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Minor constituents in the stratosphere and mesosphere

This paper is a brief survey of a portion of the research on trace constituents in the stratosphere and mesosphere between 1971 and 1974. A primary motivation for much of the stratospheric research came from the realization that man's activities may influence global climate and the atmospheric ozone content, our shield against certain UV wavelengths. A great deal of progress has been reported in understanding both the present background stratosphere and the responses to be expected from additions of nitrogen oxides, water, and chlorine oxides, especially with respect to ozone. Trace constituents in the mesosphere have been modeled and measured to increase our understanding of the physics and chemistry of the mesosphere but also to relate mesospheric composition and transport to ionospheric processes at higher altitudes, to D region ion chemistry, and to upper stratospheric composition.

Cicerone, R. J.↗

Rocket/Radar Investigation of Lower Ionospheric Electrodynamics Associated with Intense Midlatitude Sporadic-E Layers

Sporadic layers, which appear in the region from 100 km to 120 km are thought to be formed by convergent Pedersen drifts induced by altitude gradients in the zonal neutral wind. In this altitude region NO+ and 02+ are the major ions produced by photoionization and charge exchange of atmospheric and ionospheric species. The relative composition of atmospheric ions and meteoric ions in sporadic layers is important in determining their persistence, the time scales for formation, and the electrical conductivity of the layers. This rocket investigation will include a diagnosis of the neutral wind field and the electric field distribution. Coupled with ion composition measurements we will be able to expose the relevant formation mechanisms and the electrodynamic consequences of their existence. A rocket trajectory has been chosen to provide substantial horizontal sampling of the layer properties and knowledge of the horizontal gradients in composition and density are essential to determine the polarization electric fields that may be associated with ionospheric layers. The University of Texas at Dallas (UTD) is responsible for designing, building, and operating the ion mass spectrometers included on these rockets. The following provides a summary of the UTD accomplishments in the second year of the project as well as a description of the plans for the third year's activities. The UTD mass spectrometer acronym has been coined as PRIMS for Puerto Rico Ion Mass Spectrometer.

Heelis, R. A.↗

The ionosphere of Venus - Observations and their interpretation

The implications of Soviet and U.S. observations of the Venus ionosphere's density, temperature, composition, motion, and magnetic structure are discussed, in view of the strong influence exerted on nearly all ionospheric parameters by the solar wind. The IMF conveys solar wind pressure to the ionosphere, compressing, accelerating, heating and removing plasma, forming the ionopause and inducing a nightward convection of plasma. Within the ionosphere, the main electron density peak is at an altitude of about 140 km on the day side, and is believed to be formed by local production and loss analogous to the earth's E region. Throughout most of the ionosphere, the nightward ion flow is primarily driven by the day-to-night pressure gradient, and electron precipitation also contributes to the nightside ionization. The lower atmosphere is dominated by O2(+), except at the lowest altitudes at night, where NO(+) and CO2(+) become significant ions.

Brace, L. H.↗

Initial ion composition results from the Isis 2 satellite

Isis 2 satellite carried, among other ionospheric instruments an ion mass spectrometer designed to measure the composition of the ionosphere in the mass range from 1 to 64 amu. The satellite, in a nearly constant 1400-km orbit, was launched on April 1, 1971. Examples of data show a wide variation in ion composition from 99% H(+) at night near the equator to greater than 95% O(+) and N(+) in the daytime poleward of the plasmapause. Both H(+) and He(+) are observed to be streaming outward from the high-latitude regions with velocities of several kilometers per second (the polar wind), determined from phase shifts in roll modulation maximums between light and heavy ion species. During the August 1972 magnetic storm a unique ionosphere developed, consisting of N(+) as the dominant species between 55 and 80 deg invariant latitude (above the plasmapause) and N2(+), NO(+), and O2(+) at the 1000 per cu cm concentration level, whereas these molecular species are usually below the detection limit of 1 ion per cu cm in quiet times at this altitude.

Hoffman, J. H.↗

Large decreases in ionospheric total electron content as a result of thermospheric composition changes during geomagnetic storms

The geomagnetic storms of April 17-21,2002 and May 29-30,2003 caused large decreases in the O/N2 column density ratio in the thermosphere. For these storms, ON2 column density decreases of greater than 50% were observed to extend to mid-to-low latitudes with the FUV sensitive Earth Camera of the Visible Imaging System (VIS) on the Polar spacecraft. Simultaneously in these same regions, the ground-based GPS network observed approximately 80% reductions in the Total Electron Content (TEC) of the ionosphere. The reduction in the Om2 column density ratio is due mainly to increases in the molecular species that have welled-up into the thermosphere from the lower levels of the atmosphere due to auroral heating. The geomagnetic-storm driven increase in molecular densities at typical ionospheric heights rapidly charge exchange with the ambient ionized atoms and subsequently dissociatively recombine with the ionospheric electrons leading to a reduction in the total charge density. The transition boundaries between high and low regions of O/N2 as well as TEC can be tracked in the images and the thermospheric winds can be determined from the motion of the boundaries. The motion of these boundaries during the development of the geomagnetic storm will be discussed.

Sigwarth, J. B.↗

Ion escape fluxes from the terrestrial high-latitude ionosphere

In this paper, the hydrodynamic transport equations for H(+) and O(+) are solved, including the important dynamic, collisional, and chemical effects that operate in the F region ionosphere below regions of ion acceleration. It is found that the most important parameter controlling the amount of O(+) in plasma outflows is the total ion flux demand imposed on the ionosphere by the higher-altitude acceleration region. The O(+) content is further modulated by the temperature of the exosphere and the resultant composition in the topside ionosphere, and by the location of the lower boundary of the ion acceleration region relative to the crossover altitude, where O and H have equal densities. As solar activity increases, the limiting O(+) escape flux increases, while the limiting H(+) escape flux decreases.

Barakat, A. R.↗

The distribution of singly ionized ionospheric helium from 304 A backscatter observations

The theoretical distribution of helium ions in the ionosphere is studied as a function of such ionospheric parameters as the remaining ion composition and distribution, temperature, magnetic field topology, and ionospheric dynamics. An attempt is made to verify the theoretical predictions of the H(+) distribution in the ionosphere on the basis of observations of 304 A radiation resonantly scattered from He(+).

Chakrabarti, S.↗

Observations of the nightside Venus ionosphere: Final encounter of the Pioneer Venus Orbiter Ion Mass Spectrometer

During the last orbital sequences of the Pioneer-Venus spacecraft prior to final encounter and atmospheric entry, data were obtained by the Orbiter Ion Mass Spectrometer (OIMS) at the lowest periapsis altitudes of the mission. These data verified OIMS observations of the nightside ionospheric peak reported earlier in the mission, and revealed additional details related to composition, energetics and maintenance of the nightside ionosphere. OIMS observations of the ion peak during the final encounter sequence are compared with radio occultation data and OIMS peak observations obtained earlier. OIMS ion density and Orbiter Electron Temperature Probe (OETP) electron density are found to correlate near the peak. Coupling of mass channels 30 and 32 during nightside passes is observed and its interpretation considered. Changes in high altitude composition of the nightside ionosphere, especially the relative changes in O(+) and H(+), are described.

Cloutier, P. A.↗

Observations of the Nightside Venus Ionosphere: Final Encounter of the Pioneer Venus Orbiter Ion Mass Spectrometer

During the last orbital sequences of the Pioneer Venus spacecraft prior to final encounter and atmospheric entry, data were obtained by the Orbiter Ion Mass Spectrometer (OIMS) at the lowest periapsis altitudes of the mission. These data verified OIMS observations of the nightside ionospheric peak reported-earlier in the mission, and revealed additional details related to composition, energetics and maintenance of the nightside ionosphere. OIMS observations of the ion peak during the final encounter sequence are compared with radio occultation data and OIMS peak observations obtained earlier. OIMS ion density and Orbiter Electron Temperature Probe (OETP) electron density are found to correlate near the peak. Coupling of mass channels 30 and 32 during nightside passes is observed and its interpretation considered. Changes in high altitude composition of the nightside ionosphere, especially the relative changes in O(+) and H(+), are described.

Cloutier, P. A.↗

Ionosphere of Venus - First observations of the effects of dynamics on the dayside ion composition

Data obtained by Bennett radio-frequency ion mass spectrometers indicate that the ionosphere envelope, dominated above 200 km by O(+), responds dramatically to variations in the solar wind pressure. The pressure compresses the thermal ion distributions from heights as great as 1800 km inward to 280 km. At the thermal ion boundary, or ionopause, the ambient ions are swept away by the solar wind, while at higher altitudes energetic ion currents are detected. Within the ionosphere, ion convection stimulated by the solar wind interaction causes pass-to-pass differences in the ion scale heights.

Taylor, H. A., Jr.↗

On explaining magnetic storm phenomena in the upper atmosphere and ionosphere.

Changes in ion and neutral compositions and in neutral, ion, and electron temperatures during the main phase of a magnetic storm are studied by solving a system of basic ionospheric and atmospheric differential equations. It is shown that a decrease in the atomic-to-molecular concentration ratio in the lower thermosphere may help explain several phenomena observed during a magnetic storm. These phenomena include decreases in the columnar electron content and increases in neutral temperature.

Stubbe, P.↗

Anomaly of the composition of the F-2 equatorial region of the ionosphere during the hours after sunset according to data from the mass-spectrometer experiment on the Cosmos-274

A mass spectrometer on board Cosmos-274 measured concentrations of light atoms and ions. While traversing the geomagnetic equator during the evening hours it recorded on anomalous drop in ionized molecular oxygen and ionized atomic oxygen and nitrogen. A similar, less dramatic, decline was observed in the concentration of neutral atomic oxygen. A possible explanation for this and previously observed behavior is an ascent in altitude of the F layer in the hours after sunset, a possibility which is supported by calculations.

Gaydukov, V. Y.↗

Ionospheric models for Venus and Mars

The ways in which different models employ the multifluid continuity, momentum, and energy equations to characterize the ionospheres of Mars and Venus on the basis of in situ neutral and ion compositions are discussed. The Venus ionosphere is permeated by large-scale magnetic fields when the solar wind dynamic pressure is high, but is free from such fields under conditions of low solar wind dynamic pressure. Large-scale magnetic fields are nearly always present in the Mars ionosphere. Plasma moves downward on both planets for magnetized conditions, and magnetic flux is carried from the magnetosheath down into the ionosphere. Ohmic dissipation of the currents responsible for the magnetic field takes place deep in the ionospheres of both planets.

Cravens, T. E.↗

Continuation of data analysis from the ion mass spectrometer on the ISIS-2 spacecraft

The spectrometer measures the composition and number density of the positive ion species in the ionosphere as well as the ion flux normal to the spacecraft trajectory. The measurement of high latitude ionospheric dynamics is reported. Plans for an empirical composition model of the polar ionosphere at 1400 km altitude consisting of maps of the major constituent are also reported.

Hoffman, J. H.↗

In Situ Measurements of Meteoric Ions

Extraterrestrial material is the source of metal ions in the Earth's atmosphere, Each year approx. 10(exp 8) kg of material is intercepted by the Earth. The origin of this material is predominantly solar orbiting interplanetary debris from comets or asteroids that crosses the Earth's orbit. It contains a very small amount of interstellar material. On occasion the Earth passes through enhanced amounts of debris associated with the orbit of a decaying comet. This leads to enhanced meteor shower displays for up to several days. The number flux of shower material is typically several times the average sporadic background influx of material. Meteoric material is some of the earliest material formed in the solar system. By studying the relative elemental abundances of atmospheric metal ions, information can be gained on the chemical composition of cometary debris and the chemical makeup of the early solar system. Using in situ sampling with rocket-borne ion mass spectrometers; there have been approximately 50 flights that made measurements of the metal ion abundances at attitudes between 80 and 130 km. It is this altitude range where incoming meteoric particles am ablated, the larger ones giving rise to visible meteor. displays. In several rocket measurements isotopic ratios of different atomic ion mass components and metal molecular ion concentrations have been determined and used to identify unambiguously the measured species and to investigate the processes controlling the metal ion distributions The composition of the Earth's ionosphere was first sampled by an ion mass spectrometer flown an a rocket in 1956. In 1958 a rocket-borne ion spectrometer identified, fbr the first time, a layer of metal ions near 95 km. These data were interpreted as evidence of an extraterrestrial rather than a terrestrial source. Istomin predicted: "It seems probable that with some improvement in the method that analysis of the ion composition in the E-region may be used for determining the chemical composition of those meteors which do not reach the ground. Particularly, we hope to get information about the composition difference between particles of different meteor showers and also sporadic and shower meteoroids". These visions categorized the aims of many subsequent rocket-borne ion mass spectrometer experiments in the lower ionosphere, Although the use such measurements to deduce the composition of different classes of meteoroids has not been successful, the past four decades of rocket observations have provided po%erful sets of data for advancing our understanding of meteor ablation, meteoric composition, metal neutral and ion chemistry as well as ionospheric dynamics.

Grebowsky, Joseph M.↗

Plasma Ion Composition Measurements for Europa

Jupiter magnetospheric interactions and surface composition, both important to subsurface ocean detection for the Galilean icy moons Europa, Ganymede, and Callisto, can be measured using plasma ion mass spectrometry on either an orbiting spacecraft or one designed for multiple flybys of these moons. Detection of emergent oceanic materials at the Europa surface is more likely than at Ganymede and Callisto. A key challenge is to resolve potential intrinsic Europan materials from the space weathering patina of iogenic species implanted onto the sensible surface by magnetospheric interactions. Species resolved measurements of pickup ion currents are also critical to extraction of oceanic induced magnetic fields from magnetospheric interaction background dominated by these currents. In general the chemical astrobiological potential of Europa should be determined through the combination of surface, ionospheric, and pickup ion composition measurements. The requisite Ion Mass Spectrometer (IMS) for these measurements would need to work in the high radiation environment of Jupiter's magnetosphere between the orbits of Europa and Ganymede, and beyond. A 3D hybrid model of the moon magnetosphere interaction is also needed to construct a global model of the electric and magnetic fields, and the plasma environment, around Europa. Europa's ionosphere is probably usually dominated by hot pickup ions with 100-1000 eV temperatures, excursions to a "classical" cold ionosphere likely being infrequent. A field aligned ionospheric wind driven by the electron polarization electric field should arise and be measurable.

Plasma↗

The atmosphere of Mars

Effects of Mariner IV ionospheric data on Mars atmosphere composition predictions

MARS ATMOSPHERE↗