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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 145 records · Page 8
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NASA NTRS2003

The Stable Isotope Fractionation of Abiotic Reactions: A Benchmark in the Detection of Life

One very important tool in the analysis of biogenic, and potentially biogenic, samples is the study of their stable isotope distributions. The isotope distribution of a sample depends on the process(es) that created it. One important application of the analysis of C & N stable isotope ratios has been in the determination of whether organic matter in a sample is of biological origin or was produced abiotically. For example, the delta C-13 of organic material found embedded in phosphate grains was cited as a critical part of the evidence for life in 3.8 billion year old samples. The importance of such analysis in establishing biogenicity was highlighted again by the role this issue played in the recent debate over the validity of what had been accepted as the Earth s earliest microfossils. These kinds of analysis imply a comparison with the fractionation that one would have seen if the organic material had been produced by alternative, abiotic, pathways. Could abiotic reactions account for the same level of fractionation? Additionally, since the fractionation can vary between different abiotic reactions, understanding their fractionations can be important in distinguishing what reactions may have been significant in the formation of different abiological samples (such as extraterrestrial samples). There is however, a scarcity of data on the fractionation of carbon and nitrogen by abiotic reactions. In order to interpret properly what the stable isotope ratios of samples tell us about their biotic or abiotic nature, more needs to be known about how abiotic reactions fractionate C and N. Carbon isotope fractionations have been studied for a few abiotic processes. These studies presumed the presence of a reducing atmosphere, focusing on reactions involving spark discharge, W photolysis of reducing gas mixtures, and cyanide polymerization in the presence of ammonia. They did find that the initial products showed a depletion in I3C with values in the range of a few per mil to as low as -60 % (potentially comparable to that which accompanies the biosynthesis of organic matter). We need to understand what kind of fractionations are observed with reactions under the non-reducing or mildly reducing conditions now thought to be present on the early Earth. While nitrogen is receiving increased attention as a tool for these kinds of analyses, almost nothing is known about the isotope fractionation that one would expect for abiotic sources of fixed/reduced nitrogen. This project will measure the fixation from a series of abiotic reactions that may have been present on the early Earth (and other terrestrial planets) and produced organic material that could have ended up in the rock record. The work will look at a number of reactions, under a non- reducing, or mildly reducing, atmosphere, covering sources of prebiotic organic C & N from shock heating, to photochemistry, to hydrothermal reactions. Some reactions that we plan to study are; Shock heating of a non-reducing atmosphere to produce CO and NO (in collaboration with Chris McKay), formation of formaldehyde (and related compounds) from COY the formation of ammonia from nitrogen oxides (ultimately from NO) by ferrous iron reduction, and the hydrothermal synthesis of compounds including the hydrocarboxylation/hydrocarbonylation reaction (in collaboration with George Cody), reactions of oxalate to form hydrocarbons and other oxygenated compounds and the formation of lipids from oxalic/formic acid (in collaboration with Tom McCollom), and reactions of carbon monoxide & carbon dioxide with N2, ammonia or nitritehitrate to form hydrogen cyanide, nitriles, ammonia/amines and nitrous

Summers, David P.↗
NASA NTRS1986

Detections of C-13-substituted C3H2 in astronomical sources

The more abundant C-13-substituted variant of the new interstellar ring molecule, C3H2, has been detected in TMC-1 and Sgr B2, and a tentative detection has been made in IRC + 10216. The fractional abundance relative to H2 is 1-2 x 10 to the -8th in TMC-1, a value similar to that of HCN. In Sgr B2, the C-12 species shows a self-absorbed profile and the relative abundance of C3H2 is about an order of magnitude less than in TMC-1. In IRC + 10216, the fractional abundance of C3H2 is an order of magnitude greater than that in TMC-1.

Madden, Suzanne C.↗
NASA NTRS1978

Turbulence in planetary occultations. II - Effects on atmospheric profiles derived from Doppler measurements. III - Effects on atmospheric profiles derived from intensity measurements

The nature and magnitude of turbulence-induced errors in atmospheric profiles derived from Doppler measurements made during radio occultations are investigated. It is found that turbulence in planetary atmospheres induces both fluctuating and systematic errors in derived profiles, but the errors of both types are very small. Consideration of the occultation of Mariner 10 by Venus and of the Pioneer occultations by Jupiter shows that the rms fractional errors in the atmospheric profiles derived from these observations were less than 0.01 in both temperature and pressure, while the fractional systematic errors were typically of the order of 1 millionth. The extent to which atmospheric profiles derived from radio and optical intensity measurements are affected by turbulence is also examined. The results indicate that turbulence in planetary atmospheres has only a marginal effect on derived profiles in the weak-scattering limit and that the turbulence-induced errors in this case are always much larger than the corresponding errors in profiles derived from radio Doppler measurements.

Haugstad, B. S.↗
NASA NTRS1981

Preacceleration in collapsing magnetic neutral sheets and anomalous abundances of solar flare particles

Levine's (1974) concept of a collapsing magnetic neutral sheet which can accelerate ambient protons to several times the mean thermal speed, provided that the collapse time scale is shorter than the proton Coulomb loss time, is applied to heavier elements in an investigation of the composition of the particles which can be accelerated by such a sheet. Tables of ionization equilibrium are combined with the thermal structure of a constant pressure loop in order to calculate phi sub x (the fraction of an element x which is accelerated) of 18 heavy elements, from carbon to nickel which satisfy a maximum-ionization criterion. Normalizing phi sub x to oxygen, it is found that relative to the composition of the ambient materials, C and N can be depleted by factors of up to 2-10, while other heavy elements, along with hydrogen, are enhanced. The numerical results obtained are qualitatively similar to anomalous abundances reported among solar flare particles.

Mullan, D. J.↗
NASA NTRS1983

Enstatite chondrites - Trace element clues to their origin

Three EH and three EL chondrites have been subjected to RNAA analysis for 20 trace elements, and interelement correlations were examined in order to assess the effects of nebular fractionation and metamorphism. The refractory siderophiles Ir, Os, and Re correlate with the normal siderophiles Ni, Pd, Au, Sb, and Ge, in ELs but not in EHs. The two element groups presumably condensed on separate phases at first, but concentrated in metal during metabolism. Volatiles are consistently more depleted in ELs than EHs. Strong correlations are found for In-Tl, Tl-Bi, and Zn-Cd-In, which are equally consistent with predicted condensation curves for the solar nebula and with volatilization curves for artificially heated Abee. The three factors accounting for 93 percent of variance reflect volatile, siderophile, and chalcophile behavior.

Hertogen, J.↗
NASA NTRS1992

Variable frequency pulsed phase-locked loop method for measuring material nonlinearity

The design of a pressure vessel with an isothermal volume to measure changes in the natural velocities of material continuously over a wide temperature range is reported. Highly sensitive pulsed phase-locked loop technology is used to measure the natural velocity of fatigued aluminum 2024-T4 as a function of pressure at different temperatures. Second derivative variations with respect to pressure and temperature are found to exhibit order-of-magnitude changes at a gauge pressure near 950 kPa at room temperature. This indicates a significant change in certain combinations of second-order and higher-order elastic constants at relatively low pressures. Fractional frequency change as a function of applied pressure for aluminum 2024-T4 with fatigue damage is illustrated.

Yost, William T.↗
NASA NTRS1993

Radiative temperature measurements at Kupaianaha lava lake, Kilauea Volcano, Hawaii

The radiative temperature of the surface of Kupaianaha lava lake is computed using field spectroradiometer data. Observations were made during periods of active overturning. The lake surface exhibits three stages of activity. Magma fountaining and overturning events characterize stage 1, which exhibits the hottest crustal temperatures and the largest fractional hot areas. Rifting events between plates of crust mark stage 2; crustal temperatures in this stage are between 100 C and 340 C, and fractional hot areas are at least an order of magnitude smaller than those in stage 1. Stage 3 is characterized by quiescent periods when the lake is covered by a thick crust. This stage dominates the activity of the lake more than 90 percent of the time. The results of this study are relevant for satellite and airborne measurement of the thermal characteristics of active volcanoes, and indicate that the thermal output of a lava lake varies on a time scale of seconds to minutes.

Flynn, Luke P.↗
NASA NTRS1994

The End of Comet Shoemaker-Levy 9

The pieces of the former Comet Shoemaker-Levy 9 struck Jupiter during the week of July 16-22 1994. We divide the general impact phenomena into four phases: (1) Atmospheric entry should have been accompanied by an entry flash, probably only detectable by the Galileo spacecraft. (2) Aerodynamic forces cause the impactor to explode. We show that the apparent altitude of the explosions is consistent with the analytical model proposed by Zahnle and Chyba et al, with numerical models calculated by Mac Low and Zahnle and Yabe et al., and with dynamically-based estimates of fragment masses Suggested by Scotti and Melosh and Asphaug and Benz. (3) The explosion produces a fireball that propagates most quickly up the wake, as predicted by Takata et al. and Crawford et al. The fireball's luminosity fades over a timescale of 30-60 seconds. (4) Each explosion produced a plume that reached thousands of kilometers above the cloud-tops. The plumes appear to have been dusty and SO illuminated when they reached sunlight. The plumes rose and fell over a period of ten or twenty minutes, governed by the simple laws of ballistics. When plume material (dust) fell back on the atmosphere it was reheated and glowed brightly in the thermal infrared for a period of order ten to twenty minutes; a large fraction of the impact energy was spent thus. Geometry introduces additional factors that complicate interpretation of the observed light curves.

Zahnle, K. J.↗
NASA NTRS2007

Uncertainty Analysis of Historical Hurricane Data

An analysis of variance (ANOVA) study was conducted for historical hurricane data dating back to 1851 that was obtained from the U. S. Department of Commerce National Oceanic and Atmospheric Administration (NOAA). The data set was chosen because it is a large, publicly available collection of information, exhibiting great variability which has made the forecasting of future states, from current and previous states, difficult. The availability of substantial, high-fidelity validation data, however, made for an excellent uncertainty assessment study. Several factors (independent variables) were identified from the data set, which could potentially influence the track and intensity of the storms. The values of these factors, along with the values of responses of interest (dependent variables) were extracted from the data base, and provided to a commercial software package for processing via the ANOVA technique. The primary goal of the study was to document the ANOVA modeling uncertainty and predictive errors in making predictions about hurricane location and intensity 24 to 120 hours beyond known conditions, as reported by the data set. A secondary goal was to expose the ANOVA technique to a broader community within NASA. The independent factors considered to have an influence on the hurricane track included the current and starting longitudes and latitudes (measured in degrees), and current and starting maximum sustained wind speeds (measured in knots), and the storm starting date, its current duration from its first appearance, and the current year fraction of each reading, all measured in years. The year fraction and starting date were included in order to attempt to account for long duration cyclic behaviors, such as seasonal weather patterns, and years in which the sea or atmosphere were unusually warm or cold. The effect of short duration weather patterns and ocean conditions could not be examined with the current data set. The responses analyzed were the storm latitude, longitude and intensity, as recorded in the data set, 24 or 120 hours beyond the current state. Several ANOVA modeling schemes were examined. Two forms of validation were used: 1) comparison with official hurricane prediction performance metrics and 2) cases studies conducted on hurricanes from the 2005 season, which were not included within the model construction and ANOVA assessment. In general, the ANOVA technique did not perform as well as the established official prediction performance metrics published by NOAA; still, the technique did remarkably well in this demonstration with a difficult data set and could probably be made to perform better with more knowledge of hurricane development and dynamics applied to the problem. The technique provides a repeatable prediction process that eliminates the need for judgment in the forecast.

Green, Lawrence L.↗
NASA NTRS2010

An Assessment of Cumulative Axial and Torsional Fatigue in a Cobalt-Base Superalloy

Cumulative fatigue under axial and torsional loading conditions can include both load-order (higMow and low/high) as well as load-type sequence (axial/torsional and torsional/axial) effects. Previously reported experimental studies on a cobalt-base superalloy, Haynes 188 at 538 C, addressed these effects. These studies characterized the cumulative axial and torsional fatigue behavior under high amplitude followed by low amplitude (Kalluri, S. and Bonacuse, P. J., "Cumulative Axial and Torsional Fatigue: An Investigation of Load-Type Sequance Effects," in Multiaxial Fatigue and Deformation: Testing and Prediction, ASTM STP 1387, S. Kalluri, and P. J. Bonacuse, Eds., American Society for Testing and Materials, West Conshohocken, PA, 2000, pp. 281-301) and low amplitude followed by high amplitude (Bonacuse, P. and Kalluri, S. "Sequenced Axial and Torsional Cumulative Fatigue: Low Amplitude Followed by High Amplitude Loading," Biaxial/Multiaxial Fatigue and Fracture, ESIS Publication 31, A. Carpinteri, M. De Freitas, and A. Spagnoli, Eds., Elsevier, New York, 2003, pp. 165-182) conditions. In both studies, experiments with the following four load-type sequences were performed: (a) axial/axial, (b) torsional/torsional, (c) axial/torsional, and (d) torsional/axial. In this paper, the cumulative axial and torsional fatigue data generated in the two previous studies are combined to generate a comprehensive cumulative fatigue database on both the load-order and load-type sequence effects. This comprehensive database is used to examine applicability of the Palmgren-langer-Miner linear damage rule and a nonlinear damage curve approach for Haynes 188 subjected to the load-order and load-type sequencing described above. Summations of life fractions from the experiments are compared to the predictions from both the linear and nonlinear cumulative fatigue damage approaches. The significance of load-order versus load-type sequence effects for axial and torsional loading conditions is discussed. Possible reasons for the observed differences between the computed and observed summations of cycle fractions are rationalized in terms of the observed ever lutions of cyclic axial and shear stress ranges in the cumulative fatigue tests.

Kalluri, Sreeramesh↗
NASA NTRS2001

Dynamics of Aqueous Foam Drops

We develop a model for the nonlinear oscillations of spherical drops composed of aqueous foam. Beginning with a simple mixture law, and utilizing a mass-conserving bubble-in-cell scheme, we obtain a Rayleigh-Plesset-like equation for the dynamics of bubbles in a foam mixture. The dispersion relation for sound waves in a bubbly liquid is then coupled with a normal modes expansion to derive expressions for the frequencies of eigenmodal oscillations. These eigenmodal (breathing plus higher-order shape modes) frequencies are elicited as a function of the void fraction of the foam. A Mathieu-like equation is obtained for the dynamics of the higher-order shape modes and their parametric coupling to the breathing mode. The proposed model is used to explain recently obtained experimental data.

Akhatov, Iskander↗
NASA NTRS1998

Removal of Thin Cirrus Path Radiances in the 0.4-1.0 micron Spectral Region Using the 1.375-micron Strong Water Vapor Absorption Channel

Through analysis of spectral imaging data acquired with the Airborne Visible Infrared Imaging Spectrometer (AVIRIS) from an ER-2 aircraft at 20 km altitude during several field programs, it was found that narrow channels near the center of the strong 1.38-micron water vapor band are very sensitive in detecting thin cirrus clouds. Based on this observation from AVIRIS data, a channel centered at 1.375 microns with a width of 30 nm was selected for the Moderate Resolution Imaging Spectrometer (MODIS) for remote sensing of cirrus clouds from space. The sensitivity of the 1.375-micron MODIS channel to detect thin cirrus clouds during the day time is expected to be one to two orders of magnitude better than the current infrared emission techniques. As a result, a larger fraction of the satellite data will likely be identified as containing cirrus clouds. In order to make better studies of surface reflectance properties, thin cirrus effects must be removed from satellite images. We have developed an empirical approach for removing/correcting thin cirrus effects in the 0.4 - 1.0 micron region using channels near 1.375 microns. This algorithm will be incorporated into the present MODIS atmospheric correction algorithms for ocean color and land applications and will yield improved MODIS atmospheric aerosol, land surface, and ocean color products.

Gao, Bo-Cai↗
NASA NTRSDate not supplied

Flow field Reconstruction for Inhomogeneous Turbulence using Data and Physics Driven Models

A methodology combining Large Eddy Simulation (LES) trained data and a physics driven wave packet model to obtain a reduced order reconstruction for broadband, three-dimensional, temporally stationary but spatially inhomogeneous, incompressible turbulence. Wake turbulence generated by an axisymmetric dragging disk with a turbulent co-flow serves as the benchmark test case. We begin by studying the proper-orthogonal decomposition of the turbulent fluctuations taken from a high-resolution LES to first identify whether the fields demonstrate a low-rank character. It is argued that the presence of the turbulent co-flow results in a largely broadband character lacking any tonal properties. This is especially true for Strouhal numbers greater than 1 and only a small fraction of energy is contained in the leading order Kelvin-Helmholtz modes. As such reconstructions and reduced order modeling purely relying on data from LES does not appear to be a lucrative solution - contrary to problems with strongly tonal character. To supplement the missing energy from a low order truncated mode expansion, we utilize a physics based super-resolution (enrichment) algorithm that relies on spatio-temporally localized Gabor wave packets whose time evolution is described using a set of ordinary differential equations. The reconstructed flow has single- and two-point correlations that are consistent with the reference high resolution simulation data.

SLS↗
NASA NTRS2003

Observations and Simulations on the M-I Coupling of Bursty Convection

This final report summarizes the development and application of the first ever method to measure a proxy of the global merging along the solar wind-Earth separatrix. The ultimate aim of the project is to quantify the reconnection potential in the magnetotail and the fraction of it that is due to bursty bulk flows (BBFs). To achieve this goal, we developed the first method that allows the measurement of the distribution of reconnection rate along the polar cap boundary. The method was then applied to substorms and steady magnetospheric convection (labeled as SMC or convection bay) periods in order to quantify the strength of reconnection and the fraction of it that is contributed by BBFs in each case. Results of this research were reported in two manuscripts submitted to the Journal of Geophysical Research and presented at three international conferences. This report is organized as follows. In Section 2 we discuss the conceptual framework that is the foundation of the method. In Section 3 we describe the details of the method. In Section 4 we describe the application of the technique to substorms and SMCs. In Section 5 we summarize the results of this investigation and provide references to the manuscripts and conference presentations that report on the results of this project.

Sanchez, Ennio R.↗
NASA NTRS1972

Cosmogenic nuclides in football-sized rocks.

The activity of long- and short-lived isotopes in a series of samples from a vertical column through the center of rock 14321 was measured. Rock 14321 is a 9 kg fragmental rock whose orientation was photographically documented on the lunar surface. Also investigated was a sample from the lower portion of rock 14310, where, in order to study target effects, two different density fractions (mineral separates) were analyzed. A few nuclides in a sample from the comprehensive fines 14259 were measured. This material has been collected largely from the top centimeter of the lunar soil. The study of the deep samples of 14321 and 14310 provided values for the activity of isotopes at points where only effects produced by galactic cosmic rays are significant.

Wahlen, M.↗
NASA NTRS1983

Inelastic electron tunneling spectroscopy

Inelastic electron tunneling spectroscopy is a useful technique for the study of vibrational modes of molecules adsorbed on the surface of oxide layers in a metal-insulator-metal tunnel junction. The technique involves studying the effects of adsorbed molecules on the tunneling spectrum of such junctions. The data give useful information about the structure, bonding, and orientation of adsorbed molecules. One of the major advantages of inelastic electron tunneling spectroscopy is its sensitivity. It is capable of detecting on the order of 10 to the 10th molecules (a fraction of a monolayer) on a 1 sq mm junction. It has been successfully used in studies of catalysis, biology, trace impurity detection, and electronic excitations. Because of its high sensitivity, this technique shows great promise in the area of solid-state electronic chemical sensing.

Khanna, S. K.↗
NASA NTRS1986

Interaction of two collisionless shocks

Kinetic simulations of the interaction between two collisionless shocks are presented. During the collision of two perpendicular shocks, the shock electromagnetic field structures pass through each other, while the previously shocked ions are kept separate by the electric field arising in the collision. When two supercritical shocks collide, a fraction of ions are accelerated up to an order of magnitude in energy by first being reflected at one shock, then interacting with the electric fields of the other shock.

Cargill, P. J.↗
NASA NTRS1990

Selection of component modes

Structural dynamic models of complex spacecraft are often assembled from a number of component models. In this paper, three methods for reducing the order of these component models are presented by selecting 'important' fixed interface component modes. These methods are applied to two component structures of the Space Station Freedom: a photovoltaic (PV) array and a solar dynamic collector. The reduced order models of these components retain a small fraction of the number of modes in the original models while accurately representing a set of outputs chosen by the user.

Blelloch, Paul A.↗