glass spheres and fragments of the Luna 24 core sample are presented. High and low MgO mare basalt compositional clusters are found, suggesting the derivation of southern Mare Crisium basalts from two magmas. A model of Luna 24 soils as being composed of a mixture of glass-poor mare material and glass-rich highland material is found to be consistent with glass and agglutinate modal abundances. Comparisons show that potassium, and by inference all lithophile trace elements, are depleted on the eastern limb of the moon relative to the central nearside. The observed depletion is interpreted to be characteristic of the underlying crust and mantle as well as the surface.

Warner, J. L.↗
NASA NTRS1973

Chemistry and thermal history of metal particles in Luna 20 soils.

Individual metal particles from Luna 20 thin sections 521, 513 and 514 as well as several small metallic inclusions in silicate particles from Luna 20 thin sections 501 and 502 were examined using optical microscopy and the electron microprobe. All the metallic particles and inclusions analyzed are of meteoritic Co-Ni content as are most of the metallic particles from the Fra Mauro and the Apollo 16 highlands sites. It is proposed that most of the metal at these 3 sites had its origin in the meteoritic projectiles that bombarded and accumulated in the early lunar crust. It is apparent that the metallic particles and some of the metallic inclusions in the Luna 20 soil have been subjected to reheating on the moon and this process has removed any evidence of the original meteoritic microstructure of the metal.

Goldstein, J. I.↗
NASA NTRS1977

Magma oceanography. II - Chemical evolution and crustal formation

A description is presented of an empirical model of fractional crystallization which predicts that slightly modified versions of certain of the proposed whole moon compositions can reproduce the major-element chemistry and mineralogy of most of the primitive highland rocks through equilibrium and fractional crystallization processes combined with accumulation of crystals and trapping of residual liquids. These compositions contain sufficient Al to form a plagioclase-rich crust 60 km thick on top of a magma ocean that was initially no deeper than about 300 km. Implicit in the model are the assumptions that all cooling and crystallization take place at low pressure and that there are no compositional or thermal gradients in the liquid. Discussions of the cooling and crystallization of the proposed magma ocean show these assumptions to be disturbingly naive when applied to the ocean as a whole. However, the model need not be applied to the whole ocean, but only to layers of cooling liquid near the surface.

Longhi, J.↗
NASA NTRS1993

Magnesian anorthosites from the western highlands of the Moon: Isotope geochemistry and petrogenesis

Breccias from the Apollo 14 landing site have provided a wealth of information on the genesis of the lunar highlands. Various pristine rock-types have been discovered in relative abundance including rare ferroan anorthosites and alkali-suite and magnesian-suite rocks. Mineral-chemical and radiogenic isotopic data are reported here for a newly discovered Mg-suite anorthosite from Apollo 14, sample 14303,347. Meyer et al. reported U-Pb zircon analyses of Mg-suite highlands rocks from the western limb of the Moon. We have compiled these ages and generated a weighted average age of 4211 = 6 Ma; some 200 Ma younger than ferroan anorthosites. Utilizing this age for Mg-anorthosite 14303,347, our data results in an initial epsilon(sub Nd) value of -1.0 and initial Sr-87/Sr-86 of 0.69915. Based on trace-element, isotopic, and mineral-chemical data, the western highlands Mg-suite is interpreted to be crustal precipitates of a picritic magma, which assimilated KREEPy trapped liquid from upper-mantle cumulates during its transport to the crust.

Snyder, Gregory A.↗
NASA NTRS1996

Lunar Meteorite Queen Alexandra Range 93069 and the Iron Concentration of the Lunar Highlands Surface

Lunar meteorite Queen Alexandra Range 93069 is a clast-rich, glassy-matrix regolith breccia of ferroan, highly aluminous bulk composition. It is similar in composition to other feldspathic lunar meteorites but differs in having higher concentrations of siderophile elements and incompatible trace elements. Based on electron microprobe analyses of the fusion crust, glassy matrix, and clasts, and instrumental neutron activation analysis of breccia fragments, QUE 93069 is dominated by nonmare components of ferroan, noritic- anorthosite bulk composition. Thin section QUE 93069,31 also contains a large, impact-melted, partially devitrified clast of magnesian, anorthositic-norite composition. The enrichment in Fe, Sc, and Cr and lower Mg/Fe ratio of lunar meteorites Yamato 791197 and Yamato 82192/3 compared to other feldspathic lunar meteorites can be attributed to a small proportion (5-10%) of low-Ti mare basalt. It is likely that the non- mare components of Yamato 82192/3 are similar to and occur in similar abundance to those of Yamato 86032, with which it is paired. There is a significant difference between the average FeO concentration of the lunar highlands surface as inferred from the feldspathic lunar meteorites (mean: approx. 5.0%; range: 4.3-6.1 %) and a recent estimate based on data from the Clementine mission (3.6%).

Korotev, Randy L.↗
NASA NTRS1972

The chemical composition of soil from the Apollo 16 and Luna 20 sites.

The concentrations of the rare earth elements K, Rb, Sr, Ba, U, Zr, and Cr for the Luna 20 soil and four different Apollo 16 soils are reported. These trace element abundances imply: (1) that the lunar highlands consist of a mixture of rocks rich in large ion lithophile (LIL) elements and LIL-element improverished anorthosites; or (2) that the bulk of the aluminum-rich crust did not originate by upward segregation of plagioclase in a primitive liquid shell. The Luna 20 soil is distinguished from the Apollo 16 soil by lower aluminum and LIL element abundances.

Bansal, B. M.↗