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At least 145 records · Page 8

Electromagnetic Dissociation and Spacecraft Electronics Damage

When protons or heavy ions from galactic cosmic rays (GCR) or solar particle events (SPE) interact with target nuclei in spacecraft, there can be two different types of interactions. The more familiar strong nuclear interaction often dominates and is responsible for nuclear fragmentation in either the GCR or SPE projectile nucleus or the spacecraft target nucleus. (Of course, the proton does not break up, except possibly to produce pions or other hadrons.) The less familiar, second type of interaction is due to the very strong electromagnetic fields that exist when two charged nuclei pass very close to each other. This process is called electromagnetic dissociation (EMD) and primarily results in the emission of neutrons, protons and light ions (isotopes of hydrogen and helium). The cross section for particle production is approximately defined as the number of particles produced in nucleus-nucleus collisions or other types of reactions. (There are various kinematic and other factors which multiply the particle number to arrive at the cross section.) Strong, nuclear interactions usually dominate the nuclear reactions of most interest that occur between GCR and target nuclei. However, for heavy nuclei (near Fe and beyond) at high energy the EMD cross section can be much larger than the strong nuclear interaction cross section. This paper poses a question: Are there projectile or target nuclei combinations in the interaction of GCR or SPE where the EMD reaction cross section plays a dominant role? If the answer is affirmative, then EMD mechanisms should be an integral part of codes that are used to predict damage to spacecraft electronics. The question can become more fine-tuned and one can ask about total reaction cross sections as compared to double differential cross sections. These issues will be addressed in the present paper.

Norbury, John W.↗

The Importance of Understanding the Last Glacial Maximum for Climate Change

The last glacial maximum (LGM) at approximately 23–18k (k—thousand calendar years) provides an important contrast to our present and pre-industrial climate in a warming world. Global observational datasets of LGM land and sea surface conditions have been synthesized and present some interesting challenges both for providing another scenario for understanding climate change and for climate sensitivity. These challenges are ongoing, as data increase and modeling improves. By definition, the LGM is defined as the time during the last glacial interval in which maximum ice was sequestered in ice sheets as visible in the marine isotopic records. Maximum cooling is visible from pollen and macrofossil records 14C dated to this interval, and ice sheets and alpine glaciers are roughly at their maximum extent throughout the globe. The ice cores extracted from Greenland and Antarctica have given us high-resolution records of greenhouse gases, dust, and isotopes of hydrogen and oxygen which reveal the progression out of the LGM at 18k as climate warmed.

Peteet, Dorothy↗

A Multi-Sims Investigation of Water Content and D/H Ratios in Roberts Massif 04262 with Insight to Sources of Hydrogen in Maskelynite

We want to define the H2O content ([H2O]) and hydrogen (H) isotope composition of meteoritic material from Mars [1-3] with motivation to understand Mars’ volatile history, constrain geochemical signatures of interior water reservoirs (i.e. the Martian mantle) and explore effects of planetary (e.g. planet formation, magma ocean degassing) and local (e.g. volcanic degassing, impact melting and degassing) processes on H incorporated in minerals. Secondary ion mass spectrometry (SIMS) allows multiple avenues to address these questions. However, application to (1) precious astromaterials and (2) low level H measurements, pose specific challenges that are further complicated when combined. We present preliminary data of a multi-approach (SIMS vs. NanoSIMS) study of H in Roberts Massif 04262 (RBT 04262), an enriched lherzolitic shergottite with nonpoikilitic (NP) and poikilitic (P) lithologies [4]. We analyze olivine, pyrox-ene, and melt inclusions to compare indigenous mantle water, with impact-generated maskelynite to investigate H signatures due to shock.

Dudley, J. M.↗

Hydrogen transport in iron and steel

The permeabilities of protium, deuterium, and tritium in foil specimens of Marz grade iron, 4130 steel, Armco iron, HP-9-4-20, and T-1 steels were studied at hydrogen pressures between 0.02 and 0.5 MPa over the temperature range 260-700 K. The permeability was measured by a pressure-rise method, deuterium counting with a detector, and radioactivity counting. Good agreement is found between the measurement techniques used. It is shown that the permeabilities of protium, deuterium, and tritium in iron and T-1 steel at temperatures as low as 260 K are in good agreement with the equation proposed by Gonzalez (1967). However, the permeabilities of HP-9-4-20 and 4130 steel to hydrogen are typically lower than predicted. The isotope effect on hydrogen permeability of HP-9-4-20, 4130 and T-1 steels, and high-purity iron can be estimated by an inverse square root of mass correction.

Louthan, M. R., Jr.↗

Evidence for Surprising Heavy Nitrogen Isotopic Enrichment in Comet 46P/Wirtanen's Hydrogen Cyanide

46P/Wirtanen is a Jupiter-family comet, probably originating from the solar system's Kuiper Belt, that now resides on a 5.4 yr elliptical orbit. During its 2018 apparition, comet 46P passed unusually close to the Earth (within 0.08 au), presenting an outstanding opportunity for close-up observations of its inner coma. Here we present observations of HCN, H13CN, and HC15N emission from 46P using the Atacama Compact Array. The data were analyzed using the SUBLIME non-LTE radiative transfer code to derive 12C/13C and 14N/15N ratios. The HCN/H13CN ratio is found to be consistent with a lack of significant 13C fractionation, whereas the HCN/HC15N ratio of 68 ± 27 (using our most conservative 1σ uncertainties), indicates a strong enhancement in 15N compared with the solar and terrestrial values. The observed 14N/15N ratio is also significantly lower than the values of ∼140 found in previous comets, implying a strong 15N enrichment in 46P's HCN. This indicates that the nitrogen in Jupiter-family comets could reach larger isotopic enrichments than previously thought, with implications for the diversity of 14N/15N ratios imprinted into icy bodies at the birth of the solar system.

Short period comets↗

Spectroscopic observations of the planets

The first phase of a program to determine D/H in the atmospheres of all of the major planets and Titan was completed. D/H on Titan and Uranus is significantly higher than on Jupiter and Saturn. Titan has the highest value, consistent with the possibility for hydrogen escape. These measurements were all made in terms of CH3D/CH4. They suggest that at least two reservoirs for deuterium exist in the outer solar system - a large one in hydrogen and a much smaller one in hydrogen-containing compounds that have not isotopically equilibrated with the hydrogen. This result also demonstrates that a large fraction of the carbon in the outer solar nebula was in the form of methane and it supports the nucleation model for the formation of the outer planets. Other studies included an investigation of the phosphine abundance over the Great Red Spot (GRS) of Jupiter, pre-Voyager determination of the amount of acetylene on Uranus, and the carbon isotope ratio in Halley's Comet. UV spectra of the GRS obtained with the IUE show no evidence of the enhancement of phosphine that would be expected if the red color of this object is caused by P4.

Owen, T.↗

Stripping in collisions between hydrogen molecules below 500 eV.

Measurement of the cross section of stripping the mass 2 and 4 isotopes from molecular hydrogen in their parent gases at kinetic energies between 50 and 500 eV. The angular dependence of the ions is found to be highly peaked in the forward direction, at energies above 100 eV. Plotted vs incident velocity, the cross sections for H2 and D2 approached the same value at the highest velocities and did diverge toward lower velocities. The behavior of the cross sections is found to be consistent with a theoretical model suggested by Demkov and Komarov (1968).

Peterson, R. K.↗

Isotopic Measurements of Sulphonates and Phosphonates and Investigations of Possible Formaldehyde Products from the Murchison Meteorite

Intramolecular carbon, hydrogen, and sulfur isotope measurements have been made on a homologous series of organic sulfonates discovered in the Murchison meteorite. Mass independent sulfur isotope fractionations were observed along with D/H ratios clearly larger than terrestrial. The sulfur fractionations may be produced chemically and due to molecular symmetry factors. The deuterium enrichments indicate formation of the hydrocarbon portion of these compounds in a low temperature astrophysical environment consistent with that of molecular clouds. The source of the sulfonate precursors may have been the reactive interstellar molecule, CS. Low temperature CS reactions also produce other sulfur containing compounds as well as a solid phase. Isotopic measurements on bulk phosphonates were also made.

Cooper, George↗

Isotopic Measurements of Organic Sulfonates From The Murchison Meteorite

Organic sulfonates and phosphonates have been extracted from the Murchison meteorite for stable isotope measurements. Preliminary stable isotope measurements of individual alkyl sulfonates, R-SO3H (R=C(sub n)H(sub 2n+l)), are shown. These compounds were found in aqueous extracts of Murchison. Both groups show trends similar to other homologous series of organic compounds indigenous to Murchison. Molecular abundances decrease with increasing carbon number, and all possible isomers at each carbon number (through C-4) are present. Carbon isotope measurements of the sulfonates show a decrease in the C-13/C-12 ratio with increasing carbon number. The overall objectives of this project are to obtain dime element carbon, hydrogen, and sulfur - intramolecular isotopic analyses of individual sulfonates, and isotopic measurement of carbon and hydrogen of the phosphonates as a group. The Murchison meteorite is the best characterized carbonaceous chondrite with respect to organic chemistry. The finding of organic sulfonates and phosphonates in Murchison is of interest because they are the first well-characterized series of sulfur and phosphorus containing organic compounds found in meteorites. Also, meteorites, comets, and interplanetary dust particles may have been involved in chemical evolution on the early Earth. Because of the critical role of organic phosphorus and sulfur in all living systems, it is particularly interesting to see examples of abiotic syntheses of these classes of compounds. The study of the isotopic composition of the sulfonates and phosphonates can yield insight into their possible interstellar origin as well as their mechanisms of synthesis in the early solar system. Previous isotopic analyses of other classes of organic compounds indigenous to meteorites, e.g., amino acids, carboxylic acids, and hydrocarbons indicate the possibility that interstellar molecules were incorporated into meteorite parent bodies. In these compounds the ratios of heavy to light isotopes of hydrogen (D/H), carbon (C-13/C-12), and nitrogen (N-15/N-14), are anomalous relative to bulk terrestrial and meteoritic values. In some cases, the D/H ratios approach those observed for molecules in interstellar clouds.

Cooper, G. W.↗

The ground state properties of spin-aligned atomic hydrogen, deuterium, and tritium

The internal energy, pressure, and compressibility of ground-state, spin-aligned atomic hydrogen, deuterium, and tritium are calculated assuming that all pair interactions occur via the atomic triplet (spin-aligned) potential. The conditions required to obtain atomic hydrogen and its isotopes in bulk are discussed; such a development would be of value in propulsion systems because of the light mass and energetic recombination of atomic hydrogen. Results show that atomic triplet hydrogen and deuterium remain gaseous at 0 K, and that tritium forms a liquid with a binding energy of approximately -0.75 K per atom at a molar volume of 130 cu cm per mole. The pair distribution function for these systems is calculated, and the predicted superfluid behavior of atomic triplet hydrogen and tritium is briefly discussed.

Etters, R. D.↗

Speculation on a Solar Chronometer for Climate

Solar activity has been correlated to climatic fluctuations and has been postulated as a major factor in quasi-periodic global climatic change. However, correlations are not explanations of physical mechanisms and do not couple cause with effect. A mechanism for a chronometer for solar output variability is proposed based on relations between properties of thermonuclear fusion, nuclear magnetic moment, and nuclear magnetic resonance. A fundamental oscillation of a nucleus with a net nuclear magnetic moment (NMM) is the precession of its axis of rotation when subjected to a magnetic field. Nuclear magnetic resonance (NMR) is the preferred frequency of precession for a nucleus of a particular isotope when placed in a magnetic field of specific intensity. The NMM for those isotopes involved in the proton-proton (p-p) chain pathway for solar fusion varies from strong positive to strong negative. Individual fusion events, for hydrogen and helium isotopes which release varying amounts of energy, may be controlled by NMR frequencies. The pulses of energy from fusion events occurring at NMR frequencies in the solar interior may be transformed into pressure or gravity waves that emerge as gravity or acoustic waves at the surface. Dictated by spherical harmonics, certain wavelengths may be reinforced and reenter the solar interior to modulate the fusion process. Qualitative analysis of solar and climatic data support the interaction of the three basic components of the chronometer, magnetic activity, oscillation frequency, and solar energy output.

Perry, Charles A.↗

The isotopic composition of cosmic-ray helium from 123 to 279 MeV per nucleon - A new measurement and analysis

A description is given of an experiment which was designed to measure the spectra and composition of cosmic-ray hydrogen and helium isotopes in the interval 120-280 MeV per nucleon to compare with the recent values observed at low energies and also with the only earlier measurement in this high-energy regime. The results presented were obtained during a high-altitude balloon flight from Thompson, Manitoba, in 1973 August. This flight occurred during the period in which the presence of the anomalous component in the helium spectrum became apparent, and provides the opportunity of determining whether this component extends to higher energies than those studied by satellite experiments. The results place an upper limit on the flux of 'anomalous' He-4 (which appeared at low energy in 1972) of at most 15% in the energy range of this experiment, and combined with the low-energy observations of the Chicago group, show an energy dependence of the average ratio of the helium isotopes in the modulated cosmic rays which is difficult to reconcile with current modulation models.

Leech, H. W.↗