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Sensing the gas metal arc welding process

Control of gas metal arc welding (GMAW) requires real-time sensing of the process. Three sensing techniques for GMAW are being developed at the Idaho National Engineering Laboratory (INEL). These are (1) noncontacting ultrasonic sensing using a laser/EMAT (electromagnetic acoustic transducer) to detect defects in the solidified weld on a pass-by-pass basis, (2) integrated optical sensing using a CCD camera and a laser stripe to obtain cooling rate and weld bead geometry information, and (3) monitoring fluctuations in digitized welding voltage data to detect the mode of metal droplet transfer and assure that the desired mass input is achieved.

Carlson, N. M.↗

Capabilities Enhanced for Researching the Reduction of Emissions in Future Aircraft

Aircraft future aircraft jet engines will run at higher pressures to obtain greater fuel efficiency and performance. This will require new combustor designs to keep the nitrogen oxide and carbon monoxide emissions at environmentally acceptable levels. The actual pressures and temperatures found in gas turbine combustors must be duplicated in a laboratory to verify the emissions characteristics of gas turbine engines. Recognizing this, the U.S. aircraft gas turbine industry identified a need for a national facility that could duplicate the severe inlet conditions of future combustors. Because of our expertise in combustion emissions reduction research and in the design and operation of high-pressure test facilities, the NASA Lewis Research Center was seen as the natural location for such a facility. As a national laboratory, Lewis could provide these facilities to all U.S. gas turbine engine manufacturers while protecting their proprietary interests. Called the Advanced Subsonic Combustion Rig, the facility will provide up to 60-atm pressures at inlet temperatures up to 1300 F and air flow rates up to 38 lb/sec. Furthermore, it will offer state-of-the-art diagnostic methods for characterizing advanced combustor concepts. Aeronautical combustion research at Lewis provided several significant accomplishments recently in support of both the High Speed Research (HSR) and Advanced Subsonic Technology (AST) programs. For example, in the High Speed Research Program, NO_x reductions of up to 90 percent were achieved in prototype combustor hardware. Advanced computational analysis, gas sampling, and laser diagnostic techniques were critical to this success. Working closely with the gas turbine industry, we have successfully transferred this low-emissions combustor technology into engine prototype hardware. This hardware is now being tested at the engine manufacturers facilities. Complementary tests in Lewis currently available 30-atm test facilities are also underway, taking advantage of Lewis unique diagnostic capabilities. By utilizing test facilities belonging to both NASA and its industry partners, we have tested multiple combustor concepts in a shorter period of time.

Source record↗

Identification of Surface and Near Surface Defects and Damage Evaluation by Laser Speckle Techniques

As a part of the grant activity, a laboratory was established within the Department of Electrical Engineering for the study for measurements of surface defects and damage evaluation. This facility has been utilized for implementing several algorithms for accurate measurements of defects. Experiments were conducted using simulated images and multiple images were fused to achieve accurate measurements. During the nine months of the grants when the principal investigator was transferred in my name, experiments were conducted using simulated synthetic aperture radar (SAR) images. This proved useful when several algorithms were used on images of smooth objects with minor deformalities. Given the time constraint, the derived algorithms could not be applied to actual images of smooth objects with minor abnormalities.

Gowda, Chandrakanth H.↗

Photon-Counting Microlaser Rangers, Transponders, and Altimeters

Unlike current manned systems, NASA's next generation SLR2000 Satellite Laser Ranging (SLR) station is fully autonomous. eye-safe, relatively compact and inexpensive. and, during daytime tracking operates at signal-to-noise ratios several orders of magnitude below unity. Tiny, passively Q-switched microlasers generate ultra-short pulses with output energies on the order of 100 micron-J at few kHz rates to achieve mm-level ranging precision to satellite altitudes of 20,000 km. Special ranging receivers, combined with Poisson statistical analysis of the received photon distribution, enable the system to rapidly and reliably identify and extract the single photon laser echoes from the solar background. The enhanced rate of return, combined with a uniform signal strength, can actually drive down both systematic and random range errors. The new SLR2000 technology has already spawned exciting new applications. Compact microlaser altimeters, capable of mapping the surface of a planet or other celestial body at multikilohertz rates, is one such application, and a high altitude, airborne version is currently being developed under NASA's Instrument Incubator Program. Interplanetary microlaser transponders would be capable of performing decimeter ranging or subnanosecond time transfer to spacecraft throughout the inner Solar System. resulting in improved knowledge of planetary motions and liberations and enhanced General Relativity experiments.

Degnan, John J.↗

NASA Johnson Space Center SBIR STTR Program Technology Innovations

The Small Business Innovation Research (SBIR) Program increases opportunities for small businesses to participate in research and development (R&D), increases employment, and improves U.S. competitiveness. Specifically the program stimulates U.S. technological innovation by using small businesses to meet federal R&D needs, increasing private-sector commercialization of innovations derived from federal R&D, and fostering and encouraging the participation of socially disadvantaged businesses. In 2000, the Small Business Technology Transfer (STTR) Program extended and strengthened the SBIR Program, increasing its emphasis on pursuing commercial applications by awarding contracts to small business concerns for cooperative R&D with a nonprofit research institution. Modeled after the SBIR Program, STTR is nevertheless a separately funded activity. Technologies that have resulted from the Johnson Space Center SBIR STTR Program include: a device for regenerating iodinated resin beds; laser-assisted in-situ keratomileusis or LASIK; a miniature physiological monitoring device capable of collecting and analyzing a multitude of real-time signals to transmit medical data from remote locations to medical centers for diagnosis and intervention; a new thermal management system for fibers and fabrics giving rise to new line of garments and thermal-enhancing environments; and a highly electropositive material that attracts and retains electronegative particles in water.

Krishen, Kumar↗

Optical Communications Systems for NASA's Human Space Flight Missions

The Laser-Enhanced Mission Communications Navigation and Operational Services (LEMNOS) office at Goddard Space Flight Center (GSFC) manages two NASA optical communication related projects, the Orion EM-2 Optical Communications Terminal (O2O) and the Integrated Laser Communications Relay Demonstration (LCRD) Low-Earth Orbit (LEO) User Modem and Amplifier Terminal (ILLUMA-T) projects. The main goal of LEMNOS is the advancement and implementation of optical communications systems and technologies for NASA missions. The O2O mission is sponsored by NASA's Human Exploration and Operations (HEO) Mission Directorate. The O2O project will provide optical communications capability to the Orion series of spacecraft, starting with the demonstration of operational utility on EM-2. It will be the first time a human exploration mission will rely on optical communications for its high-bandwidth link. ILLUMA-T is sponsored by the Space Communications and Navigation (SCaN) Program Office. It is destined for the International Space Station (ISS) as an external payload attached to the Japanese Experiment Module - Exposed Facility (JEM-EF). The ILLUMA-T project is developing an optical communications user terminal to demonstrate high bandwidth data transfer between LEO and the ground through the geosynchronous LCRD relay. ILLUMA-T will be the first demonstration of a LEO user of the LCRD system, pointing and tracking from a moving spacecraft at LEO to GEO satellite and vice versa, end-to-end operational utility of optical communications, and 51 Mbps forward link to ISS from ground. Both projects are collaborations between GSFC, Massachusetts Institute of Technology-Lincoln Laboratory (MIT-LL), and a number of contractors.

Laser Communications↗

Measurements of the methane relaxation times for application to the infrared emission models of the upper atmospheres of outer planets and Titan

The 7.8 micrometer emission from the nu(sub 4) band of methane (CH4) is a regularly observed feature in the stratosphere of all the giant planets and Titan. On Jupiter, enhancements in this emission are associated with the infrared hot spots in the auroral zone. Attempts to model this phenomenon in particular, and to understand the role of methane in general, have been hampered in part by a lack of adequate laboratory measurements of the collisional relaxation times for the nu(sub 3) and nu(sub 4) levels over the appropriate temperature range. To provide this needed data, a series of laboratory experiments were initiated. In the experimental arrangement the nu(sub3) band of methane is pumped at 3.3 micrometers using a pulsed infrared source (Nd:YAG/dye laser system equipped with a wave-length extender). The radiative lifetime of the nu(sub 3) level (approximately 37 ms) is much shorter than the nu(sub 4) lifetime (approximately 390 ms); however, a rapid V-V energy transfer rate ensures that the nu(sub 4) level is substantially populated. The photoacoustic technique is used to acquire relaxation rate information. The experiments are performed using a low-temperature, low-pressure cell. Experimental apparatus and technique are described. In addition some of the experimental difficulties associated with making these measurements are discussed and some preliminary results are presented.

Halthore, Rangasayi N.↗

Simulation Studies of Satellite Laser CO2 Mission Concepts

Results of mission simulation studies are presented for a laser-based atmospheric CO2 sounder. The simulations are based on real-time carbon cycle process modeling and data analysis. The mission concept corresponds to ASCENDS as recommended by the US National Academy of Sciences Decadal Survey. Compared to passive sensors, active (lidar) sensing of CO2 from space has several potentially significant advantages that hold promise to advance CO2 measurement capability in the next decade. Although the precision and accuracy requirements remain at unprecedented levels of stringency, analysis of possible instrument technology indicates that such sensors are more than feasible. Radiative transfer model calculations, an instrument model with representative errors, and a simple retrieval approach complete the cycle from "nature" run to "pseudodata" CO2. Several mission and instrument configuration options are examined, and the sensitivity to key design variables is shown. Examples are also shown of how the resulting pseudo-measurements might be used to address key carbon cycle science questions.

Kawa, Stephan Randy↗

Optical Communications Systems for NASA's Human Space Flight Missions

The Laser-Enhanced Mission Communications Navigation and Operational Services (LEMNOS) office at Goddard Space Flight Center (GSFC) manages two NASA optical communication related projects, the Orion EM-2 Optical Communications Terminal (O2O) and the Integrated Laser Communications Relay Demonstration (LCRD) Low-Earth Orbit (LEO) User Modem and Amplifier Terminal (ILLUMA-T) projects. The main goal of LEMNOS is the advancement and implementation of optical communications systems and technologies for NASA missions. The O2O mission is sponsored by NASA's Human Exploration and Operations (HEO) Mission Directorate. The O2O project will provide optical communications capability to the Orion series of spacecraft, starting with the demonstration of operational utility on EM-2. It will be the first time a human exploration mission will rely on optical communications for its high-bandwidth link. ILLUMA-T is sponsored by the Space Communications and Navigation (SCaN) Program Office. It is destined for the International Space Station (ISS) as an external payload attached to the Japanese Experiment Module - Exposed Facility (JEM-EF). The ILLUMA-T project is developing an optical communications user terminal to demonstrate high bandwidth data transfer between LEO and the ground through the geosynchronous LCRD relay. ILLUMA-T will be the first demonstration of a LEO user of the LCRD system, pointing and tracking from a moving spacecraft at LEO to GEO satellite and vice versa, end-to-end operational utility of optical communications, and 51 Mbps forward link to ISS from ground. Both projects are collaborations between GSFC, Massachusetts Institute of Technology â€" Lincoln Laboratory (MIT-LL), and a number of contractors.

Lasercom↗

Flame-Vortex Interactions Imaged in Microgravity - To Assess the Theory Flame Stretch

The goals of this research are to: 1) Assess the Theory of Flame Stretch by operating a unique flame-vortex experiment under microgravity conditions in the NASA Glenn 2.2 Second Drop Tower (drops to identify operating conditions have been completed); 2) Obtain high speed shadowgraph images (500-1000 frames/s) using the drop rig (images were obtained at one-g, and the NASA Kodak RO camera is being mounted on the drop rig); 3) Obtain shadowgraph and PIV images at 1-g while varying the effects of buoyancy by controlling the Froude number (completed); 4) Numerically model the inwardly-propagating spherical flame that is observed in the experiment using full chemistry and the RUN 1DL code (completed); 5) Send images of the flame shape to Dr. G. Patniak at NRL who is numerically simulating the entire flame-vortex interaction of the present experiment (data transfer completed); and 6) Assess the feasibility of obtaining PIV velocity field images in the drop rig, which would be useful (but not required) for our assessment of the Theory of Flame Stretch (PIV images were obtained at one-g using same low laser power that is available from fiber optic cable in drop tower). The motivation for the work is to obtain novel measurement needed to develop a physically accurate model of turbulent combustion that can help in the control of engine pollutants. The unique experiment allows, for the first time, the detailed study of a negatively-curved (negatively stretched) flame, which is one of the five fundamental types of premixed flames. While there have been studies of flat flames, positively-curved (outwardly-propagating) cases and positively-strained (counterflow) cases, this is the first detailed study of a negatively-curved (inwardly-propagating) flame. The first set of drops in the 2.2 Second Drop Tower showed that microgravity provides more favorable conditions for achieving inwardly-propagating flames (IPFs) than 1-g. A vortex interacts with a flame and creates a spherical pocket, which burns inwardly. Shadowgraphs at 1000 frames/sec quantify the Markstein number and flame speed. A Low-Laser Power PIV System was developed and is being added to the drop package. Numerical computations were required to explain why the Markstein numbers measured for the inwardly-propagating flames differ from those of outward propagating flames; this is an important research issue in the assessment of the Theory of Flame Stretch. The RUN-1DL code (developed by Prof. B. Rogg) was run for IPF and OPFs with complex methane and propane chemistry. Results confirmed that Ma for the IPFs are larger than for OPFs as was observed experimentally. Physical reasons for these new findings about the Theory of Flame Stretch are being determined from the experiments and the computations. Several journal papers have been published; the drop package is described in the AIAA Journal, while the one-g results appear in three other journal papers.

Driscoll, James F.↗

Organic Matter in Extraterrestrial Water-Bearing Salt Crystals

Introduction: Direct samples of early Solar System fluids are present in two thermally-metamorphosed ordinary chondrite regolith breccias (Monahans (1998) [H5] and Zag [H3-6]), which were found to contain brine-bearing halite (NaCl) crystals that have been added to the regolith of an S-type asteroid following asteroidal metamorphism [1, 2]. The brine-bearing halite grains were proposed to be formed on an icy C-type asteroids (possibly Ceres), and transferred to an S-type asteroid via cryovolcanic event(s) [3]. A unique aspect of these halites is that they contain abundant organic rich solid inclusions hosted within the halites alongside the water inclusions. Methods: We analyzed in detail the compositions of the organic solids and the amino acid content of the halite crystals with two-step laser desorption/laser ionization mass spectrometry (L(sup 2) MS), Raman spectroscopy, X-ray absorption near edge structure (XANES), nanoscale secondary ion mass spectrometry (NanoSIMS), and ultra-performance liquid chromatography fluorescence detection and quadrupole time of flight hybrid mass spectrometry (UPLC-FD/QToF-MS). Results and Discussion: The L(sup 2) MS results show signatures of low-mass polyaromatic hydro-carbons (PAHs) indicated by sequences of peaks separated by 14 atomic mass units (amu) due to successive addition of methylene (CH2) groups to the PAH skeletons [4]. Raman spectra of the micron-sized solid inclusions of the halites indicate the presence of abundant and highly variable organic matter that include a mixture of short-chain aliphatic compounds and macromolecular carbon. C-XANES analysis identified C-rich areas with peaks at 285.0 eV (aromatic C=C) and 286.6 eV (vinyl-keto C=O). However, there is no 1s-sigma* exciton peak (291.7 eV) that is indicative of the development of graphene structure [5], which suggests the organics were synthesized cold. Na-noSIMS analyses show C-rich and N-rich areas that exhibit similar isotopic values with that of the IOM in the unweathered CR chondrites and less metamorphosed meteorites [6], and are moderately enriched in N-15 (delta N-15 = 106.1-164.5 per mille). The total amino acid distribution and abundance of the Zag matrix (approximately 1,940 parts per billion [ppb]) is comparable to other ordinary chondrites (60-3,330 ppb) [7, 8]. While the Zag matrix is gamma-ABA and EACA-deficient, the halite is shown to exhibit an opposite trend and is almost depleted in amino acids. The striking difference in the amino acid contents between the halite and matrix indicates their separate synthetic origins. Conclusion: Abundant, primitive, and highly-diverse N-15-rich organic compounds were detected in brine-water bearing halite crystals that were synthesized on a cryovolcanically-active asteroid. Our study suggests that the asteroidal parent body where the halite precipitated, potentially Ceres, is a host to abundance large variety organic precursors. Insoluble organic matter and amino acids can be synthesized from similar organic precusors under hydrous conditions [9].We envision that similar organic synthetic processes could have occurred on Ceres that synthesized organic solids as well as biologically relevant molecules.

Chan, Q. H. S.↗

High-Density, High-Bandwidth, Multilevel Holographic Memory

A proposed holographic memory system would be capable of storing data at unprecedentedly high density, and its data transfer performance in both reading and writing would be characterized by exceptionally high bandwidth. The capabilities of the proposed system would greatly exceed even those of a state-of-the art memory system, based on binary holograms (in which each pixel value represents 0 or 1), that can hold .1 terabyte of data and can support a reading or writing rate as high as 1 Gb/s. The storage capacity of the state-of-theart system cannot be increased without also increasing the volume and mass of the system. However, in principle, the storage capacity could be increased greatly, without significantly increasing the volume and mass, if multilevel holograms were used instead of binary holograms. For example, a 3-bit (8-level) hologram could store 8 terabytes, or an 8-bit (256-level) hologram could store 256 terabytes, in a system having little or no more size and mass than does the state-of-the-art 1-terabyte binary holographic memory. The proposed system would utilize multilevel holograms. The system would include lasers, imaging lenses and other beam-forming optics, a block photorefractive crystal wherein the holograms would be formed, and two multilevel spatial light modulators in the form of commercially available deformable-mirror-device spatial light modulators (DMDSLMs) made for use in high speed input conversion of data up to 12 bits. For readout, the system would also include two arrays of complementary metal oxide/semiconductor (CMOS) photodetectors matching the spatial light modulators. The system would further include a reference-beam sterring device (equivalent of a scanning mirror), containing no sliding parts, that could be either a liquid-crystal phased-array device or a microscopic mirror actuated by a high-speed microelectromechanical system. Time-multiplexing and the multilevel nature of the DMDSLM would be exploited to enable writing and reading of multilevel holograms. The DMDSLM would also enable transfer of data at a rate of 7.6 Gb/s or perhaps somewhat higher.

Chao, Tien-Hsin↗

Lidar Remote Sensing of Forests: New Instruments and Modeling Capabilities

Lidar instruments provide scientists with the unique opportunity to characterize the 3D structure of forest ecosystems. This information allows us to estimate properties such as wood volume, biomass density, stocking density, canopy cover, and leaf area. Structural information also can be used as drivers for photosynthesis and ecosystem demography models to predict forest growth and carbon sequestration. All lidars use time-in-flight measurements to compute accurate ranging measurements; however, there is a wide range of instruments and data types that are currently available, and instrument technology continues to advance at a rapid pace. This seminar will present new technologies that are in use and under development at NASA for airborne and space-based missions. Opportunities for instrument and data fusion will also be discussed, as Dr. Cook is the PI for G-LiHT, Goddard's LiDAR, Hyperspectral, and Thermal airborne imager. Lastly, this talk will introduce radiative transfer models that can simulate interactions between laser light and forest canopies. Developing modeling capabilities is important for providing continuity between observations made with different lidars, and to assist the design of new instruments. Dr. Bruce Cook is a research scientist in NASA's Biospheric Sciences Laboratory at Goddard Space Flight Center, and has more than 25 years of experience conducting research on ecosystem processes, soil biogeochemistry, and exchange of carbon, water vapor and energy between the terrestrial biosphere and atmosphere. His research interests include the combined use of lidar, hyperspectral, and thermal data for characterizing ecosystem form and function. He is Deputy Project Scientist for the Landsat Data Continuity Mission (LDCM); Project Manager for NASA s Carbon Monitoring System (CMS) pilot project for local-scale forest biomass; and PI of Goddard's LiDAR, Hyperspectral, and Thermal (G-LiHT) airborne imager.

Cook, Bruce D.↗

Two-micron Laser Atmospheric Wind Sounder (LAWS) pointing/tracking study

The objective of the study was to identify and model major sources of short-term pointing jitter for a free-flying, full performance 2 micron LAWS system and evaluate the impact of the short-term jitter on wind-measurement performance. A fast steering mirror controls system was designed for the short-term jitter compensation. The performance analysis showed that the short-term jitter performance of the controls system over the 5.2 msec round-trip time for a realistic spacecraft environment was = 0.3 micro rad, rms, within the specified value of less than 0.5 micro rad, rms, derived in a 2 micron LAWS System Study. Disturbance modes were defined for: (1) the Bearing and Power Transfer Assembly (BAPTA) scan bearing, (2) the spacecraft reaction wheel torques, and (3) the solar array drive torques. The scan bearing disturbance was found to be the greatest contributing noise source to the jitter performance. Disturbances from the fast steering mirror reaction torques and a boom-mounted cross-link antenna clocking were also considered but were judged to be small compared to the three principal disturbance sources above and were not included in the final controls analysis.

Manlief, Scott↗

Micromachined Active Magnetic Regenerator for Low-Temperature Magnetic Coolers

A design of an Active Magnetic Regenerative Refrigeration (AMRR) system has been developed for space applications. It uses an innovative 3He cryogenic circulator to provide continuous remote/distributed cooling at temperatures in the range of 2 K with a heat sink at about 15 K. A critical component technology for this cooling system is a highly efficient active magnetic regenerator, which is a regenerative heat exchanger with its matrix material made of magnetic refrigerant gadolinium gallium garnet (GGG). Creare Inc. is developing a microchannel GGG regenerator with an anisotropic structured bed for high system thermal efficiency. The regenerator core consists of a stack of thin, single-crystal GGG disks alternating with thin polymer insulating layers. The insulating layers help minimize the axial conduction heat leak, since GGG has a very high thermal conductivity in the regenerator s operating temperature range. The GGG disks contain micro channels with width near 100 micrometers, which enhance the heat transfer between the circulating flow and the refrigerant bed. The unique flow configuration of the GGG plates ensures a uniform flow distribution across the plates. The main fabrication challenges for the regenerator are the machining of high-aspect-ratio microchannels in fragile, single-crystal GGG disks and fabrication and assembly of the GGG insulation layers. Feasibility demonstrations to date include use of an ultrashort- pulse laser to machine microchannels without producing unacceptable microcracking or deposition of recast material, as shown in the figure, and attachment of a thin insulation layer to a GGG disk without obstructing the flow paths. At the time of this reporting, efforts were focused on improving the laser machining process to increase machining speed and further reduce microcracking.

Chen, Weibo↗

Performance Considerations for the SIMPL Single Photon, Polarimetric, Two-Color Laser Altimeter as Applied to Measurements of Forest Canopy Structure and Composition

The Slope Imaging Multi-polarization Photon-counting Lidar (SIMPL) is a multi-beam, micropulse airborne laser altimeter that acquires active and passive polarimetric optical remote sensing measurements at visible and near-infrared wavelengths. SIMPL was developed to demonstrate advanced measurement approaches of potential benefit for improved, more efficient spaceflight laser altimeter missions. SIMPL data have been acquired for wide diversity of forest types in the summers of 2010 and 2011 in order to assess the potential of its novel capabilities for characterization of vegetation structure and composition. On each of its four beams SIMPL provides highly-resolved measurements of forest canopy structure by detecting single-photons with 15 cm ranging precision using a narrow-beam system operating at a laser repetition rate of 11 kHz. Associated with that ranging data SIMPL provides eight amplitude parameters per beam unlike the single amplitude provided by typical laser altimeters. Those eight parameters are received energy that is parallel and perpendicular to that of the plane-polarized transmit pulse at 532 nm (green) and 1064 nm (near IR), for both the active laser backscatter retro-reflectance and the passive solar bi-directional reflectance. This poster presentation will cover the instrument architecture and highlight the performance of the SIMPL instrument with examples taken from measurements for several sites with distinct canopy structures and compositions. Specific performance areas such as probability of detection, after pulsing, and dead time, will be highlighted and addressed, along with examples of their impact on the measurements and how they limit the ability to accurately model and recover the canopy properties. To assess the sensitivity of SIMPL's measurements to canopy properties an instrument model has been implemented in the FLIGHT radiative transfer code, based on Monte Carlo simulation of photon transport. SIMPL data collected in 2010 over the Smithsonian Environmental Research Center, MD are currently being modelled and compared to other remote sensing and in situ data sets. Results on the adaptation of FLIGHT to model micropulse, single'photon ranging measurements are presented elsewhere at this conference. NASA's ICESat-2 spaceflight mission, scheduled for launch in 2016, will utilize a multi-beam, micropulse, single-photon ranging measurement approach (although non-polarimetric and only at 532 nm). Insights gained from the analysis and modelling of SIMPL data will help guide preparations for that mission, including development of calibration/validation plans and algorithms for the estimation of forest biophysical parameters.

Dabney, Philip W.↗

Scanning tunneling microscopy studies of diamond films and optoelectronic materials

In this report, we report on progress achieved from 12/1/92 to 10/1/93 under the grant entitled 'Scanning Tunneling Microscopy Studies of Diamond Films and Optoelectronic Materials'. We have set-up a chemical vapor deposition (CVD) diamond film growth system and a Raman spectroscopy system to study the nucleation and growth of diamond films with atomic resolution using scanning tunneling microscopy (STM). A unique feature of the diamond film growth system is that diamond films can be transferred directly to the ultrahigh vacuum (UHV) chamber of a scanning tunneling microscope without contaminating the films by exposure to air. The University of North Texas (UNT) provided $20,000 this year as matching funds for the NASA grant to purchase the diamond growth system. In addition, UNT provided a Coherent Innova 90S Argon ion laser, a Spex 1404 double spectrometer, and a Newport optical table costing $90,000 to set-up the Raman spectroscopy system. The CVD diamond growth system and Raman spectroscopy system will be used to grow and characterize diamond films with atomic resolution using STM as described in our proposal. One full-time graduate student and one full-time undergraduate student are supported under this grant. In addition, several graduate and undergraduate students were supported during the summer to assist in setting-up the diamond growth and Raman spectroscopy systems. We have obtained research results concerning STM of the structural and electronic properties of CVD grown diamond films, and STM and scanning tunneling spectroscopy of carbon nanotubes. In collaboration with the transmission electron microscopy (TEM) group at UNT, we have also obtained results concerning the optoelectronic material siloxene. These results were published in refereed scientific journals, submitted for publication, and presented as invited and contributed talks at scientific conferences.

Perez, Jose M.↗

Spectral attenuation coefficients from measurements of light transmission in bare ice on the Greenland Ice Sheet

Light transmission into bare glacial ice affects surface energy balance, biophotochemistry, and light detection and ranging (lidar) laser elevation measurements but has not previously been reported for the Greenland Ice Sheet. We present measurements of spectral transmittance at 350–900 nm in bare glacial ice collected at a field site in the western Greenland ablation zone (67.15∘ N, 50.02∘ W). Empirical irradiance attenuation coefficients at 350–750 nm are ∼ 0.9–8.0 m−1 for ice at 12–124 cm depth. The absorption minimum is at ∼ 390–397 nm, in agreement with snow transmission measurements in Antarctica and optical mapping of deep ice at the South Pole. From 350–530 nm, our empirical attenuation coefficients are nearly 1 order of magnitude larger than theoretical values for optically pure ice. The estimated absorption coefficient at 400 nm suggests the ice volume contained a light-absorbing particle concentration equivalent to ∼ 1–2 parts per billion (ppb) of black carbon, which is similar to pre-industrial values found in remote polar snow. The equivalent mineral dust concentration is ∼ 300–600 ppb, which is similar to values for Northern Hemisphere warm periods with low aeolian activity inferred from ice cores. For a layer of quasi-granular white ice (weathering crust) extending from the surface to ∼ 10 cm depth, attenuation coefficients are 1.5 to 4 times larger than for deeper bubbly ice. Owing to higher attenuation in this layer of near-surface granular ice, optical penetration depth at 532 nm is 14 cm (20 %) lower than asymptotic attenuation lengths for optically pure bubbly ice. In addition to the traditional concept of light scattering on air bubbles, our results imply that the granular near-surface ice microstructure of weathering crust is an important control on radiative transfer in bare ice on the Greenland Ice Sheet ablation zone, and we provide new values of flux attenuation, absorption, and scattering coefficients to support model development and validation.

IceSat-2↗