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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
DOE OSTI2025

A Business Case Evaluation of Gas Switching Reforming (GSR) Technology: A Promising Technology for Natural Gas Reforming with Integrated CO2 Capture

Hydrogen is essential in the transition to sustainable energy, and developing low-carbon production methods is a key research focus. Traditional steam methane reforming (SMR) dominates the hydrogen industry but contributes substantially to CO2 emissions. In response, Gas Switching Reforming (GSR) has emerged as a novel process that integrates carbon capture and utilizes process heat more efficiently. Unlike other reforming methods, GSR consolidates oxidation and reduction reactions within a single reactor, which minimizes external energy inputs and simplifies scaling. Like conventional steam methane reforming (SMR), GSR can be integrated with water-gas shift and pressure swing adsorption units for pure hydrogen production. This work presents a comprehensive business case analysis of GSR technology based on experimental results in Technology Readiness Level 3, Life Cycle Assessment (LCA) and Techno-Economic (TEA) evaluation incorporating ASPEN Plus process modeling considering different configurations and energy scenarios. The TEA incorporates data from kinetic experiments from various catalysts to evaluate the GSR process under various conditions. The goal of this work is to evaluate GSR’s potential to serve as a low-carbon alternative to SMR, focusing on global warming potential and additional impact categories to evaluate a wide spectrum of environmental impacts. Comparative assessments were conducted with SMR, chemical loop reforming (CLR), and proton exchange membrane (PEM) electrolysis to explore trade-offs across environmental metrics. The environmental impact assessment of this work encompasses the entire hydrogen production lifecycle from raw material extraction to plant decommissioning, using a cradle-to-gate boundary. Preliminary findings highlight that GSR, when integrated with low-carbon energy sources, could significantly reduce environmental impacts, making it a promising candidate for low-carbon hydrogen infrastructure. The insights from this business case evaluation aim to guide industry in scale-up and commercialization of this promising clean energy technology.

03 NATURAL GAS↗
DOE OSTI2026

Photochemically Triggered Para-Hydrogen-Induced Polarization in a Diplatinum Trihydride Complex

Transition metal complexes containing platinum(II) are of substantial interest for their rich photophysics, biomedical applications, and catalytic function. Nuclear magnetic resonance (NMR) spectra of the spin-1/2 isotope, 195Pt, offer detailed insights into the molecular structures of closed-shell Pt(II) complexes, including solvent effects. However, the sensitivity of 195Pt NMR is mediocre, and its NMR spectra are typically complex. As a result, 1H NMR spectra are used as the primary characterization tool for Pt(II)-based molecules, relying on J-coupling to the 195Pt nucleus to provide structural information from the resulting satellite peaks. In efforts to significantly improve the information content from 1H NMR spectroscopy in a Pt(II)-containing molecule, we utilize [Pt2H2(μ-H)(μ-dppm)2]PF6, where dppm is bis(diphenylphosphino)methane, and leverage its established photoactivity with UV light and H2 for para-hydrogen-induced polarization (PHIP) to enhance the resultant NMR signals, revealing numerous 195Pt J-couplings. Moreover, we investigate direct solvent hyperpolarization effects, as well as the indirect effects of solvent on the various observed J-coupling constants in the Pt species, demonstrating correlations with both Lewis basicity and dielectric constant.

Brown, Emily E. [Department of Chemistry; North Ca↗
NASA NTRS1975

Studies of the use of high-temperature nuclear heat from an HTGR for hydrogen production

The results of a study which surveyed various methods of hydrogen production using nuclear and fossil energy are presented. A description of these methods is provided, and efficiencies are calculated for each case. The process designs of systems that utilize the heat from a general atomic high temperature gas cooled reactor with a steam methane reformer and feed the reformer with substitute natural gas manufactured from coal, using reforming temperatures, are presented. The capital costs for these systems and the resultant hydrogen production price for these cases are discussed along with a research and development program.

Peterman, D. D.↗
NASA NTRS1977

Hydrogen fueled subsonic aircraft - A prospective

The performance characteristics of hydrogen-fueled subsonic transport aircraft are compared with those of aircraft using conventional aviation kerosene. Results of the Cryogenically Fueled Aircraft Technology Program sponsored by NASA indicate that liquid hydrogen may be particularly efficient for subsonic transport craft when ranges of 4000 km or more are involved; however, development of advanced cryogenic tanks for liquid hydrogen fuel is required. The NASA-sponsored program also found no major technical obstacles for international airports converting the liquid hydrogen fueling systems. Resource utilization efficiency and fuel production costs for hydrogen produced by coal gasification or for liquid methane or synthetic aviation kerosene are also assessed.

Witcofski, R. D.↗
NASA NTRS1998

Nitrogen Species in the Post-Pinatubo Stratosphere: Model Analysis Utilizing UARS Measurements

We present an analysis of the impact of heterogeneous chemistry on the partitioning of nitrogen species measured by the Upper Atmosphere Research Satellite (UARS) instruments. The UARS measurements utilized include: N2O, HNO3 and ClONO2 (Cryogen Limb Array Etalon Spectrometer (CLAES), version 7), temperature, methane, ozone, H2O, HCl, NO and NO2 (HALogen Occultation Experiment (HALOE), version 18). The analysis is carried out for the data from January 1992 to September 1994 in the 100-1 mbar (approx.17-47 km) altitude range and over 10 degree latitude bins from 70degS to 70degN. Temporal-spatial evolution of aerosol surface area density (SAD) is adopted according to the Stratospheric Aerosol and Gas Experiment (SAGE) 11 data. A diurnal steady-state photochemical box model, constrained by the temperature, ozone, H2O, CH4, aerosol SAD and columns of O2 and O3 above the point of interest, has been used as the main tool to analyze these data. Total inorganic nitrogen (NO(y)) is obtained by three different methods: (1) as a sum of the UARS measured NO, NO2, HNO3, and ClONO2; (2) from the N2O-NO(y) correlation, and (3) from the CH4-NO(y) correlation. To validate our current understanding of stratospheric heterogeneous chemistry for post-Pinatubo conditions, the model-calculated NO(x)/NO(y) ratios and the NO, NO2, and HNO3 profiles are compared to the UARS-derived data. In general, the UARS-constrained box model captures the main features of nitrogen species partitioning in the post-Pinatubo years. However, the model underestimates the NO2 content, particularly, in the 30-7 mbar (approx. 23-32 km) range. Comparisons of the calculated temporal behavior of the partial columns of NO2 and HNO3 and ground based measurements at 45degS and 45degN are also presented. Our analysis indicates that ground-based and HALOE v. 18 measurements of the NO2 vertical columns are consistent within the range of their uncertainties and are systematically higher (up to 50%) than the model results at mid-latitudes in both hemispheres. Reasonable agreement is obtained for HNO3 columns at 45degS suggesting some problems with nitrogen species partitioning in the model. Outstanding uncertainties are discussed.

Danilin, M. Y.↗
NASA NTRS1998

Nitrogen Species in the Post-Pinatubo Stratosphere: Model Analysis Utilizing UARS Measurements

We present an analysis of the impact of heterogeneous chemistry on the partitioning of nitrogen species measured by the Upper Atmosphere Research Satellite (UARS) instruments. The UARS measurements utilized include: N2O, HNO3 and ClONO2 (Cryogen Limb Array Etalon Spectrometer (CLAES), version 7), temperature, methane, ozone, H2O, HCI, NO and NO2 (HALogen Occultation Experiment (HALOE), version 18). The analysis is carried out for the data from January 1992 to September 1994 in the 100-1 mbar (approximately 17-47 km) altitude range and over 10 degree latitude bins from 70 deg S to 70 deg N. Temporal-spatial evolution of aerosol surface area density (SAD) is adopted according to the Stratospheric Aerosol and Gas Experiment (SAGE) II data. A diurnal steady-state photochemical box model, constrained by the temperature, ozone, H2O, CH4, aerosol SAD and columns of O2 and O3 above the point of interest, has been used as the main tool to analyze these data. Total inorganic nitrogen (NOy) is obtained by three different methods: (1) as a sum of the UARS measured NO, NO2, HNO3, and CIONO2; (2) from the N2O-NOy correlation, (3) from the CH4-NOy correlation. To validate our current understanding of stratospheric heterogeneous chemistry for post-Pinatubo conditions, the model-calculated NOx/NOy ratios and the NO, NO2, and HNO3 profiles are compared to the UARS-derived data. In general, the UARS-constrained box model captures the main features of nitrogen species partitioning in the post-Pinatubo years. However, the model underestimates the NO2 content, particularly, in the 30-7 mbar (approximately 23-32 km) range. Comparisons of the calculated temporal behavior of the partial columns of NO2 and HNO3 and ground based measurements at 45 deg S and 45 deg N are also presented. Our analysis indicates that ground-based and HALOE v.18 measurements of the NO2 vertical columns are consistent within the range of their uncertainties and are systematically higher (up to 50%) than the model results at mid-latitudes in both hemispheres. Reasonable agreement is obtained for HNO3 columns at 45 deg S suggesting some problems with nitrogen species partitioning in the model. Outstanding uncertainties are discussed.

Danilin, M. Y.↗
NASA NTRS2015

In-Space Propulsion, Logistics Reduction, and Evaluation of Steam Reformer Kinetics: Problems and Prospects

Human space missions generate waste materials. A 70-kg crewmember creates a waste stream of 1 kg per day, and a four-person crew on a deep space habitat for a 400+ day mission would create over 1600 kg of waste. Converted into methane, the carbon could be used as a fuel for propulsion or power. The NASA Advanced Exploration Systems (AES) Logistics Reduction and Repurposing (LRR) project is investing in space resource utilization with an emphasis on repurposing logistics materials for useful purposes and has selected steam reforming among many different competitive processes as the preferred method for repurposing organic waste into methane. Already demonstrated at the relevant processing rate of 5.4 kg of waste per day, high temperature oxygenated steam consumes waste and produces carbon dioxide, carbon monoxide, and hydrogen which can then be converted into methane catalytically. However, the steam reforming process has not been studied in microgravity. Data are critically needed to understand the mechanisms that allow use of steam reforming in a reduced gravity environment. This paper reviews the relevant literature, identifies gravity-dependent mechanisms within the steam gasification process, and describes an innovative experiment to acquire the crucial kinetic information in a small-scale reactor specifically designed to operate within the requirements of a reduced gravity aircraft flight. The experiment will determine if the steam reformer process is mass-transport limited, and if so, what level of forced convection will be needed to obtain performance comparable to that in 1-g.

Logistics↗
NASA NTRS2017

Testing and Modeling of the Mars Atmospheric Processing Module

Here we report further progress in the development of the MARCO POLO-Mars Pathfinder Atmospheric Processing Module (APM). The APM is designed to demonstrate in situ resource utilization (ISRU) of the Martian atmosphere, which primarily consists of carbon dioxide (CO2). The APM is part of a larger project with the overall goal of collecting and utilizing CO2 found in the atmosphere and water in the regolith of Mars to produce methane and oxygen to be used as rocket propellant, eliminating the need to import those to Mars for human missions, thus significantly reducing costs. The initial focus of NASA's new ISRU Project is modeling of key ISRU components, such as the CO2 Freezers and the Sabatier reactor of the APM. We have designed models of those components and verified the models with the APM by gathering additional data for the Sabatier reactor. Future efforts will be focused on simultaneous operations of the APM and other MARCO POLO-Mars Pathfinder modules.

Mars In Situ Resource Utilizatio↗
NASA NTRS2024

Development of a Surface Water Transportation System for ISRU Operations on Mars

NASA is working to define the architecture needed for a Mars exploration campaign. Initial analysis assumptions allow for pre-deployment of essential cargo and equipment to support a crew landing, including the pre-positioning of a Mars Ascent Vehicle (MAV). This MAV is likely to represent the largest single payload that must be landed on the Mars surface. Its size would be influenced by the amount of mass that state-of-the-art Entry, Descent, and Landing (EDL) systems would be capable of placing on Mars. One possible method of increasing the usable size of the MAV without exceeding available EDL capabilities is to land the MAV without ascent propellant on board. Following such a method may necessitate a strategy to acquire sufficient ascent propellant to allow a crew to safely depart the Martian surface. This paper describes a conceptual return propellant strategy that uses a liquid transportation skid, or pallet, to be used in conjunction with a rover mobility system to transfer water across the Martian surface from a source point to an in-situ resource utilization (ISRU) plant that would use this water as a feedstock to generate oxygen and methane to enable launch of the MAV. Design considerations, concept of operations, and rover energetics will be discussed in this paper.

Fluid Structure Interface↗
NASA NTRSDate not supplied

Assessment of a Surface Water Transportation System for ISRU Operations on Mars

NASA is working to define the architecture needed for a Mars exploration campaign. Initial analysis assumptions allow for pre-deployment of essential cargo and equipment to support a crew landing, including the pre-positioning of a Mars Ascent Vehicle (MAV). This MAV is likely to represent the largest single payload that must be landed on the Mars surface. Its size would be influenced by the amount of mass that state-of-the-art Entry, Descent, and Landing (EDL) systems would be capable of placing on Mars. One possible method of increasing the usable size of the MAV without exceeding available EDL capabilities is to land the MAV without ascent propellant on board. Following such a method may necessitate a strategy to acquire sufficient ascent propellant to allow a crew to safely depart the Martian surface. This paper describes a conceptual return propellant strategy that uses a liquid transportation skid, or pallet, to be used in conjunction with a rover mobility system to transfer water across the Martian surface from a source point to an in-situ resource utilization (ISRU) plant that would use this water as a feedstock to generate oxygen and methane to enable launch of the MAV. Design considerations, concept of operations, and rover energetics will be discussed in this paper.

Fluid Structure Interface↗
DOE OSTI2026

Upgrading Biogas through in situ Conversion of Carbon Dioxide to Biomethane in Anaerobic Digesters

Organic waste streams generated by wastewater treatment plants, agricultural operations, and food processing industries represent an important yet underutilized opportunity for renewable energy production in the United States. Through anaerobic digestion, these waste streams can produce biogas, a mixture primarily composed of methane (CH4) and carbon dioxide (CO2), that can be upgraded to pipeline-quality natural gas. However, most existing upgrading technologies remove CO2 from biogas rather than utilizing it, leaving a significant portion of the potential energy unused. This project investigates a novel biological upgrading approach that converts CO2 into additional CH4 by supplying hydrogen (H2) to specialized microorganisms capable of performing hydrogenotrophic methanation. The main challenges associated with biological biogas upgrading are related to hydrogen supply, gas-liquid mass transfer, and process stability. First, due to the high cost of hydrogen gas, it is preferable that H2 be produced on-site using renewable energy sources such as wind or solar power. Second, hydrogen has low solubility in liquids, which limits its availability to microorganisms and requires strategies to improve gas dissolution and transfer within the reactor. Third, process inhibition may occur as a result of increased pH caused by CO2 consumption or elevated H2 partial pressure, both of which can negatively affect methanogenic activity. Although research in these areas has advanced during the course of this project, these challenges have not yet been fully resolved. To date, the biological systems that have achieved the highest methane concentrations are typically ex-situ reactors, where operational conditions can be more easily controlled. For this reason, the findings of the present project remain highly relevant. The project goal was to develop an innovative system that can accomplish biogas upgrading via biological conversion of CO2 to CH4, in a novel hybrid approach that combines the advantages of both in-situ and ex-situ systems. The proposed system employs a three-phase upflow anaerobic bioreactor with H2 delivery through a gas-permeable membrane, enabling efficient hydrogen transfer and microbial conversion. Under optimized operating conditions, the system achieved 99% H2 consumption and 90% CO2 conversion. A subsequent gas cleaning stage was implemented to further improve gas quality and meet target purity standards. The upgraded gas composition reached 97.7% CH4, 2.2% CO2, and 0.97% O2, while H2S concentrations remained below detection limits. In addition, a flue gas-driven inorganic thermoelectric generator (TEG) system was designed and experimentally validated as a potential source of electricity for H2 production. The system consisted of six TEG modules connected in series and achieved an open-circuit voltage of 4.5 V and a maximum power output of 224 mW at a temperature difference of approximately 53.5 °C, demonstrating effective conversion of waste heat into electrical power under simulated flue gas conditions. Finally, a comprehensive techno-economic analysis was completed to evaluate the capital and operating costs associated with the proposed system. The results provide important insights to guide future scale-up, optimization, and potential deployment of integrated biological biogas upgrading technologies.

09 BIOMASS FUELS↗
NASA NTRS2016

Using Unmanned Air Systems to Monitor Methane in the Atmosphere

Methane is likely to be an important contributor to global warming, and our current knowledge of its sources, distributions, and transport is insufficient. It is estimated that there could be from 7.5 to 400 billion tons carbon-equivalent of methane in the arctic region, a broad range that is indicative of the uncertainty within the Earth Science community. Unmanned Air Systems (UASs) are often used for combat or surveillance by the military, but they also have been used for Earth Science field missions. In this study, we will analyze the utility of the NASA Global Hawk and the Aurora Flight Sciences Orion UASs compared to the manned DC-8 aircraft for conducting a methane monitoring mission. The mission will focus on the measurement of methane along the boundaries of Arctic permafrost thaw and melting glaciers. The use of Long Endurance UAS brings a new range of possibilities including the ability to obtain long- term and persistent observations and to significantly augment methane measurements/retrievals collected by satellite. Furthermore, we discuss the future of long endurance UAS and their potential for science applications in the next twenty to twenty-five years.

Clow, Jacqueline↗
NASA NTRSDate not supplied

Impact of Trace CH 4 on Shock Layer Radiation in Outer Planet Entry

This paper reports experimental characterization of shock layer radiation from H 2 /He mixtures with a small amount of methane (CH 4 ) addition in the Electric Arc Shock Tube at NASA Ames Research Center. The work follows on a previous test series for entry probes to Saturn and Uranus, which quantified the expected radiance in the absence of methane. However, the Saturn stratosphere is estimated to have approximately 0.4% of CH 4 . The current test series utilized mixtures of 0.886/0.110/0.004 H 2 /He/CH 4 (by mole.) Freestream pressures included 0.1 and 0.5 Torr and velocities from 15-26 km/s. Data compares favorably to similar conditions collected in the Oxford T6 facility. Additional radiation features attributable to CH and C 2 Swan bands are observed, albeit at low intensities. Comparisons to data collected in previous EAST tests suggest that the CH 4 does not significantly alter reaction kinetics below 26 km/s.

Radiation↗
NASA NTRS1980

A New Image for the Water Hyacinth

Walt Disney Company activated a sewage treatment plan using NASA technology to create water hyacinths to clean wastewater by absorbing and metabolizing pollutants. Plants have exciting promise as a natural water purification system which can be established at a fraction of the cost of a conventional sewage treatment facility. Harvested plants can be used as fertilizer. They can also be heat-treated to produce consumer energy in the form of methane gas. If an economical method of drying plants can be developed they may find further utility as high protein animal feed.

Source record↗
NASA NTRSDate not supplied

Unbounded Learning Environments as an Approach to Preserving Design Flexibility Demonstrated With Nasa Stem Enhancement in Earth Science (SEES) Students

The Artemis Lunar program is providing opportunity for young scientists and engineers to contribute towards leading edge design concepts regarding early on-surface work areas that are aligned with major national initiatives. Therefore, it is imperative in any discovery process that those young scientists and engineers be provided the bandwidth or operating in a ‘greenfield’ technology environment that encourages new ideas, and perhaps the discovery of ideas that would not be realized within typical structured engineering constraints. To facilitate this concept, the use of unbounded teaching methods was utilized to provide a low-constraint environment from which students can design and discover the requirements that are bounded by the natural environment of the lunar surface, and then build up design requirements un-hindered by budgetary and/or logistics realizations of the moment funding capabilities. Specifically, this design exercise provided the students to operate with unlimited budgets, and unlimited up-mass lifts to the lunar surface to develop a preliminary feasible process for establishing a working lunar research based upon the near-area permanently shadowed regions within the lunar surface. In concept, working near PSRs will be advantageous as they receive near eternal shielding from solar radiation and may potentially host numerous volatile substances such as water ice, methane, hydrogen sulfide and helium-3 that will be the target of scientific investigation and in-situ resource utilization ISRU. The advantage of an upstream working area is that the quality of return materials could potentially be exponential when including an upstream analysis prior to earth-return missions. Furthermore, it’s well known within the scientific and engineering community that working with the base materials in front of human eyes elucidates new features and observations that may not survive when stored and shipped to Earth. Finally, it is theorized that these methods and techniques developing on the lunar surface would be applicable to other planets or cometary surfaces.

Education↗
NASA NTRS2000

Laser-Induced Fluorescence Measurements and Modeling of Nitric Oxide in Counterflow Diffusion Flames

The feasibility of making quantitative nonintrusive NO concentration ([NO]) measurements in nonpremixed flames has been assessed by obtaining laser-induced fluorescence (LIF) measurements of [NO] in counterflow diffusion flames at atmospheric and higher pressures. Comparisons at atmospheric pressure between laser-saturated fluorescence (LSF) and linear LIF measurements in four diluted ethane-air counterflow diffusion flames with strain rates from 5 to 48/s yielded excellent agreement from fuel-lean to moderately fuel-rich conditions, thus indicating the utility of a model-based quenching correction technique, which was then extended to higher pressures. Quantitative LIF measurements of [NO] in three diluted methane-air counterflow diffusion flames with strain rates from 5 to 35/s were compared with OPPDIF model predictions using the GRI (version 2.11) chemical kinetic mechanism. The comparisons revealed that the GRI mechanism underpredicts prompt-NO by 30-50% at atmospheric pressure. Based on these measurements, a modified reaction rate coefficient for the prompt-NO initiation reaction was proposed which causes the predictions to match experimental data. Temperature measurements using thin filament pyrometry (TFP) in conjunction with a new calibration method utilizing a near-adiabatic H2-air Hencken burner gave very good comparisons with model predictions in these counterflow diffusion flames. Quantitative LIF measurements of [NO] were also obtained in four methane-air counterflow partially-premixed flames with fuel-side equivalence ratios (phi(sub B)) of 1.45, 1.6, 1.8 and 2.0. The measurements were in excellent agreement with model predictions when accounting for radiative heat loss. Spatial separation between regions dominated by the prompt and thermal NO mechanisms was observed in the phi(sub B) = 1.45 flame. The modified rate coefficient proposed earlier for the prompt-NO initiation reaction improved agreement between code predictions and measurements in the region where prompt-NO dominates. Finally, LIF measurements of NO were obtained in counterflow diffusion flames at 2 to 5 atm. Comparisons between [NO] measurements and predictions show that the GRI mechanism underpredicts prompt-NO by a factor of two to three at all pressures. In general, the results indicate a need for refinement of the CH chemistry, especially the pressure-dependent CH formation and destruction reactions.

Ravikrishna, Rayavarapu V.↗
DOE OSTI2026

Life Cycle Analysis of Natural Gas Supply Chain and End Use Applications in the United States

Natural gas (NG) plays a crucial role in current and future energy systems in the United States due to its abundance and affordability. In this study a life cycle analysis of the NG supply chain in the United States was conducted using Argonne's R&D GREET model, examining stages from recovery to distribution using reported field data processed and documented by National Energy Technology Laboratory. Supply chain emissions were evaluated across multiple spatial scales, including national average, overall regional production, region-to-region, and basin-to-region scenarios. The GHG intensity of the U.S. average NG supply chain was estimated at 10.3 kg CO 2 e/MMBtu (lower heating value), with a range across regions from 7.8 kg CO 2 e/MMBtu (Northeast) to 15.1 kg CO 2 e/MMBtu (Pacific). The analysis further assessed how upstream NG emissions influence the life cycle GHG emissions of key end-use applications, including electricity generation (0.044–0.086 kg CO 2 e/kWh from upstream NG in combined cycle facilities), hydrogen production (1.04–2.20 kg CO 2 e/kg H 2 for steam methane reforming [SMR] and 1.06–2.23 kg CO 2 e/kg for autothermal reforming [ATR]), and transit bus operation utilizing compressed natural gas fuel (0.19–0.37 kg CO 2 e/mile) and hydrogen fuel (0.12–0.25 kg CO 2 e/mile for hydrogen produced in SMR and ATR).

compression↗
NASA NTRS1987

Structure, vibrational spectrum, and energetics of the CH5(+) ion - A theoretical investigation

Analytic derivative techniques are utilized to determine molecular geometries, vibration spectra, molecular force field, proton affinity, and energetics of clustering of protonated methane. It is observed that the geometries are gradient optimized, while the harmonic force fields and IR intensities are also determined analytically at the SCF level. It is determined that the frequency of the torsional model for rotation of the H2 about the pseudothreefold axis of the CH3(+) group is extremely low, and the proton affinity of CH4 is calculated as 129.0 kcal/mol.

Komornicki, Andrew↗