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At least 145 records · Page 8

Comparison of gamma-gamma Phase Coarsening Responses of Three Powder Metal Disk Superalloys

The phase microstructures of several powder metal (PM) disk superalloys were quantitatively evaluated. Contents, chemistries, and lattice parameters of gamma and gamma strengthening phase were determined for conventionally heat treated Alloy 10, LSHR, and ME3 superalloys, after electrolytic phase extractions. Several of long term heat treatments were then performed, to allow quantification of the precipitation, content, and size distribution of gamma at a long time interval to approximate equilibrium conditions. Additional coarsening heat treatments were performed at multiple temperatures and shorter time intervals, to allow quantification of the precipitation, contents and size distributions of gamma at conditions diverging from equilibrium. Modest differences in gamma and gamma lattice parameters and their mismatch were observed among the alloys, which varied with heat treatment. Yet, gamma coarsening rates were very similar for all three alloys in the heat treatment conditions examined. Alloy 10 had higher gamma dissolution and formation temperatures than LSHR and ME3, but a lower lattice mismatch, which was slightly positive for all three alloys at room temperature. The gamma precipitates of Alloy 10 appeared to remain coherent at higher temperatures than for LSHR and ME3. Higher coarsening rates were observed for gamma precipitates residing along grain boundaries than for those within grains in all three alloys, during slow-moderate quenching from supersolvus solution heat treatments, and during aging at temperatures of 843 C and higher.

Superalloys↗

Changing Circulation Structure and Precipitation Characteristics in Asian Monsoon Regions: Greenhouse Warming vs. Aerosol Effects

Using model outputs from CMIP5 historical integrations, we have investigated the relative roles of anthropogenic emissions of greenhouse gases (GHG) and aerosols in changing the characteristics of the large-scale circulation and rainfall in Asian summer monsoon (ASM) regions. Under GHG warming, a strong positive trend in low-level moist static energy (MSE) is found over ASM regions, associated with increasing large-scale land-sea thermal contrast from 1870's to present. During the same period, a mid tropospheric convective barrier (MCB) due to widespread reduction in relative humidity in the mid- and lower troposphere is strengthening over the ASM regions, in conjunction with expanding areas of anomalous subsidence associated with the Deep Tropical Squeeze (DTS) [Lau and Kim, 2015]. The opposing effects of MSE and MCB lead to enhanced total ASM rainfall, but only a partial strengthening of the southern portion of the monsoon meridional circulation, coupled to anomalous multi-cellar overturning motions over ASM land. Including anthropogenic aerosol emissions strongly masks MSE but enhances MCB via increased stability in the lower troposphere, resulting in an overall weakened ASM circulation with suppressed rainfall. Rainfall characteristics analyses indicate that under GHG, overall precipitation efficiency over the ASM region is reduced, manifesting in less moderate but more extreme heavy rain events. Under combined effects of GHG and aerosols, precipitation efficiency is unchanged, with more moderate, but less extreme rainfall.

Asian monsoon↗

The resistance of selected high strength alloys to embrittlement by a hydrogen environment

Selected high strength iron base and cobalt base alloys with yield strengths in the range from 1233 to 2129 MN per sq m (179 to 309 KSI) were resistant to degradation of mechanical properties in a one atmosphere hydrogen environment at ambient temperature. These alloys were strengthened initially by cold working which produced strain induced epsilon prime-hcp martensite and fcc mechanical twins in an fcc matrix. Heat treatment of the cobalt base alloy after cold working produced carbide precipitates with retention of an hcp epsilon phase which increased the yield strength level to a maximum of 2129 MN per sq m (309 KSI). High-strength alloys can be produced which have some resistance to degradation of mechanical properties by a hydrogen environment under certain conditions.

Benson, R. B., Jr.↗

Ab-Initio Study of Stacking Fault Segregation Behavior in Ni-based Superalloys at High Temperatures

Ni-based superalloys demonstrate extraordinary creep properties compared to traditional metallic systems due to the formation of L12 (γ’) precipitates. Despite experimental evidence of alloying element segregation to the stacking faults, prior ab-initio efforts indicated repulsion of Nb from superlattice intrinsic stacking faults (SISFs) . Due to the importance of this element in key strengthening mechanisms, we developed a new technique to account for multi-component segregation behavior at temperature combining ab-initio molecular dynamics (AIMD) and Monte-Carlo (MC) simulations. Using this technique, we replicated experimentally observed segregation behavior of Nb, Co, and Ti to the SISF in L12 (Figure 1). Furthermore, we investigated the co-segregation behaviors of individual pairs of alloying elements to determine the interaction effects which lead to this segregation behavior in the full alloy system. By simulating the reduced-chemistry models using our approach, we reconciled previous ab-initio calculations demonstrating repulsion of Nb from the SISF and the experimentally observed segregation behavior.

Molecular Dynamics↗

Measurements and mechanisms of localized aqueous corrosion in aluminum-lithium-copper alloys

Summary information is included for electrochemical aspects of stress corrosion cracking in alloy 2090 and an introduction to the work to be initiated on the new X2095 (Weldalite) alloy system. Stress corrosion cracking (SCC) was studied in both S-T and L-T orientations in alloy 2090. A constant load TTF test was performed in several environments with a potentiostatically applied potential. In the same environments the electrochemical behavior of phases found along subgrain boundaries was assessed. It was found that rapid failure due to SCC occurred when the following criteria was met: E(sub BR,T1) is less than E(sub applied) is less than E(sub Br, matrix phase). Although the L-T orientation is usually considered more resistant to SCC, failures in this orientation occurred when the stated criteria was met. This may be due to the relatively isotropic geometry of the subgrains which measure approximately 12 to 25 microns in diameters. Initial studies of alloy X2095 includes electrochemical characterization of three compositional variations each at three temperatures. The role of T(sub 1) dissolution in SCC behavior is addressed using techniques similar to those used in the research of 2090 described. SCC susceptibility is also studied using alternate immersion facilities at Reynolds Metals Corporation. Pitting is investigated in terms of stability, role of precipitate phases and constituent particles, and as initiation sites for SCC. In all research endeavors, attempts are made to link electrochemistry to microstructure. Previous work on 2090 provides a convenient basis for comparison since both alloys contain T(sub 1) precipitates but with different distributions. In 2090 T(sub 1) forms preferentially on subgrain boundaries whereas in X2095 the microstructure appears to be more homogeneous with finer T(sub 1) particles. Another point for comparison is the delta prime strengthening phase found in 2090 but absent in X2095.

Wall, Douglas↗

A Numerical Study of Hurricane Erin (2001): Model Verification and Storm Evolution - Part 1

The Pennsylvania State University-National Center for Atmospheric Research mesoscale model MM5 is used to simulate Hurricane Erin (2001) at high resolution (4-km spacing) from its early development as a tropical depression on 7 September 2001, through a period of rapid intensification into a strong hurricane (8-9 September), and finally into a stage during which it maintains its intensity on 10 September. These three stages of development, intensification, and maintenance in the simulation are in good agreement with the observed evolution of Erin. The simulation shows that during the development and early portions of the intensification stages, intensification is favored because the environmental wind shear is weak and the system moves over a warm tongue of water. As Erin intensifies, the wind'shear gradually increases with the approach of an upper-level trough and strengthening of a low-level high pressure system. By 10 September, the wind shear peaks and begins to decrease, the storm moves over slightly cooler waters, and the intensification ends. Important structural changes occur at this time as the outer precipitation shift from the northeastern and eastern sides to the western side of the eye and precipitation begins to surround the entire eye to initiate the development of a secondary wind maximum and an outer eyewall. The simulation is used to investigate the role of vertical wind shear in the changes of the precipitation structure that took place between 9-10 September by examining the effects of both storm-relative flow changes and changes in the shear-induced tilt. Qualitative agreement is found between the divergence pattern and advection of vorticity by the relative flow with convergence (divergence) generally associated with asymmetric inflow (outflow) in the eyewall region. The shift in the outer precipitation is consistent with a shift in the low-level relative inflow from the northeastern to the northwestern side of the storm. The changes in the relative flow are associated with changes in the winds as the hurricane moves relative to the upper tough and the low-level high pressure system. Examination of the shear-induced tilt of the vortex shows that the change in the tilt direction is greater than that of the shear direction as the tilt shifts from a northerly orientation to northwesterly. Consistent with theory for adiabatic vortices, the maximum low-level convergence and upper-level divergence (and the maximum upward motion) occurs in the direction of tilt. Consequently, both mechanisms may play roles in the changes in the precipitation pattern.

Wu, Liquang↗

A Numerical Study of Hurricane Erin (2001): Model Verification and Storm Evolution - Part 1

The fifth-generation Pennsylvania State University National Center for Atmospheric Research (PSU NCAR) Mesoscale Model (MM5) is used to simulate Hurricane Erin (2001) at high resolution (4-km spacing) from its early development as a tropical depression on 7 September 2001, through a period of rapid intensification into a strong hurricane (8 9 September), and finally into a stage during which it maintains its intensity on 10 September. These three stages of formation, intensification, and maintenance in the simulation are in good agreement with the observed evolution of Erin. The simulation shows that during the formation and early portions of the intensification stages, intensification is favored because the environmental wind shear is weak and the system moves over a warm tongue of water. As Erin intensifies, the wind shear gradually increases with the approach of an upper-level trough and strengthening of a low-level high pressure system. By 10 September, the wind shear peaks and begins to decrease, the storm moves over slightly cooler waters, and the intensification ends. Important structural changes occur at this time as the outer precipitation shifts from the northeastern and eastern sides to the western side of the eye. A secondary wind maximum and an outer eyewall begin to develop as precipitation begins to surround the entire eye. The simulation is used to investigate the role of vertical wind shear in the changes of the precipitation structure that took place between 9 and 10 September by examining the effects of changes in storm-relative flow and changes in the shear-induced tilt. Qualitative agreement is found between the divergence pattern and advection of vorticity by the relative flow with convergence (divergence) generally associated with asymmetric inflow (outflow) in the eyewall region. The shift in the outer precipitation is consistent with a shift in the low-level relative inflow from the northeastern to the northwestern side of the storm. The changes in the relative flow are associated with changes in the environmental winds as the hurricane moves relative to the upper trough and the low-level high pressure system. Examination of the shear-induced tilt of the vortex shows that the change in the tilt direction is greater than that of the shear direction as the tilt shifts from a northerly orientation to northwesterly. Consistent with theory for adiabatic vortices, the maximum low-level convergence and upper-level divergence (and the maximum upward motion) occurs in the direction of tilt. Consequently, both mechanisms may play roles in the changes in the precipitation pattern.

Wu, Liguang↗

Atmospheric Circulation Anomalies During Two Persistent North American Droughts: 1932-1939 and 1948-1957

We use an early twentieth century (1908-1958) atmospheric reanalysis, based on assimilation of surface and sea level pressure observations, to contrast atmospheric circulation during two periods of persistent drought in North America: 1932-1939 (the Dust Bowl) and 1948-1957. Primary forcing for both droughts is believed to come from anomalous sea surface temperatures (SSTs): a warm Atlantic and a cool eastern tropical Pacific. For boreal winter (October-March) in the 1950s, a stationary wave pattern originating from the tropical Pacific is present, with positive centers over the north Pacific and north Atlantic ocean basins and a negative center positioned over northwest North America and the tropical/subtropical Pacific. This wave train is largely absent for the 1930s drought; boreal winter height anomalies are organized much more zonally, with positive heights extending across northern North America. For boreal summer (April-September) during the 1930s, a strong upper level ridge is centered over the Great Plains; this feature is absent during the 1950s and appears to be linked to a weakening of the Great Plains low-level jet (GPLLJ). Subsidence anomalies are co-located over the centers of each drought: in the central Great Plains for the 1930s and in a band extending from the southwest to the southeastern United States for the 1950s. The location and intensity of this subsidence during the 1948-1957 drought is a typical response to a cold eastern tropical Pacific, but for 1932-1939 deviates in terms of the expected intensity, location, and spatial extent. Overall, circulation anomalies during the 1950s drought appear consistent with the expected response to the observed SST forcing. This is not the case for the 1930s, implying some other causal factor may be needed to explain the Dust Bowl drought anomalies. In addition to SST forcing, the 1930s were also characterized by massive alterations to the land surface, including regional-scale devegetation from crop failures and intensive wind erosion and dust storms. Incorporation of these land surface factors into a general circulation model greatly improves the simulation of precipitation and subsidence anomalies during this drought, relative to simulations with SST forcing alone. Even with additional forcing from the land surface, however, the model still has difficulty reproducing some of the other circulation anomalies, including weakening of the GPLLJ and strengthening of the upper level ridge during AMJJAS. This may be due to either weaknesses in the model or uncertainties in the boundary condition estimates. Still, analysis of the circulation anomalies supports the conclusion of an earlier paper (Cook et al. in Proc Natl Acad Sci 106:4997, 2009), demonstrating that land degradation factors are consistent with the anomalous nature of the Dust Bowl drought.

Cook, Benjamin↗

Development of ductile high-strength chromium alloys, phase 2

Strength and ductility were evaluated for chromium alloys dispersion hardened with the putative TaC, TaB, CbC, and CbB compounds. TaC and TaB proved to be the most potent strengtheners, but when combined, their effect far outweighed that produced individually. Tests at 1422 K (2100 F) on an alloy containing these two compounds at the combined level of 0.5 m/o revealed a 495 MN/sq m (70 ksi) tensile strength for wrought material, and a 100 hour rupture strength of 208 MN/sq m (30 ksi) when solution annealed and aged to maximize creep resistance. These levels of high temperature strength greatly exceed that reported for any other chromium-base alloy. The ductile-to-brittle transition temperature (DBTT) of the two phase strengthened alloy occurred at approximately 588 K (600 F) when heat treated to optimize creep strength and was not improved by fabrication to produce a wrought and recovered microstructure. The lowest DBTT measured on any of the alloys investigated was 422 K (300 F). Strengthening phases actually formed in Cr-Ta-B and Cr-Cb-B compositions are probable M2CrB2 (M=Ta or Cb) compounds of tetragonal crystal structure. The likely habit relationship between these compounds and chromium is postulated. Cube habit coherency was identified for TaC precipitation in chromium by electron microscopy. In another study, the maximum solubility of carbon in chromium was indicated to lie between 3/4 and 1 a/o and that of boron to be 1/2 a/o.

Filippi, A. M.↗

Immiscible materials and alloys

Only immiscible materials which involve a fluid phase have a potential advantage when considered for space processing. Processing of such systems at low gravity can lead to a material which is very homogeneous and contains a finely dispersed mixture of phases. Materials with such structures may exhibit potentially useful properties for such applications as superconductors, dispersion-strengthened materials, superplastic materials, permanent magnets, etc. These conclusions have resulted from review of past efforts in the field of low-g processing of materials containing a liquid phase miscibility gap and from present efforts dealing with such systems. These studies have concentrated on precipitation of liquid droplets in a host liquid during cooling through the miscibility gap. This effort has been to study the agglomeration of the droplets both experimentally and through computer simulation in order to understand the mechansism involved and to deduce the effect of gravity on the droplet distribution and resulting structure of the solidified material. The agglomeration mechanisms treated in detail are those due to diffusional growth and collision processes caused by Stokes on convection current-induced droplet migration.

Markworth, A. J.↗

Development Of A Novel Discontinuously-Reinforced Aluminum For Space Applications

Discontinuously-reinforced aluminum (DRA) has been used in aerospace structures such as Ventral Fins and Fan Exit Guide Vanes owing to its superior specific stiffness, specific strength, wear resistance, and thermal resistance as compared to the unreinforced aluminum alloys. In order to reduce engine weight, DRA materials are now being considered for space applications. Higher specific strength at ambient and cryogenic temperatures is one of the main requirements in certain rocket applications. The commercial DRA materials use 6xxx and 2xxx precipitation hardened aluminum alloys as matrices which have limited strengths. Therefore, an aluminum alloy which can provide significantly higher ambient and cryogenic strengths is required. In this paper, a novel aluminum alloy based on Al-Sc-X composition with improved ambient and cryogenic temperature strengthening capability is proposed. In addition, this alloy showed promise for improved strength at elevated temperature. The monolithic alloy and the composite with 15 volume percent SiC and B4C particles were processed using a powder metallurgy approach. The influence of processing parameters on the microstructures and mechanical properties of the monolithic and composite materials is discussed. The alloy showed very high strength and moderate ductility. The influence of hydrogen on the properties of monolithic and composite materials is discussed. The thermal stability of these materials is also evaluated. The strength of the material is discussed in terms of solid solution strengthening, Orowan strengthening, and antiphase boundary strengthening models.

Pandey, A. B.↗

Be-Cu precipitation hardening experiment

The following is a laboratory experiment designed to further a student's understanding of materials science. The student performing this experiment should have a knowledge of binary phase diagrams. The objectives of this experiment are as follows: (1) to give the student a hands-on approach to changing materials properties through heat treatment of a specimen; (2) to quantify the amount of strengthening obtained in the specimen; and (3) to encourage the student to speculate about the structural changes that have occurred in the material to cause the changes in strength.

Cowan, Richard L.↗

A10 Convective Systems Observed During TRMM Field Campaigns

The Tropical Rainfall Measuring Mission (TRMM) will have completed three years in orbit at the time of the Fall 2000 AGU meeting. A summary of research highlights will be presented focusing on application of TRMM data to topics ranging from climate analysis, through improving forecasts to microphysical research. Surface rainfall estimates based on different instruments on TRMM currently differ by 20%. The difference is not surprising considering the different type of observations available for the first time with TRMM through both the passive and active microwave sensors. Resolving that difference will strengthen the validity and utility of ocean rainfall estimates and is the topic of ongoing research utilizing various facets of the TRMM validation and field experiment programs. The TRMM rainfall estimates will be intercompared among themselves and with other estimates, including those of the standard, monthly Global Precipitation Climatology Project (GPCP) analysis. The GPCP analysis agrees roughly in magnitude with the passive microwave-based TRMM estimates which is not surprising considering GPCP over-ocean estimates are based on passive microwave observations. A summary of validation of TRMM estimates against raingauge and radar/raingauge analyses will be presented. At finer time scales results of merging TRMM, other passive microwave observations, and geosynchronous estimates into a 3-hour time resolution analysis will be described.

Adler, Robert↗

Ellicott City Disasters II: Enhancing a Statistical Flood Risk Model to Continue Improving Early Warning Systems and Public Safety in Ellicott City, Maryland

As flooding events in the United States grow in frequency and intensity, the use of technological advancements and applied science are increasingly necessary for effective flood monitoring and warning systems. The NASA DEVELOP Ellicott City Disasters II project investigated the use of machine learning for applications in flood risk detection to support the improvement of early warning systems. To strengthen the efforts of the Howard County Office of Emergency Management (OEM) in building a more robust flood monitoring system, the project improved the original statistical flood risk model, FLuME (Flood Learning Model Environment), programmed by the first DEVELOP term. The enhancements incorporated an additional six years of precipitation and soil moisture data from the North American Land Data Assimilation System (NLDAS), modeled using Aqua Advanced Microwave Scanning Radiometer for EOS and Tropical Rainfall Measuring Mission (TRMM) Microwave Imager. These Earth observations were supplemented by stream gauge data from the OEM and the US Geological Survey. The resultant flood risk model FLASH (Flood Learning Environment and Severity Assessment Hub) was trained to evaluate input variables and predict stage height in Ellicott City in real time. The addition of an advanced deep learning framework known as long short-term memory improved the model’s ability to capture relationships between variables. To assess the effectiveness of the new model, FLASH produced a model efficiency metric of 0.99, a significant improvement over the 0.85 value produced by the previous model. The project assisted the OEM in pursuing the integration of open data and NASA Earth observations into a threat matrix capable of informing near real-time decision making.

Disasters↗

Ellicott City Disasters II: Enhancing a Statistical Flood Risk Model to Continue Improving Early Warning Systems and Public Safety in Ellicott City, Maryland

As flooding events in the United States grow in frequency and intensity, the use of technological advancements and applied science are increasingly necessary for effective flood monitoring and warning systems. The NASA DEVELOP Ellicott City Disasters II project investigated the use of machine learning for applications in flood risk detection to support the improvement of early warning systems. To strengthen the efforts of the Howard County Office of Emergency Management (OEM) in building a more robust flood monitoring system, the project improved the original statistical flood risk model, FLuME (Flood Learning Model Environment), programmed by the first DEVELOP term The enhancements incorporated an additional six years of precipitation and soil moisture data from the North American Land Data Assimilation System (NLDAS), modeled using Aqua Advanced Microwave Scanning Radiometer for EOS and Tropical Rainfall Measuring Mission TRMM Microwave Imager. These Earth observations were supplemented by stream gauge data from the OEM and the US Geological Survey. The resultant flood risk model FLASH (Flood Learning Environment and Severity Assessment Hub) was trained to evaluate input variables and predict stage height in Ellicott City in real time. The addition of an advanced deep learning framework known as long short-term memory improved the model’s ability to capture relationships between variables. To assess the effectiveness of the new model, FLASH produced a model efficiency metric of 0.99, a significant improvement over the 0.85 value produced by the previous model. The project assisted the OEM in pursuing the integration of open data and NASA Earth observations into a threat matrix capable of informing near real-time decision making.

Disasters↗

Western Pacific Hydroclimate Linked to Global Climate Variability Over the Past Two Millennia

Interdecadal modes of tropical Pacific ocean-atmosphere circulation have a strong influence on global temperature, yet the extent to which these phenomena influence global climate on multicentury timescales is still poorly known. Here we present a 2,000-year, multiproxy reconstruction of western Pacific hydroclimate from two speleothem records for southeastern Indonesia. The composite record shows pronounced shifts in monsoon rainfall that are antiphased with precipitation records for East Asia and the central-eastern equatorial Pacific. These meridional and zonal patterns are best explained by a poleward expansion of the Australasian Intertropical Convergence Zone and weakening of the Pacific Walker circulation (PWC) between B1000 and 1500 CE Conversely, an equatorward contraction of the Intertropical Convergence Zone and strengthened PWC occurred between B1500 and 1900 CE. Our findings, together with climate model simulations, highlight the likelihood that century-scale variations in tropical Pacific climate modes can significantly modulate radiatively forced shifts in global temperature.

Pacific Ocean↗

Development of advanced high strength tantalum base alloys. Part 1: Screening investigation

Five experimental tantalum alloy compositions containing 13-18% W+Re+Hf solid solution solute additions with dispersed phase strengthening achieved by carbon or nitrogen additions were prepared as 1.4 inch diameter ingot processed to 3/8 inch diameter rod and evaluated. Elevated temperature tensile and creep strength increased monotonically with increasing solute content. Room temperature elongation decreased for 20% to less than 2% as the solute content was increased above 16%. Phase identification indicated that the precipitating phase in the carbide containing alloys was Ta2C.

Buckman, R. W., Jr.↗

Building a Real-Time Flood Prediction Model for Improving Early Warning Systems in Ellicott City, Maryland

As flood events in the United States grow in frequency and intensity, the use of applied remote sensing analyses is increasingly necessary for effective flood monitoring and warning systems. The NASA DEVELOP National Program partnered with the local government of Howard County, Maryland, to investigate the use of machine learning for advanced flood risk detection, and to test the feasibility of integrating this approach into the county’s flood early warning system. To strengthen the efforts of the Howard County Office of Emergency Management (OEM), the project developed a statistical model capable of hindcasting the two severe flash flood events that devastated Ellicott City and transitioned to a ‘Long Short-Term Memory’ based sequence-to-sequence deep learning model with 8-hour forecast capability. The team combined data inputs from public sources including river and precipitation gauges, NASA and NOAA Earth observations, and numerical weather model products using scripts written in the Google Colaboratory Python scripting environment. In addition to designing the deep learning architecture, the team trained and tested the model, and evaluated its performance using Nash-Sutcliffe Efficiency. The final product, the Sequentially Trained Real-time EstimAted Model (STREAM) predicts stage height for the Hudson Branch gauge in Ellicott City using data products available in near real-time, including the High-Resolution Rapid Refresh model’s accumulated precipitation forecasts supplemented by stream gauge data from the OEM and the U.S. Geological Survey. STREAM was incorporated into an online dashboard in a user-friendly interface capable of triggering the alarms that initiate emergency response protocols up to 8 hours in advance of a predicted severe flood event. The project demonstrated the potential for the integration of open data and Earth observations into a flood risk forecasting tool capable of informing near real-time decision making.

NASA DEVELOP↗