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At least 145 records · Page 8
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NASA NTRS2024

San Joaquin Valley Health & Air Quality II: Assessing Urban Heat Island Distribution and its Intersections with Air Quality to Understand Converging Vulnerabilities

The city of Stockton, California, located within the San Joaquin Valley (SJV), is a major hub for agricultural production and has endured the continuous threat to community health from nitrogen dioxide (NO 2 ) and increasing temperatures. The convergence of these issues occurs within historically segregated communities that are disproportionately facing health risks related to heat and air quality. Little Manila Rising (LMR), a social and environmental justice (EJ) advocacy non-profit, partnered with NASA DEVELOP for a second term project to evaluate county wide urban heat islands, sociodemographic vulnerability, landcover classification, and the convergence of these variables. We utilized Landsat 8 Thermal Infrared Sensor (TIRS) and Operational Land Imager (OLI) data to produce a land surface temperature (LST) and Normalized Difference Vegetation Index map. They added Centers for Disease Control (CDC) socioeconomic data from 2020 to identify which communities in Stockton were more susceptible to these environmental factors. Additionally, we used NAIP imagery to create a landcover map differentiating developed infrastructure from tree canopy cover. We discovered that south Stockton, where LMR resides, had the worst convergence of heat, air pollution, low canopy coverage and sociodemographic vulnerability compared to northern and rural parts of the city. This was further substantiated by statistical analysis showing a strong positive relationship between areas of high LST and low vegetation. The results provided LMR with compelling evidence to use in their EJ advocacy, and in their efforts to inform state officials of the discriminatory issues they face.

Urban Heat Islands↗
NASA NTRSDate not supplied

Biomass burning declines lead to large net reductions in NO2 concentrations over north equatorial Africa in spite of growing fossil fuel emissions

Socio-economic development in low and middle-income countries has been accompanied by increased emissions of air pollutants such as nitrogen oxides (NOx: nitrogen dioxide (NO2) + nitric oxide (NO)), which affect human health. In sub-Saharan Africa, fossil fuel combustion has nearly doubled since 2000. At the same time, biomass burning—another important NOx source—has declined in Africa’s northern biomass burning region, attributed to changes in climate and anthropogenic fire management associated with agricultural development. Here we use satellite observations of tropospheric NO2 vertical column densities (VCDs) and burned area to identify NO2 trends and drivers over Africa. Across the northern ecosystems where biomass burning occurs—home to over 350 million people—mean annual tropospheric NO2 VCDs decreased by 4.5% from 2005 through 2017 during the biomass burning season of November through February. Reductions in burned area explained the majority of these change in NO2 VCDs, but there were also weaker relationships between changes in NO2 VCDs and fossil fuel emissions over parts of West Africa, which were stronger during rainy season. Over Africa’s biomass burning regions, NO2 VCDs tended to decrease with increasing population density up to a threshold of approximately 180 people per km2, suggesting that anthropogenic activity causes a net reduction in NO2 emissions across roughly 90% of the continent’s biomass burning regions. In contrast to the widely-held perception that socio-economic development worsens air quality in low and middle-income nations, our results suggest that countries in Africa’s northern biomass burning region are following a different pathway, resulting in regional air quality benefits. However, these benefits may be lost with increasing fossil fuel use.

Biomass burning↗
NASA NTRS2020

Assessment of NO2 Observations During DISCOVER-AQ and KORUS-AQ Field Campaigns

NASA’s Deriving Information on Surface Conditions from Column and Vertically Resolved Observations Relevant to Air Quality (DISCOVER-AQ, conducted in 2011–2014) campaign in the United States and the joint NASA and National Institute of Environmental Research (NIER) Korea–United States Air Quality Study (KORUS-AQ, conducted in 2016) in South Korea were two field study programs that provided comprehensive, integrated data sets of airborne and surface observations of atmospheric constituents, including nitrogen dioxide (NO2), with the goal of improving the interpretation of spaceborne remote sensing data. Various types of NO2 measurements were made, including in situ concentrations and column amounts of NO2 using ground- and aircraft-based instruments, while NO2 column amounts were being derived from the Ozone Monitoring Instrument (OMI) on the Aura satellite. This study takes advantage of these unique datasets by first evaluating in situ data taken from two different instruments on the same aircraft platform, comparing coincidently sampled profile-integrated columns from aircraft spirals with remotely sensed column observations from ground-based Pandora spectrometers, intercomparing column observations from the ground (Pandora), aircraft (in situ vertical spirals), and space (OMI), and evaluating NO2 simulations from coarse Global Modeling Initiative (GMI) and high-resolution regional models. We then use these data to interpret observed discrepancies due to differences in sampling and deficiencies in the data reduction process. Finally, we assess satellite retrieval sensitivity to observed and modeled a priori NO2 profiles. Contemporaneous measurements from two aircraft instruments that likely sample similar air masses generally agree very well but are also found to differ in integrated columns by up to 31.9 %. These show even larger differences with Pandora, reaching up to 53.9 %, potentially due to a combination of strong gradients in NO2 fields that could be missed by aircraft spirals and errors in the Pandora retrievals. OMI NO2 values are about a actor of 2 lower in these highly polluted environments due in part to inaccurate retrieval assumptions (e.g., a priori pro-files) but mostly to OMI’s large footprint (>312 km2).

Nitrogen dioxide↗
NASA NTRSDate not supplied

Verification of TROPOMI NO2 Product Using OMI NO2 algorithm

We evaluated S5P TROPOspheric Monitoring Instrument (TROPOMI) operational nitrogen dioxide (NO2) product by comparing with the NO2 retrievals from Ozone Monitoring Instrument (OMI) onboard NASA’s Aura satellite. We compared spatially matched NO2 vertical column density (VCD) data from OMI and TROPOMI to identify any discrepancies between the two operational products. We also applied OMI Air-Mass Factor (AMF) algorithm to TROPOMI Slant Column Density (SCD) data (v02.03.01) aiming to create long-term merged NO2 Earth Science Data Record (https://disc.gsfc.nasa.gov/datasets/TROPOMI_MINDS_NO2_1.1/summary ). The algorithm (version 4.0) uses new Geometry-dependent Lambertian Equivalent surface Reflectivity (GLER) product available for each TROPOMI pixel. GLER is pre-calculated using the vector linearized discrete ordinate radiative transfer (VLIDORT) model, which uses as input high-resolution bidirectional reflectance distribution function (BRDF) information from NASA's Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) over land and the wind-dependent Cox–Munk wave-facet slope distribution over water, the latter with a contribution from the water-leaving radiance based on MODIS gap-filled in-water chlorophyll-a data. The GLER data, combined with consistently retrieved cloud parameters, provide improved information for the calculation of the scattering weight profiles. Additional AMF improvements result from using high resolution (0.25o latitude x 0.25o longitude) a priori NO2 profile shapes and other auxiliary information from the Global Modeling Initiative (GMI) Replay simulation sampled using S5P orbital simulator. Our TROPOMI_MINDS_NO2 algorithm employs the stratosphere-troposphere separation scheme, de-striping, and surface snow/ice treatment consistently with the latest OMI NO2 re-processing (version 4). We evaluate the TROPOMI_MINDS_NO2 product by comparing with the S5P operational NO2 product as well as with independent NO2 observations from ground-based Pandora and aircraft observations. Our results indicate that the new TROPOMI_MINDS_NO2 retrievals are generally higher than the S5P operational NO2 product over polluted regions and show improved agreement with independent validation data.

TROPOMI↗
NASA NTRS1973

Correlation interferometric measurement of trace species in the atmosphere.

Two correlation interferometers, a breadboard model and an engineering model, have been designed, constructed, and tested for the measurement of selected atmospheric trace species. Test results showed that errors of less than 10% are attainable for atmospheric amounts of carbon monoxide and methane measured at 2.3 microns. Based on these results a program has been undertaken to determine the feasibility of measuring other trace species by correlation interferometry. It shown that in addition to carbon monoxide and methane, carbon dioxide, water vapor, ammonia, nitric oxide, nitrous oxide, nitrogen dioxide, and sulfur dioxide can also be accurately measured with this instrument.

Goldstein, H. W.↗
NASA NTRS1973

The remote measurement of trace atmospheric species by correlation interferometry. I - Carbon monoxide and methane

A correlation interferometer has been developed for the measurement of carbon monoxide and methane at 2.35 micrometers in the troposphere and in the stratosphere. This instrument has been tested in laboratory tests, solar-looking outdoor tests, and downward-looking airplane-based tests. The aircraft tests were flown on a Falcon fanjet provided by The Canada Centre for Remote Sensing over both polluted and unpolluted regions of North America. The results of these various tests are discussed. Based on the results obtained for carbon monoxide and methane, a study was undertaken to investigate the feasibility of measuring other atmospheric trace species by correlation interferometry. Results of the feasibility study for carbon dioxide, water vapor, ammonia, nitrous oxide, nitric oxide, nitrogen dioxide, sulfur dioxide, and several hydrocarbons are presented.

Goldstein, H. W.↗
NASA NTRS1980

Ground cloud air quality effects

The effects of the ground cloud associated with launching of a large rocket on air quality are discussed. The ground cloud consists of the exhaust emitted by the rocket during the first 15 to 25 seconds following ignition and liftoff, together with a large quantity of entrained air, cooling water, dust and other debris. Immediately after formation, the ground cloud rises in the air due to the buoyant effect of its high thermal energy content. Eventually, at an altitude typically between 0.7 and 3 km, the cloud stabilizes and is carried along by the prevailing wind at that altitude. For the use of heavy lift launch vehicles small quantities of nitrogen oxides, primarily nitric oxide and nitrogen dioxide, are expected to be produced from a molecular nitrogen impurity in the fuel or liquid oxygen, or from entrainment and heating of ambient air in the hot rocket exhaust. In addition, possible impurities such as sulfur in the fuel would give rise to a corresponding amount of oxidation products such as sulfur dioxide.

Brubaker, K. L.↗
NASA NTRS1999

Mesospheric Odd Nitrogen Enhancements During Relativistic Electron Precipitation Events

The behavior of mesospheric odd nitrogen species during and following relativistic and diffuse auroral precipitation events is simulated, Below 75 km nitric oxide is enhanced in proportion to the ion pair production function associated with the electron precipitation and the length of the event. Nitrogen dioxide and nitric acid are also enhanced. At 65 km the percentage of odd nitrogen for N is 0.1%, HNO3 is 1.6%, NO2 is 15%, and NO is 83.3%. Between 75 and 85 km NO is depleted during particle events due to the faster destruction of NO by N relative to the production of NO by N reacting with O2. Recovery of NO depends on transport from the lower thermosphere, where NO is produced in abundant amounts during particle events.

Aikin, A. C.↗
NASA NTRS1979

Reaction between nitric oxide and ozone in solid nitrogen

Nitrogen dioxide, NO2, is produced when nitric oxide, NO, and ozone, O3, are suspended in a nitrogen matrix at 11-20 K. The NO2 is formed with first-order kinetics, a 12 K rate constant of (1.4 + or - 0.2) x 0.00001/sec, and an apparent activation energy of 106 + or - 10 cal/mol. Isotopic labeling, variation of concentrations, and cold shield experiments show that the growth of NO2 is due to reaction between ozone molecules and NO monomers, and that the reaction is neither infrared-induced nor does it seem to be a heavy atom tunneling process. Reaction is attributed to nearest-neighbor NO.O3 pairs probably held in a specific orientational relationship that affects the kinetic behavior. When the temperature is raised, more such reactive pairs are generated, presumably by local diffusion. Possible mechanisms are discussed.

Lucas, D.↗
NASA NTRS2004

Space-Based Diagnosis of Surface Ozone Sensitivity to Anthropogenic Emissions

We present a novel capability in satellite remote sensing with implications for air pollution control strategy. We show that the ratio of formaldehyde columns to tropospheric nitrogen dioxide columns is an indicator of the relative sensitivity of surface ozone to emissions of nitrogen oxides (NO(x) = NO + NO2) and volatile organic compounds (VOCs). The diagnosis from these space-based observations is highly consistent with current understanding of surface ozone chemistry based on in situ observations. The satellite-derived ratios indicate that surface ozone is more sensitive to emissions of NO(x) than of VOCs throughout most continental regions of the Northern Hemisphere during summer. Exceptions include Los Angeles and industrial areas of Germany. A seasonal transition occurs in the fall when surface ozone becomes less sensitive to NOx and more sensitive to VOCs.

Martin, Randall V.↗
NASA NTRS2013

The Observed Response of Ozone Monitoring Instrument (OMI) NO2 Columns to NOx Emission Controls on Power Plants in the United States: 2005-2011

We show that Aura Ozone Monitoring Instrument (OMI) nitrogen dioxide (NO2) tropospheric column data may be used to assess changes of the emissions of nitrogen oxides (NOx) from power plants in the United States, though careful interpretation of the data is necessary. There is a clear response for OMI NO2 data to NOx emission reductions from power plants associated with the implementation of mandated emission control devices (ECDs) over the OMI record (2005e2011). This response is scalar for all intents and purposes, whether the reduction is rapid or incremental over several years. However, it is variable among the power plants, even for those with the greatest absolute decrease in emissions. We document the primary causes of this variability, presenting case examples for specific power plants.

remote sensing↗
NASA NTRS1997

A Summary of Ambient Air at John F. Kennedy Space Center with a Comparison to Data from the Florida Statewide Monitoring Network (1983-1992)

The EPA criteria air pollutants were monitored at Kennedy Space Center (KSC) since 1983 to comply the prevention of significant deterioration requirements under the Clean Air Act amendments passed by Congress in 1977 and 1990. Monitoring results show that monthly maximum 24-hour total suspended particulates decreased from 144.6 micograms/cu m in 1988 to 73.0 micrograms/cu m in 1991 and increased to 149.3 micrograms/cu m in 1992. Inhalable particulates increased from 56.1 gg/M3 in 1983 to 131.4 micrograms/cu m in 1988, and then decreased to 38.5 micrograms/cu m in 1992. Sulfur dioxide monthly maximum 24-hour average concentrations decreased each year from 135.2 micrograms/cu m in 1983 to 33.8 micrograms/cu m in 1992. Nitrogen dioxide concentrations increased from 5.1 micrograms/cu m in 1983 to 5.9 micrograms/cu m in 1988, then decreased to 4.5 micrograms/cu m in 1992. Carbon monoxide annual average concentrations decreased from 6.2 micrograms/cu m in 1983 to 1.1 micrograms/cu m in 1988, and increased to 1.2 micrograms/cu m in 1992. Ozone maximum 1-hour concentrations increased from 98 parts per billion (ppb) in 1983 to 134 ppb in 1989, and then decreased to 80 ppb in 1992. Total annual rainfall ranged from 37.47 inches to 57.47 inches and shows a 6.6 percent increase over this same ten year period.

Drese, John H.↗
NASA NTRS2006

Evaluation of Space-Based Constraints on Global Nitrogen Oxide Emissions with Regional Aircraft Measurements over and Downwind of Eastern North America

We retrieve tropospheric nitrogen dioxide (NO 2) columns for May 2004 to April 2005 from the SCIAMACHY satellite instrument to derive top-down emissions of nitrogen oxides (NO(x) = NO + NO2) via inverse modeling with a global chemical transport model (GEOS-Chem). Simulated NO 2 vertical profiles used in the retrieval are evaluated with airborne measurements over and downwind of North America (ICARTT); a northern midlatitude lightning source of 1.6 Tg N/yr minimizes bias in the retrieval. Retrieved NO2 columns are validated (r2 = 0.60, slope = 0.82) with coincident airborne in situ measurements. The top-down emissions are combined with a priori information from a bottom-up emission inventory with error weighting to achieve an improved a posteriori estimate of the global distribution of surface NOx emissions. Our a posteriori NOx emission inventory for land surface NOx emissions (46.1 Tg N/yr) is 22% larger than the GEIA-based a priori bottom-up inventory for 1998, a difference that reflects rising anthropogenic emissions, especially from East Asia A posteriori NOx emissions for East Asia (9.8 Tg N/yr) exceed those from other continents. The a posteriori inventory improves the GEOS-Chem simulation of NOx, peroxyacetylnitrate, and nitric acid with respect to airborne in situ measurements over and downwind of New York City. The a posteriori is 7% larger than the EDGAR 3.2FT2000 global inventory, 3% larger than the NEI99 inventory for the United States, and 68% larger than a regional inventory for 2000 for eastern Asia. SCIAMACHY NO2 columns over the North Atlantic show a weak plume from lightning NO(x).

Martin, Randall V.↗
NASA NTRS1973

Metabolic analyzer

An apparatus is described for the measurement of metabolic rate and breathing dynamics in which inhaled and exhaled breath are sensed by sealed, piston-displacement type spirometers. These spirometers electrically measure the volume of inhaled and exhaled breath. A mass spectrometer analyzes simultaneously for oxygen, carbon dioxide, nitrogen, and water vapor. Circuits responsive to the outputs of the spirometers, mass spectrometer, temperature, pressure, and timing signals compute oxygen consumption, carbon dioxide production, minute volume, and respiratory exchange ratio. A selective indicator provides for readout of these data at predetermined cyclic intervals.

Perry, C. L.↗