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NASA NTRS2016

Water Content of Lunar Alkali Fedlspar

Detection of indigenous hydrogen in a diversity of lunar materials, including volcanic glass, melt inclusions, apatite, and plagioclase suggests water may have played a role in the chemical differentiation of the Moon. Spectroscopic data from the Moon indicate a positive correlation between water and Th. Modeling of lunar magma ocean crystallization predicts a similar chemical differentiation with the highest levels of water in the K- and Th-rich melt residuum of the magma ocean (i.e. urKREEP). Until now, the only sample-based estimates of water content of KREEP-rich magmas come from measurements of OH, F, and Cl in lunar apatites, which suggest a water concentration of < 1 ppm in urKREEP. Using these data, predict that the bulk water content of the magma ocean would have <10 ppm. In contrast, estimate water contents of 320 ppm for the bulk Moon and 1.4 wt % for urKREEP from plagioclase in ferroan anorthosites. Results and interpretation: NanoSIMS data from granitic clasts from Apollo sample 15405,78 show that alkali feldspar, a common mineral in K-enriched rocks, can have approx. 20 ppm of water, which implies magmatic water contents of approx. 1 wt % in the high-silica magmas. This estimate is 2 to 3 orders of magnitude higher than that estimated from apatite in similar rocks. However, the Cl and F contents of apatite in chemically similar rocks suggest that these melts also had high Cl/F ratios, which leads to spuriously low water estimates from the apatite. We can only estimate the minimum water content of urKREEP (+ bulk Moon) from our alkali feldspar data because of the unknown amount of degassing that led to the formation of the granites. Assuming a reasonable 10 to 100 times enrichment of water from urKREEP into the granites produces an estimate of 100-1000 ppm of water for the urKREEP reservoir. Using the modeling of and the 100-1000 ppm of water in urKREEP suggests a minimum bulk silicate Moon water content between 2 and 20 ppm. However, hydrogen loss was likely very significant in the evolution of the lunar mantle. Conclusions: Lunar granites crystallized between 4.3-3.8 Ga from relatively wet melts that degassed upon crystallization. The formation of these granites likely removed significant amounts of water from some mantle source regions, e.g. later mare basalts predicting derivation from a mantle with <10 ppm water. However, this would have been a heterogeneous pro-cess based on K distribution. Thus some, if not most of the mantle may not have been devolatilized by this process; as seen by water in volcanic glasses and melt inclusions.

Mills, R. D.↗

NASA NTRS2014

On Helium-Dominated Stellar Evolution: The Mysterious Role of the O(He)-Type Stars

Context. About a quarter of all post-asymptotic giant branch (AGB) stars are hydrogen-deficient. Stellar evolutionary models explain the carbon-dominated H-deficient stars by a (very) late thermal pulse scenario where the hydrogen-rich envelope is mixed with the helium-rich intershell layer. Depending on the particular time at which the final flash occurs, the entire hydrogen envelope may be burned. In contrast, helium-dominated post-AGB stars and their evolution are not yet understood. Aims. A small group of very hot, helium-dominated stars is formed by O(He)-type stars. A precise analysis of their photospheric abundances will establish constraints to their evolution. Methods. We performed a detailed spectral analysis of ultraviolet and optical spectra of four O(He) stars by means of state-of-the-art non-LTE model-atmosphere techniques. Results. We determined effective temperatures, surface gravities, and the abundances of H, He, C, N, O, F, Ne, Si, P, S, Ar, and Fe. By deriving upper limits for the mass-loss rates of the O(He) stars, we found that they do not exhibit enhanced mass-loss. The comparison with evolutionary models shows that the status of the O(He) stars remains uncertain. Their abundances match predictions of a double helium white dwarf (WD) merger scenario, suggesting that they might be the progeny of the compact and of the luminous helium-rich sdO-type stars. The existence of planetary nebulae that do not show helium enrichment around every other O(He) star precludes a merger origin for these stars. These stars must have formed in a different way, for instance via enhanced mass-loss during their post-AGB evolution or a merger within a common-envelope (CE) of a CO-WD and a red giant or AGB star. Conclusions. A helium-dominated stellar evolutionary sequence exists that may be fed by different types of mergers or CE scenarios. It appears likely that all these pass through the O(He) phase just before they become WDs.

evolution↗

NASA NTRS1982

Thermonuclear processes and accretion onto neutron star envelopes - X-ray burst and transient sources

A Lagrangian, fully implicit, one-dimensional hydrodynamic computer code is used to investigate the evolution of thermonuclear runaways in the thick accreted hydrogen-rich envelopes of 1.0-solar-mass neutron stars having radii of 10 km and 20 km. The simulations produce outbursts that range in time scale from about 2000 seconds to more than a day. For the 10-km study, the peak effective temperature is 3.3 x 10 to the 7th K, and the peak luminosity is 2 x 10 to the 5th solar luminosities. The 20-km neutron star produces a peak effective temperature and luminosity of 5.3 x 10 to the 6th K and 5.9 x 10 to the 2nd solar luminosities. Also investigated are the effects of changes in the rates of the O-14(alpha, proton) and O-15(alpha, gamma) reactions on the evolution. Hydrodynamic expansion on the 10-km neutron star produces a precursor lasting about 10 to the -6th sec. The evolution of a gas cloud impacting the surface of a 20-km, 1-solar-mass neutron star is studied in an attempt to simulate the magnetospheric gate model of the X-ray burst sources.

Starrfield, S.↗

NASA NTRS2007

Origin and Evolution of Nitrogen on Titan, Enceladus, Triton, and Pluto

Nitrogen, together with carbon, hydrogen, oxygen, phosphorus and sulfur (CHNOPS), plays a central role in life as we know it. Indeed, molecular nitrogen is the most abundant component of the terrestrial atmosphere, and second only to carbon dioxide on Mars and Venus. The Voyager and Cassini-Huygens observations show that copious nitrogen is present on Titan also, comprising some 95% by volume of this moon's 1500 millibar atmosphere. After water vapor, it may be the most abundant (4%) of the gases around tiny Enceladus, as revealed by the recent Cassini observations. A thin nitrogen atmosphere is found even on the coldest of the solar system bodies, Triton and Pluto. The available evidence on nitrogen isotopes and the heavy noble gases suggests that Titan acquired its nitrogen largely in the form of ammonia. Subsequent chemical evolution, beginning with the photolysis of NH3 on primordial Titan, led to the nitrogen atmosphere we see on Titan today. This is also the scenario for the origin of nitrogen on the terrestrial planets. Contrary to Titan, the colder outer solar system objects, Triton and Pluto, neither had the luxury of receiving much arnmonia in the first place, nor of photolyzing whatever little ammonia they did receive in the planetesimals that formed them. On the other hand, it is plausible the planetesimals were capable of trapping and delivering molecular nitrogen directly to Triton and Pluto, unlike Titan. The origin of nitrogen on Enceladus is somewhat enigmatic. A scenario similar to Titan's, but with a role for the interior processes, may be at work. In this paper, we will discuss the source and loss of nitrogen for the above objects, and why Ganymede, the largest moon in the solar system, is nitrogen starved.

Atreya, S. K.↗

NASA NTRS1985

Photochemical modelling of Venus clouds using Pioneer Venus data

In order to understand the evolution of water on Venus, we must know the hydrogen escape flux as a function of the tropospheric water abundance. We have studied the connection between total stratospheric hydrogen and exobase hydrogen available to non-thermal escape processes and examined the details of the photochemical trap for water at the Venus cloud tops. Our immediate goal is to calculate the stratospheric water abundance as a function of the tropospheric water abundance. Photochemical production of H2SO4 acts as a sink for both water and sulfur and is capable of keeping stratospheric abundances low if a proper balance exists between the tropospheric abundances. If production of H2SO4 were the only sink for H2O and SO2, the excess in tropospheric abundance of one over the other would reach the stratosphere, and the functional dependence of stratospheric H2O on tropospheric H2O would be linear near the present state. On Venus, however, sulfuric acid condenses at cloud top temperatures and the resulting aerosols can absorb additional water of hydration. This complicates the water budget, increasing the efficiency of sulfur as a sink for water. We have investigated the balance between tropospheric H2O and SO2 and how delicate the balance is. Our major conclusions from this work are the following: (1) H2O and SO2 are mutually limiting if proper tropospheric balance is maintained; (2) changes in tropospheric abundances on the order of 5 ppm are significant; and (3) changes in mixing rates near the cloud tops can cause dramatic changes in SO2 without causing dramatic changes in H2O.

Mcelroy, Michael B.↗

NASA NTRS2001

Escape of H and D from Mars' Atmosphere and the Evolution of its Crustal Water Reservoirs

The evolution of water on Mars involves preferential escape of hydrogen over deuterium, producing its deuterium rich atmosphere with a D/H ratio 5.2 times that of terrestrial water. In the past decade, several estimates have been made of the magnitudes of current and ancient crustal water reservoirs on Mars that freely exchange with its atmosphere. Some of the differences in the magnitudes of the reservoirs are influenced by differences in the following basic parameters: composition of H, D, H2 and HD at the exobase; thermal history of the atmosphere; escape mechanisms; and the D/H ratio of earlier epochs as inferred from meteorites. The dominant escape mechanism used in the estimates is Jeans escape. However, the Jeans escape flux is enhanced considerably when atmospheric winds and rotation are applied at the exobase . This constraint is of particular importance because the enhancement of the D escape flux can be an order of magnitude greater than the enhancement of the H escape flux. This preferential enhancement of the D escape flux over that of H means that a great deal more H must escape (than in the case without winds and rotation) to attain the same D/H ratio in the today's atmosphere. Another new constraint on reservoir magnitudes comes from the recent interpretation of Martian meteorite data, which suggests that the D/H ratio was 2 times that of terrestrial water at the end of the heavy bombardment period (1). These two constraints together lead to larger current and ancient crustal water reservoirs. Applying Rayleigh fractionation, new estimates of the sizes of the water reservoirs are made using the above constraints along with plausible values for hydrogen and deuterium densities, temperatures, wind speeds and rotation rates at the exobase.

Hartle, Richard E.↗

NASA NTRS1997

Glycolonitrile oligomerization: structure of isolated oxazolines, potential heterocycles on the early earth

A study of glycolonitrile polymerization has led to the isolation and characterization of two 2,5-dihydro-4-aminooxazoles, 4 and 5. Previous reports have misassigned these structures as s-triazines or pyrimidines. X-ray diffraction analysis of crystals of 4 and an acetylated oxazole derivative of 5 (6) confirm the proposed structures. Ab initio computations are used to assess the relative thermodynamic stability of three trimer isomers (an s-triazine, an aminohydroxypyrimidine, and an aminooxazoline), and the results indicate that 4 is a novel kinetic product. Mechanistic considerations rationalize kinetic oxazole formation over the more customary triazine or pyrimidine trimers.

Non-NASA Center↗

NASA NTRS2006

NASA Crew and Cargo Launch Vehicle Development Approach Builds on Lessons from Past and Present Missions

The United States (US) Vision for Space Exploration, announced in January 2004, outlines the National Aeronautics and Space Administration's (NASA) strategic goals and objectives, including retiring the Space Shuttle and replacing it with new space transportation systems for missions to the Moon, Mars, and beyond. The Crew Exploration Vehicle (CEV) that the new human-rated Crew Launch Vehicle (CLV) lofts into space early next decade will initially ferry astronauts to the International Space Station (ISS) Toward the end of the next decade, a heavy-lift Cargo Launch Vehicle (CaLV) will deliver the Earth Departure Stage (EDS) carrying the Lunar Surface Access Module (LSAM) to low-Earth orbit (LEO), where it will rendezvous with the CEV launched on the CLV and return astronauts to the Moon for the first time in over 30 years. This paper outlines how NASA is building these new space transportation systems on a foundation of legacy technical and management knowledge, using extensive experience gained from past and ongoing launch vehicle programs to maximize its design and development approach, with the objective of reducing total life cycle costs through operational efficiencies such as hardware commonality. For example, the CLV in-line configuration is composed of a 5-segment Reusable Solid Rocket Booster (RSRB), which is an upgrade of the current Space Shuttle 4- segment RSRB, and a new upper stage powered by the liquid oxygen/liquid hydrogen (LOX/LH2) J-2X engine, which is an evolution of the J-2 engine that powered the Apollo Program s Saturn V second and third stages in the 1960s and 1970s. The CaLV configuration consists of a propulsion system composed of two 5-segment RSRBs and a 33- foot core stage that will provide the LOX/LED needed for five commercially available RS-68 main engines. The J-2X also will power the EDS. The Exploration Launch Projects, managed by the Exploration Launch Office located at NASA's Marshall Space Flight Center, is leading the design, development, testing, and operations planning for these new space transportation systems. Utilizing a foundation of heritage hardware and management lessons learned mitigates both technical and programmatic risk. Project engineers and managers work closely with the Space Shuttle Program to transition hardware, infrastructure, and workforce assets to the new launch systems, leveraging a wealth of knowledge from Shuffle operations. In addition, NASA and its industry partners have tapped into valuable Apollo databases and are applying corporate wisdom conveyed firsthand by Apollo-era veterans of America s original Moon missions. Learning from its successes and failures, NASA employs rigorous systems engineering and systems management processes and principles in a disciplined, integrated fashion to further improve the probability of mission success.

Dumbacher, Daniel L.↗

NASA NTRS2007

Theoretical Developments in Understanding Massive Star Formation

Except under special circumstances massive stars in galactic disks will form through accretion. The gravitational collapse of a molecular cloud core will initially produce one or more low mass quasi-hydrostatic objects of a few Jupiter masses. Through subsequent accretion the masses of these cores grow as they simultaneously evolve toward hydrogen burning central densities and temperatures. We review the evolution of accreting (proto-)stars, including new results calculated with a publicly available stellar evolution code written by the authors.

stellar evolution↗

NASA NTRS2015

Composition, Structure and Formation of Low-Density Planets Within 0.5 AU of Their Star

Kepler has discovered that tens of percent of sunlike stars possess one or more planets larger than Earth within 0.5 AU. Masses of dozens of small and mid-sized exoplanets have been measured using radial velocity or transit timing variations. Few transiting planets larger than 1.6 Earth radii are rocky. Rather, the planetary mass-radius diagram for planetary radius between 1.6 and 8 times that of Earth shows a tendency for mass to increase slowly with size. The scatter is larger than can be explained by observational errors and correlations with temperature, implying that the population is heterogeneous. Many Neptune-size planets have very low densities and must have a substantial fraction of their volumes occupied by hydrogen and/or helium. Models of the structure, growth and evolution of planets made of mixtures of rock and light gases will be presented and compared with observations of both individual bodies and of the characteristics of the population as a whole.

radial velocity↗

NASA NTRS2019

Measuring the D/H Ratios of Exoplanets and Brown Dwarfs

The relative abundance of deuterium and hydrogen is a potent tracer of planet formation and evolution. Jupiter and Saturn have protosolar atmospheric D/H ratios, a relic of substantial gas accretion from the nebula, while the atmospheres of Neptune and Uranus are enhanced in D by accretion of ices into their envelopes. For terrestrial planets, D/H ratios are used to determine the mechanisms of volatile delivery and subsequent atmosphere loss over the lifetime of the planet. Planets and brown dwarfs more massive than ~13 M(J) quickly fuse their initial D reservoir. Here, we simulate spectra for giant exoplanets and brown dwarfs (2 M(Neptune) to ~10 M(Jupiter)) from T(eff) = 200–1800 K including both CH3D and HDO to determine the observability of these dominant deuterium isotopologues in mid-infrared thermal emission spectra. Colder objects have stronger molecular features in their spectra, due to the temperature dependence of molecular cross sections. CH3D is easier to observe than HDO at all temperatures considered, due to the strength of its absorption bands and locations of features at wavelengths with few other strong absorption features. We predict that for nearby cool brown dwarfs, the CH3D abundance can be measured at high signal to noise with the James Webb Space Telescope (JWST); for objects from 200 to 800 K closer than 10 pc, a protosolar D/H ratio would be readily observable in 2.5 hr. Moderately young Jupiter-mass planets (100–300 Myr) and young Neptunes (10 Myr) may be discovered with JWST and provide the best targets for detecting deuterium on an exoplanet in the coming decade. Future telescope designs should consider the importance of isotopes for understanding the formation and evolution of planetary atmospheres.

Caroline V. Morley↗

NASA NTRS2023

Design of a Minimal di-Nickel Hydrogenase Peptide

The most ancient processes for energy production in the evolution of life involve the reversible oxidation of molecular hydrogen by hydrogenase. Extant hydrogenase enzymes are complex, comprising hundreds of amino acids and multiple cofactors. We designed a 13 amino acid nickel-binding peptide capable of robustly producing molecular hydrogen from protons under a wide variety of conditions. The peptide forms a di-nickel cluster structurally analogous to a Ni-Fe cluster in [NiFe]-hydrogenase and the Ni-Ni cluster in acetyl-CoA synthase (ACS), two ancient, extant proteins central to metabolism. These experimental results clearly demonstrate that modern enzymes, despite their enormous complexity, likely evolved from simple peptide precursors on early Earth. One Sentence Summary: Small metal-binding peptides were the likely precursors of modern enzymes.

Joshua A. Mancini↗

NASA NTRS1981

A model for dwarf novae as progenitors of Type I supernovae

It is suggested that a Type I supernova event can be produced as a result of accretion at low rates (less than 10 to the -10th solar mass/year) onto the white dwarf component of a dwarf-nova close binary. At these low rates, diffusion of the CNO nuclei out of the accreted hydrogen envelope can occur on the accretion time scale, and nuclear burning will occur mainly by the proton-proton chain. Studies of this process show that, when the CNO abundance in the envelope is less than 0.0025 of solar, no thermonuclear flash occurs and no mass is lost. The result of the evolution is a gradually increasing layer of helium beneath the hydrogen-burning shell.

Starrfield, S.↗

NASA NTRS2002

Compatibility Studies of Hydrogen Peroxide and a New Hypergolic Fuel Blend

Several preliminary materials compatibility studies have been conducted to determine the practicality of a new hypergolic fuel system. Hypergolic fuel ignites spontaneously as the oxidizer decomposes and releases energy in the presence of the fuel. The bipropellant system tested consists of high-test hydrogen peroxide (HTP) and a liquid fuel blend consisting of a hydrocarbon fuel, an ignition enhancer and a transition metal catalyst. In order for further testing of the new fuel blend to take place, some basic materials compatibility and HTP decomposition studies must be accomplished. The thermal decomposition rate of HTP was tested using gas evolution and isothermal microcalorimetry (IMC). Materials were analyzed for compatibility with hydrogen peroxide including a study of the affect welding has on stainless steel elemental composition and its relation to HTP decomposition. Compatibility studies of valve materials in the fuel blend were performed to determine the corrosion resistance of the materials.

Baldridge, Jennifer↗

NASA NTRS1994

Calculation of the thermoneutral potential of NiCd and NiH2 cells

The thermoneutral potential of a nickel cadmium or nickel hydrogen cell is the potential at which the cell charge or discharge process puts out zero heat, and thus is the potential corresponding to the enthalpy change of the charge/discharge reaction, delta H. A relatively straightforward method for obtaining the thermoneutral potential E(sub tn), is based on the measured potential and temperature derivative of the cell reactions, which are related to the free energy change delta G, and entropy change delta S, respectively. Particularly in the nickel hydrogen cell, the pressure of hydrogen can often vary over an order of magnitude or more during the course of a charge or discharge. In a nickel cadmium cell, although significant changes in oxygen pressure can occur during charge or discharge, since oxygen does not enter into the charge/discharge reaction, these pressure changes are related to the heat generated from oxygen evolution and recombination. However, the entropy changes due to changes in hydrogen pressure relative to the 1 atm standard state must be included to apply this method to the nickel hydrogen cell.

Zimmerman, Albert H.↗

NASA NTRS2015

Evidence from Hydrogen Isotopes in Meteorites for a Subsurface Hydrogen Reservoir on Mars

The surface geology and geomorphology of Mars indicates that it was once warm enough to maintain a large body of liquid water on its surface, though such a warm environment might have been transient. The transition to the present cold and dry Mars is closely linked to the history of surface water, yet the evolution of surficial water is poorly constrained. We have conducted in situ hydrogen isotope (D/H) analyses of quenched and impact glasses in three Martian meteorites (Yamato 980459, EETA79001, LAR 06319) by Cameca ims-6f at Digital Terrain Models (DTM) following the methods of [1]. The hydrogen isotope analyses provide evidence for the existence of a distinct but ubiquitous water/ice reservoir (D/H = 2-3 times Earth's ocean water: Standard Mean Ocean Water (SMOW)) that lasted from at least the time when the meteorites crystallized (173-472 Ma) to the time they were ejected by impacts (0.7-3.3 Ma), but possibly much longer [2]. The origin of this reservoir appears to predate the current Martian atmospheric water (D/H equals approximately 5-6 times SMOW) and is unlikely to be a simple mixture of atmospheric and primordial water retained in the Martian mantle (D/H is approximately equal to SMOW [1]). Given the fact that this intermediate-D/H reservoir (2-3 times SMOW) is observed in a diverse range of Martian materials with different ages (e.g., SNC (Shergottites, Nakhlites, Chassignites) meteorites, including shergottites such as ALH 84001; and Curiosity surface data [3]), we conclude that this intermediate-D/H reservoir is likely a global surficial feature that has remained relatively intact over geologic time. We propose that this reservoir represents either hydrated crust and/or ground ice interbedded within sediments. Our results corroborate the hypothesis that a buried cryosphere accounts for a large part of the initial water budget of Mars.

Usui, Tomohiro↗

NASA NTRS1986

Primordial stellar evolution - The protostar phase

The structure and evolution of a protostar forming from a cloud composed of pure hydrogen and helium gas are calculated. Using an accretion rate of 0.0044 solar mass/yr, the collapse of the cloud is followed numerically as a sequence of steady state accretion flows onto the hydrostatic core, which grows from an initial mass of 0.01 solar mass to 10.5 solar masses. The core is surrounded by an optically thick radiative precursor for most of its evolution. The core radius reaches 47 solar radii when the mass is 1 solar mass. For sufficiently massive cores, the deep interior contracts strongly, driving out a 'luminosity wave' which reaches the surface when the mass is 8 solar masses. This results in a large increase in core radius, the establishment of surface convection, and the disappearance of the radiative precursor. The dependence of core radius on the mass and accretion rate is analytically derived, and a new table or Rosseland mean opacities for metal-free gas is presented.

Stahler, S. W.↗

NASA NTRS1974

Studies of hydrodynamic events in stellar evolution. III Ejection of planetary nebulae

Investigation of the dynamic behavior of the hydrogen-rich envelope (0.101 solar mass) of an evolved star (1.1 solar mass) as the luminosity rises to 19,000 solar luminosities during the second ascent of the red-giant branch. For luminosities in the range 3100 less than L less than 19,000 solar luminosities the H-rich envelope pulsates like a long-period variable (LPV) with periods of the order of a year. As L reaches 19,000 solar luminosities, the entire H-rich envelope is ejected as a shell with speeds of a few times 10 km sec. The ejection occurs on a time scale of a few LPV pulsation periods. This ejection is shown to be related to the formation of a planetary nebula. The computations are based on an implicit hydrodynamic computer code. Tand rho-dependent opacities and excitation and ionization energies are included. As the H-rich envelope is accelerated off the stellar core, the gap between envelope and core is approximated by a vacuum filled with radiation.

Kutter, G. S.↗