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Substrates coated with a precious-metal salt KAuCl4 have been found to be useful for detecting hydrazine vapors in air at and above a concentration of the order of 0.01 parts per million (ppm). Upon exposure to air containing a sufficient amount of hydrazine for a sufficient time, the coating material undergoes a visible change in color.
Recent and numerous failures of reaction wheels have cut short and/or limited the mission functions of several spacecraft including DAWN, Mars Odyssey, and Kepler among others. A micro Newton impulse-bit hydrazine thruster has the potential to backup or even replace reaction wheels on most missions, thereby extending mission life. This paper will discuss the development and test of a plug-and-play hydrazine thruster with 30 – 130 milliNewton thrust levels, and impulse bits < 50 microNewton-sec. In addition, this paper will address mission applications that include backup for, or even replacement of reaction wheels, delta-V thrust for CubeSats, and primary attitude control for the 20 – 50 kg class of spacecraft.
A small thruster, that will herein be called the Hydrazine milliNewton Thruster (HmNT), has been designed and vacuum hot-fire tested, demonstrating a range of thrust and impulse far below the current state-of-the-art (SOA) hydrazine thruster. Steady-state thrust levels of 35–135 mN, and minimum impulse-bits of 25–120 μN-s were demonstrated over a typical operating range of inlet pressures. These capabilities provide new spacecraft and mission design options, including the following: Functional backup for Reaction Wheel Assemblies (RWAs), which can be used to prolong the useful life of RWAs; RWA replacement for certain missions to save mass, power, and cost; Precision delta-V that can be used for: proximity operations and docking maneuvers, formation flying, primary attitude control for SmallSats and CubeSats, and primary delta-V for CubeSats.
Trace contaminants in high-purity hydrazine (HPH) propellant impact a wide variety of commercial, Department of Defense (DoD), and NASA missions. Depending on thruster design, elemental contaminants must be kept at extremely low levels and are verified as such by routine analysis. A number of these contaminants have recently undergone an assessment to shed light on their quantities present following changes in the HPH supply chain. A round robin analysis utilizing four separate laboratories resulted in unacceptably high variability in the quantification of these contaminants. The principal objective of this technical bulletin is to signal the availability of a new analysis methodology which yields accurate and repeatable quantification by providing best practices for both quantitation methodology and strategies for avoiding sample contamination during analysis.
Hydrogen carriers, such as hydrazine (N 2 H 4 ), may facilitate long duration energy storage, a vital component for resilient grids by enabling more renewable energy generation. Lanthanide coordination chemistry with N 2 H 4 as well as efforts to displace N 2 H 4 from the metal coordination sphere to develop an efficient catalytic production cycle were detailed. Modeling the equilibrium of different ligand coordination, it was predicted that strong sigma donor molecules would be required to displace N 2 H 4 . Monitoring competition experiments with nuclear magnetic resonance confirmed that trimethyl phosphine oxide, dimethylformamide, and dimethyl sulfoxide displaced N 2 H 4 in large or small lanthanide complexes.
The rate coefficient k 1 for NH 2 + N 2 H 4 was measured to be (5.4 ± 0.4) × 10 –14 cm 3 molecule –1 s –1 at 296 K. NH 2 was generated by pulsed laser photolysis of NH 3 at 193 nm, and monitored as a function of time by pulsed laser-induced fluorescence excited at 570.3 nm under pseudo-first order conditions in the presence of excess N 2 H 4 in an Ar bath gas. This reaction was also investigated computationally, with geometries and scaled frequencies obtained with M06-2X/6-311+G(2df,2p) theory, and single-point energies from CCSD(T)-F12b/cc-pVTZ-F12 theory, plus a term to correct approximately for electron correlation through CCSDT(Q). Three connected transition states are involved and rate constants were obtained via Multistructural Improved Canonical Variational Transition State Theory with Small Curvature Tunneling. Combination of experiment and theory leads to a recommended rate coefficient for hydrogen abstraction of k 1 = 6.3 × 10 –23 T 3.44 exp(+289 K/T) cm 3 molecule –1 s –1 . The minor channel for H + N 2 H 4 forming NH 2 + NH 3 was characterized computationally as well, to yield 5.0 × 10 –19 T 2.07 exp(-4032 K/T) cm 3 molecule –1 s –1 . Finally, these results are compared to several discordant prior estimates, and are employed in an overall mechanism to compare with measurements of half-lives of hydrazine in a shock tube.
Determination of water in hydrazine by gas chromatography
Flame analysis of diborane-hydrazine systems at low pressure
Low-pressure environment reaction of hydrazine and nitrogen tetroxide
The effect of some additives on the burning rate of liquid hydrazine in a nitrogen atmosphere
Reaction of hydrazine and nitrogen tetroxide at pressures of .001 mm hg in a steel vacuum tank
Radiation testing monomethyl hydrazine propellant for rift project
Ignition delay time of hydrazine nitrogen tetroxide system in presence of various additives
Hydrazine and derivations affecting carbon dioxide respiratory pattern of various metabolic substrates in rats
Performance tests of shower-head, triplet, and like-on-like liquid hydrazine-fluorine injectors in uncooled rocket engine
Analytic study of catalytic reactors for hydrazine decomposition
Liquid hydrazine decomposition process to determine what chemical or physical changes may be occurring that cause breaks in burning rate/ pressure curves, measuring flame temperature and light emission
Molecular elimination of nitrogen from hydrazine from single molecule and not radical-radical combination